(a) Interpretation: The nitro compound, nitrile and amide which are reduced to given amine are to be determined. Concept introduction: The synthesis of amine can be carried out by reduction of nitro compounds, nitriles and amides. Nitro compounds can be reduced to amines using catalytic hydrogenation or iron/palladium metal in presence of acid. Nitriles and amides are reduced to primary amines using lithium aluminium hydride.

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Answer 1

Question

Chapter 23.6, Problem 9P

Interpretation Introduction

(a)

Interpretation: The nitro compound, nitrile and amide which are reduced to given amine are to be determined.

Concept introduction: The synthesis of amine can be carried out by reduction of nitro compounds, nitriles and amides. Nitro compounds can be reduced to amines using catalytic hydrogenation or iron/palladium metal in presence of acid. Nitriles and amides are reduced to primary amines using lithium aluminium hydride.

Interpretation Introduction

(b)

Interpretation: The nitro compound, nitrile and amide which are reduced to given amine are to be determined.

Concept introduction: The synthesis of amine can be carried out by reduction of nitro compounds, nitriles and amides. Nitro compounds can be reduced to amines using catalytic hydrogenation or iron/palladium metal in presence of acid. Nitriles and amides are reduced to primary amines using lithium aluminium hydride.

Interpretation Introduction

(c)

Interpretation: The nitro compound, nitrile and amide which are reduced to given amine are to be determined.

Concept introduction: The synthesis of amine can be carried out by reduction of nitro compounds, nitriles and amides. Nitro compounds can be reduced to amines using catalytic hydrogenation or iron/palladium metal in presence of acid. Nitriles and amides are reduced to primary amines using lithium aluminium hydride.

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4. Read paragraph 4.15 from your textbook, use your calculated lattice energy values for CuO, CuCO3 and Cu(OH)2 an explain thermal decomposition reaction of malachite: Cu2CO3(OH)2 →2CuO + H2O + CO2 (3 points)

Answer 2

Question

Chapter 23.6, Problem 9P

Interpretation Introduction

(a)

Interpretation: The nitro compound, nitrile and amide which are reduced to given amine are to be determined.

Concept introduction: The synthesis of amine can be carried out by reduction of nitro compounds, nitriles and amides. Nitro compounds can be reduced to amines using catalytic hydrogenation or iron/palladium metal in presence of acid. Nitriles and amides are reduced to primary amines using lithium aluminium hydride.

Interpretation Introduction

(b)

Interpretation: The nitro compound, nitrile and amide which are reduced to given amine are to be determined.

Concept introduction: The synthesis of amine can be carried out by reduction of nitro compounds, nitriles and amides. Nitro compounds can be reduced to amines using catalytic hydrogenation or iron/palladium metal in presence of acid. Nitriles and amides are reduced to primary amines using lithium aluminium hydride.

Interpretation Introduction

(c)

Interpretation: The nitro compound, nitrile and amide which are reduced to given amine are to be determined.

Concept introduction: The synthesis of amine can be carried out by reduction of nitro compounds, nitriles and amides. Nitro compounds can be reduced to amines using catalytic hydrogenation or iron/palladium metal in presence of acid. Nitriles and amides are reduced to primary amines using lithium aluminium hydride.

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Answer 3

Question

Chapter 23.6, Problem 9P

Interpretation Introduction

(a)

Interpretation: The nitro compound, nitrile and amide which are reduced to given amine are to be determined.

Concept introduction: The synthesis of amine can be carried out by reduction of nitro compounds, nitriles and amides. Nitro compounds can be reduced to amines using catalytic hydrogenation or iron/palladium metal in presence of acid. Nitriles and amides are reduced to primary amines using lithium aluminium hydride.

Interpretation Introduction

(b)

Interpretation: The nitro compound, nitrile and amide which are reduced to given amine are to be determined.

Concept introduction: The synthesis of amine can be carried out by reduction of nitro compounds, nitriles and amides. Nitro compounds can be reduced to amines using catalytic hydrogenation or iron/palladium metal in presence of acid. Nitriles and amides are reduced to primary amines using lithium aluminium hydride.

Interpretation Introduction

(c)

Interpretation: The nitro compound, nitrile and amide which are reduced to given amine are to be determined.

Concept introduction: The synthesis of amine can be carried out by reduction of nitro compounds, nitriles and amides. Nitro compounds can be reduced to amines using catalytic hydrogenation or iron/palladium metal in presence of acid. Nitriles and amides are reduced to primary amines using lithium aluminium hydride.

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Answer 4

Question

Chapter 23.6, Problem 9P

Interpretation Introduction

(a)

Interpretation: The nitro compound, nitrile and amide which are reduced to given amine are to be determined.

Concept introduction: The synthesis of amine can be carried out by reduction of nitro compounds, nitriles and amides. Nitro compounds can be reduced to amines using catalytic hydrogenation or iron/palladium metal in presence of acid. Nitriles and amides are reduced to primary amines using lithium aluminium hydride.

Interpretation Introduction

(b)

Interpretation: The nitro compound, nitrile and amide which are reduced to given amine are to be determined.

