a) Interpretation: The alkene that will give 1-bromocyclopentane in an addition reaction is to be identified. Concept introduction: In addition reactions small molecules like HCl, H 2 O, HBr etc. add to the double bond in an alkene to yield a single product. The addition to unsymmetrical alkenes will follow Markovnikov’s rule which states that “in the addition of HX to an alkene, the H adds to the carbon with fewer alkyl substituents and X adds to the carbon with more alkyl substituents”. To state: Which alkene will give 1-bromocyclopentane as product in an addition reaction.

Question

Find out what kind of reaction each alkene goes through. Figure out what the main products of each equation will be. Draw these things and name them.

Answer 1

Question

Chapter 7.8, Problem 17P

Interpretation Introduction

a)

Interpretation:

The alkene that will give 1-bromocyclopentane in an addition reaction is to be identified.

Concept introduction:

In addition reactions small molecules like HCl, H₂O, HBr etc. add to the double bond in an alkene to yield a single product. The addition to unsymmetrical alkenes will follow Markovnikov’s rule which states that “in the addition of HX to an alkene, the H adds to the carbon with fewer alkyl substituents and X adds to the carbon with more alkyl substituents”.

To state:

Which alkene will give 1-bromocyclopentane as product in an addition reaction.

Interpretation Introduction

b)

Interpretation:

The alkene that will give 1-ethyl-1-iodocyclopentane in an addition reaction is to be identified.

Concept introduction:

In addition reactions small molecules like HCl, H₂O, HBr etc. add to the double bond in an alkene to yield a single product. The addition to unsymmetrical alkenes will follow Markovnikov’s rule which states that “in the addition of HX to an alkene, the H adds to the carbon with fewer alkyl substituents and X adds to the carbon with more alkyl substituents”.

To state:

Which alkene will give 1-ethyl-1-iodocyclohexane as product in an addition reaction.

Interpretation Introduction

c)

Interpretation:

The alkene that will give 3-bromohexane in an addition reaction is to be identified.

Concept introduction:

In addition reactions small molecules like HCl, H₂O, HBr etc. add to the double bond in an alkene to yield a single product. The addition to unsymmetrical alkenes will follow Markovnikov’s rule which states that “in the addition of HX to an alkene, the H adds to the carbon with fewer alkyl substituents and X adds to the carbon with more alkyl substituents”.

To state:

Which alkene will give 3-bromohexane as product in an addition reaction.

Interpretation Introduction

d)

Interpretation:

The alkene that will give 1-chloroethylcyclopentane in an addition reaction is to be identified.

Concept introduction:

In addition reactions small molecules like HCl, H₂O, HBr etc. add to the double bond in an alkene to yield a single product. The addition to unsymmetrical alkenes will follow Markovnikov’s rule which states that “in the addition of HX to an alkene, the H adds to the carbon with fewer alkyl substituents and X adds to the carbon with more alkyl substituents”.

To state:

Which alkene will give 1-chloroethylcyclohexane as product in an addition reaction.

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Answer 2

Question

Chapter 7.8, Problem 17P

Interpretation Introduction

a)

Interpretation:

The alkene that will give 1-bromocyclopentane in an addition reaction is to be identified.

Concept introduction:

In addition reactions small molecules like HCl, H₂O, HBr etc. add to the double bond in an alkene to yield a single product. The addition to unsymmetrical alkenes will follow Markovnikov’s rule which states that “in the addition of HX to an alkene, the H adds to the carbon with fewer alkyl substituents and X adds to the carbon with more alkyl substituents”.

To state:

Which alkene will give 1-bromocyclopentane as product in an addition reaction.

Interpretation Introduction

b)

Interpretation:

The alkene that will give 1-ethyl-1-iodocyclopentane in an addition reaction is to be identified.

Concept introduction:

In addition reactions small molecules like HCl, H₂O, HBr etc. add to the double bond in an alkene to yield a single product. The addition to unsymmetrical alkenes will follow Markovnikov’s rule which states that “in the addition of HX to an alkene, the H adds to the carbon with fewer alkyl substituents and X adds to the carbon with more alkyl substituents”.

To state:

Which alkene will give 1-ethyl-1-iodocyclohexane as product in an addition reaction.

Interpretation Introduction

c)

Interpretation:

The alkene that will give 3-bromohexane in an addition reaction is to be identified.

