Structural formula for the given aldehyde has to be drawn. Concept Introduction: Structure of the given aldehyde can be drawn from the IUPAC name. In the IUPAC name, the parent chain of carbon atom can be identified and then the substituents present in it can also be identified. With these information, the structure for the given compound can be drawn. In an aldehyde the counting has to be always from the carbonyl carbon that is given the number 1. The structural representation of organic compound can be done in 2D and 3D. In two-dimensional representation, there are four types of representation in which an organic compound can be drawn. They are, • Expanded structural formula • Condensed structural formula • Skeletal structural formula • Line-angle structural formula Structural formula which shows all the atoms in a molecule along with all the bonds that is connecting the atoms present in the molecule is known as Expanded structural formula. Structural formula in which grouping of atoms are done and in which the central atoms along with the other atoms are connected to them are treated as group is known as Condensed structural formula. Structural formula that shows the bonding between carbon atoms alone in the molecule ignoring the hydrogen atoms being shown explicitly is known as Skeletal structural formula. Structural formula where a line represent carbon‑carbon bond and the carbon atom is considered to be present in each point and the end of lines is known as Line-angle structural formula.

Question

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Answer 1

Question

Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 4, Problem 4.25EP

(a)

Interpretation Introduction

Interpretation:

Structural formula for the given aldehyde has to be drawn.

Concept Introduction:

Structure of the given aldehyde can be drawn from the IUPAC name. In the IUPAC name, the parent chain of carbon atom can be identified and then the substituents present in it can also be identified. With these information, the structure for the given compound can be drawn. In an aldehyde the counting has to be always from the carbonyl carbon that is given the number 1.

The structural representation of organic compound can be done in 2D and 3D. In two-dimensional representation, there are four types of representation in which an organic compound can be drawn. They are,

• Expanded structural formula

• Condensed structural formula

• Skeletal structural formula

• Line-angle structural formula

Structural formula which shows all the atoms in a molecule along with all the bonds that is connecting the atoms present in the molecule is known as Expanded structural formula.

Structural formula in which grouping of atoms are done and in which the central atoms along with the other atoms are connected to them are treated as group is known as Condensed structural formula.

Structural formula that shows the bonding between carbon atoms alone in the molecule ignoring the hydrogen atoms being shown explicitly is known as Skeletal structural formula.

Structural formula where a line represent carbon‑carbon bond and the carbon atom is considered to be present in each point and the end of lines is known as Line-angle structural formula.

(a)

Expert Solution

Answer to Problem 4.25EP

The structural formula for formaldehyde is,

Organic And Biological Chemistry, Chapter 4, Problem 4.25EP , additional homework tip 2

Explanation of Solution

The given name of the compound is formaldehyde. From the name it is understood that the parent carbon chain is methane and it contains only one carbon atom. Two hydrogen atoms are attached to the carbonyl carbon atom. The structure of formaldehyde is given below,

Organic And Biological Chemistry, Chapter 4, Problem 4.25EP , additional homework tip 3

Conclusion

Structural formula for the given aldehyde is drawn.

(b)

Interpretation Introduction

Interpretation:

Structural formula for the given aldehyde has to be drawn.

Concept Introduction:

Structure of the given aldehyde can be drawn from the IUPAC name. In the IUPAC name, the parent chain of carbon atom can be identified and then the substituents present in it can also be identified. With these information, the structure for the given compound can be drawn. In an aldehyde the counting has to be always from the carbonyl carbon that is given the number 1.

The structural representation of organic compound can be done in 2D and 3D. In two-dimensional representation, there are four types of representation in which an organic compound can be drawn. They are,

• Expanded structural formula

• Condensed structural formula

• Skeletal structural formula

• Line-angle structural formula

Structural formula which shows all the atoms in a molecule along with all the bonds that is connecting the atoms present in the molecule is known as Expanded structural formula.

Structural formula in which grouping of atoms are done and in which the central atoms along with the other atoms are connected to them are treated as group is known as Condensed structural formula.

Structural formula that shows the bonding between carbon atoms alone in the molecule ignoring the hydrogen atoms being shown explicitly is known as Skeletal structural formula.

Structural formula where a line represent carbon‑carbon bond and the carbon atom is considered to be present in each point and the end of lines is known as Line-angle structural formula.

(b)

Expert Solution

Answer to Problem 4.25EP

The structural formula for propionaldehyde is,

Organic And Biological Chemistry, Chapter 4, Problem 4.25EP , additional homework tip 5

Explanation of Solution

The given name of the compound is propionaldehyde. From the name it is understood that the parent carbon chain is propane and it contains three carbon atoms. The parent chain can be drawn as shown below,

Organic And Biological Chemistry, Chapter 4, Problem 4.25EP , additional homework tip 6

From the name of the given aldehyde, the substituents that are present can be identified. In this case, there are no substitutents. The first carbon atom has to be the carbonyl carbon atom as the given compound is an aldehyde.

