a) Interpretation: To assign E or Z configuration for the compound given. Concept introduction: The member that ranks higher can be determined by considering the atomic number of the first atom of the two substituents separately. The atom with highest atomic number gets a higher rank. If a decision cannot be made by considering the atomic number of the first atom in each substituent then the second, third, fourth atoms away from double bond are considered until the first difference is found. Multiple bonded atoms are considered as equivalent to the same number of single bonded atoms. The isomer that has the higher ranked groups on each carbon are on the same side of the double bond is said to have Z configuration. If the higher ranked groups are on opposite sides, the alkene is said to have E configuration. To assign: The configuration for the compound given as E or Z.

Question

Determine the isomeric relationships between the following compounds. The possible relationships are identical, enantiomers, diastereomers, no relationships, and structural isomers. - D, H - A, C - B, E - G,F - E,F - A, H - B, F

Answer 1

Question

Chapter 7.SE, Problem 46AP

Interpretation Introduction

a)

Interpretation:

To assign E or Z configuration for the compound given.

Concept introduction:

The member that ranks higher can be determined by considering the atomic number of the first atom of the two substituents separately. The atom with highest atomic number gets a higher rank. If a decision cannot be made by considering the atomic number of the first atom in each substituent then the second, third, fourth atoms away from double bond are considered until the first difference is found. Multiple bonded atoms are considered as equivalent to the same number of single bonded atoms. The isomer that has the higher ranked groups on each carbon are on the same side of the double bond is said to have Z configuration. If the higher ranked groups are on opposite sides, the alkene is said to have E configuration.

To assign:

The configuration for the compound given as E or Z.

Interpretation Introduction

b)

Interpretation:

To assign E or Z configuration for the compound given.

Concept introduction:

The member that ranks higher can be determined by considering the atomic number of the first atom of the two substituents separately. The atom with highest atomic number gets a higher rank. If a decision cannot be made by considering the atomic number of the first atom in each substituent then the second, third, fourth atoms away from double bond are considered until the first difference is found. Multiple bonded atoms are considered as equivalent to the same number of single bonded atoms. The isomer that has the higher ranked groups on each carbon are on the same side of the double bond is said to have Z configuration. If the higher ranked groups are on opposite sides, the alkene is said to have E configuration.

To assign:

The configuration for the compound given as E or Z.

Interpretation Introduction

c)

Interpretation:

To assign E or Z configuration for the compound given.

Concept introduction:

The member that ranks higher can be determined by considering the atomic number of the first atom of the two substituents separately. The atom with highest atomic number gets a higher rank. If a decision cannot be made by considering the atomic number of the first atom in each substituent then the second, third, fourth atoms away from double bond are considered until the first difference is found. Multiple bonded atoms are considered as equivalent to the same number of single bonded atoms. The isomer that has the higher ranked groups on each carbon are on the same side of the double bond is said to have Z configuration. If the higher ranked groups are on opposite sides, the alkene is said to have E configuration.

To assign:

The configuration for the compound given as E or Z.

Interpretation Introduction

d)

Interpretation:

To assign E or Z configuration for the compound given.

Concept introduction:

The member that ranks higher can be determined by considering the atomic number of the first atom of the two substituents separately. The atom with highest atomic number gets a higher rank. If a decision cannot be made by considering the atomic number of the first atom in each substituent then the second, third, fourth atoms away from double bond are considered until the first difference is found. Multiple bonded atoms are considered as equivalent to the same number of single bonded atoms. The isomer that has the higher ranked groups on each carbon are on the same side of the double bond is said to have Z configuration. If the higher ranked groups are on opposite sides, the alkene is said to have E configuration.

To assign:

The configuration for the compound given as E or Z.

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Determine the isomeric relationships between the following compounds. The possible relationships are identical, enantiomers, diastereomers, no relationships, and structural isomers. - D, H - A, C - B, E - G,F - E,F - A, H - B, F

Classify the following pair of compounds as the same compound, enantiomers, diastereomers, constitutional isomers, or not isomeric. Also, select the correct IUPAC name, including the correct (R) or (S) designation, for each same compound enantiomers Н Н diastereomers с constitutional isomers not isomeric The correct IUPAC names are: Compound I: (2s,3S)-2,3-dichlorobutane, Compound I: (2R,3R)-2,3-dichlorobutane Compound I: (2R,3S)-2,3-dichlorobutane, Compound ll: (2s,3R)-2,3-dchlorobutane Compound I: (2R3R)-2,3-dichlorobutane, Compound l: (2R,3S)-2,3-dichlorobutane Compound I: (2S,3R)-2,3-dichlorobutane, Compound I: (2R,3S)-2,3-dichlorobutane

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Answer 2

Question

Chapter 7.SE, Problem 46AP

Interpretation Introduction

a)

Interpretation:

To assign E or Z configuration for the compound given.

