Chapter 2, Problem 54P

ORGANIC CHEMISTRY W/ALEKS

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ISBN: 9781264905430

Author: SMITH

Publisher: MCG CUSTOM

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Chapter 2, Problem 53P

Chapter 2, Problem 55P

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Consider the following four solutions: (1) apple juice, pH 3.8, (2) pickle juice, pH 3.5, (3) carbonated beverage, pH 3.0, and (4) drinking water, pH 7.2. a. Which solution has the highest [H3O+]? b. Which solution has the highest [OH]? c. List the solutions in order of increasing acidity. d. List the solutions in order of decreasing basicity.
Rank the following acids (M=0.10)in order of decreasing[ H+ ]: HFHCl HCN HCIO
What is the conjugate acid of each of the following? What is the conjugate base of each?. (a) OH-. (b) H2O. (c) HCO3-. (d) NH3. (e) HSO4-. (f) H2O2. (g) HS-. (h) H5N2+
Which of the following compounds or ions has the weakest conjugate base? Briefly explain your choice. a) HCN b) HClO c) NH4+
The following reactions illustrate Brnsted acid-base behavior. Complete each equation. a.HI(aq)+?H3O+(aq)+I(aq) b.NH3(l)+?NH4++NH2 c.H2C2O4(aq)+H2O(l)?+HC2O4(aq) d.H2N2O2(aq)+H2O(l)H3O+(aq)+? e.?+H2O(l)H3O+(aq)+CO32(aq)
Place the species in each of the following groups in order of increasing acid strength. a. H2O, H2S, H2Se (bond energies: HO, 467 kJ/mol; HS, 363 kJ/mol; HSe, 276 kJ/mol) b. CH3CO2H, FCH2CO2H, F2CHCO2H, F3CCO2H c. NH4+, HONH3+ d. NH4+, PH4+ (bond energies: NH, 391 kJ/mol; PH, 322 kJ/mol) Give reasons for the orders you chose.
Which of each pair of acids is stronger? Why? (a) HClO3, HClO4 (b) H2S, H2Se
Several acids and their respective equilibrium constants are: Which is the strongest acid? Which is the weakest acid? Which acid has the weakest conjugate base? Which acid has the strongest conjugate base?
What is the conjugate acid of each of the following? What is the conjugate base of each?. (a) H2S. (b) H2 PO4-. (c) PH3. (d) HS-. (e) HSO3-. (f) H3O2+. (g) H4N2. (h) CH3OH
Gastric juice, the digestive ?uid produced in the stomach, contains hydrochloric acid, HCl, Milk of Magnesia, a suspension of solid Mg(OH)2 in an aqueous medium, is sometimes used to neutralize-excess stomach acid. Write a complete balanced equation for the neutralization reaction, and identify the conjugate acid—base pairs.
. A strong acid has a weak conjugate base, whereas a weak acid has a relatively strong conjugate base. Explain.
Calculate the ionization constant for each of the following acids or bases from the ionization constant of its conjugate base or conjugate acid: (a) HTe- (as a base]. (b) (CH3)3 NH+. (c) HAsO43- (as a base). (d) H02 _ (as a base). (e) C6H5NH3+. (f) HSO3- (as a base)

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