The structure of carboxylic acid that is formed from the aldehyde when it undergoes oxidation has to be drawn. Concept Introduction: In organic chemistry , oxidation reaction is referred to the number C − O bonds increase and/or number of C − H bonds decrease. In organic chemistry, reduction reaction is referred to the number C − O bonds decrease and/or number of C − H bonds increase. Alcohols undergo oxidation reaction and reduction reaction. This depends upon the number of hydrogen atoms that is bonded to the alpha carbon atom. Primary and secondary alcohol undergoes oxidation reaction while tertiary alcohol does not undergo oxidation reaction. Primary alcohols undergo oxidation to give aldehyde and carboxylic acid as product. Secondary alcohol undergoes oxidation to give ketone as the product. Aldehyde undergoes oxidation to give carboxylic acid as the product while ketone does not undergo oxidation reaction.

Question

Part II. Given two isomers: 2-methylpentane (A) and 2,2-dimethyl butane (B) answer the following: (a) match structures of isomers given their mass spectra below (spectra A and spectra B) (b) Draw the fragments given the following prominent peaks from each spectrum: Spectra A m/2 =43 and 1/2-57 spectra B m/2 = 43 (c) why is 1/2=57 peak in spectrum A more intense compared to the same peak in spectrum B. Relative abundance Relative abundance 100 A 50 29 29 0 10 -0 -0 100 B 50 720 30 41 43 57 71 4-0 40 50 60 70 m/z 43 57 8-0 m/z = 86 M 90 100 71 m/z = 86 M -O 0 10 20 30 40 50 60 70 80 -88 m/z 90 100

Answer 1

Question

Chapter 4, Problem 4.75EP

(a)

Interpretation Introduction

Interpretation:

The structure of carboxylic acid that is formed from the aldehyde when it undergoes oxidation has to be drawn.

Concept Introduction:

In organic chemistry, oxidation reaction is referred to the number C−O bonds increase and/or number of C−H bonds decrease.

In organic chemistry, reduction reaction is referred to the number C−O bonds decrease and/or number of C−H bonds increase.

Alcohols undergo oxidation reaction and reduction reaction. This depends upon the number of hydrogen atoms that is bonded to the alpha carbon atom. Primary and secondary alcohol undergoes oxidation reaction while tertiary alcohol does not undergo oxidation reaction. Primary alcohols undergo oxidation to give aldehyde and carboxylic acid as product. Secondary alcohol undergoes oxidation to give ketone as the product.

Aldehyde undergoes oxidation to give carboxylic acid as the product while ketone does not undergo oxidation reaction.

(b)

Interpretation Introduction

Interpretation:

The structure of carboxylic acid that is formed from the aldehyde when it undergoes oxidation has to be drawn.

Concept Introduction:

In organic chemistry, oxidation reaction is referred to the number C−O bonds increase and/or number of C−H bonds decrease.

In organic chemistry, reduction reaction is referred to the number C−O bonds decrease and/or number of C−H bonds increase.

Alcohols undergo oxidation reaction and reduction reaction. This depends upon the number of hydrogen atoms that is bonded to the alpha carbon atom. Primary and secondary alcohol undergoes oxidation reaction while tertiary alcohol does not undergo oxidation reaction. Primary alcohols undergo oxidation to give aldehyde and carboxylic acid as product. Secondary alcohol undergoes oxidation to give ketone as the product.

Aldehyde undergoes oxidation to give carboxylic acid as the product while ketone does not undergo oxidation reaction.

(c)

Interpretation Introduction

Interpretation:

The structure of carboxylic acid that is formed from the aldehyde when it undergoes oxidation has to be drawn.

Concept Introduction:

In organic chemistry, oxidation reaction is referred to the number C−O bonds increase and/or number of C−H bonds decrease.

In organic chemistry, reduction reaction is referred to the number C−O bonds decrease and/or number of C−H bonds increase.

Alcohols undergo oxidation reaction and reduction reaction. This depends upon the number of hydrogen atoms that is bonded to the alpha carbon atom. Primary and secondary alcohol undergoes oxidation reaction while tertiary alcohol does not undergo oxidation reaction. Primary alcohols undergo oxidation to give aldehyde and carboxylic acid as product. Secondary alcohol undergoes oxidation to give ketone as the product.

