ORGANIC CHEMISTRY W/ALEKS
6th Edition
ISBN: 9781264905430
Author: SMITH
Publisher: MCG CUSTOM
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For each conjugate acid-base pair, identify the first species as an acid or a base and the second species as its conjugate acid or base. In addition, draw Lewis structures for each species, showing all valence electrons and any formal charge.
(a) CH3CH3 CH3CH2-
For the following equilibrium shown below: (a) Predict the products of the acid-base equilibrium. (b) Label the acid, base, conjugate acid, and conjugate base. (c) Estimate the Keq of the reaction.
Benzoic acid (C6H5COOH) and aniline (C6H5NH2) areboth derivatives of benzene. Benzoic acid is an acid withKa = 6.3 x10-5 and aniline is a base with Ka = 4.3 x10-10.
(a) What are the conjugate base of benzoic acid andthe conjugate acid of aniline? (b) Anilinium chloride(C6H5NH3Cl) is a strong electrolyte that dissociates intoanilinium ions (C6H5NH3+) and chloride ions. Which willbe more acidic, a 0.10 M solution of benzoic acid or a 0.10M solution of anilinium chloride? (c) What is the value ofthe equilibrium constant for the following equilibrium?C6H5COOH(aq) + C6H5NH2(aq) ⇌ C6H5COO-(aq) + C6H5NH3+(aq)
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- Summarize the relationship between pKa and base strength by completing the followingsentences: a. For a given base, the higher the pKa of its conjugate acid, the stronger or weaker the base. b. For a given base, the lower the pKa of its conjugate acid, the stronger or weaker the base.arrow_forwardComplete the equation for the reaction between each Lewis acid-base pair. In each equation, label which starting material is the Lewis acid and which is the Lewis base; use curved arrows to show the flow of electrons in each reaction. In doing this problem, it is essential that you show valence electrons for all atoms participating in each reaction. (a) (b) (c) (d)arrow_forwardPredict the position of equilibrium for this acid-base reaction.arrow_forward
- For the Brønsted acid-base reaction shown in the image, determine the conjugate acid-base pairs, then give the curved-arrow notation for the reaction in the left-to-right direction. l'om A + B is an acid and - (b) Add curved arrows to species A + B. (a) Complete the statements to indicate the conjugate acid-base pairs. It does not matter which pair is listed first. Species is an acid and is its conjugate base. Species is its conjugate base. LA H H :0 H 1 H H Darrow_forwardFor each conjugate acid-base pair, identify the first species as an acid or a base and the second species as its conjugate acid or base. In addition, draw Lewis structures for each species, showing all valence electrons and any formal charge. (a) HCOOH HCOO-arrow_forwardConsider the following reaction: (a) What is the acid on the left side of the equation? (b) What is the base on the left side of the equation? (c) What is the conjugate base of the acid on the left? (d) What is the conjugate acid of the base on the left? (e) What is the acid on the right side of the equation? (f) What is the base on the right side of the equation? (g) What is the conjugate base of the acid on the right? (h) What is the conjugate acid of the base on the right?arrow_forward
- (a) Predict the products of the following acid-base reactions using curved-arrow mechanisms to indicate electron flow. (b) Indicate the acid, base, conjugate acid, and conjugate base of each reaction. (c) Indicate whether the reactants or products are favored at equilibrium a) CH,COOH CH3O b) CH,CH,OH H2Narrow_forwardConsider cyclohexane and benzene (draw the structures below). Draw the conjugate base of each molecule and then explain why cyclohexane is the weaker acid.arrow_forward6. For the following reaction: Z-H + H-O HOH N. + :0 (a) Use curved arrow formalism to show how the reactants get converted into the products. (b) Label the acid, base, conjugate acid, and conjugate base.arrow_forward
- 6. Acids and bases are defined by their donation or acceptance of a proton according to the (a) Arrhenius model. (b) Bronsted-Lowry model. (c) Lewis model.arrow_forward1. A typical acid-base reaction involves an acid (losing proton) and a base (gaining proton) as reactant and corresponding conjugate base (product from acid losing proton) and conjugate acid (product from base gaining proton) as product. Acid + Base Û Conjugate Base + Conjugate Acid Look at the following acid-base reactions and identify reactant acid, base and product conjugate base, conjugate acid. (a) HC1 + OH Û H₂O + CI Acid Base (b) HNO, + OH Û H₂O + NO, Acid Base ; Base ; Conjugate Acid Acid Base Base ; Conjugate Acid (c) NH, + H,O Ô NH+OH ; Base ; Conjugate Acid ; Conjugate ; Conjugate ; Conjugatearrow_forwardCan you please answer Question 2 a,b please thanksarrow_forward
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