Organic And Biological Chemistry, Chapter 4, Problem 4.25EP , additional homework tip 7

Carbon atom has a valence of four. Hence, carbon atom can form four covalent bonds. The remaining bonds are satisfied by hydrogen atom. The structure is obtained as shown below,

Organic And Biological Chemistry, Chapter 4, Problem 4.25EP , additional homework tip 8

Conclusion

Structural formula for the given aldehyde is drawn.

(c)

Interpretation Introduction

Interpretation:

Structural formula for the given aldehyde has to be drawn.

Concept Introduction:

Structure of the given aldehyde can be drawn from the IUPAC name. In the IUPAC name, the parent chain of carbon atom can be identified and then the substituents present in it can also be identified. With these information, the structure for the given compound can be drawn. In an aldehyde the counting has to be always from the carbonyl carbon that is given the number 1.

The structural representation of organic compound can be done in 2D and 3D. In two-dimensional representation, there are four types of representation in which an organic compound can be drawn. They are,

• Expanded structural formula

• Condensed structural formula

• Skeletal structural formula

• Line-angle structural formula

Structural formula which shows all the atoms in a molecule along with all the bonds that is connecting the atoms present in the molecule is known as Expanded structural formula.

Structural formula in which grouping of atoms are done and in which the central atoms along with the other atoms are connected to them are treated as group is known as Condensed structural formula.

Structural formula that shows the bonding between carbon atoms alone in the molecule ignoring the hydrogen atoms being shown explicitly is known as Skeletal structural formula.

Structural formula where a line represent carbon‑carbon bond and the carbon atom is considered to be present in each point and the end of lines is known as Line-angle structural formula.

(c)

Expert Solution

Answer to Problem 4.25EP

The structural formula for 2-chlorobenzaldehyde is,

Organic And Biological Chemistry, Chapter 4, Problem 4.25EP , additional homework tip 10

Explanation of Solution

The given name of the compound is 2-chlorobenzaldehyde. From the name it is understood that the parent carbon chain is benzene ring. The parent chain can be drawn as shown below,

Organic And Biological Chemistry, Chapter 4, Problem 4.25EP , additional homework tip 11

From the name of the given aldehyde, the substituents that are present can be identified. In this case, the substituent is a chloro group in the second carbon atom. The first carbon atom has to be the carbonyl carbon atom as the given compound is an aldehyde.

Organic And Biological Chemistry, Chapter 4, Problem 4.25EP , additional homework tip 12

Carbon atom has a valence of four. Hence, carbon atom can form four covalent bonds. The remaining bonds are satisfied by hydrogen atom. The structure is obtained as shown below,

Organic And Biological Chemistry, Chapter 4, Problem 4.25EP , additional homework tip 13

Conclusion

Structural formula for the given aldehyde is drawn.

(d)

Interpretation Introduction

Interpretation:

Structural formula for the given aldehyde has to be drawn.

Concept Introduction:

Structure of the given aldehyde can be drawn from the IUPAC name. In the IUPAC name, the parent chain of carbon atom can be identified and then the substituents present in it can also be identified. With these information, the structure for the given compound can be drawn. In an aldehyde the counting has to be always from the carbonyl carbon that is given the number 1.

The structural representation of organic compound can be done in 2D and 3D. In two-dimensional representation, there are four types of representation in which an organic compound can be drawn. They are,

• Expanded structural formula

• Condensed structural formula

• Skeletal structural formula

• Line-angle structural formula

Structural formula which shows all the atoms in a molecule along with all the bonds that is connecting the atoms present in the molecule is known as Expanded structural formula.

Structural formula in which grouping of atoms are done and in which the central atoms along with the other atoms are connected to them are treated as group is known as Condensed structural formula.

Structural formula that shows the bonding between carbon atoms alone in the molecule ignoring the hydrogen atoms being shown explicitly is known as Skeletal structural formula.

Structural formula where a line represent carbon‑carbon bond and the carbon atom is considered to be present in each point and the end of lines is known as Line-angle structural formula.

(d)

Expert Solution

Answer to Problem 4.25EP

The structural formula for 2,4-dimethylbenzaldehyde is,

Organic And Biological Chemistry, Chapter 4, Problem 4.25EP , additional homework tip 15

Explanation of Solution

The given name of the compound is 2,4-dimethylbenzaldehyde. From the name it is understood that the parent carbon chain is benzene ring. The parent chain can be drawn as shown below,

Organic And Biological Chemistry, Chapter 4, Problem 4.25EP , additional homework tip 16

From the name of the given aldehyde, the substituents that are present can be identified. In this case, the substituents are two methyl groups, each on second carbon atom and fourth carbon atom. The first carbon atom has to be the carbonyl carbon atom as the given compound is an aldehyde.

