Organic Chemistry (6th Edition)
Organic Chemistry (6th Edition)
6th Edition
ISBN: 9781260119107
Author: Janice Gorzynski Smith
Publisher: McGraw Hill Education
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Chapter 11.10, Problem 14P
Interpretation Introduction

(a)

Interpretation: The products that are formed by the reaction of the given terminal alkyne, with [1] H2O, H2SO4 and HgSO4 or [2] R2BH followed by H2O2, OH are to be drawn.

Concept introduction: A stepwise procedure of transforming an alkyne into a carbonyl group is known hydroboration-oxidation reaction. In a hydroboration-oxidation reaction, a terminal alkyne reacts with R2BH followed by H2O2, OH to form an aldehyde.

A terminal alkyne reacts with H2O, H2SO4 (strong acid) and HgSO4 to form a ketone.

Interpretation Introduction

(b)

Interpretation: The products that are formed by the reaction of the given terminal alkyne, with [1] H2O, H2SO4 and HgSO4 or [2] R2BH followed by H2O2, OH are to be drawn.

Concept introduction: A stepwise procedure of transforming an alkyne into a carbonyl group is known hydroboration-oxidation reaction. In a hydroboration-oxidation reaction, a terminal alkyne reacts with R2BH followed by H2O2, OH to form an aldehyde.

A terminal alkyne reacts with H2O, H2SO4 (strong acid) and HgSO4 to form a ketone.

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Chapter 11 Solutions

Organic Chemistry (6th Edition)

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