a) Interpretation: To rank the double bond in the compounds given in terms of increasing stability. Concept introduction: The stability of a double bond can be determined by the number of hydrogens on adjacent carbons attached to both carbons in the double bond. (H’s on the Î± carbon). More the number of such hydrogens, the more hyperconjugation occur and more stable the alkene .

Question

19.78 Write the products of the following sequences of reactions. Refer to your reaction road- maps to see how the combined reactions allow you to "navigate" between the different functional groups. Note that you will need your old Chapters 6-11 and Chapters 15-18 roadmaps along with your new Chapter 19 roadmap for these. (a) 1. BHS 2. H₂O₂ 3. H₂CrO4 4. SOCI₂ (b) 1. Cl₂/hv 2. KOLBU 3. H₂O, catalytic H₂SO4 4. H₂CrO4 Reaction Roadmap An alkene 5. EtOH 6.0.5 Equiv. NaOEt/EtOH 7. Mild H₂O An alkane 1.0 2. (CH3)₂S 3. H₂CrO (d) (c) 4. Excess EtOH, catalytic H₂SO OH 4. Mild H₂O* 5.0.5 Equiv. NaOEt/EtOH An alkene 6. Mild H₂O* A carboxylic acid 7. Mild H₂O* 1. SOC₁₂ 2. EtOH 3.0.5 Equiv. NaOEt/E:OH 5.1.0 Equiv. NaOEt 6. NH₂ (e) 1. 0.5 Equiv. NaOEt/EtOH 2. Mild H₂O* Br (f) i H An aldehyde 1. Catalytic NaOE/EtOH 2. H₂O*, heat 3. (CH,CH₂)₂Culi 4. Mild H₂O* 5.1.0 Equiv. LDA Br An ester 4. NaOH, H₂O 5. Mild H₂O* 6. Heat 7. MgBr 8. Mild H₂O* 7. Mild H₂O+

Answer 1

Question

Chapter 7.SE, Problem 48AP

Interpretation Introduction

a)

Interpretation:

To rank the double bond in the compounds given in terms of increasing stability.

Concept introduction:

The stability of a double bond can be determined by the number of hydrogens on adjacent carbons attached to both carbons in the double bond. (H’s on the Î± carbon). More the number of such hydrogens, the more hyperconjugation occur and more stable the alkene.

Interpretation Introduction

b)

Interpretation:

To rank the double bond in the compounds given in terms of increasing stability.

Concept introduction:

The stability of a double bond can be determined by the number of hydrogens on adjacent carbons attached to both carbons in the double bond.(H’s on the Î± carbon). More the number of such hydrogens, the more hyperconjugation occur and more stable the alkene.

Interpretation Introduction

c)

Interpretation:

To rank the double bond in the compounds given in terms of increasing stability.

Concept introduction:

The stability of a double bond can be determined by the number of hydrogens on adjacent carbons attached to both carbons in the double bond.(H’s on the Î± carbon). More the number of such hydrogens, the more hyperconjugation occur and more stable the alkene.

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19.78 Write the products of the following sequences of reactions. Refer to your reaction road- maps to see how the combined reactions allow you to "navigate" between the different functional groups. Note that you will need your old Chapters 6-11 and Chapters 15-18 roadmaps along with your new Chapter 19 roadmap for these. (a) 1. BHS 2. H₂O₂ 3. H₂CrO4 4. SOCI₂ (b) 1. Cl₂/hv 2. KOLBU 3. H₂O, catalytic H₂SO4 4. H₂CrO4 Reaction Roadmap An alkene 5. EtOH 6.0.5 Equiv. NaOEt/EtOH 7. Mild H₂O An alkane 1.0 2. (CH3)₂S 3. H₂CrO (d) (c) 4. Excess EtOH, catalytic H₂SO OH 4. Mild H₂O* 5.0.5 Equiv. NaOEt/EtOH An alkene 6. Mild H₂O* A carboxylic acid 7. Mild H₂O* 1. SOC₁₂ 2. EtOH 3.0.5 Equiv. NaOEt/E:OH 5.1.0 Equiv. NaOEt 6. NH₂ (e) 1. 0.5 Equiv. NaOEt/EtOH 2. Mild H₂O* Br (f) i H An aldehyde 1. Catalytic NaOE/EtOH 2. H₂O*, heat 3. (CH,CH₂)₂Culi 4. Mild H₂O* 5.1.0 Equiv. LDA Br An ester 4. NaOH, H₂O 5. Mild H₂O* 6. Heat 7. MgBr 8. Mild H₂O* 7. Mild H₂O+