Organic And Biological Chemistry, Chapter 4, Problem 4.25EP , additional homework tip 17

Carbon atom has a valence of four. Hence, carbon atom can form four covalent bonds. The remaining bonds are satisfied by hydrogen atom. The structure is obtained as shown below,

Organic And Biological Chemistry, Chapter 4, Problem 4.25EP , additional homework tip 18

Conclusion

Structural formula for the given aldehyde is drawn.

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Answer 2

Question

Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 4, Problem 4.25EP

(a)

Interpretation Introduction

Interpretation:

Structural formula for the given aldehyde has to be drawn.

Concept Introduction:

Structure of the given aldehyde can be drawn from the IUPAC name. In the IUPAC name, the parent chain of carbon atom can be identified and then the substituents present in it can also be identified. With these information, the structure for the given compound can be drawn. In an aldehyde the counting has to be always from the carbonyl carbon that is given the number 1.

The structural representation of organic compound can be done in 2D and 3D. In two-dimensional representation, there are four types of representation in which an organic compound can be drawn. They are,

• Expanded structural formula

• Condensed structural formula

• Skeletal structural formula

• Line-angle structural formula

Structural formula which shows all the atoms in a molecule along with all the bonds that is connecting the atoms present in the molecule is known as Expanded structural formula.

Structural formula in which grouping of atoms are done and in which the central atoms along with the other atoms are connected to them are treated as group is known as Condensed structural formula.

Structural formula that shows the bonding between carbon atoms alone in the molecule ignoring the hydrogen atoms being shown explicitly is known as Skeletal structural formula.

Structural formula where a line represent carbon‑carbon bond and the carbon atom is considered to be present in each point and the end of lines is known as Line-angle structural formula.

(a)

Expert Solution

Answer to Problem 4.25EP

The structural formula for formaldehyde is,

Organic And Biological Chemistry, Chapter 4, Problem 4.25EP , additional homework tip 2

Explanation of Solution

The given name of the compound is formaldehyde. From the name it is understood that the parent carbon chain is methane and it contains only one carbon atom. Two hydrogen atoms are attached to the carbonyl carbon atom. The structure of formaldehyde is given below,

Organic And Biological Chemistry, Chapter 4, Problem 4.25EP , additional homework tip 3

Conclusion

Structural formula for the given aldehyde is drawn.

(b)

Interpretation Introduction

Interpretation:

Structural formula for the given aldehyde has to be drawn.

Concept Introduction:

Structure of the given aldehyde can be drawn from the IUPAC name. In the IUPAC name, the parent chain of carbon atom can be identified and then the substituents present in it can also be identified. With these information, the structure for the given compound can be drawn. In an aldehyde the counting has to be always from the carbonyl carbon that is given the number 1.

The structural representation of organic compound can be done in 2D and 3D. In two-dimensional representation, there are four types of representation in which an organic compound can be drawn. They are,

• Expanded structural formula

• Condensed structural formula

• Skeletal structural formula

• Line-angle structural formula

Structural formula which shows all the atoms in a molecule along with all the bonds that is connecting the atoms present in the molecule is known as Expanded structural formula.

Structural formula in which grouping of atoms are done and in which the central atoms along with the other atoms are connected to them are treated as group is known as Condensed structural formula.

Structural formula that shows the bonding between carbon atoms alone in the molecule ignoring the hydrogen atoms being shown explicitly is known as Skeletal structural formula.

Structural formula where a line represent carbon‑carbon bond and the carbon atom is considered to be present in each point and the end of lines is known as Line-angle structural formula.

(b)

Expert Solution

Answer to Problem 4.25EP

The structural formula for propionaldehyde is,

Organic And Biological Chemistry, Chapter 4, Problem 4.25EP , additional homework tip 5

Explanation of Solution

The given name of the compound is propionaldehyde. From the name it is understood that the parent carbon chain is propane and it contains three carbon atoms. The parent chain can be drawn as shown below,

Organic And Biological Chemistry, Chapter 4, Problem 4.25EP , additional homework tip 6

From the name of the given aldehyde, the substituents that are present can be identified. In this case, there are no substitutents. The first carbon atom has to be the carbonyl carbon atom as the given compound is an aldehyde.

Organic And Biological Chemistry, Chapter 4, Problem 4.25EP , additional homework tip 7

Carbon atom has a valence of four. Hence, carbon atom can form four covalent bonds. The remaining bonds are satisfied by hydrogen atom. The structure is obtained as shown below,

Organic And Biological Chemistry, Chapter 4, Problem 4.25EP , additional homework tip 8

Conclusion

Structural formula for the given aldehyde is drawn.