Concept introduction:

The member that ranks higher can be determined by considering the atomic number of the first atom of the two substituents separately. The atom with highest atomic number gets a higher rank. If a decision cannot be made by considering the atomic number of the first atom in each substituent then the second, third, fourth atoms away from double bond are considered until the first difference is found. Multiple bonded atoms are considered as equivalent to the same number of single bonded atoms. The isomer that has the higher ranked groups on each carbon are on the same side of the double bond is said to have Z configuration. If the higher ranked groups are on opposite sides, the alkene is said to have E configuration.

To assign:

The configuration for the compound given as E or Z.

Interpretation Introduction

b)

Interpretation:

To assign E or Z configuration for the compound given.

Concept introduction:

The member that ranks higher can be determined by considering the atomic number of the first atom of the two substituents separately. The atom with highest atomic number gets a higher rank. If a decision cannot be made by considering the atomic number of the first atom in each substituent then the second, third, fourth atoms away from double bond are considered until the first difference is found. Multiple bonded atoms are considered as equivalent to the same number of single bonded atoms. The isomer that has the higher ranked groups on each carbon are on the same side of the double bond is said to have Z configuration. If the higher ranked groups are on opposite sides, the alkene is said to have E configuration.

To assign:

The configuration for the compound given as E or Z.

Interpretation Introduction

c)

Interpretation:

To assign E or Z configuration for the compound given.

Concept introduction:

The member that ranks higher can be determined by considering the atomic number of the first atom of the two substituents separately. The atom with highest atomic number gets a higher rank. If a decision cannot be made by considering the atomic number of the first atom in each substituent then the second, third, fourth atoms away from double bond are considered until the first difference is found. Multiple bonded atoms are considered as equivalent to the same number of single bonded atoms. The isomer that has the higher ranked groups on each carbon are on the same side of the double bond is said to have Z configuration. If the higher ranked groups are on opposite sides, the alkene is said to have E configuration.

To assign:

The configuration for the compound given as E or Z.

Interpretation Introduction

d)

Interpretation:

To assign E or Z configuration for the compound given.

Concept introduction:

The member that ranks higher can be determined by considering the atomic number of the first atom of the two substituents separately. The atom with highest atomic number gets a higher rank. If a decision cannot be made by considering the atomic number of the first atom in each substituent then the second, third, fourth atoms away from double bond are considered until the first difference is found. Multiple bonded atoms are considered as equivalent to the same number of single bonded atoms. The isomer that has the higher ranked groups on each carbon are on the same side of the double bond is said to have Z configuration. If the higher ranked groups are on opposite sides, the alkene is said to have E configuration.

To assign:

The configuration for the compound given as E or Z.

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Answer 3

Question

Chapter 7.SE, Problem 46AP

Interpretation Introduction

a)

Interpretation:

To assign E or Z configuration for the compound given.

Concept introduction:

The member that ranks higher can be determined by considering the atomic number of the first atom of the two substituents separately. The atom with highest atomic number gets a higher rank. If a decision cannot be made by considering the atomic number of the first atom in each substituent then the second, third, fourth atoms away from double bond are considered until the first difference is found. Multiple bonded atoms are considered as equivalent to the same number of single bonded atoms. The isomer that has the higher ranked groups on each carbon are on the same side of the double bond is said to have Z configuration. If the higher ranked groups are on opposite sides, the alkene is said to have E configuration.

To assign:

The configuration for the compound given as E or Z.

Interpretation Introduction

b)

Interpretation:

To assign E or Z configuration for the compound given.

Concept introduction:

The member that ranks higher can be determined by considering the atomic number of the first atom of the two substituents separately. The atom with highest atomic number gets a higher rank. If a decision cannot be made by considering the atomic number of the first atom in each substituent then the second, third, fourth atoms away from double bond are considered until the first difference is found. Multiple bonded atoms are considered as equivalent to the same number of single bonded atoms. The isomer that has the higher ranked groups on each carbon are on the same side of the double bond is said to have Z configuration. If the higher ranked groups are on opposite sides, the alkene is said to have E configuration.