Aldehyde undergoes oxidation to give carboxylic acid as the product while ketone does not undergo oxidation reaction.

(d)

Interpretation Introduction

Interpretation:

The structure of carboxylic acid that is formed from the aldehyde when it undergoes oxidation has to be drawn.

Concept Introduction:

In organic chemistry, oxidation reaction is referred to the number C−O bonds increase and/or number of C−H bonds decrease.

In organic chemistry, reduction reaction is referred to the number C−O bonds decrease and/or number of C−H bonds increase.

Alcohols undergo oxidation reaction and reduction reaction. This depends upon the number of hydrogen atoms that is bonded to the alpha carbon atom. Primary and secondary alcohol undergoes oxidation reaction while tertiary alcohol does not undergo oxidation reaction. Primary alcohols undergo oxidation to give aldehyde and carboxylic acid as product. Secondary alcohol undergoes oxidation to give ketone as the product.

Aldehyde undergoes oxidation to give carboxylic acid as the product while ketone does not undergo oxidation reaction.

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Part II. Given two isomers: 2-methylpentane (A) and 2,2-dimethyl butane (B) answer the following: (a) match structures of isomers given their mass spectra below (spectra A and spectra B) (b) Draw the fragments given the following prominent peaks from each spectrum: Spectra A m/2 =43 and 1/2-57 spectra B m/2 = 43 (c) why is 1/2=57 peak in spectrum A more intense compared to the same peak in spectrum B. Relative abundance Relative abundance 100 A 50 29 29 0 10 -0 -0 100 B 50 720 30 41 43 57 71 4-0 40 50 60 70 m/z 43 57 8-0 m/z = 86 M 90 100 71 m/z = 86 M -O 0 10 20 30 40 50 60 70 80 -88 m/z 90 100

Part IV. C6H5 CH2CH2OH is an aromatic compound which was subjected to Electron Ionization - mass spectrometry (El-MS) analysis. Prominent m/2 values: m/2 = 104 and m/2 = 9) was obtained. Draw the structures of these fragments.

For each reaction shown below follow the curved arrows to complete each equationby showing the structure of the products. Identify the acid, the base, the conjugated acid andconjugated base. Consutl the pKa table and choose the direciton theequilibrium goes. However show the curved arrows. Please explain if possible.

Answer 2

Question

Chapter 4, Problem 4.75EP

(a)

Interpretation Introduction

Interpretation:

The structure of carboxylic acid that is formed from the aldehyde when it undergoes oxidation has to be drawn.

Concept Introduction:

In organic chemistry, oxidation reaction is referred to the number C−O bonds increase and/or number of C−H bonds decrease.

In organic chemistry, reduction reaction is referred to the number C−O bonds decrease and/or number of C−H bonds increase.

Alcohols undergo oxidation reaction and reduction reaction. This depends upon the number of hydrogen atoms that is bonded to the alpha carbon atom. Primary and secondary alcohol undergoes oxidation reaction while tertiary alcohol does not undergo oxidation reaction. Primary alcohols undergo oxidation to give aldehyde and carboxylic acid as product. Secondary alcohol undergoes oxidation to give ketone as the product.

Aldehyde undergoes oxidation to give carboxylic acid as the product while ketone does not undergo oxidation reaction.

(b)

Interpretation Introduction

Interpretation:

The structure of carboxylic acid that is formed from the aldehyde when it undergoes oxidation has to be drawn.

Concept Introduction:

In organic chemistry, oxidation reaction is referred to the number C−O bonds increase and/or number of C−H bonds decrease.

In organic chemistry, reduction reaction is referred to the number C−O bonds decrease and/or number of C−H bonds increase.

Alcohols undergo oxidation reaction and reduction reaction. This depends upon the number of hydrogen atoms that is bonded to the alpha carbon atom. Primary and secondary alcohol undergoes oxidation reaction while tertiary alcohol does not undergo oxidation reaction. Primary alcohols undergo oxidation to give aldehyde and carboxylic acid as product. Secondary alcohol undergoes oxidation to give ketone as the product.

Aldehyde undergoes oxidation to give carboxylic acid as the product while ketone does not undergo oxidation reaction.

