The given ketone has to be named using IUPAC nomenclature . Concept Introduction: For naming a ketone in IUPAC nomenclature, the suffix “-one” is added to the parent alkane name. IUPAC rules for naming a ketone: The longest parent carbon chain is identified that includes the carbonyl group. The parent chain name is changed by replacing the suffix “-e” with “-one”. Numbering is done in a way that the carbonyl group gets the least numbering. The position of the carbonyl group is indicated in the name. The identity and location of substituents if any has to be determined and this information has to be added in front of the IUPAC name. Cyclic ketones are named by adding the suffix “-one” to the name of the carbon ring. The substituents are numbered so that it gets the least numbering starting from the carbonyl group that is given the number 1.

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Answer 1

Question

Chapter 4, Problem 4.31EP

(a)

Interpretation Introduction

Interpretation:

The given ketone has to be named using IUPAC nomenclature.

Concept Introduction:

For naming a ketone in IUPAC nomenclature, the suffix “-one” is added to the parent alkane name.

IUPAC rules for naming a ketone:

The longest parent carbon chain is identified that includes the carbonyl group.

The parent chain name is changed by replacing the suffix “-e” with “-one”.

Numbering is done in a way that the carbonyl group gets the least numbering. The position of the carbonyl group is indicated in the name.

The identity and location of substituents if any has to be determined and this information has to be added in front of the IUPAC name.

Cyclic ketones are named by adding the suffix “-one” to the name of the carbon ring. The substituents are numbered so that it gets the least numbering starting from the carbonyl group that is given the number 1.

(b)

Interpretation Introduction

Interpretation:

The given ketone has to be named using IUPAC nomenclature.

Concept Introduction:

For naming a ketone in IUPAC nomenclature, the suffix “-one” is added to the parent alkane name.

IUPAC rules for naming a ketone:

The longest parent carbon chain is identified that includes the carbonyl group.

The parent chain name is changed by replacing the suffix “-e” with “-one”.

Numbering is done in a way that the carbonyl group gets the least numbering. The position of the carbonyl group is indicated in the name.

The identity and location of substituents if any has to be determined and this information has to be added in front of the IUPAC name.

Cyclic ketones are named by adding the suffix “-one” to the name of the carbon ring. The substituents are numbered so that it gets the least numbering starting from the carbonyl group that is given the number 1.

(c)

Interpretation Introduction

Interpretation:

The given ketone has to be named using IUPAC nomenclature.

Concept Introduction:

For naming a ketone in IUPAC nomenclature, the suffix “-one” is added to the parent alkane name.

IUPAC rules for naming a ketone:

The longest parent carbon chain is identified that includes the carbonyl group.

The parent chain name is changed by replacing the suffix “-e” with “-one”.

Numbering is done in a way that the carbonyl group gets the least numbering. The position of the carbonyl group is indicated in the name.

The identity and location of substituents if any has to be determined and this information has to be added in front of the IUPAC name.

Cyclic ketones are named by adding the suffix “-one” to the name of the carbon ring. The substituents are numbered so that it gets the least numbering starting from the carbonyl group that is given the number 1.

(d)

Interpretation Introduction

Interpretation:

The given ketone has to be named using IUPAC nomenclature.

Concept Introduction:

For naming a ketone in IUPAC nomenclature, the suffix “-one” is added to the parent alkane name.

IUPAC rules for naming a ketone:

The longest parent carbon chain is identified that includes the carbonyl group.

The parent chain name is changed by replacing the suffix “-e” with “-one”.

Numbering is done in a way that the carbonyl group gets the least numbering. The position of the carbonyl group is indicated in the name.

The identity and location of substituents if any has to be determined and this information has to be added in front of the IUPAC name.

Cyclic ketones are named by adding the suffix “-one” to the name of the carbon ring. The substituents are numbered so that it gets the least numbering starting from the carbonyl group that is given the number 1.

