Organic Chemistry (6th Edition)
6th Edition
ISBN: 9781260119107
Author: Janice Gorzynski Smith
Publisher: McGraw Hill Education
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Textbook Question
Chapter 17.13, Problem 26P
What ester and Grignard reagent are needed to prepare each alcohol?
a. 
b. 
c. 
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Indicate the processes in the dismutation of Cu2O.
1. Consider these three reactions as the elementary steps in the mechanism for a chemical reaction.
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Potential Energy (kJ)
600
400
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0
-200-
-400
-600-
-800
(i) Cl₂ (g) + Pt(s) → 2Cl (g) + Pt(s)
(ii) Cl (g)+ CO (g) + Pt (s) → CICO (g) + Pt (s)
Ea = 1550 kJ
Ea = 2240 kJ
(iii) Cl (g) + CICO (g) → Cl₂CO (g)
Ea
= 2350 kJ
AH=-950 kJ
ΔΗ = 575 ΚΙ
AH=-825 kJ
a. Draw the potential energy diagram for the reaction. Label the data points for clarity.
The potential energy of the reactants is 600 kJ
Reaction Progress
b. What is the overall chemical equation?
c. What is the overall change in enthalpy for the above chemical reaction?
d. What is the overall amount of activation energy for the above chemical reaction?
e. Which reaction intermediate would be considered a catalyst (if any) and why?
f. If you were to add 2700kJ of energy to the reaction (e.g. 2700 kl of heat or electricity), would
you be able to make the reaction reverse itself (i.e. have…
draw the enolate anion and the carbonyl that would be needed to make this product through an aldol addition reaction.
Chapter 17 Solutions
Organic Chemistry (6th Edition)
Ch. 17.1 - Prob. 1PCh. 17.2 - Which carbonyl groups in the anticancer drug taxol...Ch. 17.2 - Prob. 3PCh. 17.4 - Problem 20.4 What alcohol is formed when each...Ch. 17.4 - Problem 20.5 What aldehyde or ketone is needed to...Ch. 17.5 - Problem 20.8 Draw the products formed (including...Ch. 17.7 - Problem 20.10 Draw a stepwise mechanism for the...Ch. 17.7 - Prob. 10PCh. 17.7 - Problem 20.12 Draw the products formed from ...Ch. 17.7 - Prob. 12P
Ch. 17.7 - Prob. 13PCh. 17.8 - Prob. 14PCh. 17.8 - Problem-20.16 Review the oxidation reactions using...Ch. 17.9 - Problem-20.17 Write the step(s) needed to convert ...Ch. 17.9 - Prob. 18PCh. 17.10 - Problem 20.21 Draw the product of each reaction.
...Ch. 17.10 - Problem 20.22 Draw the products (including...Ch. 17.11 - Problem 20.23 What Grignard reagent and carbonyl...Ch. 17.11 - Problem 20.24 Linalool (the Chapter 9 opening...Ch. 17.11 - Problem 20.25 What Grignard reagent and carbonyl...Ch. 17.12 - Prob. 24PCh. 17.13 - Problem 20.28 What ester and Grignard reagent are...Ch. 17.13 - Prob. 27PCh. 17.13 - Problem 20.30 What reagent is needed to convert ...Ch. 17.13 - Prob. 29PCh. 17.14 - What carboxylic acid formed from each alkyl halide...Ch. 17 - 20.37 Devise a synthesis of each alcohol from...Ch. 17 - 20.38 Draw the products formed when pentanal is...Ch. 17 - 20.39 Draw the product formed when is treated...Ch. 17 - The stereochemistry of the products of reduction...Ch. 17 - Prob. 40PCh. 17 - 20.42 Draw the products or each reduction...Ch. 17 - 20.44 Draw all stereoisomers formed in each...Ch. 17 - 20.54 Draw a stepwise mechanism for the following...Ch. 17 - Prob. 57PCh. 17 - Prob. 58PCh. 17 - 20.57 What ester and Grignard reagent are needed...Ch. 17 - 20.58 What organolithium reagent and carbonyl...Ch. 17 - 20.59 What epoxide and organometallic reagent are...Ch. 17 - Prob. 62PCh. 17 - 20.69 An unknown compound A (molecular formula )...Ch. 17 - 20.70 Treatment of compound C (molecular formula )...
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