a) -CH 3 , -OH, -H, -Cl Interpretation: The substituents in the set, -CH 3 , -OH, -H, -Cl, are to be ranked according to the sequence rules. Concept introduction: The member that ranks higher can be determined by considering the atomic number of the first atom in each substituent. The atom with highest atomic number gets the higher rank. If a decision cannot be made by considering the atomic number of the first atom in each substituent then the second, third, fourth atoms can be considered until the first difference is found. Multiple bonded atoms are considered as equivalent to the same number of single bonded atoms. To rank: The substituents in the set, -CH 3 , -OH, -H, -Cl, according to the sequence rules.

Question

Q2 Give the stereochemical relationships between each pair of structures. Examples are same compound, structural isomers, enantiomers, diastereomers. CH,OH CH,OH (c) ÇH, ÇH, (a) CH, CH, (b) Но HO H H OH HO-H HO H H- ОН НО H OH H- H- HO- H OH HO H H OH CH, CH, CH, CH, CH, CH, onared

Answer 1

Question

Chapter 7.5, Problem 12P

Interpretation Introduction

a) -CH₃, -OH, -H, -Cl

Interpretation:

The substituents in the set, -CH₃, -OH, -H, -Cl, are to be ranked according to the sequence rules.

Concept introduction:

The member that ranks higher can be determined by considering the atomic number of the first atom in each substituent. The atom with highest atomic number gets the higher rank. If a decision cannot be made by considering the atomic number of the first atom in each substituent then the second, third, fourth atoms can be considered until the first difference is found. Multiple bonded atoms are considered as equivalent to the same number of single bonded atoms.

To rank:

The substituents in the set, -CH₃, -OH, -H, -Cl, according to the sequence rules.

Interpretation Introduction

b) -CH₃, -CH₂CH₃, -CH=CH₂, -CH₂OH

Interpretation:

The substituents in the set, -CH₃, -CH₂CH₃, -CH=CH₂, -CH₂OH, are to be ranked according to the sequence rules.

Concept introduction:

The member that ranks higher can be determined by considering the atomic number of the first atom in each substituent. The atom with highest atomic number gets the higher rank. If a decision cannot be made by considering the atomic number of the first atom in each substituent then the second, third, fourth atoms can be considered until the first difference is found. Multiple bonded atoms are considered as equivalent to the same number of single bonded atoms.

To rank:

The substituents in the set, -CH₃, -CH₂CH₃, -CH=CH₂, -CH₂OH, according to the sequence rules.

Interpretation Introduction

Interpretation:

The substituents in the given set are to be ranked according to the sequence rules.

Concept introduction:

The member that ranks higher can be determined by considering the atomic number of the first atom in each substituent. The atom with highest atomic number gets the higher rank. If a decision cannot be made by considering the atomic number of the first atom in each substituent then the second, third, fourth atoms can be considered until the first difference is found. Multiple bonded atoms are considered as equivalent to the same number of single bonded atoms.

To rank:

The substituents in the given set according to the sequence rules.

Interpretation Introduction

Interpretation:

The substituents in the given set are to be ranked according to the sequence rules.

Concept introduction:

The member that ranks higher can be determined by considering the atomic number of the first atom in each substituent. The atom with highest atomic number gets the higher rank. If a decision cannot be made by considering the atomic number of the first atom in each substituent then the second, third, fourth atoms can be considered until the first difference is found. Multiple bonded atoms are considered as equivalent to the same number of single bonded atoms.

To rank:

The substituents in the given set according to the sequence rules.

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Q2 Give the stereochemical relationships between each pair of structures. Examples are same compound, structural isomers, enantiomers, diastereomers. CH,OH CH,OH (c) ÇH, ÇH, (a) CH, CH, (b) Но HO H H OH HO-H HO H H- ОН НО H OH H- H- HO- H OH HO H H OH CH, CH, CH, CH, CH, CH, onared

Pyrethrin II and pyrethrosin are two natural products isolated from plants of the chrysanthemum family. Pyrethrin II is a natural insecticide and is marketed as such. Q,)State the number of stereoisomers possible for each molecule.

