Organic Chemistry (6th Edition)
6th Edition
ISBN: 9781260119107
Author: Janice Gorzynski Smith
Publisher: McGraw Hill Education
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Chapter 11, Problem 27P
Give the IUPAC name for each
a. 
c. 
e. 
b. 
d. 
f. 
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A 45.0 mL solution containing a mixture of 0.0634 M KCN and 0.0634 M KCI is titrated with 0.107 M AgNO.
From this mixture, which silver salt will precipitate first? A list of Ksp values can be found in the table of solubility constants.
• AgCI
• not enough information to determine
AgCN
What is the concentration of Ag* at the first equivalence point?
[Ag*] =
Will the second silver salt begin to precipitate at the first equivalence point before the first silver salt has completely precipitated?
• not enough information to determine
• yes
• no
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Indicate whether the pair of structures shown represent stereoisomers, constitutional isomers, different conformations of the
same compound, or the same conformation of a compound viewed from a different perspective.
Note that cis, trans isomers are an example of stereoisomers.
H₂N
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Chapter 11 Solutions
Organic Chemistry (6th Edition)
Ch. 11.1 - Problem 11.1 Neopheliosyne B is a novel acetylenic...Ch. 11.2 - Give the IUPAC name for each compound.Ch. 11.2 - Give the structures corresponding to each of the...Ch. 11.3 - Prob. 4PCh. 11.5 - Prob. 5PCh. 11.6 - Which bases can deprotonate acetylene? The pKa...Ch. 11.7 - Draw the organic products formed when each alkyne...Ch. 11.7 - Draw additional resonance structures for each...Ch. 11.8 - Problem 11.9 Draw the products formed when is...Ch. 11.8 - Explain the following result. Although alkenes...
Ch. 11.9 - Problem 11.11 Draw the keto tautomer of each...Ch. 11.9 - Prob. 12PCh. 11.9 - a Draw two different enol tautomers of...Ch. 11.10 - Prob. 14PCh. 11.10 - Problem 11.15 Draw the organic products formed in...Ch. 11.11 - Problem 11.16 What acetylide anion and alkyl...Ch. 11.11 - Problem. 11.17 Show how , and can be used to...Ch. 11.11 - Prob. 18PCh. 11.11 - Draw the products of each reaction. a. b.Ch. 11.11 - Prob. 20PCh. 11 - Prob. 25PCh. 11 - 11.25 Answer the following questions about...Ch. 11 - 11.26 Give the IUPAC name for each alkyne.
a. ...Ch. 11 - Prob. 28PCh. 11 - Which of the following pairs of compounds...Ch. 11 - Prob. 30PCh. 11 - 11.30 How is each compound related to A? Choose...Ch. 11 - Prob. 32PCh. 11 - 11.33 Draw the products formed when is treated...Ch. 11 - What reagents are needed to convert (CH3CH2)3CCCH...Ch. 11 - 11.36 What alkynes give each of the following...Ch. 11 - 11.37 What alkyne gives each compound as the only...Ch. 11 - 11.38 Draw the organic products formed in each...Ch. 11 - 11.42 What reactions are needed to convert alcohol...Ch. 11 - 11.50 What acetylide anion and alkyl halide are...Ch. 11 - 11.52 Devise a synthesis of each compound using ...Ch. 11 - Prob. 58PCh. 11 - 11.59 N-Chlorosuccinimide (NCS) serves as a source...Ch. 11 - 11.60 Draw a stepwise mechanism for the following...Ch. 11 - 11.61 Draw a stepwise mechanism for the following...
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