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The reaction: 2NO2(g) ⇌ N2O4(g) is an exothermic reaction, ΔH=-58.0 kJ/molrxn at 0°C the KP is 58.If the initial partial pressures of both NO2(g) and N2O4(g) are 2.00 atm:A) Is the reaction at equilibrium? If not, what is the value of Q? B) Which direction will the reaction go to reach equilibrium? C) Use an ICE table to find the equilibrium pressures.

The dissociation of the weak acid, nitrous acid, HNO2, takes place according to the reaction: HNO2 (aq) ⇌ H+(aq) + NO2–(aq) K=7.2 X 10-4 When 1.00 mole of HNO2 is added to 1.00 L of water, the H+ concentration at equilibrium is 0.0265 M.A) Calculate the value of Q if 1.00 L of water is added? B) How will reaction shift if 1.00 L of water is added?

Answer 2

Question

Chapter 4, Problem 4.31EP

(a)

Interpretation Introduction

Interpretation:

The given ketone has to be named using IUPAC nomenclature.

Concept Introduction:

For naming a ketone in IUPAC nomenclature, the suffix “-one” is added to the parent alkane name.

IUPAC rules for naming a ketone:

The longest parent carbon chain is identified that includes the carbonyl group.

The parent chain name is changed by replacing the suffix “-e” with “-one”.

Numbering is done in a way that the carbonyl group gets the least numbering. The position of the carbonyl group is indicated in the name.

The identity and location of substituents if any has to be determined and this information has to be added in front of the IUPAC name.

Cyclic ketones are named by adding the suffix “-one” to the name of the carbon ring. The substituents are numbered so that it gets the least numbering starting from the carbonyl group that is given the number 1.

(b)

Interpretation Introduction

Interpretation:

The given ketone has to be named using IUPAC nomenclature.

Concept Introduction:

For naming a ketone in IUPAC nomenclature, the suffix “-one” is added to the parent alkane name.

IUPAC rules for naming a ketone:

The longest parent carbon chain is identified that includes the carbonyl group.

The parent chain name is changed by replacing the suffix “-e” with “-one”.

Numbering is done in a way that the carbonyl group gets the least numbering. The position of the carbonyl group is indicated in the name.

The identity and location of substituents if any has to be determined and this information has to be added in front of the IUPAC name.

Cyclic ketones are named by adding the suffix “-one” to the name of the carbon ring. The substituents are numbered so that it gets the least numbering starting from the carbonyl group that is given the number 1.

(c)

Interpretation Introduction

Interpretation:

The given ketone has to be named using IUPAC nomenclature.

Concept Introduction:

For naming a ketone in IUPAC nomenclature, the suffix “-one” is added to the parent alkane name.

IUPAC rules for naming a ketone:

The longest parent carbon chain is identified that includes the carbonyl group.

The parent chain name is changed by replacing the suffix “-e” with “-one”.

Numbering is done in a way that the carbonyl group gets the least numbering. The position of the carbonyl group is indicated in the name.

The identity and location of substituents if any has to be determined and this information has to be added in front of the IUPAC name.

Cyclic ketones are named by adding the suffix “-one” to the name of the carbon ring. The substituents are numbered so that it gets the least numbering starting from the carbonyl group that is given the number 1.

(d)

Interpretation Introduction

Interpretation:

The given ketone has to be named using IUPAC nomenclature.

Concept Introduction:

For naming a ketone in IUPAC nomenclature, the suffix “-one” is added to the parent alkane name.

IUPAC rules for naming a ketone:

The longest parent carbon chain is identified that includes the carbonyl group.

The parent chain name is changed by replacing the suffix “-e” with “-one”.

Numbering is done in a way that the carbonyl group gets the least numbering. The position of the carbonyl group is indicated in the name.

The identity and location of substituents if any has to be determined and this information has to be added in front of the IUPAC name.

Cyclic ketones are named by adding the suffix “-one” to the name of the carbon ring. The substituents are numbered so that it gets the least numbering starting from the carbonyl group that is given the number 1.

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Answer 3

Question

Chapter 4, Problem 4.31EP

(a)

Interpretation Introduction

Interpretation:

The given ketone has to be named using IUPAC nomenclature.