1

Answer 2

Question

Chapter 7.5, Problem 12P

Interpretation Introduction

a) -CH₃, -OH, -H, -Cl

Interpretation:

The substituents in the set, -CH₃, -OH, -H, -Cl, are to be ranked according to the sequence rules.

Concept introduction:

The member that ranks higher can be determined by considering the atomic number of the first atom in each substituent. The atom with highest atomic number gets the higher rank. If a decision cannot be made by considering the atomic number of the first atom in each substituent then the second, third, fourth atoms can be considered until the first difference is found. Multiple bonded atoms are considered as equivalent to the same number of single bonded atoms.

To rank:

The substituents in the set, -CH₃, -OH, -H, -Cl, according to the sequence rules.

Interpretation Introduction

b) -CH₃, -CH₂CH₃, -CH=CH₂, -CH₂OH

Interpretation:

The substituents in the set, -CH₃, -CH₂CH₃, -CH=CH₂, -CH₂OH, are to be ranked according to the sequence rules.

Concept introduction:

The member that ranks higher can be determined by considering the atomic number of the first atom in each substituent. The atom with highest atomic number gets the higher rank. If a decision cannot be made by considering the atomic number of the first atom in each substituent then the second, third, fourth atoms can be considered until the first difference is found. Multiple bonded atoms are considered as equivalent to the same number of single bonded atoms.

To rank:

The substituents in the set, -CH₃, -CH₂CH₃, -CH=CH₂, -CH₂OH, according to the sequence rules.

Interpretation Introduction

Interpretation:

The substituents in the given set are to be ranked according to the sequence rules.

Concept introduction:

The member that ranks higher can be determined by considering the atomic number of the first atom in each substituent. The atom with highest atomic number gets the higher rank. If a decision cannot be made by considering the atomic number of the first atom in each substituent then the second, third, fourth atoms can be considered until the first difference is found. Multiple bonded atoms are considered as equivalent to the same number of single bonded atoms.

To rank:

The substituents in the given set according to the sequence rules.

Interpretation Introduction

Interpretation:

The substituents in the given set are to be ranked according to the sequence rules.

Concept introduction:

The member that ranks higher can be determined by considering the atomic number of the first atom in each substituent. The atom with highest atomic number gets the higher rank. If a decision cannot be made by considering the atomic number of the first atom in each substituent then the second, third, fourth atoms can be considered until the first difference is found. Multiple bonded atoms are considered as equivalent to the same number of single bonded atoms.

To rank:

The substituents in the given set according to the sequence rules.

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Answer 3

Question

Chapter 7.5, Problem 12P

Interpretation Introduction

a) -CH₃, -OH, -H, -Cl

Interpretation:

The substituents in the set, -CH₃, -OH, -H, -Cl, are to be ranked according to the sequence rules.

Concept introduction:

The member that ranks higher can be determined by considering the atomic number of the first atom in each substituent. The atom with highest atomic number gets the higher rank. If a decision cannot be made by considering the atomic number of the first atom in each substituent then the second, third, fourth atoms can be considered until the first difference is found. Multiple bonded atoms are considered as equivalent to the same number of single bonded atoms.

To rank:

The substituents in the set, -CH₃, -OH, -H, -Cl, according to the sequence rules.

Interpretation Introduction

b) -CH₃, -CH₂CH₃, -CH=CH₂, -CH₂OH

Interpretation:

The substituents in the set, -CH₃, -CH₂CH₃, -CH=CH₂, -CH₂OH, are to be ranked according to the sequence rules.

Concept introduction:

The member that ranks higher can be determined by considering the atomic number of the first atom in each substituent. The atom with highest atomic number gets the higher rank. If a decision cannot be made by considering the atomic number of the first atom in each substituent then the second, third, fourth atoms can be considered until the first difference is found. Multiple bonded atoms are considered as equivalent to the same number of single bonded atoms.

