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Convert each ball-and-stick model to a Fischer projection.
a.
b. 
(a)
Interpretation: The given ball-and-stick model is to be converted into Fischer projection.
Concept introduction: In Fischer projection formula, the horizontal and vertical line represents the bonds that are present above and below the plane, respectively. The verticals bonds are represented as dashed wedge and horizontal bonds as dark wedge.
Answer to Problem 36P
The Fischer projection of given ball and stick model is shown below.
Figure 1
Explanation of Solution
The ball and stick model of given compound is,
Figure 2
Black colored atoms have four bonds. So, these are the carbon atoms. The grey colored balls have one bond. So, these are the hydrogen atoms. The red colored atoms have two bonds. So, these are oxygen atoms. The molecular structure of given compound is,
Figure 3
The conversion of given compound into Fisher projection is as follows:
The structure
Figure 4
Rotate all the bonds around the carbon atom in such way that all staggered form converted into the eclipsed form in structure
Figure 5
The structure
Figure 6
The Fischer projection of given ball and stick model is shown in Figure 1.
(b)
Interpretation: The products of given reaction are to be drawn.
Concept introduction: In Fischer projection formula, the horizontal and vertical line represents the bonds that are present above and below the plane, respectively. The verticals bonds are represented as dashed wedge and horizontal bonds as dark wedge.
Answer to Problem 36P
The Fischer projection of given ball and stick model is shown below.
Figure 7
Explanation of Solution
The ball and stick model of given compound is,
Figure 8
Black colored atoms have four bonds. So, these are the carbon atoms. The grey colored balls have one bond. So, these are the hydrogen atoms. The red colored atoms have two bonds. So, these are oxygen atoms. The molecular structure of given compound is,
Figure 9
The conversion of given compound into Fisher projection is follow:
The structure
Figure 10
Rotate all the bonds around the carbon atom in such way that all staggered form converts into the eclipsed form in structure
Figure 11
The structure
Figure 12
The Fischer projection of given ball and stick model is shown in Figure 7.
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Chapter 26 Solutions
Organic Chemistry (6th Edition)
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Organic Chemistry: A Guided InquiryChemistryISBN:9780618974122Author:Andrei StraumanisPublisher:Cengage Learning