Organic Chemistry (6th Edition)
6th Edition
ISBN: 9781260119107
Author: Janice Gorzynski Smith
Publisher: McGraw Hill Education
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Textbook Question
Chapter 24.4, Problem 11P
What reagents are needed to convert 2-methylpropene
a. b. c.
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Draw the products of combustion of each alkane.
a.
CH;CH,CH,CH2CH(CH3)2
b.
B. Give the IUPAC name for each compound.
F
CH3
ÇI
1. CH;CH2CHCH2CH2CHCH3
5.
CH,CH3
F
2.
CI
6.
OH
CI
NO,
7.
NO,
NO,
Br
8.
Br
3.
Name each compound in which the benzene ring is best treated
as a substituent.
CH3
a. CH3-CH-CH,-CH-CH,-CH–CH,-CH;
CH,-CH3
b. CH,-CH-CH=CH-CH,-CH,–CH,-CH,
c. CH3-C=C-CH-CH-CH-CH2-CH3
CH3 CH3
Chapter 24 Solutions
Organic Chemistry (6th Edition)
Ch. 24.1 - Prob. 1PCh. 24.1 - Prob. 2PCh. 24.1 - Prob. 3PCh. 24.2 - Prob. 4PCh. 24.2 - Prob. 5PCh. 24.4 - Problem 26.10
What reagents are needed to convert...Ch. 24.5 - Problem 26.11
What product is formed when each...Ch. 24.5 - Prob. 13PCh. 24.6 - Problem 26.13
Draw the products formed when each...Ch. 24.6 - Problem 26.14
What products are formed when ...
Ch. 24 - 26.19 What product is formed by ring-closing...Ch. 24 - 26.20 Draw the products formed in each...Ch. 24 - What organic halide is needed to convert lithium...Ch. 24 - 26.22 How can you convert ethynylcyclohexane to...Ch. 24 - 26.23 What compound is needed to convert styrene...Ch. 24 - 26.24 What steps are needed to convert to octane...Ch. 24 - Prob. 27PCh. 24 - 26.27 Draw the products (including stereoisomers)...Ch. 24 - 26.28 Treatment of cyclohexene with and forms...Ch. 24 - Prob. 32PCh. 24 - 26.30 What starting material is needed to prepare...Ch. 24 - Prob. 37PCh. 24 - Prob. 38PCh. 24 - When certain cycloalkenes are used in metathesis...Ch. 24 - 26.34 Draw the products formed in each reaction.
...Ch. 24 - Prob. 41PCh. 24 - Draw a stepwise mechanism for the following...Ch. 24 - Sulfur ylides, like the phosphorus ylides of...Ch. 24 - Although diazomethane is often not a useful...Ch. 24 - Prob. 46PCh. 24 - Prob. 47PCh. 24 - 26.45 Devise a synthesis of each compound from...Ch. 24 - 26.46 Devise a synthesis of each substituted...Ch. 24 - Biaryls, compounds containing two aromatic rings...
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- 8. Give the IUPAC name for each alkene. CH3 CH2CH,CH3 Br а.arrow_forwardDraw the constitutional isomer formed when the following alkenes are treated with each set of reagents: [1] H20, H,SO,; or [2] BH3 followed by H2O2, "OH. a. b. c.arrow_forwardIndicate the product obtained by reacting A and B. A || H3C-S-CH₂ Na* || CH 3 B CH2. C. CH3 H3C CH3arrow_forward
- Draw all constitutional isomers formed when each alkene is treated with NBS + hv. -CH3 CH c. CH2=C(CH2CH3)2 a. CH,CH=CHCH3 b.arrow_forward3. What alcohol is formed when each alkene is treated with H2O in the presence of H2SO4 (as the catalyst)? а. СНЗСН-СНСНЗ b. CH3CH2CH=CH2 С. CH3 CH3arrow_forwardName each alkene: a. CH3CH=CHCH2CH2CH3 b. CH3CH=CH2 c. CH2CH3 l CH2=CHCH2CHCH3arrow_forward
- Draw the eight constitutional isomers having the molecular formula C5H11Cl.a. Give the IUPAC name for each compound (ignoring R and S designations).b. Classify each alkyl halide as 1°, 2°, or 3°.c. Label any stereogenic centers.d. For each constitutional isomer that contains a stereogenic center, draw all possible stereoisomers, and label each stereogenic center as R or S.arrow_forwardDraw the eight constitutional isomers having the molecular formula C5H11Cl. a.Give the IUPAC name for each compound (ignoring R and S designations). b.Classify each alkyl halide as 1°, 2°, or 3°. c.Label any stereogenic centers. d.For each constitutional isomer that contains a stereogenic center, draw all possible stereoisomers, and label each stereogenic center as R or S.arrow_forwardDraw the organic products formed when cyclopentene is treated with each reagent. With some reagents, no reaction occurs. a.H2 + Pd-C b.H2 + Lindlar catalyst c.Na, NH3 d.CH3CO3H e.[1] CH3CO3H; [2] H2O, HO− f.[1]OsO4 + NMO; [2] NaHSO3, H2O g.KMnO4, H2O, HO− h.[1] LiAlH4; [2] H2O i. [1] O3; [2] CH3SCH3 j.(CH3)3COOH, Ti[OCH(CH3)2]4, (−)-DET k.mCPBA l.Product in (k); then [1] LiAlH4; [2] H2Oarrow_forward
- cdn.fbsbx.com I. What products are formed when each alcohol is oxidized with K,Cr,0,? a. CH,CH,CH,CH,CH,OH OH OH H3C CH3 b. C. II, Give the structure corresponding to each IUPAC name:arrow_forwardGive the IUPAC name for each compound. a. (CHa)3CCH,CH(CHCH3)2 b. CH3(CH2)3CH(CH,CH2CH3)CH(CH32 d.arrow_forwarda. What hydrocarbon with molecular formula C4H10 forms only two monochlorinated products? Both products are achiral. b. What hydrocarbon with the same molecular formula as in part a forms three monochlorinated products? One is achiral and two are chiral.arrow_forward
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