Concept Introduction:

For naming a ketone in IUPAC nomenclature, the suffix “-one” is added to the parent alkane name.

IUPAC rules for naming a ketone:

The longest parent carbon chain is identified that includes the carbonyl group.

The parent chain name is changed by replacing the suffix “-e” with “-one”.

Numbering is done in a way that the carbonyl group gets the least numbering. The position of the carbonyl group is indicated in the name.

The identity and location of substituents if any has to be determined and this information has to be added in front of the IUPAC name.

Cyclic ketones are named by adding the suffix “-one” to the name of the carbon ring. The substituents are numbered so that it gets the least numbering starting from the carbonyl group that is given the number 1.

(b)

Interpretation Introduction

Interpretation:

The given ketone has to be named using IUPAC nomenclature.

Concept Introduction:

For naming a ketone in IUPAC nomenclature, the suffix “-one” is added to the parent alkane name.

IUPAC rules for naming a ketone:

The longest parent carbon chain is identified that includes the carbonyl group.

The parent chain name is changed by replacing the suffix “-e” with “-one”.

Numbering is done in a way that the carbonyl group gets the least numbering. The position of the carbonyl group is indicated in the name.

The identity and location of substituents if any has to be determined and this information has to be added in front of the IUPAC name.

Cyclic ketones are named by adding the suffix “-one” to the name of the carbon ring. The substituents are numbered so that it gets the least numbering starting from the carbonyl group that is given the number 1.

(c)

Interpretation Introduction

Interpretation:

The given ketone has to be named using IUPAC nomenclature.

Concept Introduction:

For naming a ketone in IUPAC nomenclature, the suffix “-one” is added to the parent alkane name.

IUPAC rules for naming a ketone:

The longest parent carbon chain is identified that includes the carbonyl group.

The parent chain name is changed by replacing the suffix “-e” with “-one”.

Numbering is done in a way that the carbonyl group gets the least numbering. The position of the carbonyl group is indicated in the name.

The identity and location of substituents if any has to be determined and this information has to be added in front of the IUPAC name.

Cyclic ketones are named by adding the suffix “-one” to the name of the carbon ring. The substituents are numbered so that it gets the least numbering starting from the carbonyl group that is given the number 1.

(d)

Interpretation Introduction

Interpretation:

The given ketone has to be named using IUPAC nomenclature.

Concept Introduction:

For naming a ketone in IUPAC nomenclature, the suffix “-one” is added to the parent alkane name.

IUPAC rules for naming a ketone:

The longest parent carbon chain is identified that includes the carbonyl group.

The parent chain name is changed by replacing the suffix “-e” with “-one”.

Numbering is done in a way that the carbonyl group gets the least numbering. The position of the carbonyl group is indicated in the name.

The identity and location of substituents if any has to be determined and this information has to be added in front of the IUPAC name.

Cyclic ketones are named by adding the suffix “-one” to the name of the carbon ring. The substituents are numbered so that it gets the least numbering starting from the carbonyl group that is given the number 1.

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Answer 4

Question

Chapter 4, Problem 4.31EP

(a)

Interpretation Introduction

Interpretation:

The given ketone has to be named using IUPAC nomenclature.

Concept Introduction:

For naming a ketone in IUPAC nomenclature, the suffix “-one” is added to the parent alkane name.

IUPAC rules for naming a ketone:

The longest parent carbon chain is identified that includes the carbonyl group.

The parent chain name is changed by replacing the suffix “-e” with “-one”.

Numbering is done in a way that the carbonyl group gets the least numbering. The position of the carbonyl group is indicated in the name.

The identity and location of substituents if any has to be determined and this information has to be added in front of the IUPAC name.

Cyclic ketones are named by adding the suffix “-one” to the name of the carbon ring. The substituents are numbered so that it gets the least numbering starting from the carbonyl group that is given the number 1.

(b)

Interpretation Introduction

Interpretation:

The given ketone has to be named using IUPAC nomenclature.

Concept Introduction:

For naming a ketone in IUPAC nomenclature, the suffix “-one” is added to the parent alkane name.

