(a) Interpretation: The stepwise mechanism that illustrates the formation of E is to be drawn. Concept introduction: The treatment of an organic halide with an alkene in the presence of Pd catalyst to form an alkene that is highly substituted with a new C − C bond is known as Heck reaction. Generally, [ Pd ( OAc ) 2 ] in the presence of [ P ( o -tolyl ) 3 ] is utilized as a catalyst. The reaction is carried out in the presence of organic base, like Et 3 N .

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Answer 1

Question

Chapter 24, Problem 46P

Interpretation Introduction

(a)

Interpretation: The stepwise mechanism that illustrates the formation of E is to be drawn.

Concept introduction: The treatment of an organic halide with an alkene in the presence of Pd catalyst to form an alkene that is highly substituted with a new C−C bond is known as Heck reaction. Generally, [Pd(OAc)2] in the presence of [P(o-tolyl)3] is utilized as a catalyst. The reaction is carried out in the presence of organic base, like Et3N.

Interpretation Introduction

(b)

Interpretation: The suggestion made by the formation of E about the stereochemistry of elimination reaction is to be stated.

Concept introduction: The treatment of an organic halide with an alkene in the presence of Pd catalyst to form an alkene that is highly substituted with a new C−C bond is known as Heck reaction. Generally, [Pd(OAc)2] in the presence of [P(o-tolyl)3] is utilized as a catalyst. The reaction is carried out in the presence of organic base, like Et3N.

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Answer 2

Question

Chapter 24, Problem 46P

Interpretation Introduction

(a)

Interpretation: The stepwise mechanism that illustrates the formation of E is to be drawn.

Concept introduction: The treatment of an organic halide with an alkene in the presence of Pd catalyst to form an alkene that is highly substituted with a new C−C bond is known as Heck reaction. Generally, [Pd(OAc)2] in the presence of [P(o-tolyl)3] is utilized as a catalyst. The reaction is carried out in the presence of organic base, like Et3N.

Interpretation Introduction

(b)

Interpretation: The suggestion made by the formation of E about the stereochemistry of elimination reaction is to be stated.

Concept introduction: The treatment of an organic halide with an alkene in the presence of Pd catalyst to form an alkene that is highly substituted with a new C−C bond is known as Heck reaction. Generally, [Pd(OAc)2] in the presence of [P(o-tolyl)3] is utilized as a catalyst. The reaction is carried out in the presence of organic base, like Et3N.

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Answer 3

Question

Chapter 24, Problem 46P

Interpretation Introduction

(a)

Interpretation: The stepwise mechanism that illustrates the formation of E is to be drawn.

Concept introduction: The treatment of an organic halide with an alkene in the presence of Pd catalyst to form an alkene that is highly substituted with a new C−C bond is known as Heck reaction. Generally, [Pd(OAc)2] in the presence of [P(o-tolyl)3] is utilized as a catalyst. The reaction is carried out in the presence of organic base, like Et3N.

Interpretation Introduction

(b)

Interpretation: The suggestion made by the formation of E about the stereochemistry of elimination reaction is to be stated.

Concept introduction: The treatment of an organic halide with an alkene in the presence of Pd catalyst to form an alkene that is highly substituted with a new C−C bond is known as Heck reaction. Generally, [Pd(OAc)2] in the presence of [P(o-tolyl)3] is utilized as a catalyst. The reaction is carried out in the presence of organic base, like Et3N.

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Answer 4

Question

Chapter 24, Problem 46P

Interpretation Introduction

(a)

Interpretation: The stepwise mechanism that illustrates the formation of E is to be drawn.

Concept introduction: The treatment of an organic halide with an alkene in the presence of Pd catalyst to form an alkene that is highly substituted with a new C−C bond is known as Heck reaction. Generally, [Pd(OAc)2] in the presence of [P(o-tolyl)3] is utilized as a catalyst. The reaction is carried out in the presence of organic base, like Et3N.

Interpretation Introduction

(b)

Interpretation: The suggestion made by the formation of E about the stereochemistry of elimination reaction is to be stated.

