Organic Chemistry (6th Edition)
Organic Chemistry (6th Edition)
6th Edition
ISBN: 9781260119107
Author: Janice Gorzynski Smith
Publisher: McGraw Hill Education
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Chapter 23.11, Problem 25P
Interpretation Introduction

(a)

Interpretation: The products formed by the reaction of given compound with excess CH3I followed by Ag2O are to be drawn.

Concept introduction: Amines on reaction with excess CH3I followed by Ag2O undergo Hofmann elimination. The major product formed by the Hofmann elimination of amines is alkene. The removal of proton from β carbon atom of ammonium salt leads to the formation of π bond of the alkene. The mechanism followed in the Hofmann elimination is E2.

Interpretation Introduction

(b)

Interpretation: The products formed by the reaction of given compound with excess CH3I followed by Ag2O are to be drawn.

Concept introduction: Amines on reaction with excess CH3I followed by Ag2O undergo Hofmann elimination. The major product formed by the Hofmann elimination of amines is alkene. The removal of proton from β carbon atom of ammonium salt leads to the formation of π bond of the alkene. The mechanism followed in the Hofmann elimination is E2.

Interpretation Introduction

(c)

Interpretation: The products formed by the reaction of given compound with excess CH3I followed by Ag2O are to be drawn.

Concept introduction: Amines on reaction with excess CH3I followed by Ag2O undergo Hofmann elimination. The major product formed by the Hofmann elimination of amines is alkene. The removal of proton from β carbon atom of ammonium salt leads to the formation of π bond of the alkene. The mechanism followed in the Hofmann elimination is E2.

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