(c)

Interpretation Introduction

Interpretation:

The structure of carboxylic acid that is formed from the aldehyde when it undergoes oxidation has to be drawn.

Concept Introduction:

In organic chemistry, oxidation reaction is referred to the number C−O bonds increase and/or number of C−H bonds decrease.

In organic chemistry, reduction reaction is referred to the number C−O bonds decrease and/or number of C−H bonds increase.

Alcohols undergo oxidation reaction and reduction reaction. This depends upon the number of hydrogen atoms that is bonded to the alpha carbon atom. Primary and secondary alcohol undergoes oxidation reaction while tertiary alcohol does not undergo oxidation reaction. Primary alcohols undergo oxidation to give aldehyde and carboxylic acid as product. Secondary alcohol undergoes oxidation to give ketone as the product.

Aldehyde undergoes oxidation to give carboxylic acid as the product while ketone does not undergo oxidation reaction.

(d)

Interpretation Introduction

Interpretation:

The structure of carboxylic acid that is formed from the aldehyde when it undergoes oxidation has to be drawn.

Concept Introduction:

In organic chemistry, oxidation reaction is referred to the number C−O bonds increase and/or number of C−H bonds decrease.

In organic chemistry, reduction reaction is referred to the number C−O bonds decrease and/or number of C−H bonds increase.

Alcohols undergo oxidation reaction and reduction reaction. This depends upon the number of hydrogen atoms that is bonded to the alpha carbon atom. Primary and secondary alcohol undergoes oxidation reaction while tertiary alcohol does not undergo oxidation reaction. Primary alcohols undergo oxidation to give aldehyde and carboxylic acid as product. Secondary alcohol undergoes oxidation to give ketone as the product.

Aldehyde undergoes oxidation to give carboxylic acid as the product while ketone does not undergo oxidation reaction.

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Answer 3

Question

Chapter 4, Problem 4.75EP

(a)

Interpretation Introduction

Interpretation:

The structure of carboxylic acid that is formed from the aldehyde when it undergoes oxidation has to be drawn.

Concept Introduction:

In organic chemistry, oxidation reaction is referred to the number C−O bonds increase and/or number of C−H bonds decrease.

In organic chemistry, reduction reaction is referred to the number C−O bonds decrease and/or number of C−H bonds increase.

Alcohols undergo oxidation reaction and reduction reaction. This depends upon the number of hydrogen atoms that is bonded to the alpha carbon atom. Primary and secondary alcohol undergoes oxidation reaction while tertiary alcohol does not undergo oxidation reaction. Primary alcohols undergo oxidation to give aldehyde and carboxylic acid as product. Secondary alcohol undergoes oxidation to give ketone as the product.

Aldehyde undergoes oxidation to give carboxylic acid as the product while ketone does not undergo oxidation reaction.

(b)

Interpretation Introduction

Interpretation:

The structure of carboxylic acid that is formed from the aldehyde when it undergoes oxidation has to be drawn.

Concept Introduction:

In organic chemistry, oxidation reaction is referred to the number C−O bonds increase and/or number of C−H bonds decrease.

In organic chemistry, reduction reaction is referred to the number C−O bonds decrease and/or number of C−H bonds increase.

Alcohols undergo oxidation reaction and reduction reaction. This depends upon the number of hydrogen atoms that is bonded to the alpha carbon atom. Primary and secondary alcohol undergoes oxidation reaction while tertiary alcohol does not undergo oxidation reaction. Primary alcohols undergo oxidation to give aldehyde and carboxylic acid as product. Secondary alcohol undergoes oxidation to give ketone as the product.

Aldehyde undergoes oxidation to give carboxylic acid as the product while ketone does not undergo oxidation reaction.

(c)

Interpretation Introduction

Interpretation:

The structure of carboxylic acid that is formed from the aldehyde when it undergoes oxidation has to be drawn.

Concept Introduction:

In organic chemistry, oxidation reaction is referred to the number C−O bonds increase and/or number of C−H bonds decrease.

In organic chemistry, reduction reaction is referred to the number C−O bonds decrease and/or number of C−H bonds increase.

