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(a)
Interpretation:
Oxidation number of silicon in
Concept Introduction:
Oxidation state of a species is the one that has a specified oxidation number. Increase in oxidation number corresponds to oxidation while decrease in oxidation number corresponds to reduction. Rules for assigning oxidation number for an element is given as follows;
- The oxidation number is zero for the element that is present in uncombined state.
- Sum of the oxidation number of the atoms that is present in it is equal to the charge on the species.
- Oxidation number of the element is the charge that is possessed when the more electronegative atom is imagined to be an ion.
(b)
Interpretation:
Oxidation number of tin in
Concept Introduction:
Refer part (a).
(c)
Interpretation:
Oxidation number of nitrogen in
Concept Introduction:
Refer part (a).
(d)
Interpretation:
Oxidation number of phosphorus in
Concept Introduction:
Refer part (a).
(e)
Interpretation:
Oxidation number of sulfur in
Concept Introduction:
Refer part (a).
(f)
Interpretation:
Oxidation number of phophorus in
Concept Introduction:
Refer part (a).
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Chapter F Solutions
Chemical Principles: The Quest for Insight
- The emission data in cps displayed in Table 1 is reported to two decimal places by the chemist. However, the instrument output is shown in Table 2. Table 2. Iron emission from ICP-AES Sample Blank Standard Emission, cps 579.503252562 9308340.13122 Unknown Sample 343.232365741 Did the chemist make the correct choice in how they choose to display the data up in Table 1? Choose the best explanation from the choices below. No. Since the instrument calculates 12 digits for all values, they should all be kept and not truncated. Doing so would eliminate significant information. No. Since the instrument calculates 5 decimal places for the standard, all of the values should be limited to the same number. The other decimal places are not significant for the blank and unknown sample. Yes. The way Saman made the standards was limited by the 250-mL volumetric flask. This glassware can report values to 2 decimal places, and this establishes our number of significant figures. Yes. Instrumental data…arrow_forwardSteps and explanation pleasearrow_forwardSteps and explanation to undertand concepts.arrow_forward
- Nonearrow_forward7. Draw a curved arrow mechanism for the following reaction. HO cat. HCI OH in dioxane with 4A molecular sievesarrow_forwardTry: Convert the given 3D perspective structure to Newman projection about C2 - C3 bond (C2 carbon in the front). Also, show Newman projection of other possible staggered conformers and circle the most stable conformation. Use the template shown. F H3C Br Harrow_forward
- Nonearrow_forward16. Consider the probability distribution p(x) = ax", 0 ≤ x ≤ 1 for a positive integer n. A. Derive an expression for the constant a, to normalize p(x). B. Compute the average (x) as a function of n. C. Compute σ2 = (x²) - (x)², the variance of x, as a function of n.arrow_forward451. Use the diffusion model from lecture that showed the likelihood of mixing occurring in a lattice model with eight lattice sites: Case Left Right A B C Permeable Barrier → and show that with 2V lattice sites on each side of the permeable barrier and a total of 2V white particles and 2V black particles, that perfect de-mixing (all one color on each side of the barrier) becomes increasingly unlikely as V increases.arrow_forward
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