(c)

Interpretation Introduction

Interpretation:

Structural formula for the given aldehyde has to be drawn.

Concept Introduction:

Structure of the given aldehyde can be drawn from the IUPAC name. In the IUPAC name, the parent chain of carbon atom can be identified and then the substituents present in it can also be identified. With these information, the structure for the given compound can be drawn. In an aldehyde the counting has to be always from the carbonyl carbon that is given the number 1.

The structural representation of organic compound can be done in 2D and 3D. In two-dimensional representation, there are four types of representation in which an organic compound can be drawn. They are,

• Expanded structural formula

• Condensed structural formula

• Skeletal structural formula

• Line-angle structural formula

Structural formula which shows all the atoms in a molecule along with all the bonds that is connecting the atoms present in the molecule is known as Expanded structural formula.

Structural formula in which grouping of atoms are done and in which the central atoms along with the other atoms are connected to them are treated as group is known as Condensed structural formula.

Structural formula that shows the bonding between carbon atoms alone in the molecule ignoring the hydrogen atoms being shown explicitly is known as Skeletal structural formula.

Structural formula where a line represent carbon‑carbon bond and the carbon atom is considered to be present in each point and the end of lines is known as Line-angle structural formula.

(c)

Expert Solution

Answer to Problem 4.25EP

The structural formula for 2-chlorobenzaldehyde is,

Organic And Biological Chemistry, Chapter 4, Problem 4.25EP , additional homework tip 10

Explanation of Solution

The given name of the compound is 2-chlorobenzaldehyde. From the name it is understood that the parent carbon chain is benzene ring. The parent chain can be drawn as shown below,

Organic And Biological Chemistry, Chapter 4, Problem 4.25EP , additional homework tip 11

From the name of the given aldehyde, the substituents that are present can be identified. In this case, the substituent is a chloro group in the second carbon atom. The first carbon atom has to be the carbonyl carbon atom as the given compound is an aldehyde.

Organic And Biological Chemistry, Chapter 4, Problem 4.25EP , additional homework tip 12

Carbon atom has a valence of four. Hence, carbon atom can form four covalent bonds. The remaining bonds are satisfied by hydrogen atom. The structure is obtained as shown below,

Organic And Biological Chemistry, Chapter 4, Problem 4.25EP , additional homework tip 13

Conclusion

Structural formula for the given aldehyde is drawn.

(d)

Interpretation Introduction

Interpretation:

Structural formula for the given aldehyde has to be drawn.

Concept Introduction:

Structure of the given aldehyde can be drawn from the IUPAC name. In the IUPAC name, the parent chain of carbon atom can be identified and then the substituents present in it can also be identified. With these information, the structure for the given compound can be drawn. In an aldehyde the counting has to be always from the carbonyl carbon that is given the number 1.

The structural representation of organic compound can be done in 2D and 3D. In two-dimensional representation, there are four types of representation in which an organic compound can be drawn. They are,

• Expanded structural formula

• Condensed structural formula

• Skeletal structural formula

• Line-angle structural formula

Structural formula which shows all the atoms in a molecule along with all the bonds that is connecting the atoms present in the molecule is known as Expanded structural formula.

Structural formula in which grouping of atoms are done and in which the central atoms along with the other atoms are connected to them are treated as group is known as Condensed structural formula.

Structural formula that shows the bonding between carbon atoms alone in the molecule ignoring the hydrogen atoms being shown explicitly is known as Skeletal structural formula.

Structural formula where a line represent carbon‑carbon bond and the carbon atom is considered to be present in each point and the end of lines is known as Line-angle structural formula.

(d)

Expert Solution

Answer to Problem 4.25EP

The structural formula for 2,4-dimethylbenzaldehyde is,

Organic And Biological Chemistry, Chapter 4, Problem 4.25EP , additional homework tip 15

Explanation of Solution

The given name of the compound is 2,4-dimethylbenzaldehyde. From the name it is understood that the parent carbon chain is benzene ring. The parent chain can be drawn as shown below,

Organic And Biological Chemistry, Chapter 4, Problem 4.25EP , additional homework tip 16

From the name of the given aldehyde, the substituents that are present can be identified. In this case, the substituents are two methyl groups, each on second carbon atom and fourth carbon atom. The first carbon atom has to be the carbonyl carbon atom as the given compound is an aldehyde.

Organic And Biological Chemistry, Chapter 4, Problem 4.25EP , additional homework tip 17

Carbon atom has a valence of four. Hence, carbon atom can form four covalent bonds. The remaining bonds are satisfied by hydrogen atom. The structure is obtained as shown below,

Organic And Biological Chemistry, Chapter 4, Problem 4.25EP , additional homework tip 18

Conclusion

Structural formula for the given aldehyde is drawn.