Alcohols undergo oxidation reaction and reduction reaction. This depends upon the number of hydrogen atoms that is bonded to the alpha carbon atom. Primary and secondary alcohol undergoes oxidation reaction while tertiary alcohol does not undergo oxidation reaction. Primary alcohols undergo oxidation to give aldehyde and carboxylic acid as product. Secondary alcohol undergoes oxidation to give ketone as the product.

Aldehyde undergoes oxidation to give carboxylic acid as the product while ketone does not undergo oxidation reaction.

(d)

Interpretation Introduction

Interpretation:

The structure of carboxylic acid that is formed from the aldehyde when it undergoes oxidation has to be drawn.

Concept Introduction:

In organic chemistry, oxidation reaction is referred to the number C−O bonds increase and/or number of C−H bonds decrease.

In organic chemistry, reduction reaction is referred to the number C−O bonds decrease and/or number of C−H bonds increase.

Alcohols undergo oxidation reaction and reduction reaction. This depends upon the number of hydrogen atoms that is bonded to the alpha carbon atom. Primary and secondary alcohol undergoes oxidation reaction while tertiary alcohol does not undergo oxidation reaction. Primary alcohols undergo oxidation to give aldehyde and carboxylic acid as product. Secondary alcohol undergoes oxidation to give ketone as the product.

Aldehyde undergoes oxidation to give carboxylic acid as the product while ketone does not undergo oxidation reaction.

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Answer 4

Question

Chapter 4, Problem 4.75EP

(a)

Interpretation Introduction

Interpretation:

The structure of carboxylic acid that is formed from the aldehyde when it undergoes oxidation has to be drawn.

Concept Introduction:

In organic chemistry, oxidation reaction is referred to the number C−O bonds increase and/or number of C−H bonds decrease.

In organic chemistry, reduction reaction is referred to the number C−O bonds decrease and/or number of C−H bonds increase.

Alcohols undergo oxidation reaction and reduction reaction. This depends upon the number of hydrogen atoms that is bonded to the alpha carbon atom. Primary and secondary alcohol undergoes oxidation reaction while tertiary alcohol does not undergo oxidation reaction. Primary alcohols undergo oxidation to give aldehyde and carboxylic acid as product. Secondary alcohol undergoes oxidation to give ketone as the product.

Aldehyde undergoes oxidation to give carboxylic acid as the product while ketone does not undergo oxidation reaction.

(b)

Interpretation Introduction

Interpretation:

The structure of carboxylic acid that is formed from the aldehyde when it undergoes oxidation has to be drawn.

Concept Introduction:

In organic chemistry, oxidation reaction is referred to the number C−O bonds increase and/or number of C−H bonds decrease.

In organic chemistry, reduction reaction is referred to the number C−O bonds decrease and/or number of C−H bonds increase.

Alcohols undergo oxidation reaction and reduction reaction. This depends upon the number of hydrogen atoms that is bonded to the alpha carbon atom. Primary and secondary alcohol undergoes oxidation reaction while tertiary alcohol does not undergo oxidation reaction. Primary alcohols undergo oxidation to give aldehyde and carboxylic acid as product. Secondary alcohol undergoes oxidation to give ketone as the product.

Aldehyde undergoes oxidation to give carboxylic acid as the product while ketone does not undergo oxidation reaction.

(c)

Interpretation Introduction

Interpretation:

The structure of carboxylic acid that is formed from the aldehyde when it undergoes oxidation has to be drawn.

Concept Introduction:

In organic chemistry, oxidation reaction is referred to the number C−O bonds increase and/or number of C−H bonds decrease.

In organic chemistry, reduction reaction is referred to the number C−O bonds decrease and/or number of C−H bonds increase.

Alcohols undergo oxidation reaction and reduction reaction. This depends upon the number of hydrogen atoms that is bonded to the alpha carbon atom. Primary and secondary alcohol undergoes oxidation reaction while tertiary alcohol does not undergo oxidation reaction. Primary alcohols undergo oxidation to give aldehyde and carboxylic acid as product. Secondary alcohol undergoes oxidation to give ketone as the product.

Aldehyde undergoes oxidation to give carboxylic acid as the product while ketone does not undergo oxidation reaction.

(d)

Interpretation Introduction

Interpretation:

The structure of carboxylic acid that is formed from the aldehyde when it undergoes oxidation has to be drawn.

