Organic Chemistry (6th Edition)
Organic Chemistry (6th Edition)
6th Edition
ISBN: 9781260119107
Author: Janice Gorzynski Smith
Publisher: McGraw Hill Education
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Chapter 12.13, Problem 25P
Interpretation Introduction

(a)

Interpretation: The carbonyl compound formed when the given alcohol is treated with HCrO4-AmberlystA-26 resin is to be predicted.

Concept introduction: HCrO4-AmberlystA-26 is an insoluble polymeric reagent. It consists of complex hydrocarbon network with cationic ammonium ion which acts a counter ion to anionic chromium ion. This is a green chemistry method for oxidation of alcohols as it avoids the usage of strong acids and also it forms by-product with carcinogenic Cr3+ which can be removed by filtration.

Interpretation Introduction

(b)

Interpretation: The carbonyl compound formed when the given alcohol is treated with HCrO4-AmberlystA-26 resin is to be predicted.

Concept introduction: HCrO4-AmberlystA-26 is an insoluble polymeric reagent. It consists of complex hydrocarbon network with cationic ammonium ion which acts a counter ion to anionic chromium ion. This is a green chemistry method for oxidation of alcohols as it avoids the usage of strong acids and also it forms by-product with carcinogenic Cr3+ which can be removed by filtration.

Interpretation Introduction

(c)

Interpretation: The carbonyl compound formed when the given alcohol is treated with HCrO4-AmberlystA-26 resin is to be predicted.

Concept introduction: HCrO4-AmberlystA-26 is an insoluble polymeric reagent. It consists of complex hydrocarbon network with cationic ammonium ion which acts a counter ion to anionic chromium ion. This is a green chemistry method for oxidation of alcohols as it avoids the usage of strong acids and also it forms by-product with carcinogenic Cr3+ which can be removed by filtration.

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Organic Chemistry (6th Edition)

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