Organic Chemistry (6th Edition)
Organic Chemistry (6th Edition)
6th Edition
ISBN: 9781260119107
Author: Janice Gorzynski Smith
Publisher: McGraw Hill Education
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Chapter 24.1, Problem 1P
Interpretation Introduction

(a)

Interpretation: Product of the given coupling reaction is to be predicted.

Concept introduction: Organocuprate reagents (R2CuLi) react with halides of organic compounds, RX to form coupling products. Only one alkyl group of the organocuprate reagent is transferred to form the product, while the other becomes part of reaction’s by-product.

Interpretation Introduction

(b)

Interpretation: Product of the coupling reaction is to be predicted.

Concept introduction: Organocuprate reagents (R2CuLi) react with halides of organic compounds RX to form coupling products.

Only one alkyl group of the organocuprate reagent is transferred to form the product, while the other becomes part of reaction’s by-product.

Interpretation Introduction

(c)

Interpretation: Product of the coupling reaction is to be predicted.

Concept introduction: Organocuprate reagents (R2CuLi) react with halides of organic compounds RX to form coupling products.

Only one alkyl group of the organocuprate reagent is transferred to form the product, while the other becomes part of reaction’s by-product.

Interpretation Introduction

(d)

Interpretation: Product of the coupling reaction is to be predicted.

Concept introduction: Organocuprate reagents (R2CuLi) react with halides of organic compounds RX to form coupling products.

Only one alkyl group of the organocuprate reagent is transferred to form the product, while the other becomes part of reaction’s by-product.

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Order-disorder phenomenaa) do not have conductive properties.b) are cooperative.c) have few industrial implications.
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Chapter 24 Solutions

Organic Chemistry (6th Edition)

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