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Answer 3

Question

Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 4, Problem 4.25EP

(a)

Interpretation Introduction

Interpretation:

Structural formula for the given aldehyde has to be drawn.

Concept Introduction:

Structure of the given aldehyde can be drawn from the IUPAC name. In the IUPAC name, the parent chain of carbon atom can be identified and then the substituents present in it can also be identified. With these information, the structure for the given compound can be drawn. In an aldehyde the counting has to be always from the carbonyl carbon that is given the number 1.

The structural representation of organic compound can be done in 2D and 3D. In two-dimensional representation, there are four types of representation in which an organic compound can be drawn. They are,

• Expanded structural formula

• Condensed structural formula

• Skeletal structural formula

• Line-angle structural formula

Structural formula which shows all the atoms in a molecule along with all the bonds that is connecting the atoms present in the molecule is known as Expanded structural formula.

Structural formula in which grouping of atoms are done and in which the central atoms along with the other atoms are connected to them are treated as group is known as Condensed structural formula.

Structural formula that shows the bonding between carbon atoms alone in the molecule ignoring the hydrogen atoms being shown explicitly is known as Skeletal structural formula.

Structural formula where a line represent carbon‑carbon bond and the carbon atom is considered to be present in each point and the end of lines is known as Line-angle structural formula.

(a)

Expert Solution

Answer to Problem 4.25EP

The structural formula for formaldehyde is,

Organic And Biological Chemistry, Chapter 4, Problem 4.25EP , additional homework tip 2

Explanation of Solution

The given name of the compound is formaldehyde. From the name it is understood that the parent carbon chain is methane and it contains only one carbon atom. Two hydrogen atoms are attached to the carbonyl carbon atom. The structure of formaldehyde is given below,

Organic And Biological Chemistry, Chapter 4, Problem 4.25EP , additional homework tip 3

Conclusion

Structural formula for the given aldehyde is drawn.

(b)

Interpretation Introduction

Interpretation:

Structural formula for the given aldehyde has to be drawn.

Concept Introduction:

Structure of the given aldehyde can be drawn from the IUPAC name. In the IUPAC name, the parent chain of carbon atom can be identified and then the substituents present in it can also be identified. With these information, the structure for the given compound can be drawn. In an aldehyde the counting has to be always from the carbonyl carbon that is given the number 1.

The structural representation of organic compound can be done in 2D and 3D. In two-dimensional representation, there are four types of representation in which an organic compound can be drawn. They are,

• Expanded structural formula

• Condensed structural formula

• Skeletal structural formula

• Line-angle structural formula

Structural formula which shows all the atoms in a molecule along with all the bonds that is connecting the atoms present in the molecule is known as Expanded structural formula.

Structural formula in which grouping of atoms are done and in which the central atoms along with the other atoms are connected to them are treated as group is known as Condensed structural formula.

Structural formula that shows the bonding between carbon atoms alone in the molecule ignoring the hydrogen atoms being shown explicitly is known as Skeletal structural formula.

Structural formula where a line represent carbon‑carbon bond and the carbon atom is considered to be present in each point and the end of lines is known as Line-angle structural formula.

(b)

Expert Solution

Answer to Problem 4.25EP

The structural formula for propionaldehyde is,

Organic And Biological Chemistry, Chapter 4, Problem 4.25EP , additional homework tip 5

Explanation of Solution

The given name of the compound is propionaldehyde. From the name it is understood that the parent carbon chain is propane and it contains three carbon atoms. The parent chain can be drawn as shown below,

Organic And Biological Chemistry, Chapter 4, Problem 4.25EP , additional homework tip 6

From the name of the given aldehyde, the substituents that are present can be identified. In this case, there are no substitutents. The first carbon atom has to be the carbonyl carbon atom as the given compound is an aldehyde.

Organic And Biological Chemistry, Chapter 4, Problem 4.25EP , additional homework tip 7

Carbon atom has a valence of four. Hence, carbon atom can form four covalent bonds. The remaining bonds are satisfied by hydrogen atom. The structure is obtained as shown below,

Organic And Biological Chemistry, Chapter 4, Problem 4.25EP , additional homework tip 8

Conclusion

Structural formula for the given aldehyde is drawn.

(c)

Interpretation Introduction

Interpretation:

Structural formula for the given aldehyde has to be drawn.

Concept Introduction:

Structure of the given aldehyde can be drawn from the IUPAC name. In the IUPAC name, the parent chain of carbon atom can be identified and then the substituents present in it can also be identified. With these information, the structure for the given compound can be drawn. In an aldehyde the counting has to be always from the carbonyl carbon that is given the number 1.