To rank:

The substituents in the set, -CH₃, -CH₂CH₃, -CH=CH₂, -CH₂OH, according to the sequence rules.

Interpretation Introduction

Interpretation:

The substituents in the given set are to be ranked according to the sequence rules.

Concept introduction:

The member that ranks higher can be determined by considering the atomic number of the first atom in each substituent. The atom with highest atomic number gets the higher rank. If a decision cannot be made by considering the atomic number of the first atom in each substituent then the second, third, fourth atoms can be considered until the first difference is found. Multiple bonded atoms are considered as equivalent to the same number of single bonded atoms.

To rank:

The substituents in the given set according to the sequence rules.

Interpretation Introduction

Interpretation:

The substituents in the given set are to be ranked according to the sequence rules.

Concept introduction:

The member that ranks higher can be determined by considering the atomic number of the first atom in each substituent. The atom with highest atomic number gets the higher rank. If a decision cannot be made by considering the atomic number of the first atom in each substituent then the second, third, fourth atoms can be considered until the first difference is found. Multiple bonded atoms are considered as equivalent to the same number of single bonded atoms.

To rank:

The substituents in the given set according to the sequence rules.

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Answer 4

Question

Chapter 7.5, Problem 12P

Interpretation Introduction

a) -CH₃, -OH, -H, -Cl

Interpretation:

The substituents in the set, -CH₃, -OH, -H, -Cl, are to be ranked according to the sequence rules.

Concept introduction:

The member that ranks higher can be determined by considering the atomic number of the first atom in each substituent. The atom with highest atomic number gets the higher rank. If a decision cannot be made by considering the atomic number of the first atom in each substituent then the second, third, fourth atoms can be considered until the first difference is found. Multiple bonded atoms are considered as equivalent to the same number of single bonded atoms.

To rank:

The substituents in the set, -CH₃, -OH, -H, -Cl, according to the sequence rules.

Interpretation Introduction

b) -CH₃, -CH₂CH₃, -CH=CH₂, -CH₂OH

Interpretation:

The substituents in the set, -CH₃, -CH₂CH₃, -CH=CH₂, -CH₂OH, are to be ranked according to the sequence rules.

Concept introduction:

The member that ranks higher can be determined by considering the atomic number of the first atom in each substituent. The atom with highest atomic number gets the higher rank. If a decision cannot be made by considering the atomic number of the first atom in each substituent then the second, third, fourth atoms can be considered until the first difference is found. Multiple bonded atoms are considered as equivalent to the same number of single bonded atoms.

To rank:

The substituents in the set, -CH₃, -CH₂CH₃, -CH=CH₂, -CH₂OH, according to the sequence rules.

Interpretation Introduction

Interpretation:

The substituents in the given set are to be ranked according to the sequence rules.

Concept introduction:

The member that ranks higher can be determined by considering the atomic number of the first atom in each substituent. The atom with highest atomic number gets the higher rank. If a decision cannot be made by considering the atomic number of the first atom in each substituent then the second, third, fourth atoms can be considered until the first difference is found. Multiple bonded atoms are considered as equivalent to the same number of single bonded atoms.

To rank:

The substituents in the given set according to the sequence rules.

Interpretation Introduction

Interpretation:

The substituents in the given set are to be ranked according to the sequence rules.

Concept introduction:

The member that ranks higher can be determined by considering the atomic number of the first atom in each substituent. The atom with highest atomic number gets the higher rank. If a decision cannot be made by considering the atomic number of the first atom in each substituent then the second, third, fourth atoms can be considered until the first difference is found. Multiple bonded atoms are considered as equivalent to the same number of single bonded atoms.

To rank:

The substituents in the given set according to the sequence rules.

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Answer 5

Chapter 7.5, Problem 12P

Interpretation Introduction

a) -CH₃, -OH, -H, -Cl

Interpretation:

The substituents in the set, -CH₃, -OH, -H, -Cl, are to be ranked according to the sequence rules.