To assign:

The configuration for the compound given as E or Z.

Interpretation Introduction

c)

Interpretation:

To assign E or Z configuration for the compound given.

Concept introduction:

The member that ranks higher can be determined by considering the atomic number of the first atom of the two substituents separately. The atom with highest atomic number gets a higher rank. If a decision cannot be made by considering the atomic number of the first atom in each substituent then the second, third, fourth atoms away from double bond are considered until the first difference is found. Multiple bonded atoms are considered as equivalent to the same number of single bonded atoms. The isomer that has the higher ranked groups on each carbon are on the same side of the double bond is said to have Z configuration. If the higher ranked groups are on opposite sides, the alkene is said to have E configuration.

To assign:

The configuration for the compound given as E or Z.

Interpretation Introduction

d)

Interpretation:

To assign E or Z configuration for the compound given.

Concept introduction:

The member that ranks higher can be determined by considering the atomic number of the first atom of the two substituents separately. The atom with highest atomic number gets a higher rank. If a decision cannot be made by considering the atomic number of the first atom in each substituent then the second, third, fourth atoms away from double bond are considered until the first difference is found. Multiple bonded atoms are considered as equivalent to the same number of single bonded atoms. The isomer that has the higher ranked groups on each carbon are on the same side of the double bond is said to have Z configuration. If the higher ranked groups are on opposite sides, the alkene is said to have E configuration.

To assign:

The configuration for the compound given as E or Z.

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Answer 4

Question

Chapter 7.SE, Problem 46AP

Interpretation Introduction

a)

Interpretation:

To assign E or Z configuration for the compound given.

Concept introduction:

The member that ranks higher can be determined by considering the atomic number of the first atom of the two substituents separately. The atom with highest atomic number gets a higher rank. If a decision cannot be made by considering the atomic number of the first atom in each substituent then the second, third, fourth atoms away from double bond are considered until the first difference is found. Multiple bonded atoms are considered as equivalent to the same number of single bonded atoms. The isomer that has the higher ranked groups on each carbon are on the same side of the double bond is said to have Z configuration. If the higher ranked groups are on opposite sides, the alkene is said to have E configuration.

To assign:

The configuration for the compound given as E or Z.

Interpretation Introduction

b)

Interpretation:

To assign E or Z configuration for the compound given.

Concept introduction:

The member that ranks higher can be determined by considering the atomic number of the first atom of the two substituents separately. The atom with highest atomic number gets a higher rank. If a decision cannot be made by considering the atomic number of the first atom in each substituent then the second, third, fourth atoms away from double bond are considered until the first difference is found. Multiple bonded atoms are considered as equivalent to the same number of single bonded atoms. The isomer that has the higher ranked groups on each carbon are on the same side of the double bond is said to have Z configuration. If the higher ranked groups are on opposite sides, the alkene is said to have E configuration.

To assign:

The configuration for the compound given as E or Z.

Interpretation Introduction

c)

Interpretation:

To assign E or Z configuration for the compound given.

Concept introduction:

The member that ranks higher can be determined by considering the atomic number of the first atom of the two substituents separately. The atom with highest atomic number gets a higher rank. If a decision cannot be made by considering the atomic number of the first atom in each substituent then the second, third, fourth atoms away from double bond are considered until the first difference is found. Multiple bonded atoms are considered as equivalent to the same number of single bonded atoms. The isomer that has the higher ranked groups on each carbon are on the same side of the double bond is said to have Z configuration. If the higher ranked groups are on opposite sides, the alkene is said to have E configuration.

To assign:

The configuration for the compound given as E or Z.

Interpretation Introduction

d)

Interpretation:

To assign E or Z configuration for the compound given.

Concept introduction:

The member that ranks higher can be determined by considering the atomic number of the first atom of the two substituents separately. The atom with highest atomic number gets a higher rank. If a decision cannot be made by considering the atomic number of the first atom in each substituent then the second, third, fourth atoms away from double bond are considered until the first difference is found. Multiple bonded atoms are considered as equivalent to the same number of single bonded atoms. The isomer that has the higher ranked groups on each carbon are on the same side of the double bond is said to have Z configuration. If the higher ranked groups are on opposite sides, the alkene is said to have E configuration.

To assign:

The configuration for the compound given as E or Z.

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Answer 5

Chapter 7.SE, Problem 46AP

Interpretation Introduction

a)

Interpretation:

To assign E or Z configuration for the compound given.