Concept introduction:

In addition reactions small molecules like HCl, H₂O, HBr etc. add to the double bond in an alkene to yield a single product. The addition to unsymmetrical alkenes will follow Markovnikov’s rule which states that “in the addition of HX to an alkene, the H adds to the carbon with fewer alkyl substituents and X adds to the carbon with more alkyl substituents”.

To state:

Which alkene will give 3-bromohexane as product in an addition reaction.

Interpretation Introduction

d)

Interpretation:

The alkene that will give 1-chloroethylcyclopentane in an addition reaction is to be identified.

Concept introduction:

In addition reactions small molecules like HCl, H₂O, HBr etc. add to the double bond in an alkene to yield a single product. The addition to unsymmetrical alkenes will follow Markovnikov’s rule which states that “in the addition of HX to an alkene, the H adds to the carbon with fewer alkyl substituents and X adds to the carbon with more alkyl substituents”.

To state:

Which alkene will give 1-chloroethylcyclohexane as product in an addition reaction.

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Answer 3

Question

Chapter 7.8, Problem 17P

Interpretation Introduction

a)

Interpretation:

The alkene that will give 1-bromocyclopentane in an addition reaction is to be identified.

Concept introduction:

In addition reactions small molecules like HCl, H₂O, HBr etc. add to the double bond in an alkene to yield a single product. The addition to unsymmetrical alkenes will follow Markovnikov’s rule which states that “in the addition of HX to an alkene, the H adds to the carbon with fewer alkyl substituents and X adds to the carbon with more alkyl substituents”.

To state:

Which alkene will give 1-bromocyclopentane as product in an addition reaction.

Interpretation Introduction

b)

Interpretation:

The alkene that will give 1-ethyl-1-iodocyclopentane in an addition reaction is to be identified.

Concept introduction:

In addition reactions small molecules like HCl, H₂O, HBr etc. add to the double bond in an alkene to yield a single product. The addition to unsymmetrical alkenes will follow Markovnikov’s rule which states that “in the addition of HX to an alkene, the H adds to the carbon with fewer alkyl substituents and X adds to the carbon with more alkyl substituents”.

To state:

Which alkene will give 1-ethyl-1-iodocyclohexane as product in an addition reaction.

Interpretation Introduction

c)

Interpretation:

The alkene that will give 3-bromohexane in an addition reaction is to be identified.

Concept introduction:

In addition reactions small molecules like HCl, H₂O, HBr etc. add to the double bond in an alkene to yield a single product. The addition to unsymmetrical alkenes will follow Markovnikov’s rule which states that “in the addition of HX to an alkene, the H adds to the carbon with fewer alkyl substituents and X adds to the carbon with more alkyl substituents”.

To state:

Which alkene will give 3-bromohexane as product in an addition reaction.

Interpretation Introduction

d)

Interpretation:

The alkene that will give 1-chloroethylcyclopentane in an addition reaction is to be identified.

Concept introduction:

In addition reactions small molecules like HCl, H₂O, HBr etc. add to the double bond in an alkene to yield a single product. The addition to unsymmetrical alkenes will follow Markovnikov’s rule which states that “in the addition of HX to an alkene, the H adds to the carbon with fewer alkyl substituents and X adds to the carbon with more alkyl substituents”.

To state:

Which alkene will give 1-chloroethylcyclohexane as product in an addition reaction.

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Answer 4

Question

Chapter 7.8, Problem 17P

Interpretation Introduction

a)

Interpretation:

The alkene that will give 1-bromocyclopentane in an addition reaction is to be identified.

Concept introduction:

In addition reactions small molecules like HCl, H₂O, HBr etc. add to the double bond in an alkene to yield a single product. The addition to unsymmetrical alkenes will follow Markovnikov’s rule which states that “in the addition of HX to an alkene, the H adds to the carbon with fewer alkyl substituents and X adds to the carbon with more alkyl substituents”.

To state:

Which alkene will give 1-bromocyclopentane as product in an addition reaction.

Interpretation Introduction

b)

Interpretation:

The alkene that will give 1-ethyl-1-iodocyclopentane in an addition reaction is to be identified.

Concept introduction:

In addition reactions small molecules like HCl, H₂O, HBr etc. add to the double bond in an alkene to yield a single product. The addition to unsymmetrical alkenes will follow Markovnikov’s rule which states that “in the addition of HX to an alkene, the H adds to the carbon with fewer alkyl substituents and X adds to the carbon with more alkyl substituents”.