The structural representation of organic compound can be done in 2D and 3D. In two-dimensional representation, there are four types of representation in which an organic compound can be drawn. They are,

• Expanded structural formula

• Condensed structural formula

• Skeletal structural formula

• Line-angle structural formula

Structural formula which shows all the atoms in a molecule along with all the bonds that is connecting the atoms present in the molecule is known as Expanded structural formula.

Structural formula in which grouping of atoms are done and in which the central atoms along with the other atoms are connected to them are treated as group is known as Condensed structural formula.

Structural formula that shows the bonding between carbon atoms alone in the molecule ignoring the hydrogen atoms being shown explicitly is known as Skeletal structural formula.

Structural formula where a line represent carbon‑carbon bond and the carbon atom is considered to be present in each point and the end of lines is known as Line-angle structural formula.

(c)

Expert Solution

Answer to Problem 4.25EP

The structural formula for 2-chlorobenzaldehyde is,

Organic And Biological Chemistry, Chapter 4, Problem 4.25EP , additional homework tip 10

Explanation of Solution

The given name of the compound is 2-chlorobenzaldehyde. From the name it is understood that the parent carbon chain is benzene ring. The parent chain can be drawn as shown below,

Organic And Biological Chemistry, Chapter 4, Problem 4.25EP , additional homework tip 11

From the name of the given aldehyde, the substituents that are present can be identified. In this case, the substituent is a chloro group in the second carbon atom. The first carbon atom has to be the carbonyl carbon atom as the given compound is an aldehyde.

Organic And Biological Chemistry, Chapter 4, Problem 4.25EP , additional homework tip 12

Carbon atom has a valence of four. Hence, carbon atom can form four covalent bonds. The remaining bonds are satisfied by hydrogen atom. The structure is obtained as shown below,

Organic And Biological Chemistry, Chapter 4, Problem 4.25EP , additional homework tip 13

Conclusion

Structural formula for the given aldehyde is drawn.

(d)

Interpretation Introduction

Interpretation:

Structural formula for the given aldehyde has to be drawn.

Concept Introduction:

Structure of the given aldehyde can be drawn from the IUPAC name. In the IUPAC name, the parent chain of carbon atom can be identified and then the substituents present in it can also be identified. With these information, the structure for the given compound can be drawn. In an aldehyde the counting has to be always from the carbonyl carbon that is given the number 1.

The structural representation of organic compound can be done in 2D and 3D. In two-dimensional representation, there are four types of representation in which an organic compound can be drawn. They are,

• Expanded structural formula

• Condensed structural formula

• Skeletal structural formula

• Line-angle structural formula

Structural formula which shows all the atoms in a molecule along with all the bonds that is connecting the atoms present in the molecule is known as Expanded structural formula.

Structural formula in which grouping of atoms are done and in which the central atoms along with the other atoms are connected to them are treated as group is known as Condensed structural formula.

Structural formula that shows the bonding between carbon atoms alone in the molecule ignoring the hydrogen atoms being shown explicitly is known as Skeletal structural formula.

Structural formula where a line represent carbon‑carbon bond and the carbon atom is considered to be present in each point and the end of lines is known as Line-angle structural formula.

(d)

Expert Solution

Answer to Problem 4.25EP

The structural formula for 2,4-dimethylbenzaldehyde is,

Organic And Biological Chemistry, Chapter 4, Problem 4.25EP , additional homework tip 15

Explanation of Solution

The given name of the compound is 2,4-dimethylbenzaldehyde. From the name it is understood that the parent carbon chain is benzene ring. The parent chain can be drawn as shown below,

Organic And Biological Chemistry, Chapter 4, Problem 4.25EP , additional homework tip 16

From the name of the given aldehyde, the substituents that are present can be identified. In this case, the substituents are two methyl groups, each on second carbon atom and fourth carbon atom. The first carbon atom has to be the carbonyl carbon atom as the given compound is an aldehyde.

Organic And Biological Chemistry, Chapter 4, Problem 4.25EP , additional homework tip 17

Carbon atom has a valence of four. Hence, carbon atom can form four covalent bonds. The remaining bonds are satisfied by hydrogen atom. The structure is obtained as shown below,

Organic And Biological Chemistry, Chapter 4, Problem 4.25EP , additional homework tip 18

Conclusion

Structural formula for the given aldehyde is drawn.

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Subscribe now to access step-by-step solutions to millions of textbook problems written by subject matter experts!

Answer 4

Question

Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 4, Problem 4.25EP

(a)

Interpretation Introduction

Interpretation:

Structural formula for the given aldehyde has to be drawn.