Concept introduction:

The member that ranks higher can be determined by considering the atomic number of the first atom of the two substituents separately. The atom with highest atomic number gets a higher rank. If a decision cannot be made by considering the atomic number of the first atom in each substituent then the second, third, fourth atoms away from double bond are considered until the first difference is found. Multiple bonded atoms are considered as equivalent to the same number of single bonded atoms. The isomer that has the higher ranked groups on each carbon are on the same side of the double bond is said to have Z configuration. If the higher ranked groups are on opposite sides, the alkene is said to have E configuration.

To assign:

The configuration for the compound given as E or Z.

Interpretation Introduction

b)

Interpretation:

To assign E or Z configuration for the compound given.

Concept introduction:

The member that ranks higher can be determined by considering the atomic number of the first atom of the two substituents separately. The atom with highest atomic number gets a higher rank. If a decision cannot be made by considering the atomic number of the first atom in each substituent then the second, third, fourth atoms away from double bond are considered until the first difference is found. Multiple bonded atoms are considered as equivalent to the same number of single bonded atoms. The isomer that has the higher ranked groups on each carbon are on the same side of the double bond is said to have Z configuration. If the higher ranked groups are on opposite sides, the alkene is said to have E configuration.

To assign:

The configuration for the compound given as E or Z.

Interpretation Introduction

c)

Interpretation:

To assign E or Z configuration for the compound given.

Concept introduction:

The member that ranks higher can be determined by considering the atomic number of the first atom of the two substituents separately. The atom with highest atomic number gets a higher rank. If a decision cannot be made by considering the atomic number of the first atom in each substituent then the second, third, fourth atoms away from double bond are considered until the first difference is found. Multiple bonded atoms are considered as equivalent to the same number of single bonded atoms. The isomer that has the higher ranked groups on each carbon are on the same side of the double bond is said to have Z configuration. If the higher ranked groups are on opposite sides, the alkene is said to have E configuration.

To assign:

The configuration for the compound given as E or Z.

Interpretation Introduction

d)

Interpretation:

To assign E or Z configuration for the compound given.

Concept introduction:

The member that ranks higher can be determined by considering the atomic number of the first atom of the two substituents separately. The atom with highest atomic number gets a higher rank. If a decision cannot be made by considering the atomic number of the first atom in each substituent then the second, third, fourth atoms away from double bond are considered until the first difference is found. Multiple bonded atoms are considered as equivalent to the same number of single bonded atoms. The isomer that has the higher ranked groups on each carbon are on the same side of the double bond is said to have Z configuration. If the higher ranked groups are on opposite sides, the alkene is said to have E configuration.

To assign:

The configuration for the compound given as E or Z.

Answer 6

Chapter 7.SE, Problem 46AP

Interpretation Introduction

a)

Interpretation:

To assign E or Z configuration for the compound given.

Concept introduction:

The member that ranks higher can be determined by considering the atomic number of the first atom of the two substituents separately. The atom with highest atomic number gets a higher rank. If a decision cannot be made by considering the atomic number of the first atom in each substituent then the second, third, fourth atoms away from double bond are considered until the first difference is found. Multiple bonded atoms are considered as equivalent to the same number of single bonded atoms. The isomer that has the higher ranked groups on each carbon are on the same side of the double bond is said to have Z configuration. If the higher ranked groups are on opposite sides, the alkene is said to have E configuration.

To assign:

The configuration for the compound given as E or Z.

Answer 7

Chapter 7.SE, Problem 46AP

Interpretation Introduction

a)

Interpretation:

To assign E or Z configuration for the compound given.

Concept introduction:

The member that ranks higher can be determined by considering the atomic number of the first atom of the two substituents separately. The atom with highest atomic number gets a higher rank. If a decision cannot be made by considering the atomic number of the first atom in each substituent then the second, third, fourth atoms away from double bond are considered until the first difference is found. Multiple bonded atoms are considered as equivalent to the same number of single bonded atoms. The isomer that has the higher ranked groups on each carbon are on the same side of the double bond is said to have Z configuration. If the higher ranked groups are on opposite sides, the alkene is said to have E configuration.

To assign:

The configuration for the compound given as E or Z.

Answer 8

Interpretation Introduction

b)

Interpretation:

To assign E or Z configuration for the compound given.