To state:

Which alkene will give 1-ethyl-1-iodocyclohexane as product in an addition reaction.

Interpretation Introduction

c)

Interpretation:

The alkene that will give 3-bromohexane in an addition reaction is to be identified.

Concept introduction:

In addition reactions small molecules like HCl, H₂O, HBr etc. add to the double bond in an alkene to yield a single product. The addition to unsymmetrical alkenes will follow Markovnikov’s rule which states that “in the addition of HX to an alkene, the H adds to the carbon with fewer alkyl substituents and X adds to the carbon with more alkyl substituents”.

To state:

Which alkene will give 3-bromohexane as product in an addition reaction.

Interpretation Introduction

d)

Interpretation:

The alkene that will give 1-chloroethylcyclopentane in an addition reaction is to be identified.

Concept introduction:

In addition reactions small molecules like HCl, H₂O, HBr etc. add to the double bond in an alkene to yield a single product. The addition to unsymmetrical alkenes will follow Markovnikov’s rule which states that “in the addition of HX to an alkene, the H adds to the carbon with fewer alkyl substituents and X adds to the carbon with more alkyl substituents”.

To state:

Which alkene will give 1-chloroethylcyclohexane as product in an addition reaction.

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Answer 5

Chapter 7.8, Problem 17P

Interpretation Introduction

a)

Interpretation:

The alkene that will give 1-bromocyclopentane in an addition reaction is to be identified.

Concept introduction:

In addition reactions small molecules like HCl, H₂O, HBr etc. add to the double bond in an alkene to yield a single product. The addition to unsymmetrical alkenes will follow Markovnikov’s rule which states that “in the addition of HX to an alkene, the H adds to the carbon with fewer alkyl substituents and X adds to the carbon with more alkyl substituents”.

To state:

Which alkene will give 1-bromocyclopentane as product in an addition reaction.

Interpretation Introduction

b)

Interpretation:

The alkene that will give 1-ethyl-1-iodocyclopentane in an addition reaction is to be identified.

Concept introduction:

In addition reactions small molecules like HCl, H₂O, HBr etc. add to the double bond in an alkene to yield a single product. The addition to unsymmetrical alkenes will follow Markovnikov’s rule which states that “in the addition of HX to an alkene, the H adds to the carbon with fewer alkyl substituents and X adds to the carbon with more alkyl substituents”.

To state:

Which alkene will give 1-ethyl-1-iodocyclohexane as product in an addition reaction.

Interpretation Introduction

c)

Interpretation:

The alkene that will give 3-bromohexane in an addition reaction is to be identified.

Concept introduction:

In addition reactions small molecules like HCl, H₂O, HBr etc. add to the double bond in an alkene to yield a single product. The addition to unsymmetrical alkenes will follow Markovnikov’s rule which states that “in the addition of HX to an alkene, the H adds to the carbon with fewer alkyl substituents and X adds to the carbon with more alkyl substituents”.

To state:

Which alkene will give 3-bromohexane as product in an addition reaction.

Interpretation Introduction

d)

Interpretation:

The alkene that will give 1-chloroethylcyclopentane in an addition reaction is to be identified.

Concept introduction:

In addition reactions small molecules like HCl, H₂O, HBr etc. add to the double bond in an alkene to yield a single product. The addition to unsymmetrical alkenes will follow Markovnikov’s rule which states that “in the addition of HX to an alkene, the H adds to the carbon with fewer alkyl substituents and X adds to the carbon with more alkyl substituents”.

To state:

Which alkene will give 1-chloroethylcyclohexane as product in an addition reaction.

Answer 6

Chapter 7.8, Problem 17P

Interpretation Introduction

a)

Interpretation:

The alkene that will give 1-bromocyclopentane in an addition reaction is to be identified.

Concept introduction:

In addition reactions small molecules like HCl, H₂O, HBr etc. add to the double bond in an alkene to yield a single product. The addition to unsymmetrical alkenes will follow Markovnikov’s rule which states that “in the addition of HX to an alkene, the H adds to the carbon with fewer alkyl substituents and X adds to the carbon with more alkyl substituents”.

To state:

Which alkene will give 1-bromocyclopentane as product in an addition reaction.

Answer 7

Chapter 7.8, Problem 17P

Interpretation Introduction

a)

Interpretation:

The alkene that will give 1-bromocyclopentane in an addition reaction is to be identified.