Concept Introduction:

Structure of the given aldehyde can be drawn from the IUPAC name. In the IUPAC name, the parent chain of carbon atom can be identified and then the substituents present in it can also be identified. With these information, the structure for the given compound can be drawn. In an aldehyde the counting has to be always from the carbonyl carbon that is given the number 1.

The structural representation of organic compound can be done in 2D and 3D. In two-dimensional representation, there are four types of representation in which an organic compound can be drawn. They are,

• Expanded structural formula

• Condensed structural formula

• Skeletal structural formula

• Line-angle structural formula

Structural formula which shows all the atoms in a molecule along with all the bonds that is connecting the atoms present in the molecule is known as Expanded structural formula.

Structural formula in which grouping of atoms are done and in which the central atoms along with the other atoms are connected to them are treated as group is known as Condensed structural formula.

Structural formula that shows the bonding between carbon atoms alone in the molecule ignoring the hydrogen atoms being shown explicitly is known as Skeletal structural formula.

Structural formula where a line represent carbon‑carbon bond and the carbon atom is considered to be present in each point and the end of lines is known as Line-angle structural formula.

(a)

Expert Solution

Answer to Problem 4.25EP

The structural formula for formaldehyde is,

Organic And Biological Chemistry, Chapter 4, Problem 4.25EP , additional homework tip 2

Explanation of Solution

The given name of the compound is formaldehyde. From the name it is understood that the parent carbon chain is methane and it contains only one carbon atom. Two hydrogen atoms are attached to the carbonyl carbon atom. The structure of formaldehyde is given below,

Organic And Biological Chemistry, Chapter 4, Problem 4.25EP , additional homework tip 3

Conclusion

Structural formula for the given aldehyde is drawn.

(b)

Interpretation Introduction

Interpretation:

Structural formula for the given aldehyde has to be drawn.

Concept Introduction:

Structure of the given aldehyde can be drawn from the IUPAC name. In the IUPAC name, the parent chain of carbon atom can be identified and then the substituents present in it can also be identified. With these information, the structure for the given compound can be drawn. In an aldehyde the counting has to be always from the carbonyl carbon that is given the number 1.

The structural representation of organic compound can be done in 2D and 3D. In two-dimensional representation, there are four types of representation in which an organic compound can be drawn. They are,

• Expanded structural formula

• Condensed structural formula

• Skeletal structural formula

• Line-angle structural formula

Structural formula which shows all the atoms in a molecule along with all the bonds that is connecting the atoms present in the molecule is known as Expanded structural formula.

Structural formula in which grouping of atoms are done and in which the central atoms along with the other atoms are connected to them are treated as group is known as Condensed structural formula.

Structural formula that shows the bonding between carbon atoms alone in the molecule ignoring the hydrogen atoms being shown explicitly is known as Skeletal structural formula.

Structural formula where a line represent carbon‑carbon bond and the carbon atom is considered to be present in each point and the end of lines is known as Line-angle structural formula.

(b)

Expert Solution

Answer to Problem 4.25EP

The structural formula for propionaldehyde is,

Organic And Biological Chemistry, Chapter 4, Problem 4.25EP , additional homework tip 5

Explanation of Solution

The given name of the compound is propionaldehyde. From the name it is understood that the parent carbon chain is propane and it contains three carbon atoms. The parent chain can be drawn as shown below,

Organic And Biological Chemistry, Chapter 4, Problem 4.25EP , additional homework tip 6

From the name of the given aldehyde, the substituents that are present can be identified. In this case, there are no substitutents. The first carbon atom has to be the carbonyl carbon atom as the given compound is an aldehyde.

Organic And Biological Chemistry, Chapter 4, Problem 4.25EP , additional homework tip 7

Carbon atom has a valence of four. Hence, carbon atom can form four covalent bonds. The remaining bonds are satisfied by hydrogen atom. The structure is obtained as shown below,

Organic And Biological Chemistry, Chapter 4, Problem 4.25EP , additional homework tip 8

Conclusion

Structural formula for the given aldehyde is drawn.

(c)

Interpretation Introduction

Interpretation:

Structural formula for the given aldehyde has to be drawn.

Concept Introduction:

Structure of the given aldehyde can be drawn from the IUPAC name. In the IUPAC name, the parent chain of carbon atom can be identified and then the substituents present in it can also be identified. With these information, the structure for the given compound can be drawn. In an aldehyde the counting has to be always from the carbonyl carbon that is given the number 1.

The structural representation of organic compound can be done in 2D and 3D. In two-dimensional representation, there are four types of representation in which an organic compound can be drawn. They are,

• Expanded structural formula

• Condensed structural formula

• Skeletal structural formula

• Line-angle structural formula

Structural formula which shows all the atoms in a molecule along with all the bonds that is connecting the atoms present in the molecule is known as Expanded structural formula.

