ORGANIC CHEMISTRY W/ALEKS
6th Edition
ISBN: 9781264905430
Author: SMITH
Publisher: MCG CUSTOM
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The ammonium ion (pKa = 9.25) has a lower pKa than the methyl ammonium ion (pKa = 10.66). Explain which of the two species is the stronger base
Another way to express acid strength is by using pk b:pK a =−logK a Another way to express base strength is by using pK b pK b =−logK b A new potential heart medicine, code-named X-281, is being tested by a pharmaceutical company, Pharma-pill. As a research technician at Pharma-pill, you are told that X-281 is a monoprotic weak acid, but because of security concerns, the actual chemical formula must remain top secret. The company is interested in the drug's K a value because only the dissociated form of the chemical is active in preventing cholesterol buildup in arteries.To find the pK a of X-281, you prepare a 0.079 M M test solution of X-281 at 25.0 ∘ C The pH of the solution is determined to be 3.00. What is the pK a of X-281?
NaHCO3 can deprotonate benzoic acid but cannot deprotonate phenol. On the other hand,
NaOH can deprotonate both benzoic acid and phenol. Given this information, rank the
molecules numbered I to V in order of decreasing acidity.
COH
cOH
он
H,0
H,CO,
IV
CH3
II
I
II
(A)
V > II >I > III >
IV
(В)
II > 1 > V >
III
IV
(C)
II > V >I > IV > II
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- Which has the larger numerical value? (a) The pKa of a strong acid or the pKa of a weak acid (b) The Ka of a strong acid or the Ka of a weak acidarrow_forwardFor each value of Ka, calculate the corresponding value of pKa. Which compound is the stronger acid? (a) Acetic add, Ka = 1.74 105 (b) Chloroacetic acid, Ka= 1.38 103arrow_forwardIn each pair, select the stronger acid. (a) Pyruvic acid (pKa 2.49) or lactic acid (pKa 3.08) (b) Citric acid (pKa1 3.08) or phosphoric acid (pKa1 2.10)arrow_forward
- Will acetylene react with sodium hydride according to the following equation to form a salt and hydrogen, H2? Using pKa values given in Table 4.1, calculate Keq for this equilibrium.arrow_forwardWhat is the relative trend in acidity and pKa of the two compounds? a. Structure I is the most acidic, and Structure I has the highest pKa. b. Structure I is the most acidic, and Structure I has the lowest pKa. c. Structure II is the most acidic, and Structure I has the highest pKa. d. Structure II is the most acidic, and Structure I has the lowest pKa.arrow_forwardConsider these acids (a) Arrange the acids in order of increasing acid strength from weakest to strongest. (b) Which acid has the smallest pKa value?arrow_forward
- Calculate Ka for the weak acids that have the following PKa values. (a) 3.9(b) 10.12 (c) 13.07arrow_forwardFind the value of Kb for the conjugate base of the following organic acids. (a) picric acid used in the manufacture of explosives; Ka = 0.16 (b) trichloroacetic acid used in the treatment of warts; Ka = 0.20arrow_forwardDefine or illustrate the meaning of the following terms: a. Ka reaction b. Ka equilibrium constant c. Kb reaction d. Kb equilibrium constant e. conjugate acidbase pairarrow_forward
- What is the role of ammonium ion in the following reaction? NH3 H;0 H20 NHA + Select one: Conjugate acid Acid Conjugate base Basearrow_forwardWhat is the percent dissociation of acetic acid if the solution has a pH = 4.74 and a pK a = 4.74? What is the percent dissociation of acetic acid if the solution has a pH = 4.74 and a pK a = 4.74? 100% 10% 1% 50%arrow_forwardPlace the following fictitious monoprotic acids in order of decreasing acidity.HX 2 (pk a = 5.5408)HE 5 (pk a = 3.0557)HT (pk a = 5.1609)arrow_forward
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