IUPAC rules for naming a ketone:

The longest parent carbon chain is identified that includes the carbonyl group.

The parent chain name is changed by replacing the suffix “-e” with “-one”.

Numbering is done in a way that the carbonyl group gets the least numbering. The position of the carbonyl group is indicated in the name.

The identity and location of substituents if any has to be determined and this information has to be added in front of the IUPAC name.

Cyclic ketones are named by adding the suffix “-one” to the name of the carbon ring. The substituents are numbered so that it gets the least numbering starting from the carbonyl group that is given the number 1.

(c)

Interpretation Introduction

Interpretation:

The given ketone has to be named using IUPAC nomenclature.

Concept Introduction:

For naming a ketone in IUPAC nomenclature, the suffix “-one” is added to the parent alkane name.

IUPAC rules for naming a ketone:

The longest parent carbon chain is identified that includes the carbonyl group.

The parent chain name is changed by replacing the suffix “-e” with “-one”.

Numbering is done in a way that the carbonyl group gets the least numbering. The position of the carbonyl group is indicated in the name.

The identity and location of substituents if any has to be determined and this information has to be added in front of the IUPAC name.

Cyclic ketones are named by adding the suffix “-one” to the name of the carbon ring. The substituents are numbered so that it gets the least numbering starting from the carbonyl group that is given the number 1.

(d)

Interpretation Introduction

Interpretation:

The given ketone has to be named using IUPAC nomenclature.

Concept Introduction:

For naming a ketone in IUPAC nomenclature, the suffix “-one” is added to the parent alkane name.

IUPAC rules for naming a ketone:

The longest parent carbon chain is identified that includes the carbonyl group.

The parent chain name is changed by replacing the suffix “-e” with “-one”.

Numbering is done in a way that the carbonyl group gets the least numbering. The position of the carbonyl group is indicated in the name.

The identity and location of substituents if any has to be determined and this information has to be added in front of the IUPAC name.

Cyclic ketones are named by adding the suffix “-one” to the name of the carbon ring. The substituents are numbered so that it gets the least numbering starting from the carbonyl group that is given the number 1.

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Answer 5

Chapter 4, Problem 4.31EP

(a)

Interpretation Introduction

Interpretation:

The given ketone has to be named using IUPAC nomenclature.

Concept Introduction:

For naming a ketone in IUPAC nomenclature, the suffix “-one” is added to the parent alkane name.

IUPAC rules for naming a ketone:

The longest parent carbon chain is identified that includes the carbonyl group.

The parent chain name is changed by replacing the suffix “-e” with “-one”.

Numbering is done in a way that the carbonyl group gets the least numbering. The position of the carbonyl group is indicated in the name.

The identity and location of substituents if any has to be determined and this information has to be added in front of the IUPAC name.

Cyclic ketones are named by adding the suffix “-one” to the name of the carbon ring. The substituents are numbered so that it gets the least numbering starting from the carbonyl group that is given the number 1.

(b)

Interpretation Introduction

Interpretation:

The given ketone has to be named using IUPAC nomenclature.

Concept Introduction:

For naming a ketone in IUPAC nomenclature, the suffix “-one” is added to the parent alkane name.

IUPAC rules for naming a ketone:

The longest parent carbon chain is identified that includes the carbonyl group.

The parent chain name is changed by replacing the suffix “-e” with “-one”.

Numbering is done in a way that the carbonyl group gets the least numbering. The position of the carbonyl group is indicated in the name.

The identity and location of substituents if any has to be determined and this information has to be added in front of the IUPAC name.

Cyclic ketones are named by adding the suffix “-one” to the name of the carbon ring. The substituents are numbered so that it gets the least numbering starting from the carbonyl group that is given the number 1.

(c)

Interpretation Introduction

Interpretation:

The given ketone has to be named using IUPAC nomenclature.

Concept Introduction:

For naming a ketone in IUPAC nomenclature, the suffix “-one” is added to the parent alkane name.

IUPAC rules for naming a ketone:

The longest parent carbon chain is identified that includes the carbonyl group.

The parent chain name is changed by replacing the suffix “-e” with “-one”.