Concept Introduction:

In organic chemistry, oxidation reaction is referred to the number C−O bonds increase and/or number of C−H bonds decrease.

In organic chemistry, reduction reaction is referred to the number C−O bonds decrease and/or number of C−H bonds increase.

Alcohols undergo oxidation reaction and reduction reaction. This depends upon the number of hydrogen atoms that is bonded to the alpha carbon atom. Primary and secondary alcohol undergoes oxidation reaction while tertiary alcohol does not undergo oxidation reaction. Primary alcohols undergo oxidation to give aldehyde and carboxylic acid as product. Secondary alcohol undergoes oxidation to give ketone as the product.

Aldehyde undergoes oxidation to give carboxylic acid as the product while ketone does not undergo oxidation reaction.

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Answer 5

Chapter 4, Problem 4.75EP

(a)

Interpretation Introduction

Interpretation:

The structure of carboxylic acid that is formed from the aldehyde when it undergoes oxidation has to be drawn.

Concept Introduction:

In organic chemistry, oxidation reaction is referred to the number C−O bonds increase and/or number of C−H bonds decrease.

In organic chemistry, reduction reaction is referred to the number C−O bonds decrease and/or number of C−H bonds increase.

Alcohols undergo oxidation reaction and reduction reaction. This depends upon the number of hydrogen atoms that is bonded to the alpha carbon atom. Primary and secondary alcohol undergoes oxidation reaction while tertiary alcohol does not undergo oxidation reaction. Primary alcohols undergo oxidation to give aldehyde and carboxylic acid as product. Secondary alcohol undergoes oxidation to give ketone as the product.

Aldehyde undergoes oxidation to give carboxylic acid as the product while ketone does not undergo oxidation reaction.

(b)

Interpretation Introduction

Interpretation:

The structure of carboxylic acid that is formed from the aldehyde when it undergoes oxidation has to be drawn.

Concept Introduction:

In organic chemistry, oxidation reaction is referred to the number C−O bonds increase and/or number of C−H bonds decrease.

In organic chemistry, reduction reaction is referred to the number C−O bonds decrease and/or number of C−H bonds increase.

Alcohols undergo oxidation reaction and reduction reaction. This depends upon the number of hydrogen atoms that is bonded to the alpha carbon atom. Primary and secondary alcohol undergoes oxidation reaction while tertiary alcohol does not undergo oxidation reaction. Primary alcohols undergo oxidation to give aldehyde and carboxylic acid as product. Secondary alcohol undergoes oxidation to give ketone as the product.

Aldehyde undergoes oxidation to give carboxylic acid as the product while ketone does not undergo oxidation reaction.

(c)

Interpretation Introduction

Interpretation:

The structure of carboxylic acid that is formed from the aldehyde when it undergoes oxidation has to be drawn.

Concept Introduction:

In organic chemistry, oxidation reaction is referred to the number C−O bonds increase and/or number of C−H bonds decrease.

In organic chemistry, reduction reaction is referred to the number C−O bonds decrease and/or number of C−H bonds increase.

Alcohols undergo oxidation reaction and reduction reaction. This depends upon the number of hydrogen atoms that is bonded to the alpha carbon atom. Primary and secondary alcohol undergoes oxidation reaction while tertiary alcohol does not undergo oxidation reaction. Primary alcohols undergo oxidation to give aldehyde and carboxylic acid as product. Secondary alcohol undergoes oxidation to give ketone as the product.

Aldehyde undergoes oxidation to give carboxylic acid as the product while ketone does not undergo oxidation reaction.

(d)

Interpretation Introduction

Interpretation:

The structure of carboxylic acid that is formed from the aldehyde when it undergoes oxidation has to be drawn.

Concept Introduction:

In organic chemistry, oxidation reaction is referred to the number C−O bonds increase and/or number of C−H bonds decrease.

In organic chemistry, reduction reaction is referred to the number C−O bonds decrease and/or number of C−H bonds increase.

Alcohols undergo oxidation reaction and reduction reaction. This depends upon the number of hydrogen atoms that is bonded to the alpha carbon atom. Primary and secondary alcohol undergoes oxidation reaction while tertiary alcohol does not undergo oxidation reaction. Primary alcohols undergo oxidation to give aldehyde and carboxylic acid as product. Secondary alcohol undergoes oxidation to give ketone as the product.