Concept introduction:

The member that ranks higher can be determined by considering the atomic number of the first atom of the two substituents separately. The atom with highest atomic number gets a higher rank. If a decision cannot be made by considering the atomic number of the first atom in each substituent then the second, third, fourth atoms away from double bond are considered until the first difference is found. Multiple bonded atoms are considered as equivalent to the same number of single bonded atoms. The isomer that has the higher ranked groups on each carbon are on the same side of the double bond is said to have Z configuration. If the higher ranked groups are on opposite sides, the alkene is said to have E configuration.

To assign:

The configuration for the compound given as E or Z.

Answer 9

Interpretation Introduction

b)

Interpretation:

To assign E or Z configuration for the compound given.

Concept introduction:

The member that ranks higher can be determined by considering the atomic number of the first atom of the two substituents separately. The atom with highest atomic number gets a higher rank. If a decision cannot be made by considering the atomic number of the first atom in each substituent then the second, third, fourth atoms away from double bond are considered until the first difference is found. Multiple bonded atoms are considered as equivalent to the same number of single bonded atoms. The isomer that has the higher ranked groups on each carbon are on the same side of the double bond is said to have Z configuration. If the higher ranked groups are on opposite sides, the alkene is said to have E configuration.

To assign:

The configuration for the compound given as E or Z.

Answer 10

Interpretation Introduction

c)

Interpretation:

To assign E or Z configuration for the compound given.

Concept introduction:

The member that ranks higher can be determined by considering the atomic number of the first atom of the two substituents separately. The atom with highest atomic number gets a higher rank. If a decision cannot be made by considering the atomic number of the first atom in each substituent then the second, third, fourth atoms away from double bond are considered until the first difference is found. Multiple bonded atoms are considered as equivalent to the same number of single bonded atoms. The isomer that has the higher ranked groups on each carbon are on the same side of the double bond is said to have Z configuration. If the higher ranked groups are on opposite sides, the alkene is said to have E configuration.

To assign:

The configuration for the compound given as E or Z.

Answer 11

Interpretation Introduction

c)

Interpretation:

To assign E or Z configuration for the compound given.

Concept introduction:

The member that ranks higher can be determined by considering the atomic number of the first atom of the two substituents separately. The atom with highest atomic number gets a higher rank. If a decision cannot be made by considering the atomic number of the first atom in each substituent then the second, third, fourth atoms away from double bond are considered until the first difference is found. Multiple bonded atoms are considered as equivalent to the same number of single bonded atoms. The isomer that has the higher ranked groups on each carbon are on the same side of the double bond is said to have Z configuration. If the higher ranked groups are on opposite sides, the alkene is said to have E configuration.

To assign:

The configuration for the compound given as E or Z.

Answer 12

Interpretation Introduction

d)

Interpretation:

To assign E or Z configuration for the compound given.

Concept introduction:

The member that ranks higher can be determined by considering the atomic number of the first atom of the two substituents separately. The atom with highest atomic number gets a higher rank. If a decision cannot be made by considering the atomic number of the first atom in each substituent then the second, third, fourth atoms away from double bond are considered until the first difference is found. Multiple bonded atoms are considered as equivalent to the same number of single bonded atoms. The isomer that has the higher ranked groups on each carbon are on the same side of the double bond is said to have Z configuration. If the higher ranked groups are on opposite sides, the alkene is said to have E configuration.

To assign:

The configuration for the compound given as E or Z.

Answer 13

Interpretation Introduction

d)

Interpretation:

To assign E or Z configuration for the compound given.

Concept introduction:

The member that ranks higher can be determined by considering the atomic number of the first atom of the two substituents separately. The atom with highest atomic number gets a higher rank. If a decision cannot be made by considering the atomic number of the first atom in each substituent then the second, third, fourth atoms away from double bond are considered until the first difference is found. Multiple bonded atoms are considered as equivalent to the same number of single bonded atoms. The isomer that has the higher ranked groups on each carbon are on the same side of the double bond is said to have Z configuration. If the higher ranked groups are on opposite sides, the alkene is said to have E configuration.

To assign:

The configuration for the compound given as E or Z.

Answer 14

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Answer 25

Ch. 7.2 - Calculate the degree of unsaturation in each of...Ch. 7.2 - Prob. 2P Ch. 7.2 - Diazepam, marketed as an antianxiety medication...Ch. 7.3 - Give IUPAC names for the following compounds:Ch. 7.3 - Prob. 5P Ch. 7.3 - Prob. 6P Ch. 7.3 - Prob. 7P Ch. 7.4 - Prob. 8P Ch. 7.4 - Prob. 9P Ch. 7.4 - Prob. 10P

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