![Living by Chemistry](https://www.bartleby.com/isbn_cover_images/9781464142314/9781464142314_smallCoverImage.jpg)
Concept explainers
(a)
Interpretation:
The olecular structure of heptanes must be drawn.
Concept Introduction:
Heptane is a straight chain hydrocarbon with 7 carbons.
(a)
![Check Mark](/static/check-mark.png)
Answer to Problem C20.4RE
Molecular structure of heptane is drawn below.
Explanation of Solution
In the molecular structure of heptanes only carbon chain is shown. Hydrogens are removed for simplicity. There are total 7 carbon and 16 hydrogen atoms. All the carbon is single bonded with another 4 atoms out of which two C and two hydrogen atoms.
b)
Interpretation:
Combustion reaction of heptane must be given.
Concept Introduction:
Hydrocarbons undergo combustion reaction to produce carbon dioxide and water as shown below.
Here x and y represents number of carbon and hydrogen atoms in the hydrocarbon.
b)
![Check Mark](/static/check-mark.png)
Answer to Problem C20.4RE
Explanation of Solution
There are 7 carbons and 16 hydrogens. So from 1 mole heptanes 7 moles of carbon dioxide and 11 moles of water were obtained after complete combustion.
c)
Interpretation:
Using average bond energies, the heat of reaction of heptanes must be calculated.
Concept Introduction:
Heat of reaction is the difference of energies required to break the bonds and energy obtained after bonds formation.
c)
![Check Mark](/static/check-mark.png)
Answer to Problem C20.4RE
Heat of reaction for the above combustion reaction is -4332 kJ/mol.
Explanation of Solution
In the combustion reaction of heptanes 6 C-C, 16 C-H and 11 O=O bonds are broken. 14 C=O bonds and 16 O-H bonds are produced.
These bond energies must be considered to calculate the heat of reaction for the above combustion reaction.
Bond energies of C-C, C-H and O=O bonds are 346, 413 and 498 kJ/mol respectively.
Bond energies of C=O and O-H are 799 and 463 kJ/mol respectively.
Energy required to break 6 C-C, 16 C-H and 11 O=O bonds can be calculated as follows:
Energy obtained for the formation of 14 C=O bonds and 16 O-H bonds can be calculated as follows:
Heat of reaction
Chapter U5 Solutions
Living by Chemistry
Additional Science Textbook Solutions
Brock Biology of Microorganisms (15th Edition)
Microbiology: An Introduction
Biology: Life on Earth (11th Edition)
Campbell Essential Biology with Physiology (5th Edition)
Campbell Biology (11th Edition)
Human Biology: Concepts and Current Issues (8th Edition)
- How many milliliters of 97.5(±0.5) wt% H2SO4 with a density of 1.84(±0.01) g/mL will you need to prepare 2.000 L of 0.110 M H2SO4? If the uncertainty in delivering H2SO4 is ±0.01 mL, calculate the absolute uncertainty in the molarity (0.110 M). Assume there is negligible uncertainty in the formula mass of H2SO4 and in the final volume (2.000 L) and assume random error.arrow_forwardDon't used hand raiting and don't used Ai solutionarrow_forwardWhat should be use to complete the reaction? CN CNarrow_forward
- Don't used hand raiting and don't used Ai solutionarrow_forwardDon't used hand raiting and don't used Ai solutionarrow_forward* How many milliliters of 97.5(±0.5) wt% H2SO4 with a density of 1.84(±0.01) g/mL will you need to prepare 2.000 L of 0.110 M H2SO4? * If the uncertainty in delivering H2SO4 is ±0.01 mL, calculate the absolute uncertainty in the molarity (0.110 M). Assume there is negligible uncertainty in the formula mass of NaOH and in the final volume (2.000 L) and assume random error.arrow_forward
- You are tasked with creating a calibration curve for the absorbance of cobalt solutions of various concentrations. You must prepare 5 standards with concentrations between 1.00 mg/L and 10.0 mg/L Co2+. You have a stock solution with a concentration of 40 mg/L Co2+ and all the standard lab glassware including transfer pipets and flasks. Explain how you would make your 5 standard solutions of various concentrations, including what glassware you would use to measure and prepare each solution.arrow_forwardPredict the product and write the mechanism. CH3-CH=CH-CH2-CH3 + NBS- hv CCl4arrow_forwardHow exactly is carbon disulfide used in industry? Specifically, where does it come in during rubber or textile production and what is the chemical processes?arrow_forward
- A researcher has developed a new analytical method to determine the percent by mass iron in solids. To test the new method, the researcher purchases a standard reference material sample that is 2.85% iron by mass. Analysis of the iron standard with the new method returns values of 2.75%, 2.89%, 2.77%, 2.81%, and 2.87%. Does the new method produce a result that is significantly different from the standard value at the 95% confidence level?arrow_forwardCreate a drawing of an aceral with at least 2 isopropoxy groups, and a total of 11 carbon atomsarrow_forward4. Predict the major product(s) for each of the following reactions. HBr (1 equiv.) peroxide, A a. b. NBS, peroxide, Aarrow_forward
- ChemistryChemistryISBN:9781305957404Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCostePublisher:Cengage LearningChemistryChemistryISBN:9781259911156Author:Raymond Chang Dr., Jason Overby ProfessorPublisher:McGraw-Hill EducationPrinciples of Instrumental AnalysisChemistryISBN:9781305577213Author:Douglas A. Skoog, F. James Holler, Stanley R. CrouchPublisher:Cengage Learning
- Organic ChemistryChemistryISBN:9780078021558Author:Janice Gorzynski Smith Dr.Publisher:McGraw-Hill EducationChemistry: Principles and ReactionsChemistryISBN:9781305079373Author:William L. Masterton, Cecile N. HurleyPublisher:Cengage LearningElementary Principles of Chemical Processes, Bind...ChemistryISBN:9781118431221Author:Richard M. Felder, Ronald W. Rousseau, Lisa G. BullardPublisher:WILEY
![Text book image](https://www.bartleby.com/isbn_cover_images/9781305957404/9781305957404_smallCoverImage.gif)
![Text book image](https://www.bartleby.com/isbn_cover_images/9781259911156/9781259911156_smallCoverImage.gif)
![Text book image](https://www.bartleby.com/isbn_cover_images/9781305577213/9781305577213_smallCoverImage.gif)
![Text book image](https://www.bartleby.com/isbn_cover_images/9780078021558/9780078021558_smallCoverImage.gif)
![Text book image](https://www.bartleby.com/isbn_cover_images/9781305079373/9781305079373_smallCoverImage.gif)
![Text book image](https://www.bartleby.com/isbn_cover_images/9781118431221/9781118431221_smallCoverImage.gif)