Organic Chemistry (6th Edition)
6th Edition
ISBN: 9781260119107
Author: Janice Gorzynski Smith
Publisher: McGraw Hill Education
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Chapter 11.11, Problem 16P
What acetylide anion and
a. 
b. 
c. 
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6. Draw the molecular orbital diagram shown to determine which of the following is paramagnetic.
B22+
B22+, B2, C22, B22 and N22+
Molecular Orbital Diagram
B2
C22-
B22-
N22+
Which molecule is paramagnetic?
3. Put the following species in order of increasing bond length by using molecular orbital diagrams and
calculating their bond orders: F2, F2, F2+
Molecular Orbital Diagram
F2
F2
F2+
Bond Order
Shortest bond:
Longest bond
3. Put the following species in order of increasing bond length by using molecular orbital diagrams and
calculating their bond orders: F2, F2, F2+
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F2
F2
F2+
Bond Order
Chapter 11 Solutions
Organic Chemistry (6th Edition)
Ch. 11.1 - Problem 11.1 Neopheliosyne B is a novel acetylenic...Ch. 11.2 - Give the IUPAC name for each compound.Ch. 11.2 - Give the structures corresponding to each of the...Ch. 11.3 - Prob. 4PCh. 11.5 - Prob. 5PCh. 11.6 - Which bases can deprotonate acetylene? The pKa...Ch. 11.7 - Draw the organic products formed when each alkyne...Ch. 11.7 - Draw additional resonance structures for each...Ch. 11.8 - Problem 11.9 Draw the products formed when is...Ch. 11.8 - Explain the following result. Although alkenes...
Ch. 11.9 - Problem 11.11 Draw the keto tautomer of each...Ch. 11.9 - Prob. 12PCh. 11.9 - a Draw two different enol tautomers of...Ch. 11.10 - Prob. 14PCh. 11.10 - Problem 11.15 Draw the organic products formed in...Ch. 11.11 - Problem 11.16 What acetylide anion and alkyl...Ch. 11.11 - Problem. 11.17 Show how , and can be used to...Ch. 11.11 - Prob. 18PCh. 11.11 - Draw the products of each reaction. a. b.Ch. 11.11 - Prob. 20PCh. 11 - Prob. 25PCh. 11 - 11.25 Answer the following questions about...Ch. 11 - 11.26 Give the IUPAC name for each alkyne.
a. ...Ch. 11 - Prob. 28PCh. 11 - Which of the following pairs of compounds...Ch. 11 - Prob. 30PCh. 11 - 11.30 How is each compound related to A? Choose...Ch. 11 - Prob. 32PCh. 11 - 11.33 Draw the products formed when is treated...Ch. 11 - What reagents are needed to convert (CH3CH2)3CCCH...Ch. 11 - 11.36 What alkynes give each of the following...Ch. 11 - 11.37 What alkyne gives each compound as the only...Ch. 11 - 11.38 Draw the organic products formed in each...Ch. 11 - 11.42 What reactions are needed to convert alcohol...Ch. 11 - 11.50 What acetylide anion and alkyl halide are...Ch. 11 - 11.52 Devise a synthesis of each compound using ...Ch. 11 - Prob. 58PCh. 11 - 11.59 N-Chlorosuccinimide (NCS) serves as a source...Ch. 11 - 11.60 Draw a stepwise mechanism for the following...Ch. 11 - 11.61 Draw a stepwise mechanism for the following...
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