The value of Δ H ° for the rate determining step of the reaction of CH 4 with I 2 is to be calculated. The reason corresponding to the fact that this reaction is extremely slow is to be explained. Concept introduction: Halogens react with alkanes in presence of heat or light to form alkyl halides. This is known as halogenation reaction. This is a free radical substitution reaction. In these reactions, the halogen substitutes the hydrogen atom from C − H sigma bond of the alkane.

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Answer 1

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Chapter 13.4, Problem 7P

Interpretation Introduction

Interpretation: The value of ΔH° for the rate determining step of the reaction of CH4 with I2 is to be calculated. The reason corresponding to the fact that this reaction is extremely slow is to be explained.

Concept introduction: Halogens react with alkanes in presence of heat or light to form alkyl halides. This is known as halogenation reaction. This is a free radical substitution reaction. In these reactions, the halogen substitutes the hydrogen atom from C−H sigma bond of the alkane.

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Answer 2

Question

Chapter 13.4, Problem 7P

Interpretation Introduction

Interpretation: The value of ΔH° for the rate determining step of the reaction of CH4 with I2 is to be calculated. The reason corresponding to the fact that this reaction is extremely slow is to be explained.

Concept introduction: Halogens react with alkanes in presence of heat or light to form alkyl halides. This is known as halogenation reaction. This is a free radical substitution reaction. In these reactions, the halogen substitutes the hydrogen atom from C−H sigma bond of the alkane.

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Answer 3

Question

Chapter 13.4, Problem 7P

Interpretation Introduction

Interpretation: The value of ΔH° for the rate determining step of the reaction of CH4 with I2 is to be calculated. The reason corresponding to the fact that this reaction is extremely slow is to be explained.

Concept introduction: Halogens react with alkanes in presence of heat or light to form alkyl halides. This is known as halogenation reaction. This is a free radical substitution reaction. In these reactions, the halogen substitutes the hydrogen atom from C−H sigma bond of the alkane.

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Answer 4

Question

Chapter 13.4, Problem 7P

Interpretation Introduction

Interpretation: The value of ΔH° for the rate determining step of the reaction of CH4 with I2 is to be calculated. The reason corresponding to the fact that this reaction is extremely slow is to be explained.

Concept introduction: Halogens react with alkanes in presence of heat or light to form alkyl halides. This is known as halogenation reaction. This is a free radical substitution reaction. In these reactions, the halogen substitutes the hydrogen atom from C−H sigma bond of the alkane.

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Answer 5

Chapter 13.4, Problem 7P

Interpretation Introduction

Interpretation: The value of ΔH° for the rate determining step of the reaction of CH4 with I2 is to be calculated. The reason corresponding to the fact that this reaction is extremely slow is to be explained.

Concept introduction: Halogens react with alkanes in presence of heat or light to form alkyl halides. This is known as halogenation reaction. This is a free radical substitution reaction. In these reactions, the halogen substitutes the hydrogen atom from C−H sigma bond of the alkane.

Answer 6

Chapter 13.4, Problem 7P

Interpretation Introduction

Interpretation: The value of ΔH° for the rate determining step of the reaction of CH4 with I2 is to be calculated. The reason corresponding to the fact that this reaction is extremely slow is to be explained.

Concept introduction: Halogens react with alkanes in presence of heat or light to form alkyl halides. This is known as halogenation reaction. This is a free radical substitution reaction. In these reactions, the halogen substitutes the hydrogen atom from C−H sigma bond of the alkane.

Answer 7

Chapter 13.4, Problem 7P

Interpretation Introduction

Interpretation: The value of ΔH° for the rate determining step of the reaction of CH4 with I2 is to be calculated. The reason corresponding to the fact that this reaction is extremely slow is to be explained.

Concept introduction: Halogens react with alkanes in presence of heat or light to form alkyl halides. This is known as halogenation reaction. This is a free radical substitution reaction. In these reactions, the halogen substitutes the hydrogen atom from C−H sigma bond of the alkane.

Answer 8

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Answer 11

Ch. 13.1 - Prob. 1P Ch. 13.1 - Prob. 2P Ch. 13.2 - Prob. 3P Ch. 13.3 - Prob. 4P Ch. 13.3 - Prob. 5P Ch. 13.4 - Prob. 7P Ch. 13.5 - Problem 15.8 Which bond in the each compound is...Ch. 13.6 - Prob. 9P Ch. 13.6 - Prob. 10P Ch. 13.7 - Prob. 11P

Solution Summary: The author explains that halogens react with alkanes in presence of heat or light to form methyl radicals. This is an endothermic reaction.

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Chapter 13 Solutions