Concept explainers
(a)
Interpretation:
The IUPAC names of the product formed from hydrolysis of given acetal in an acid solution has to be given.
Concept Introduction:
Aldehydes and ketones react with alcohol to form hemiacetal as the product. This reacts with further molecule of aldehyde or ketone to form acetal.
Acetals are stable in basic solution. But in acidic solution, they undergo hydrolysis. Hydrolysis is a
Hemiacetal undergoes hydrolysis in acidic solution to form one alcohol molecule and ketone or aldehyde molecule. The general reaction for hydrolysis of hemiacetal in acid solution,
Acetal undergoes hydrolysis in acidic solution to form two alcohol molecules and ketone or aldehyde molecule. The general reaction for hydrolysis of acetal in acid solution,
(b)
Interpretation:
The IUPAC names of the product formed from hydrolysis of given acetal in an acid solution has to be given.
Concept Introduction:
Aldehydes contain a carbonyl group that is bonded to a hydrogen atom and a carbon atom. Ketones are compounds that contain a carbonyl group bonded to two carbon atoms. Aldehydes and ketones undergo addition reaction across the carbonyl group.
Aldehydes and ketones react with alcohol to form hemiacetal as the product. This reacts with further molecule of aldehyde or ketone to form acetal.
Acetals are stable in basic solution. But in acidic solution, they undergo hydrolysis. Hydrolysis is a chemical reaction in which the compound splits into two or more fragments when water is added to the compound in presence of acid or base as catalyst. Acetals undergo hydrolysis to give the respective starting materials from which it is formed.
Hemiacetal undergoes hydrolysis in acidic solution to form one alcohol molecule and ketone or aldehyde molecule. The general reaction for hydrolysis of hemiacetal in acid solution,
Acetal undergoes hydrolysis in acidic solution to form two alcohol molecules and ketone or aldehyde molecule. The general reaction for hydrolysis of acetal in acid solution,
(c)
Interpretation:
The IUPAC names of the product formed from hydrolysis of given acetal in an acid solution has to be given.
Concept Introduction:
Aldehydes contain a carbonyl group that is bonded to a hydrogen atom and a carbon atom. Ketones are compounds that contain a carbonyl group bonded to two carbon atoms. Aldehydes and ketones undergo addition reaction across the carbonyl group.
Aldehydes and ketones react with alcohol to form hemiacetal as the product. This reacts with further molecule of aldehyde or ketone to form acetal.
Acetals are stable in basic solution. But in acidic solution, they undergo hydrolysis. Hydrolysis is a chemical reaction in which the compound splits into two or more fragments when water is added to the compound in presence of acid or base as catalyst. Acetals undergo hydrolysis to give the respective starting materials from which it is formed.
Hemiacetal undergoes hydrolysis in acidic solution to form one alcohol molecule and ketone or aldehyde molecule. The general reaction for hydrolysis of hemiacetal in acid solution,
Acetal undergoes hydrolysis in acidic solution to form two alcohol molecules and ketone or aldehyde molecule. The general reaction for hydrolysis of acetal in acid solution,
(d)
Interpretation:
The IUPAC names of the product formed from hydrolysis of given acetal in an acid solution has to be given.
Concept Introduction:
Aldehydes contain a carbonyl group that is bonded to a hydrogen atom and a carbon atom. Ketones are compounds that contain a carbonyl group bonded to two carbon atoms. Aldehydes and ketones undergo addition reaction across the carbonyl group.
Aldehydes and ketones react with alcohol to form hemiacetal as the product. This reacts with further molecule of aldehyde or ketone to form acetal.
Acetals are stable in basic solution. But in acidic solution, they undergo hydrolysis. Hydrolysis is a chemical reaction in which the compound splits into two or more fragments when water is added to the compound in presence of acid or base as catalyst. Acetals undergo hydrolysis to give the respective starting materials from which it is formed.
Hemiacetal undergoes hydrolysis in acidic solution to form one alcohol molecule and ketone or aldehyde molecule. The general reaction for hydrolysis of hemiacetal in acid solution,
Acetal undergoes hydrolysis in acidic solution to form two alcohol molecules and ketone or aldehyde molecule. The general reaction for hydrolysis of acetal in acid solution,
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Chapter 4 Solutions
Organic And Biological Chemistry
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- theres 2 productsarrow_forwardDraw the major product of this solvolysis reaction. Ignore any inorganic byproducts. + CH3CH2OH Drawing Q Atoms, Bonds and Rings OCH2CH3 || OEt Charges OH 00-> | Undo Reset | Br Remove Done Drag To Pan +arrow_forwardDraw the major product of this SN1 reaction. Ignore any inorganic byproducts. CH3CO2Na CH3CO2H Drawing + Br Q Atoms, Bonds and Rings OAC Charges OH ОАс Na ဂ Br Undo Reset Remove Done Drag To Pan +arrow_forward
- Organic Functional Groups entifying positions labeled with Greek letters in acids and derivatives 1/5 ssible, replace an H atom on the a carbon of the molecule in the drawing area with a ce an H atom on the ẞ carbon with a hydroxyl group substituent. ne of the substituents can't be added for any reason, just don't add it. If neither substi er the drawing area. O H OH Oneither substituent can be added. Check D 1 Accessibility ado na witharrow_forwardDifferentiate between electrophilic and nucleophilic groups. Give examples.arrow_forwardAn aldehyde/ketone plus an alcohol gives a hemiacetal, and an excess of alcohol gives an acetal. The reaction is an equilibrium; in aldehydes, it's shifted to the right and in ketones, to the left. Explain.arrow_forward
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