Li+ is a hard acid. With this in mind, which if the following compounds should be most soluble in water? Group of answer choices LiBr LiI LiF LiCl

Q4: Write organic product(s) of the following reactions and show the curved-arrow mechanism of the reactions. Br MeOH OSO2CH3 MeOH

Answer 2

Question

Chapter 7.SE, Problem 48AP

Interpretation Introduction

a)

Interpretation:

To rank the double bond in the compounds given in terms of increasing stability.

Concept introduction:

The stability of a double bond can be determined by the number of hydrogens on adjacent carbons attached to both carbons in the double bond. (H’s on the Î± carbon). More the number of such hydrogens, the more hyperconjugation occur and more stable the alkene.

Interpretation Introduction

b)

Interpretation:

To rank the double bond in the compounds given in terms of increasing stability.

Concept introduction:

The stability of a double bond can be determined by the number of hydrogens on adjacent carbons attached to both carbons in the double bond.(H’s on the Î± carbon). More the number of such hydrogens, the more hyperconjugation occur and more stable the alkene.

Interpretation Introduction

c)

Interpretation:

To rank the double bond in the compounds given in terms of increasing stability.

Concept introduction:

The stability of a double bond can be determined by the number of hydrogens on adjacent carbons attached to both carbons in the double bond.(H’s on the Î± carbon). More the number of such hydrogens, the more hyperconjugation occur and more stable the alkene.

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Answer 3

Question

Chapter 7.SE, Problem 48AP

Interpretation Introduction

a)

Interpretation:

To rank the double bond in the compounds given in terms of increasing stability.

Concept introduction:

The stability of a double bond can be determined by the number of hydrogens on adjacent carbons attached to both carbons in the double bond. (H’s on the Î± carbon). More the number of such hydrogens, the more hyperconjugation occur and more stable the alkene.

Interpretation Introduction

b)

Interpretation:

To rank the double bond in the compounds given in terms of increasing stability.

Concept introduction:

The stability of a double bond can be determined by the number of hydrogens on adjacent carbons attached to both carbons in the double bond.(H’s on the Î± carbon). More the number of such hydrogens, the more hyperconjugation occur and more stable the alkene.

Interpretation Introduction

c)

Interpretation:

To rank the double bond in the compounds given in terms of increasing stability.

Concept introduction:

The stability of a double bond can be determined by the number of hydrogens on adjacent carbons attached to both carbons in the double bond.(H’s on the Î± carbon). More the number of such hydrogens, the more hyperconjugation occur and more stable the alkene.

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Answer 4

Question

Chapter 7.SE, Problem 48AP

Interpretation Introduction

a)

Interpretation:

To rank the double bond in the compounds given in terms of increasing stability.

Concept introduction:

The stability of a double bond can be determined by the number of hydrogens on adjacent carbons attached to both carbons in the double bond. (H’s on the Î± carbon). More the number of such hydrogens, the more hyperconjugation occur and more stable the alkene.

Interpretation Introduction

b)

Interpretation:

To rank the double bond in the compounds given in terms of increasing stability.

Concept introduction:

The stability of a double bond can be determined by the number of hydrogens on adjacent carbons attached to both carbons in the double bond.(H’s on the Î± carbon). More the number of such hydrogens, the more hyperconjugation occur and more stable the alkene.

Interpretation Introduction

c)

Interpretation:

To rank the double bond in the compounds given in terms of increasing stability.

Concept introduction:

The stability of a double bond can be determined by the number of hydrogens on adjacent carbons attached to both carbons in the double bond.(H’s on the Î± carbon). More the number of such hydrogens, the more hyperconjugation occur and more stable the alkene.