Aldehyde undergoes oxidation to give carboxylic acid as the product while ketone does not undergo oxidation reaction.

Answer 6

Chapter 4, Problem 4.75EP

(a)

Interpretation Introduction

Interpretation:

The structure of carboxylic acid that is formed from the aldehyde when it undergoes oxidation has to be drawn.

Concept Introduction:

In organic chemistry, oxidation reaction is referred to the number C−O bonds increase and/or number of C−H bonds decrease.

In organic chemistry, reduction reaction is referred to the number C−O bonds decrease and/or number of C−H bonds increase.

Alcohols undergo oxidation reaction and reduction reaction. This depends upon the number of hydrogen atoms that is bonded to the alpha carbon atom. Primary and secondary alcohol undergoes oxidation reaction while tertiary alcohol does not undergo oxidation reaction. Primary alcohols undergo oxidation to give aldehyde and carboxylic acid as product. Secondary alcohol undergoes oxidation to give ketone as the product.

Aldehyde undergoes oxidation to give carboxylic acid as the product while ketone does not undergo oxidation reaction.

Answer 7

Chapter 4, Problem 4.75EP

(a)

Interpretation Introduction

Interpretation:

The structure of carboxylic acid that is formed from the aldehyde when it undergoes oxidation has to be drawn.

Concept Introduction:

In organic chemistry, oxidation reaction is referred to the number C−O bonds increase and/or number of C−H bonds decrease.

In organic chemistry, reduction reaction is referred to the number C−O bonds decrease and/or number of C−H bonds increase.

Alcohols undergo oxidation reaction and reduction reaction. This depends upon the number of hydrogen atoms that is bonded to the alpha carbon atom. Primary and secondary alcohol undergoes oxidation reaction while tertiary alcohol does not undergo oxidation reaction. Primary alcohols undergo oxidation to give aldehyde and carboxylic acid as product. Secondary alcohol undergoes oxidation to give ketone as the product.

Aldehyde undergoes oxidation to give carboxylic acid as the product while ketone does not undergo oxidation reaction.

Answer 8

(b)

Interpretation Introduction

Interpretation:

The structure of carboxylic acid that is formed from the aldehyde when it undergoes oxidation has to be drawn.

Concept Introduction:

In organic chemistry, oxidation reaction is referred to the number C−O bonds increase and/or number of C−H bonds decrease.

In organic chemistry, reduction reaction is referred to the number C−O bonds decrease and/or number of C−H bonds increase.

Alcohols undergo oxidation reaction and reduction reaction. This depends upon the number of hydrogen atoms that is bonded to the alpha carbon atom. Primary and secondary alcohol undergoes oxidation reaction while tertiary alcohol does not undergo oxidation reaction. Primary alcohols undergo oxidation to give aldehyde and carboxylic acid as product. Secondary alcohol undergoes oxidation to give ketone as the product.

Aldehyde undergoes oxidation to give carboxylic acid as the product while ketone does not undergo oxidation reaction.

Answer 9

(b)

Interpretation Introduction

Interpretation:

The structure of carboxylic acid that is formed from the aldehyde when it undergoes oxidation has to be drawn.

Concept Introduction:

In organic chemistry, oxidation reaction is referred to the number C−O bonds increase and/or number of C−H bonds decrease.

In organic chemistry, reduction reaction is referred to the number C−O bonds decrease and/or number of C−H bonds increase.

Alcohols undergo oxidation reaction and reduction reaction. This depends upon the number of hydrogen atoms that is bonded to the alpha carbon atom. Primary and secondary alcohol undergoes oxidation reaction while tertiary alcohol does not undergo oxidation reaction. Primary alcohols undergo oxidation to give aldehyde and carboxylic acid as product. Secondary alcohol undergoes oxidation to give ketone as the product.

Aldehyde undergoes oxidation to give carboxylic acid as the product while ketone does not undergo oxidation reaction.

Answer 10

(c)

Interpretation Introduction

Interpretation:

The structure of carboxylic acid that is formed from the aldehyde when it undergoes oxidation has to be drawn.

