Concept explainers
a) 2, 5, 5-Trimethyl-2-hexene
Interpretation:
The old name 2, 5, 5-trimethyl-2-hexene is to be changed to new, post-1993 name and its structure is to be given.
Concept introduction:
In 1993, The IUPAC changed its recommendations in naming the
To change:
The old name 2, 5, 5-trimethyl-2-hexene to the new, post-1993 name and to give its structure.
b) 2, 3-Dimethyl-1, 3-cyclohexadiene
Interpretation:
The old name 2, 3-dimethyl-1, 3-cyclohexadiene is to be changed to new, post-1993 name and its structure is to be given.
Concept introduction:
In 1993, The IUPAC changed its recommendations in naming the alkenes. As per the recommendations, the number indicating the position of double bond should be placed immediately before the – ene suffix instead of before the parent name.
To change:
The old name 2, 3-dimethyl-1, 3-cyclohexadiene to the new, post-1993 name and to give its structure.
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Chapter 7 Solutions
Organic Chemistry
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- Draw the structure and give the molecular formula for a compound(a) 1-ethyl-3-methylcycloheptanearrow_forwardWrite a complete chemical equation showing reactants, products, and catalysts needed(if any) for the following reaction and (2) Draw and name the organic compound found inevery reaction.(Use condensed structural formula) (A) Reaction of cis-3,3-Dimethyl-4-propylocta-1,5-diene with two mole of HBr(B) Reaction of trans-1-Bromo-3-chlorocyclopentane with potassium hydroxide(C) Formation of Gilman reagent using isopropyl bromidearrow_forwardWrite the Lewis structure and molecular formula for each of the following hydrocarbons:(a) hexane(b) 3-methylpentane(c) cis-3-hexene(d) 4-methyl-1-pentene(e) 3-hexyne(f) 4-methyl-2-pentynearrow_forward
- (1) Write a complete chemical equation showing reactants, products, and catalysts needed (if any) for the following reaction and (2) Draw and name the organic compound found in every reaction. (a) Complete hydrogenation of 2-Methylhexa-1,5-diene (b) Complete halogenation (Br2) of 3-Ethyl-2,2-dimethylhept-3-ene (c) Reaction of (4E)-2.4-Dimethylhexa-1,4-diene with a mole of water (d) Reaction of cis-3,3-Dimethyl-4-propylocta-1,5-diene with two mole of HBr (e) Reaction of trans-1-Bromo-3-chlorocyclopentane with potassium hydroxide (f) Formation of Gilman reagent using isopropyl bromide (g) Ozonolysis of 3,3-Dimethyloct-4-yne (h) Complete halogenation (Cl2) of 3-Ethyl-5-methyl-1,6,8-decatriyne (i) Partial hydrogenation using Lindlar's Catalyst 2,2,5,5-Tetramethylhex-3-yne (i) Reaction of 3.4-Dimethylcyclodecyne with sodium amidearrow_forwardIdentify any carbon atoms that change hybridization and the change in hybridization during the reactions in (a) 2-butene is treated with water in dilute acid(b) ethanol is dehydrated to yield ethenearrow_forwardTRUE OR FALSE (a) Both ethylene and acetylene are planar molecules. (b) An alkene in which each carbon of the double bond has two different groups bonded to it will show cis-trans isomerism. (c) Cis-trans isomers have the same molecular formula but a different connectivity of their atoms. (d) Cis-2-butene and trans -2-butene can be interconverted by rotation about the carbon–carbon double bond. (e) Cis-trans isomerism is possible only among appropriately substituted alkenes. (f) Both 2-hexene and 3-hexene can exist as pairs of cis-trans isomers. (g) Cyclohexene can exist as a pair of cis-trans isomers. (h) 1-Chloropropene can exist as a pair of cis-trans isomers.arrow_forward
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