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Answer 5

Chapter 7.SE, Problem 48AP

Interpretation Introduction

a)

Interpretation:

To rank the double bond in the compounds given in terms of increasing stability.

Concept introduction:

The stability of a double bond can be determined by the number of hydrogens on adjacent carbons attached to both carbons in the double bond. (H’s on the Î± carbon). More the number of such hydrogens, the more hyperconjugation occur and more stable the alkene.

Interpretation Introduction

b)

Interpretation:

To rank the double bond in the compounds given in terms of increasing stability.

Concept introduction:

The stability of a double bond can be determined by the number of hydrogens on adjacent carbons attached to both carbons in the double bond.(H’s on the Î± carbon). More the number of such hydrogens, the more hyperconjugation occur and more stable the alkene.

Interpretation Introduction

c)

Interpretation:

To rank the double bond in the compounds given in terms of increasing stability.

Concept introduction:

The stability of a double bond can be determined by the number of hydrogens on adjacent carbons attached to both carbons in the double bond.(H’s on the Î± carbon). More the number of such hydrogens, the more hyperconjugation occur and more stable the alkene.

Answer 6

Chapter 7.SE, Problem 48AP

Interpretation Introduction

a)

Interpretation:

To rank the double bond in the compounds given in terms of increasing stability.

Concept introduction:

The stability of a double bond can be determined by the number of hydrogens on adjacent carbons attached to both carbons in the double bond. (H’s on the Î± carbon). More the number of such hydrogens, the more hyperconjugation occur and more stable the alkene.

Answer 7

Chapter 7.SE, Problem 48AP

Interpretation Introduction

a)

Interpretation:

To rank the double bond in the compounds given in terms of increasing stability.

Concept introduction:

The stability of a double bond can be determined by the number of hydrogens on adjacent carbons attached to both carbons in the double bond. (H’s on the Î± carbon). More the number of such hydrogens, the more hyperconjugation occur and more stable the alkene.

Answer 8

Interpretation Introduction

b)

Interpretation:

To rank the double bond in the compounds given in terms of increasing stability.

Concept introduction:

The stability of a double bond can be determined by the number of hydrogens on adjacent carbons attached to both carbons in the double bond.(H’s on the Î± carbon). More the number of such hydrogens, the more hyperconjugation occur and more stable the alkene.

Answer 9

Interpretation Introduction

b)

Interpretation:

To rank the double bond in the compounds given in terms of increasing stability.

Concept introduction:

The stability of a double bond can be determined by the number of hydrogens on adjacent carbons attached to both carbons in the double bond.(H’s on the Î± carbon). More the number of such hydrogens, the more hyperconjugation occur and more stable the alkene.

Answer 10

Interpretation Introduction

c)

Interpretation:

To rank the double bond in the compounds given in terms of increasing stability.

Concept introduction:

The stability of a double bond can be determined by the number of hydrogens on adjacent carbons attached to both carbons in the double bond.(H’s on the Î± carbon). More the number of such hydrogens, the more hyperconjugation occur and more stable the alkene.

Answer 11

Interpretation Introduction

c)

Interpretation:

To rank the double bond in the compounds given in terms of increasing stability.

Concept introduction:

The stability of a double bond can be determined by the number of hydrogens on adjacent carbons attached to both carbons in the double bond.(H’s on the Î± carbon). More the number of such hydrogens, the more hyperconjugation occur and more stable the alkene.

Answer 12

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Ch. 7.2 - Calculate the degree of unsaturation in each of...Ch. 7.2 - Prob. 2P Ch. 7.2 - Diazepam, marketed as an antianxiety medication...Ch. 7.3 - Give IUPAC names for the following compounds:Ch. 7.3 - Prob. 5P Ch. 7.3 - Prob. 6P Ch. 7.3 - Prob. 7P Ch. 7.4 - Prob. 8P Ch. 7.4 - Prob. 9P Ch. 7.4 - Prob. 10P

Solution Summary: The author explains the order of stability of a double bond in the compounds given in terms of increasing stability.

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