Concept introduction:

The member that ranks higher can be determined by considering the atomic number of the first atom in each substituent. The atom with highest atomic number gets the higher rank. If a decision cannot be made by considering the atomic number of the first atom in each substituent then the second, third, fourth atoms can be considered until the first difference is found. Multiple bonded atoms are considered as equivalent to the same number of single bonded atoms.

To rank:

The substituents in the set, -CH₃, -OH, -H, -Cl, according to the sequence rules.

Interpretation Introduction

b) -CH₃, -CH₂CH₃, -CH=CH₂, -CH₂OH

Interpretation:

The substituents in the set, -CH₃, -CH₂CH₃, -CH=CH₂, -CH₂OH, are to be ranked according to the sequence rules.

Concept introduction:

The member that ranks higher can be determined by considering the atomic number of the first atom in each substituent. The atom with highest atomic number gets the higher rank. If a decision cannot be made by considering the atomic number of the first atom in each substituent then the second, third, fourth atoms can be considered until the first difference is found. Multiple bonded atoms are considered as equivalent to the same number of single bonded atoms.

To rank:

The substituents in the set, -CH₃, -CH₂CH₃, -CH=CH₂, -CH₂OH, according to the sequence rules.

Interpretation Introduction

Interpretation:

The substituents in the given set are to be ranked according to the sequence rules.

Concept introduction:

The member that ranks higher can be determined by considering the atomic number of the first atom in each substituent. The atom with highest atomic number gets the higher rank. If a decision cannot be made by considering the atomic number of the first atom in each substituent then the second, third, fourth atoms can be considered until the first difference is found. Multiple bonded atoms are considered as equivalent to the same number of single bonded atoms.

To rank:

The substituents in the given set according to the sequence rules.

Interpretation Introduction

Interpretation:

The substituents in the given set are to be ranked according to the sequence rules.

Concept introduction:

The member that ranks higher can be determined by considering the atomic number of the first atom in each substituent. The atom with highest atomic number gets the higher rank. If a decision cannot be made by considering the atomic number of the first atom in each substituent then the second, third, fourth atoms can be considered until the first difference is found. Multiple bonded atoms are considered as equivalent to the same number of single bonded atoms.

To rank:

The substituents in the given set according to the sequence rules.

Answer 6

Chapter 7.5, Problem 12P

Interpretation Introduction

a) -CH₃, -OH, -H, -Cl

Interpretation:

The substituents in the set, -CH₃, -OH, -H, -Cl, are to be ranked according to the sequence rules.

Concept introduction:

The member that ranks higher can be determined by considering the atomic number of the first atom in each substituent. The atom with highest atomic number gets the higher rank. If a decision cannot be made by considering the atomic number of the first atom in each substituent then the second, third, fourth atoms can be considered until the first difference is found. Multiple bonded atoms are considered as equivalent to the same number of single bonded atoms.

To rank:

The substituents in the set, -CH₃, -OH, -H, -Cl, according to the sequence rules.

Answer 7

Chapter 7.5, Problem 12P

Interpretation Introduction

a) -CH₃, -OH, -H, -Cl

Interpretation:

The substituents in the set, -CH₃, -OH, -H, -Cl, are to be ranked according to the sequence rules.

Concept introduction:

The member that ranks higher can be determined by considering the atomic number of the first atom in each substituent. The atom with highest atomic number gets the higher rank. If a decision cannot be made by considering the atomic number of the first atom in each substituent then the second, third, fourth atoms can be considered until the first difference is found. Multiple bonded atoms are considered as equivalent to the same number of single bonded atoms.

To rank:

The substituents in the set, -CH₃, -OH, -H, -Cl, according to the sequence rules.

Answer 8

Interpretation Introduction

b) -CH₃, -CH₂CH₃, -CH=CH₂, -CH₂OH

Interpretation:

The substituents in the set, -CH₃, -CH₂CH₃, -CH=CH₂, -CH₂OH, are to be ranked according to the sequence rules.