Concept introduction:

In addition reactions small molecules like HCl, H₂O, HBr etc. add to the double bond in an alkene to yield a single product. The addition to unsymmetrical alkenes will follow Markovnikov’s rule which states that “in the addition of HX to an alkene, the H adds to the carbon with fewer alkyl substituents and X adds to the carbon with more alkyl substituents”.

To state:

Which alkene will give 1-bromocyclopentane as product in an addition reaction.

Answer 8

Interpretation Introduction

b)

Interpretation:

The alkene that will give 1-ethyl-1-iodocyclopentane in an addition reaction is to be identified.

Concept introduction:

In addition reactions small molecules like HCl, H₂O, HBr etc. add to the double bond in an alkene to yield a single product. The addition to unsymmetrical alkenes will follow Markovnikov’s rule which states that “in the addition of HX to an alkene, the H adds to the carbon with fewer alkyl substituents and X adds to the carbon with more alkyl substituents”.

To state:

Which alkene will give 1-ethyl-1-iodocyclohexane as product in an addition reaction.

Answer 9

Interpretation Introduction

b)

Interpretation:

The alkene that will give 1-ethyl-1-iodocyclopentane in an addition reaction is to be identified.

Concept introduction:

In addition reactions small molecules like HCl, H₂O, HBr etc. add to the double bond in an alkene to yield a single product. The addition to unsymmetrical alkenes will follow Markovnikov’s rule which states that “in the addition of HX to an alkene, the H adds to the carbon with fewer alkyl substituents and X adds to the carbon with more alkyl substituents”.

To state:

Which alkene will give 1-ethyl-1-iodocyclohexane as product in an addition reaction.

Answer 10

Interpretation Introduction

c)

Interpretation:

The alkene that will give 3-bromohexane in an addition reaction is to be identified.

Concept introduction:

In addition reactions small molecules like HCl, H₂O, HBr etc. add to the double bond in an alkene to yield a single product. The addition to unsymmetrical alkenes will follow Markovnikov’s rule which states that “in the addition of HX to an alkene, the H adds to the carbon with fewer alkyl substituents and X adds to the carbon with more alkyl substituents”.

To state:

Which alkene will give 3-bromohexane as product in an addition reaction.

Answer 11

Interpretation Introduction

c)

Interpretation:

The alkene that will give 3-bromohexane in an addition reaction is to be identified.

Concept introduction:

In addition reactions small molecules like HCl, H₂O, HBr etc. add to the double bond in an alkene to yield a single product. The addition to unsymmetrical alkenes will follow Markovnikov’s rule which states that “in the addition of HX to an alkene, the H adds to the carbon with fewer alkyl substituents and X adds to the carbon with more alkyl substituents”.

To state:

Which alkene will give 3-bromohexane as product in an addition reaction.

Answer 12

Interpretation Introduction

d)

Interpretation:

The alkene that will give 1-chloroethylcyclopentane in an addition reaction is to be identified.

Concept introduction:

In addition reactions small molecules like HCl, H₂O, HBr etc. add to the double bond in an alkene to yield a single product. The addition to unsymmetrical alkenes will follow Markovnikov’s rule which states that “in the addition of HX to an alkene, the H adds to the carbon with fewer alkyl substituents and X adds to the carbon with more alkyl substituents”.

To state:

Which alkene will give 1-chloroethylcyclohexane as product in an addition reaction.

Answer 13

Interpretation Introduction

d)

Interpretation:

The alkene that will give 1-chloroethylcyclopentane in an addition reaction is to be identified.

Concept introduction:

In addition reactions small molecules like HCl, H₂O, HBr etc. add to the double bond in an alkene to yield a single product. The addition to unsymmetrical alkenes will follow Markovnikov’s rule which states that “in the addition of HX to an alkene, the H adds to the carbon with fewer alkyl substituents and X adds to the carbon with more alkyl substituents”.

To state:

Which alkene will give 1-chloroethylcyclohexane as product in an addition reaction.

Answer 14

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Answer 15

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Answer 25

Ch. 7.2 - Calculate the degree of unsaturation in each of...Ch. 7.2 - Prob. 2P Ch. 7.2 - Diazepam, marketed as an antianxiety medication...Ch. 7.3 - Give IUPAC names for the following compounds:Ch. 7.3 - Prob. 5P Ch. 7.3 - Prob. 6P Ch. 7.3 - Prob. 7P Ch. 7.4 - Prob. 8P Ch. 7.4 - Prob. 9P Ch. 7.4 - Prob. 10P

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