Numbering is done in a way that the carbonyl group gets the least numbering. The position of the carbonyl group is indicated in the name.

The identity and location of substituents if any has to be determined and this information has to be added in front of the IUPAC name.

Cyclic ketones are named by adding the suffix “-one” to the name of the carbon ring. The substituents are numbered so that it gets the least numbering starting from the carbonyl group that is given the number 1.

(d)

Interpretation Introduction

Interpretation:

The given ketone has to be named using IUPAC nomenclature.

Concept Introduction:

For naming a ketone in IUPAC nomenclature, the suffix “-one” is added to the parent alkane name.

IUPAC rules for naming a ketone:

The longest parent carbon chain is identified that includes the carbonyl group.

The parent chain name is changed by replacing the suffix “-e” with “-one”.

Numbering is done in a way that the carbonyl group gets the least numbering. The position of the carbonyl group is indicated in the name.

The identity and location of substituents if any has to be determined and this information has to be added in front of the IUPAC name.

Cyclic ketones are named by adding the suffix “-one” to the name of the carbon ring. The substituents are numbered so that it gets the least numbering starting from the carbonyl group that is given the number 1.

Answer 6

Chapter 4, Problem 4.31EP

(a)

Interpretation Introduction

Interpretation:

The given ketone has to be named using IUPAC nomenclature.

Concept Introduction:

For naming a ketone in IUPAC nomenclature, the suffix “-one” is added to the parent alkane name.

IUPAC rules for naming a ketone:

The longest parent carbon chain is identified that includes the carbonyl group.

The parent chain name is changed by replacing the suffix “-e” with “-one”.

Numbering is done in a way that the carbonyl group gets the least numbering. The position of the carbonyl group is indicated in the name.

The identity and location of substituents if any has to be determined and this information has to be added in front of the IUPAC name.

Cyclic ketones are named by adding the suffix “-one” to the name of the carbon ring. The substituents are numbered so that it gets the least numbering starting from the carbonyl group that is given the number 1.

Answer 7

Chapter 4, Problem 4.31EP

(a)

Interpretation Introduction

Interpretation:

The given ketone has to be named using IUPAC nomenclature.

Concept Introduction:

For naming a ketone in IUPAC nomenclature, the suffix “-one” is added to the parent alkane name.

IUPAC rules for naming a ketone:

The longest parent carbon chain is identified that includes the carbonyl group.

The parent chain name is changed by replacing the suffix “-e” with “-one”.

Numbering is done in a way that the carbonyl group gets the least numbering. The position of the carbonyl group is indicated in the name.

The identity and location of substituents if any has to be determined and this information has to be added in front of the IUPAC name.

Cyclic ketones are named by adding the suffix “-one” to the name of the carbon ring. The substituents are numbered so that it gets the least numbering starting from the carbonyl group that is given the number 1.

Answer 8

(b)

Interpretation Introduction

Interpretation:

The given ketone has to be named using IUPAC nomenclature.

Concept Introduction:

For naming a ketone in IUPAC nomenclature, the suffix “-one” is added to the parent alkane name.

IUPAC rules for naming a ketone:

The longest parent carbon chain is identified that includes the carbonyl group.

The parent chain name is changed by replacing the suffix “-e” with “-one”.

Numbering is done in a way that the carbonyl group gets the least numbering. The position of the carbonyl group is indicated in the name.

The identity and location of substituents if any has to be determined and this information has to be added in front of the IUPAC name.

Cyclic ketones are named by adding the suffix “-one” to the name of the carbon ring. The substituents are numbered so that it gets the least numbering starting from the carbonyl group that is given the number 1.

Answer 9

(b)

Interpretation Introduction

Interpretation:

The given ketone has to be named using IUPAC nomenclature.

Concept Introduction:

For naming a ketone in IUPAC nomenclature, the suffix “-one” is added to the parent alkane name.

IUPAC rules for naming a ketone:

The longest parent carbon chain is identified that includes the carbonyl group.

The parent chain name is changed by replacing the suffix “-e” with “-one”.