Concept introduction:

The member that ranks higher can be determined by considering the atomic number of the first atom in each substituent. The atom with highest atomic number gets the higher rank. If a decision cannot be made by considering the atomic number of the first atom in each substituent then the second, third, fourth atoms can be considered until the first difference is found. Multiple bonded atoms are considered as equivalent to the same number of single bonded atoms.

To rank:

The substituents in the set, -CH₃, -CH₂CH₃, -CH=CH₂, -CH₂OH, according to the sequence rules.

Answer 9

Interpretation Introduction

b) -CH₃, -CH₂CH₃, -CH=CH₂, -CH₂OH

Interpretation:

The substituents in the set, -CH₃, -CH₂CH₃, -CH=CH₂, -CH₂OH, are to be ranked according to the sequence rules.

Concept introduction:

The member that ranks higher can be determined by considering the atomic number of the first atom in each substituent. The atom with highest atomic number gets the higher rank. If a decision cannot be made by considering the atomic number of the first atom in each substituent then the second, third, fourth atoms can be considered until the first difference is found. Multiple bonded atoms are considered as equivalent to the same number of single bonded atoms.

To rank:

The substituents in the set, -CH₃, -CH₂CH₃, -CH=CH₂, -CH₂OH, according to the sequence rules.

Answer 10

Interpretation Introduction

Interpretation:

The substituents in the given set are to be ranked according to the sequence rules.

Concept introduction:

The member that ranks higher can be determined by considering the atomic number of the first atom in each substituent. The atom with highest atomic number gets the higher rank. If a decision cannot be made by considering the atomic number of the first atom in each substituent then the second, third, fourth atoms can be considered until the first difference is found. Multiple bonded atoms are considered as equivalent to the same number of single bonded atoms.

To rank:

The substituents in the given set according to the sequence rules.

Answer 11

Interpretation Introduction

Interpretation:

The substituents in the given set are to be ranked according to the sequence rules.

Concept introduction:

The member that ranks higher can be determined by considering the atomic number of the first atom in each substituent. The atom with highest atomic number gets the higher rank. If a decision cannot be made by considering the atomic number of the first atom in each substituent then the second, third, fourth atoms can be considered until the first difference is found. Multiple bonded atoms are considered as equivalent to the same number of single bonded atoms.

To rank:

The substituents in the given set according to the sequence rules.

Answer 12

Interpretation Introduction

Interpretation:

The substituents in the given set are to be ranked according to the sequence rules.

Concept introduction:

The member that ranks higher can be determined by considering the atomic number of the first atom in each substituent. The atom with highest atomic number gets the higher rank. If a decision cannot be made by considering the atomic number of the first atom in each substituent then the second, third, fourth atoms can be considered until the first difference is found. Multiple bonded atoms are considered as equivalent to the same number of single bonded atoms.

To rank:

The substituents in the given set according to the sequence rules.

Answer 13

Interpretation Introduction

Interpretation:

The substituents in the given set are to be ranked according to the sequence rules.

Concept introduction:

The member that ranks higher can be determined by considering the atomic number of the first atom in each substituent. The atom with highest atomic number gets the higher rank. If a decision cannot be made by considering the atomic number of the first atom in each substituent then the second, third, fourth atoms can be considered until the first difference is found. Multiple bonded atoms are considered as equivalent to the same number of single bonded atoms.

To rank:

The substituents in the given set according to the sequence rules.

Answer 14

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Answer 25

Ch. 7.2 - Calculate the degree of unsaturation in each of...Ch. 7.2 - Prob. 2P Ch. 7.2 - Diazepam, marketed as an antianxiety medication...Ch. 7.3 - Give IUPAC names for the following compounds:Ch. 7.3 - Prob. 5P Ch. 7.3 - Prob. 6P Ch. 7.3 - Prob. 7P Ch. 7.4 - Prob. 8P Ch. 7.4 - Prob. 9P Ch. 7.4 - Prob. 10P

Solution Summary: The author explains that substituents are ranked according to the sequence rules. The member that ranks higher can be determined by considering the atomic number of the first atom.

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