Concept Introduction:

In organic chemistry, oxidation reaction is referred to the number C−O bonds increase and/or number of C−H bonds decrease.

In organic chemistry, reduction reaction is referred to the number C−O bonds decrease and/or number of C−H bonds increase.

Alcohols undergo oxidation reaction and reduction reaction. This depends upon the number of hydrogen atoms that is bonded to the alpha carbon atom. Primary and secondary alcohol undergoes oxidation reaction while tertiary alcohol does not undergo oxidation reaction. Primary alcohols undergo oxidation to give aldehyde and carboxylic acid as product. Secondary alcohol undergoes oxidation to give ketone as the product.

Aldehyde undergoes oxidation to give carboxylic acid as the product while ketone does not undergo oxidation reaction.

Answer 11

(c)

Interpretation Introduction

Interpretation:

The structure of carboxylic acid that is formed from the aldehyde when it undergoes oxidation has to be drawn.

Concept Introduction:

In organic chemistry, oxidation reaction is referred to the number C−O bonds increase and/or number of C−H bonds decrease.

In organic chemistry, reduction reaction is referred to the number C−O bonds decrease and/or number of C−H bonds increase.

Alcohols undergo oxidation reaction and reduction reaction. This depends upon the number of hydrogen atoms that is bonded to the alpha carbon atom. Primary and secondary alcohol undergoes oxidation reaction while tertiary alcohol does not undergo oxidation reaction. Primary alcohols undergo oxidation to give aldehyde and carboxylic acid as product. Secondary alcohol undergoes oxidation to give ketone as the product.

Aldehyde undergoes oxidation to give carboxylic acid as the product while ketone does not undergo oxidation reaction.

Answer 12

(d)

Interpretation Introduction

Interpretation:

The structure of carboxylic acid that is formed from the aldehyde when it undergoes oxidation has to be drawn.

Concept Introduction:

In organic chemistry, oxidation reaction is referred to the number C−O bonds increase and/or number of C−H bonds decrease.

In organic chemistry, reduction reaction is referred to the number C−O bonds decrease and/or number of C−H bonds increase.

Alcohols undergo oxidation reaction and reduction reaction. This depends upon the number of hydrogen atoms that is bonded to the alpha carbon atom. Primary and secondary alcohol undergoes oxidation reaction while tertiary alcohol does not undergo oxidation reaction. Primary alcohols undergo oxidation to give aldehyde and carboxylic acid as product. Secondary alcohol undergoes oxidation to give ketone as the product.

Aldehyde undergoes oxidation to give carboxylic acid as the product while ketone does not undergo oxidation reaction.

Answer 13

(d)

Interpretation Introduction

Interpretation:

The structure of carboxylic acid that is formed from the aldehyde when it undergoes oxidation has to be drawn.

Concept Introduction:

In organic chemistry, oxidation reaction is referred to the number C−O bonds increase and/or number of C−H bonds decrease.

In organic chemistry, reduction reaction is referred to the number C−O bonds decrease and/or number of C−H bonds increase.

Alcohols undergo oxidation reaction and reduction reaction. This depends upon the number of hydrogen atoms that is bonded to the alpha carbon atom. Primary and secondary alcohol undergoes oxidation reaction while tertiary alcohol does not undergo oxidation reaction. Primary alcohols undergo oxidation to give aldehyde and carboxylic acid as product. Secondary alcohol undergoes oxidation to give ketone as the product.

Aldehyde undergoes oxidation to give carboxylic acid as the product while ketone does not undergo oxidation reaction.

Answer 14

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Answer 25

Ch. 4.1 - Prob. 1QQ Ch. 4.1 - Prob. 2QQ Ch. 4.2 - Prob. 1QQ Ch. 4.2 - Prob. 2QQ Ch. 4.2 - Prob. 3QQ Ch. 4.3 - Prob. 1QQ Ch. 4.3 - Prob. 2QQ Ch. 4.3 - Prob. 3QQ Ch. 4.4 - Prob. 1QQ Ch. 4.4 - Prob. 2QQ

Solution Summary: The author explains the structure of carboxylic acid that is formed from the aldehyde when it undergoes oxidation.

Chapter 4 Solutions