Concept introduction: The treatment of an organic halide with an alkene in the presence of Pd catalyst to form an alkene that is highly substituted with a new C−C bond is known as Heck reaction. Generally, [Pd(OAc)2] in the presence of [P(o-tolyl)3] is utilized as a catalyst. The reaction is carried out in the presence of organic base, like Et3N.

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Answer 5

Chapter 24, Problem 46P

Interpretation Introduction

(a)

Interpretation: The stepwise mechanism that illustrates the formation of E is to be drawn.

Concept introduction: The treatment of an organic halide with an alkene in the presence of Pd catalyst to form an alkene that is highly substituted with a new C−C bond is known as Heck reaction. Generally, [Pd(OAc)2] in the presence of [P(o-tolyl)3] is utilized as a catalyst. The reaction is carried out in the presence of organic base, like Et3N.

Interpretation Introduction

(b)

Interpretation: The suggestion made by the formation of E about the stereochemistry of elimination reaction is to be stated.

Concept introduction: The treatment of an organic halide with an alkene in the presence of Pd catalyst to form an alkene that is highly substituted with a new C−C bond is known as Heck reaction. Generally, [Pd(OAc)2] in the presence of [P(o-tolyl)3] is utilized as a catalyst. The reaction is carried out in the presence of organic base, like Et3N.

Answer 6

Chapter 24, Problem 46P

Interpretation Introduction

(a)

Interpretation: The stepwise mechanism that illustrates the formation of E is to be drawn.

Concept introduction: The treatment of an organic halide with an alkene in the presence of Pd catalyst to form an alkene that is highly substituted with a new C−C bond is known as Heck reaction. Generally, [Pd(OAc)2] in the presence of [P(o-tolyl)3] is utilized as a catalyst. The reaction is carried out in the presence of organic base, like Et3N.

Answer 7

Chapter 24, Problem 46P

Interpretation Introduction

(a)

Interpretation: The stepwise mechanism that illustrates the formation of E is to be drawn.

Concept introduction: The treatment of an organic halide with an alkene in the presence of Pd catalyst to form an alkene that is highly substituted with a new C−C bond is known as Heck reaction. Generally, [Pd(OAc)2] in the presence of [P(o-tolyl)3] is utilized as a catalyst. The reaction is carried out in the presence of organic base, like Et3N.

Answer 8

Interpretation Introduction

(b)

Interpretation: The suggestion made by the formation of E about the stereochemistry of elimination reaction is to be stated.

Concept introduction: The treatment of an organic halide with an alkene in the presence of Pd catalyst to form an alkene that is highly substituted with a new C−C bond is known as Heck reaction. Generally, [Pd(OAc)2] in the presence of [P(o-tolyl)3] is utilized as a catalyst. The reaction is carried out in the presence of organic base, like Et3N.

Answer 9

Interpretation Introduction

(b)

Interpretation: The suggestion made by the formation of E about the stereochemistry of elimination reaction is to be stated.

Concept introduction: The treatment of an organic halide with an alkene in the presence of Pd catalyst to form an alkene that is highly substituted with a new C−C bond is known as Heck reaction. Generally, [Pd(OAc)2] in the presence of [P(o-tolyl)3] is utilized as a catalyst. The reaction is carried out in the presence of organic base, like Et3N.

Answer 10

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Answer 11

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Answer 12

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Answer 13

Ch. 24.1 - Prob. 1P Ch. 24.1 - Prob. 2P Ch. 24.1 - Prob. 3P Ch. 24.2 - Prob. 4P Ch. 24.2 - Prob. 5P Ch. 24.4 - Problem 26.10 What reagents are needed to convert...Ch. 24.5 - Problem 26.11 What product is formed when each...Ch. 24.5 - Prob. 13P Ch. 24.6 - Problem 26.13 Draw the products formed when each...Ch. 24.6 - Problem 26.14 What products are formed when ...

Solution Summary: The author explains the stepwise mechanism that illustrates the formation of E in Figure 1.

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Chapter 24 Solutions