6th Edition

ISBN: 9781260119107

Author: Janice Gorzynski Smith

Publisher: McGraw Hill Education

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Types of Polymers on the basis of Method of Preparation

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Textbook Question

Chapter 24, Problem 39P

When certain cycloalkenes are used in metathesis reactions, ring-opening

metathesis polymerization(ROMP) occurs to form a high molecular weight polymer, as shown with cyclopentene as the starting material. The reaction is driven to completion by relief of strain in the cycloalkene.

Chapter 24, Problem 39P, When certain cycloalkenes are used in metathesis reactions, ring-opening
metathesis , example 1

What products are formed by ring-opening metathesis polymerization of each alkene?

a. Chapter 24, Problem 39P, When certain cycloalkenes are used in metathesis reactions, ring-opening
metathesis , example 2 b. c.

Definition Definition Chemical process in which one or more monomers combine to produce a very large chain-like molecule called a polymer. The functional groups present on the monomers and their steric effects are responsible for polymerization through a sequence of reactions that vary in complexity. There exists a stable covalent chemical bond between monomers that sets apart polymerization from other processes.

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Chapter 24, Problem 38P

Chapter 24, Problem 40P

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Chapter 24 Solutions

Organic Chemistry (6th Edition)

Ch. 24.1 - Prob. 1P Ch. 24.1 - Prob. 2P Ch. 24.1 - Prob. 3P Ch. 24.2 - Prob. 4P Ch. 24.2 - Prob. 5P Ch. 24.4 - Problem 26.10 What reagents are needed to convert...Ch. 24.5 - Problem 26.11 What product is formed when each...Ch. 24.5 - Prob. 13P Ch. 24.6 - Problem 26.13 Draw the products formed when each...Ch. 24.6 - Problem 26.14 What products are formed when ...

Ch. 24 - 26.19 What product is formed by ring-closing...Ch. 24 - 26.20 Draw the products formed in each...Ch. 24 - What organic halide is needed to convert lithium...Ch. 24 - 26.22 How can you convert ethynylcyclohexane to...Ch. 24 - 26.23 What compound is needed to convert styrene...Ch. 24 - 26.24 What steps are needed to convert to octane...Ch. 24 - Prob. 27P Ch. 24 - 26.27 Draw the products (including stereoisomers)...Ch. 24 - 26.28 Treatment of cyclohexene with and forms...Ch. 24 - Prob. 32P Ch. 24 - 26.30 What starting material is needed to prepare...Ch. 24 - Prob. 37P Ch. 24 - Prob. 38P Ch. 24 - When certain cycloalkenes are used in metathesis...Ch. 24 - 26.34 Draw the products formed in each reaction. ...Ch. 24 - Prob. 41P Ch. 24 - Draw a stepwise mechanism for the following...Ch. 24 - Sulfur ylides, like the phosphorus ylides of...Ch. 24 - Although diazomethane is often not a useful...Ch. 24 - Prob. 46P Ch. 24 - Prob. 47P Ch. 24 - 26.45 Devise a synthesis of each compound from...Ch. 24 - 26.46 Devise a synthesis of each substituted...Ch. 24 - Biaryls, compounds containing two aromatic rings...

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Solution Summary: The author explains that the product formed by the ring-opening metathesis polymerization of given alkene is drawn in Figure 1.

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Chapter 24 Solutions