Concept introduction: The synthesis of amine can be carried out by reduction of nitro compounds, nitriles and amides. Nitro compounds can be reduced to amines using catalytic hydrogenation or iron/palladium metal in presence of acid. Nitriles and amides are reduced to primary amines using lithium aluminium hydride.

Interpretation Introduction

(c)

Interpretation: The nitro compound, nitrile and amide which are reduced to given amine are to be determined.

Concept introduction: The synthesis of amine can be carried out by reduction of nitro compounds, nitriles and amides. Nitro compounds can be reduced to amines using catalytic hydrogenation or iron/palladium metal in presence of acid. Nitriles and amides are reduced to primary amines using lithium aluminium hydride.

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Answer 5

Chapter 23.6, Problem 9P

Interpretation Introduction

(a)

Interpretation: The nitro compound, nitrile and amide which are reduced to given amine are to be determined.

Concept introduction: The synthesis of amine can be carried out by reduction of nitro compounds, nitriles and amides. Nitro compounds can be reduced to amines using catalytic hydrogenation or iron/palladium metal in presence of acid. Nitriles and amides are reduced to primary amines using lithium aluminium hydride.

Interpretation Introduction

(b)

Interpretation: The nitro compound, nitrile and amide which are reduced to given amine are to be determined.

Concept introduction: The synthesis of amine can be carried out by reduction of nitro compounds, nitriles and amides. Nitro compounds can be reduced to amines using catalytic hydrogenation or iron/palladium metal in presence of acid. Nitriles and amides are reduced to primary amines using lithium aluminium hydride.

Interpretation Introduction

(c)

Interpretation: The nitro compound, nitrile and amide which are reduced to given amine are to be determined.

Concept introduction: The synthesis of amine can be carried out by reduction of nitro compounds, nitriles and amides. Nitro compounds can be reduced to amines using catalytic hydrogenation or iron/palladium metal in presence of acid. Nitriles and amides are reduced to primary amines using lithium aluminium hydride.

Answer 6

Chapter 23.6, Problem 9P

Interpretation Introduction

(a)

Interpretation: The nitro compound, nitrile and amide which are reduced to given amine are to be determined.

Concept introduction: The synthesis of amine can be carried out by reduction of nitro compounds, nitriles and amides. Nitro compounds can be reduced to amines using catalytic hydrogenation or iron/palladium metal in presence of acid. Nitriles and amides are reduced to primary amines using lithium aluminium hydride.

Answer 7

Chapter 23.6, Problem 9P

Interpretation Introduction

(a)

Interpretation: The nitro compound, nitrile and amide which are reduced to given amine are to be determined.

Concept introduction: The synthesis of amine can be carried out by reduction of nitro compounds, nitriles and amides. Nitro compounds can be reduced to amines using catalytic hydrogenation or iron/palladium metal in presence of acid. Nitriles and amides are reduced to primary amines using lithium aluminium hydride.

Answer 8

Interpretation Introduction

(b)

Interpretation: The nitro compound, nitrile and amide which are reduced to given amine are to be determined.

Concept introduction: The synthesis of amine can be carried out by reduction of nitro compounds, nitriles and amides. Nitro compounds can be reduced to amines using catalytic hydrogenation or iron/palladium metal in presence of acid. Nitriles and amides are reduced to primary amines using lithium aluminium hydride.

Answer 9

Interpretation Introduction

(b)

Interpretation: The nitro compound, nitrile and amide which are reduced to given amine are to be determined.

Concept introduction: The synthesis of amine can be carried out by reduction of nitro compounds, nitriles and amides. Nitro compounds can be reduced to amines using catalytic hydrogenation or iron/palladium metal in presence of acid. Nitriles and amides are reduced to primary amines using lithium aluminium hydride.

Answer 10

Interpretation Introduction

(c)

Interpretation: The nitro compound, nitrile and amide which are reduced to given amine are to be determined.

Concept introduction: The synthesis of amine can be carried out by reduction of nitro compounds, nitriles and amides. Nitro compounds can be reduced to amines using catalytic hydrogenation or iron/palladium metal in presence of acid. Nitriles and amides are reduced to primary amines using lithium aluminium hydride.

Answer 11

Interpretation Introduction

(c)

Interpretation: The nitro compound, nitrile and amide which are reduced to given amine are to be determined.

Concept introduction: The synthesis of amine can be carried out by reduction of nitro compounds, nitriles and amides. Nitro compounds can be reduced to amines using catalytic hydrogenation or iron/palladium metal in presence of acid. Nitriles and amides are reduced to primary amines using lithium aluminium hydride.

Answer 12

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Answer 13

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Answer 14

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Answer 15

Ch. 23.2 - Prob. 1P Ch. 23.3 - Prob. 2P Ch. 23.3 - Prob. 3P Ch. 23.4 - Prob. 4P Ch. 23.6 - Prob. 7P Ch. 23.6 - Prob. 8P Ch. 23.6 - Prob. 9P Ch. 23.6 - Prob. 10P Ch. 23.6 - Prob. 11P Ch. 23.6 - Prob. 12P

Solution Summary: The author explains how nitro compounds, nitriles and amides can be reduced to amines using catalytic hydrogenation or iron/palladium metal in presence of acid.

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Chapter 23 Solutions