Chemical Principles: The Quest for Insight
7th Edition
ISBN: 9781464183959
Author: Peter Atkins, Loretta Jones, Leroy Laverman
Publisher: W. H. Freeman
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Chapter F, Problem F.15E
Interpretation Introduction
Interpretation:
Empirical formula for diazepam has to be given.
Concept Introduction:
Empirical formula is the one that can be determined from the molar mass of the elements that is present in the compound and the mass percentage of the elements. The mass percentage of the elements present in the compound is converted into the moles of each element considering the molar mass of each element. The relative number of moles for each type of atoms is found out finally.
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Part VII. Below are the 'HNMR, 13 C-NMR, COSY 2D- NMR, and HSQC 2D-NMR (similar with HETCOR but axes are reversed) spectra of an
organic compound with molecular formula C6H1003 - Assign chemical shift values to the H and c atoms of the
compound. Find the structure. Show complete solutions.
Predicted 1H NMR Spectrum
4.7 4.6 4.5 4.4 4.3 4.2 4.1 4.0 3.9 3.8 3.7 3.6 3.5 3.4 3.3 3.2 3.1 3.0 2.9 2.8 2.7 2.6 2.5 2.4 2.3 2.2 2.1 2.0 1.9 1.8 1.7 1.6 1.5 1.4 1.3 1.2 1.1
f1 (ppm)
Predicted 13C NMR Spectrum
100
f1 (ppm)
30
220 210 200 190 180
170
160 150 140 130 120
110
90
80
70
-26
60
50
40
46
30
20
115
10
1.0 0.9 0.8
0
-10
Q: Arrange BCC and Fec
metals, in sequence from the
Fable (Dr. R's slides) and
Calculate Volume and Density.
Aa
BCC
V
52 5
SFCC
None
Chapter F Solutions
Chemical Principles: The Quest for Insight
Ch. F - Prob. A.1ASTCh. F - Prob. A.1BSTCh. F - Prob. A.2ASTCh. F - Prob. A.2BSTCh. F - Prob. A.3ASTCh. F - Prob. A.3BSTCh. F - Prob. A.4ASTCh. F - Prob. A.4BSTCh. F - Prob. A.5ASTCh. F - Prob. A.5BST
Ch. F - Prob. A.1ECh. F - Prob. A.2ECh. F - Prob. A.3ECh. F - Prob. A.4ECh. F - Prob. A.5ECh. F - Prob. A.6ECh. F - Prob. A.7ECh. F - Prob. A.8ECh. F - Prob. A.9ECh. F - Prob. A.10ECh. F - Prob. A.11ECh. F - Prob. A.12ECh. F - Prob. A.13ECh. F - Prob. A.14ECh. F - Prob. A.15ECh. F - Prob. A.16ECh. F - Prob. A.17ECh. F - Prob. A.18ECh. F - Prob. A.19ECh. F - Prob. A.20ECh. F - Prob. A.21ECh. F - Prob. A.22ECh. F - Prob. A.23ECh. F - Prob. A.24ECh. F - Prob. A.25ECh. F - Prob. A.26ECh. F - Prob. A.27ECh. F - Prob. A.28ECh. F - Prob. A.29ECh. F - Prob. A.30ECh. F - Prob. A.31ECh. F - Prob. A.32ECh. F - Prob. A.33ECh. F - Prob. A.34ECh. F - Prob. A.35ECh. F - Prob. A.36ECh. F - Prob. A.37ECh. F - Prob. A.38ECh. F - Prob. A.39ECh. F - Prob. A.40ECh. F - Prob. A.41ECh. F - Prob. A.42ECh. F - Prob. B.1ASTCh. F - Prob. B.1BSTCh. F - Prob. B.2ASTCh. F - Prob. B.2BSTCh. F - Prob. B.3ASTCh. F - Prob. B.3BSTCh. F - Prob. B.1ECh. F - Prob. B.2ECh. F - Prob. B.3ECh. F - Prob. B.4ECh. F - Prob. B.5ECh. F - Prob. B.6ECh. F - Prob. B.7ECh. F - Prob. B.8ECh. F - Prob. B.9ECh. F - Prob. B.10ECh. F - Prob. B.11ECh. F - Prob. B.12ECh. F - Prob. B.13ECh. F - Prob. B.14ECh. F - Prob. B.15ECh. F - Prob. B.16ECh. F - Prob. B.17ECh. F - Prob. B.18ECh. F - Prob. B.19ECh. F - Prob. B.20ECh. F - Prob. B.21ECh. F - Prob. B.22ECh. F - Prob. C.1ASTCh. F - Prob. C.1BSTCh. F - Prob. C.2ASTCh. F - Prob. C.2BSTCh. F - Prob. C.1ECh. F - Prob. C.2ECh. F - Prob. C.3ECh. F - Prob. C.4ECh. F - Prob. C.5ECh. F - Prob. C.6ECh. F - Prob. C.7ECh. F - Prob. C.8ECh. F - Prob. C.9ECh. F - Prob. C.10ECh. F - Prob. C.11ECh. F - Prob. C.12ECh. F - Prob. C.13ECh. F - Prob. C.14ECh. F - Prob. C.15ECh. F - Prob. C.16ECh. F - Prob. C.17ECh. F - Prob. C.18ECh. F - Prob. C.19ECh. F - Prob. C.20ECh. F - Prob. C.21ECh. F - Prob. C.22ECh. F - Prob. D.1ASTCh. F - Prob. D.1BSTCh. F - Prob. D.2ASTCh. F - Prob. D.2BSTCh. F - Prob. D.3ASTCh. F - Prob. D.3BSTCh. F - Prob. D.4ASTCh. F - Prob. D.4BSTCh. F - Prob. D.5ASTCh. F - Prob. D.5BSTCh. F - Prob. D.1ECh. F - Prob. D.2ECh. F - Prob. D.3ECh. F - Prob. D.4ECh. F - Prob. D.5ECh. F - Prob. D.6ECh. F - Prob. D.7ECh. F - Prob. D.8ECh. F - Prob. D.9ECh. F - Prob. D.10ECh. F - Prob. D.11ECh. F - Prob. D.12ECh. F - Prob. D.13ECh. F - Prob. D.14ECh. F - Prob. D.15ECh. F - Prob. D.16ECh. F - Prob. D.17ECh. F - Prob. D.18ECh. F - Prob. D.19ECh. F - Prob. D.20ECh. F - Prob. D.21ECh. F - Prob. D.22ECh. F - Prob. D.23ECh. F - Prob. D.24ECh. F - Prob. D.25ECh. F - Prob. D.26ECh. F - Prob. D.27ECh. F - Prob. D.28ECh. F - Prob. D.29ECh. F - Prob. D.30ECh. F - Prob. D.31ECh. F - Prob. D.32ECh. F - Prob. D.33ECh. F - Prob. D.34ECh. F - Prob. D.35ECh. F - Prob. D.36ECh. F - Prob. E.1ASTCh. F - Prob. E.1BSTCh. F - Prob. E.2ASTCh. F - Prob. E.2BSTCh. F - Prob. E.3ASTCh. F - Prob. E.3BSTCh. F - Prob. E.4ASTCh. F - Prob. E.4BSTCh. F - Prob. E.5ASTCh. F - Prob. E.5BSTCh. F - Prob. E.6ASTCh. F - Prob. E.6BSTCh. F - Prob. E.1ECh. F - Prob. E.2ECh. F - Prob. E.3ECh. F - Prob. E.4ECh. F - Prob. E.5ECh. F - Prob. E.6ECh. F - Prob. E.7ECh. F - Prob. E.8ECh. F - Prob. E.9ECh. F - Prob. E.10ECh. F - Prob. E.11ECh. F - Prob. E.12ECh. F - Prob. E.13ECh. F - Prob. E.14ECh. F - Prob. E.15ECh. F - Prob. E.16ECh. F - Prob. E.17ECh. F - Prob. E.18ECh. F - Prob. E.19ECh. F - Prob. E.20ECh. F - Prob. E.21ECh. F - Prob. E.22ECh. F - Prob. E.23ECh. F - Prob. E.24ECh. F - Prob. E.25ECh. F - Prob. E.26ECh. F - Prob. E.27ECh. F - Prob. E.28ECh. F - Prob. E.29ECh. F - Prob. E.30ECh. F - Prob. E.31ECh. F - Prob. E.32ECh. F - Prob. E.33ECh. F - Prob. E.34ECh. F - Prob. F.1ASTCh. F - Prob. F.1BSTCh. F - Prob. F.2ASTCh. F - Prob. F.2BSTCh. F - Prob. F.3ASTCh. F - Prob. F.3BSTCh. F - Prob. F.4ASTCh. F - Prob. F.4BSTCh. F - Prob. F.1ECh. F - Prob. F.2ECh. F - Prob. F.3ECh. F - Prob. F.4ECh. F - Prob. F.5ECh. F - Prob. F.6ECh. F - Prob. F.7ECh. F - Prob. F.8ECh. F - Prob. F.9ECh. F - Prob. F.10ECh. F - Prob. F.11ECh. F - Prob. F.12ECh. F - Prob. F.13ECh. F - Prob. F.14ECh. F - Prob. F.15ECh. F - Prob. F.16ECh. F - Prob. F.17ECh. F - Prob. F.18ECh. F - Prob. F.19ECh. F - Prob. F.20ECh. F - Prob. F.21ECh. F - Prob. F.22ECh. F - Prob. F.23ECh. F - Prob. F.24ECh. F - Prob. F.25ECh. F - Prob. F.26ECh. F - Prob. F.27ECh. F - Prob. F.28ECh. F - Prob. G.1ASTCh. F - Prob. G.1BSTCh. F - Prob. G.2ASTCh. F - Prob. G.2BSTCh. F - Prob. G.3ASTCh. F - Prob. G.3BSTCh. F - Prob. G.4ASTCh. F - Prob. G.4BSTCh. F - Prob. G.1ECh. F - Prob. G.2ECh. F - Prob. G.3ECh. F - Prob. G.4ECh. F - Prob. G.5ECh. F - Prob. G.6ECh. F - Prob. G.7ECh. F - Prob. G.8ECh. F - Prob. G.9ECh. F - Prob. G.10ECh. F - Prob. G.11ECh. F - Prob. G.12ECh. F - Prob. G.13ECh. F - Prob. G.14ECh. F - Prob. G.15ECh. F - Prob. G.16ECh. F - Prob. G.17ECh. F - Prob. G.18ECh. F - Prob. G.19ECh. F - Prob. G.20ECh. F - Prob. G.21ECh. F - Prob. G.22ECh. F - Prob. G.23ECh. F - Prob. G.24ECh. F - Prob. G.25ECh. F - Prob. G.27ECh. F - Prob. G.28ECh. F - Prob. G.30ECh. F - Prob. H.1ASTCh. F - Prob. H.1BSTCh. F - Prob. H.1ECh. F - Prob. H.2ECh. F - Prob. H.3ECh. F - Prob. H.4ECh. F - Prob. H.5ECh. F - Prob. H.6ECh. F - Prob. H.7ECh. F - Prob. H.8ECh. F - Prob. H.9ECh. F - Prob. H.10ECh. F - Prob. H.11ECh. F - Prob. H.12ECh. F - Prob. H.13ECh. F - Prob. H.14ECh. F - Prob. H.15ECh. F - Prob. H.16ECh. F - Prob. H.17ECh. F - Prob. H.18ECh. F - Prob. H.19ECh. F - Prob. H.20ECh. F - Prob. H.21ECh. F - Prob. H.22ECh. F - Prob. H.23ECh. F - Prob. H.24ECh. F - Prob. H.25ECh. F - Prob. H.26ECh. F - Prob. I.1ASTCh. F - Prob. I.1BSTCh. F - Prob. I.2ASTCh. F - Prob. I.2BSTCh. F - Prob. I.3ASTCh. F - Prob. I.3BSTCh. F - Prob. I.1ECh. F - Prob. I.2ECh. F - Prob. I.3ECh. F - Prob. I.4ECh. F - Prob. I.5ECh. F - Prob. I.6ECh. F - Prob. I.7ECh. F - Prob. I.8ECh. F - Prob. I.9ECh. F - Prob. I.10ECh. F - Prob. I.11ECh. F - Prob. I.12ECh. F - Prob. I.13ECh. F - Prob. I.14ECh. F - Prob. I.15ECh. F - Prob. I.16ECh. F - Prob. I.17ECh. F - Prob. I.18ECh. F - Prob. I.19ECh. F - Prob. I.20ECh. F - Prob. I.21ECh. F - Prob. I.22ECh. F - Prob. I.23ECh. F - Prob. I.24ECh. F - Prob. I.25ECh. F - Prob. I.26ECh. F - Prob. J.1ASTCh. F - Prob. J.1BSTCh. F - Prob. J.2ASTCh. F - Prob. J.2BSTCh. F - Prob. J.1ECh. F - Prob. J.2ECh. F - Prob. J.3ECh. F - Prob. J.4ECh. F - Prob. J.5ECh. F - Prob. J.6ECh. F - Prob. J.7ECh. F - Prob. J.8ECh. F - Prob. J.9ECh. F - Prob. J.10ECh. F - Prob. J.11ECh. F - Prob. J.12ECh. F - Prob. J.13ECh. F - Prob. J.14ECh. F - Prob. J.15ECh. F - Prob. J.16ECh. F - Prob. J.17ECh. F - Prob. J.18ECh. F - Prob. J.19ECh. F - Prob. J.20ECh. F - Prob. J.21ECh. F - Prob. J.22ECh. F - Prob. J.23ECh. F - Prob. J.24ECh. F - Prob. K.1ASTCh. F - Prob. K.1BSTCh. F - Prob. K.2ASTCh. F - Prob. K.2BSTCh. F - Prob. K.3ASTCh. F - Prob. K.3BSTCh. F - Prob. K.4ASTCh. F - Prob. K.4BSTCh. F - Prob. K.5ASTCh. F - Prob. K.5BSTCh. F - Prob. K.1ECh. F - Prob. K.2ECh. F - Prob. K.3ECh. F - Prob. K.4ECh. F - Prob. K.5ECh. F - Prob. K.6ECh. F - Prob. K.7ECh. F - Prob. K.8ECh. F - Prob. K.9ECh. F - Prob. K.10ECh. F - Prob. K.11ECh. F - Prob. K.12ECh. F - Prob. K.13ECh. F - Prob. K.14ECh. F - Prob. K.15ECh. F - Prob. K.16ECh. F - Prob. K.17ECh. F - Prob. K.18ECh. F - Prob. K.19ECh. F - Prob. K.20ECh. F - Prob. K.21ECh. F - Prob. K.22ECh. F - Prob. K.23ECh. F - Prob. K.24ECh. F - Prob. K.25ECh. F - Prob. K.26ECh. F - Prob. L.1ASTCh. F - Prob. L.1BSTCh. F - Prob. L.2ASTCh. F - Prob. L.2BSTCh. F - Prob. L.3ASTCh. F - Prob. L.3BSTCh. F - Prob. L.1ECh. F - Prob. L.2ECh. F - Prob. L.3ECh. F - Prob. L.4ECh. F - Prob. L.5ECh. F - Prob. L.6ECh. F - Prob. L.7ECh. F - Prob. L.8ECh. F - Prob. L.9ECh. F - Prob. L.10ECh. F - Prob. L.11ECh. F - Prob. L.12ECh. F - Prob. L.13ECh. F - Prob. L.14ECh. F - Prob. L.15ECh. F - Prob. L.16ECh. F - Prob. L.17ECh. F - Prob. L.18ECh. F - Prob. L.19ECh. F - Prob. L.20ECh. F - Prob. L.21ECh. F - Prob. L.22ECh. F - Prob. L.23ECh. F - Prob. L.24ECh. F - Prob. L.25ECh. F - Prob. L.29ECh. F - Prob. L.30ECh. F - Prob. L.31ECh. F - Prob. L.32ECh. F - Prob. L.33ECh. F - Prob. L.34ECh. F - Prob. L.35ECh. F - Prob. L.37ECh. F - Prob. L.38ECh. F - Prob. L.39ECh. F - Prob. L.40ECh. F - Prob. L.41ECh. F - Prob. L.42ECh. F - Prob. M.1ASTCh. F - Prob. M.1BSTCh. F - Prob. M.2ASTCh. F - Prob. M.2BSTCh. F - Prob. M.3ASTCh. F - Prob. M.3BSTCh. F - Prob. M.4ASTCh. F - Prob. M.4BSTCh. F - Prob. M.1ECh. F - Prob. M.2ECh. F - Prob. M.3ECh. F - Prob. M.4ECh. F - Prob. M.5ECh. F - Prob. M.6ECh. F - Prob. M.7ECh. F - Prob. M.8ECh. F - Prob. M.9ECh. F - Prob. M.10ECh. F - Prob. M.11ECh. F - Prob. M.12ECh. F - Prob. M.13ECh. F - Prob. M.14ECh. F - Prob. M.15ECh. F - Prob. M.16ECh. F - Prob. M.17ECh. F - Prob. M.18ECh. F - Prob. M.19ECh. F - Prob. M.20ECh. F - Prob. M.21ECh. F - Prob. M.22ECh. F - Prob. M.23ECh. F - Prob. M.25ECh. F - Prob. M.26ECh. F - Prob. M.27ECh. F - Prob. M.28E
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