Numbering is done in a way that the carbonyl group gets the least numbering. The position of the carbonyl group is indicated in the name.

The identity and location of substituents if any has to be determined and this information has to be added in front of the IUPAC name.

Cyclic ketones are named by adding the suffix “-one” to the name of the carbon ring. The substituents are numbered so that it gets the least numbering starting from the carbonyl group that is given the number 1.

Answer 10

(c)

Interpretation Introduction

Interpretation:

The given ketone has to be named using IUPAC nomenclature.

Concept Introduction:

For naming a ketone in IUPAC nomenclature, the suffix “-one” is added to the parent alkane name.

IUPAC rules for naming a ketone:

The longest parent carbon chain is identified that includes the carbonyl group.

The parent chain name is changed by replacing the suffix “-e” with “-one”.

Numbering is done in a way that the carbonyl group gets the least numbering. The position of the carbonyl group is indicated in the name.

The identity and location of substituents if any has to be determined and this information has to be added in front of the IUPAC name.

Cyclic ketones are named by adding the suffix “-one” to the name of the carbon ring. The substituents are numbered so that it gets the least numbering starting from the carbonyl group that is given the number 1.

Answer 11

(c)

Interpretation Introduction

Interpretation:

The given ketone has to be named using IUPAC nomenclature.

Concept Introduction:

For naming a ketone in IUPAC nomenclature, the suffix “-one” is added to the parent alkane name.

IUPAC rules for naming a ketone:

The longest parent carbon chain is identified that includes the carbonyl group.

The parent chain name is changed by replacing the suffix “-e” with “-one”.

Numbering is done in a way that the carbonyl group gets the least numbering. The position of the carbonyl group is indicated in the name.

The identity and location of substituents if any has to be determined and this information has to be added in front of the IUPAC name.

Cyclic ketones are named by adding the suffix “-one” to the name of the carbon ring. The substituents are numbered so that it gets the least numbering starting from the carbonyl group that is given the number 1.

Answer 12

(d)

Interpretation Introduction

Interpretation:

The given ketone has to be named using IUPAC nomenclature.

Concept Introduction:

For naming a ketone in IUPAC nomenclature, the suffix “-one” is added to the parent alkane name.

IUPAC rules for naming a ketone:

The longest parent carbon chain is identified that includes the carbonyl group.

The parent chain name is changed by replacing the suffix “-e” with “-one”.

Numbering is done in a way that the carbonyl group gets the least numbering. The position of the carbonyl group is indicated in the name.

The identity and location of substituents if any has to be determined and this information has to be added in front of the IUPAC name.

Cyclic ketones are named by adding the suffix “-one” to the name of the carbon ring. The substituents are numbered so that it gets the least numbering starting from the carbonyl group that is given the number 1.

Answer 13

(d)

Interpretation Introduction

Interpretation:

The given ketone has to be named using IUPAC nomenclature.

Concept Introduction:

For naming a ketone in IUPAC nomenclature, the suffix “-one” is added to the parent alkane name.

IUPAC rules for naming a ketone:

The longest parent carbon chain is identified that includes the carbonyl group.

The parent chain name is changed by replacing the suffix “-e” with “-one”.

Numbering is done in a way that the carbonyl group gets the least numbering. The position of the carbonyl group is indicated in the name.

The identity and location of substituents if any has to be determined and this information has to be added in front of the IUPAC name.

Cyclic ketones are named by adding the suffix “-one” to the name of the carbon ring. The substituents are numbered so that it gets the least numbering starting from the carbonyl group that is given the number 1.

Answer 14

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Answer 25

Ch. 4.1 - Prob. 1QQ Ch. 4.1 - Prob. 2QQ Ch. 4.2 - Prob. 1QQ Ch. 4.2 - Prob. 2QQ Ch. 4.2 - Prob. 3QQ Ch. 4.3 - Prob. 1QQ Ch. 4.3 - Prob. 2QQ Ch. 4.3 - Prob. 3QQ Ch. 4.4 - Prob. 1QQ Ch. 4.4 - Prob. 2QQ

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Chapter 4 Solutions