Structural formula in which grouping of atoms are done and in which the central atoms along with the other atoms are connected to them are treated as group is known as Condensed structural formula.

Structural formula that shows the bonding between carbon atoms alone in the molecule ignoring the hydrogen atoms being shown explicitly is known as Skeletal structural formula.

Structural formula where a line represent carbon‑carbon bond and the carbon atom is considered to be present in each point and the end of lines is known as Line-angle structural formula.

(c)

Expert Solution

Answer to Problem 4.25EP

The structural formula for 2-chlorobenzaldehyde is,

Organic And Biological Chemistry, Chapter 4, Problem 4.25EP , additional homework tip 10

Explanation of Solution

The given name of the compound is 2-chlorobenzaldehyde. From the name it is understood that the parent carbon chain is benzene ring. The parent chain can be drawn as shown below,

Organic And Biological Chemistry, Chapter 4, Problem 4.25EP , additional homework tip 11

From the name of the given aldehyde, the substituents that are present can be identified. In this case, the substituent is a chloro group in the second carbon atom. The first carbon atom has to be the carbonyl carbon atom as the given compound is an aldehyde.

Organic And Biological Chemistry, Chapter 4, Problem 4.25EP , additional homework tip 12

Carbon atom has a valence of four. Hence, carbon atom can form four covalent bonds. The remaining bonds are satisfied by hydrogen atom. The structure is obtained as shown below,

Organic And Biological Chemistry, Chapter 4, Problem 4.25EP , additional homework tip 13

Conclusion

Structural formula for the given aldehyde is drawn.

(d)

Interpretation Introduction

Interpretation:

Structural formula for the given aldehyde has to be drawn.

Concept Introduction:

Structure of the given aldehyde can be drawn from the IUPAC name. In the IUPAC name, the parent chain of carbon atom can be identified and then the substituents present in it can also be identified. With these information, the structure for the given compound can be drawn. In an aldehyde the counting has to be always from the carbonyl carbon that is given the number 1.

The structural representation of organic compound can be done in 2D and 3D. In two-dimensional representation, there are four types of representation in which an organic compound can be drawn. They are,

• Expanded structural formula

• Condensed structural formula

• Skeletal structural formula

• Line-angle structural formula

Structural formula which shows all the atoms in a molecule along with all the bonds that is connecting the atoms present in the molecule is known as Expanded structural formula.

Structural formula in which grouping of atoms are done and in which the central atoms along with the other atoms are connected to them are treated as group is known as Condensed structural formula.

Structural formula that shows the bonding between carbon atoms alone in the molecule ignoring the hydrogen atoms being shown explicitly is known as Skeletal structural formula.

Structural formula where a line represent carbon‑carbon bond and the carbon atom is considered to be present in each point and the end of lines is known as Line-angle structural formula.

(d)

Expert Solution

Answer to Problem 4.25EP

The structural formula for 2,4-dimethylbenzaldehyde is,

Organic And Biological Chemistry, Chapter 4, Problem 4.25EP , additional homework tip 15

Explanation of Solution

The given name of the compound is 2,4-dimethylbenzaldehyde. From the name it is understood that the parent carbon chain is benzene ring. The parent chain can be drawn as shown below,

Organic And Biological Chemistry, Chapter 4, Problem 4.25EP , additional homework tip 16

From the name of the given aldehyde, the substituents that are present can be identified. In this case, the substituents are two methyl groups, each on second carbon atom and fourth carbon atom. The first carbon atom has to be the carbonyl carbon atom as the given compound is an aldehyde.

Organic And Biological Chemistry, Chapter 4, Problem 4.25EP , additional homework tip 17

Carbon atom has a valence of four. Hence, carbon atom can form four covalent bonds. The remaining bonds are satisfied by hydrogen atom. The structure is obtained as shown below,

Organic And Biological Chemistry, Chapter 4, Problem 4.25EP , additional homework tip 18

Conclusion

Structural formula for the given aldehyde is drawn.

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Answer 5

Chapter 4, Problem 4.25EP

(a)

Interpretation Introduction

Interpretation:

Structural formula for the given aldehyde has to be drawn.

Concept Introduction:

Structure of the given aldehyde can be drawn from the IUPAC name. In the IUPAC name, the parent chain of carbon atom can be identified and then the substituents present in it can also be identified. With these information, the structure for the given compound can be drawn. In an aldehyde the counting has to be always from the carbonyl carbon that is given the number 1.

The structural representation of organic compound can be done in 2D and 3D. In two-dimensional representation, there are four types of representation in which an organic compound can be drawn. They are,

• Expanded structural formula

• Condensed structural formula

• Skeletal structural formula

• Line-angle structural formula

Structural formula which shows all the atoms in a molecule along with all the bonds that is connecting the atoms present in the molecule is known as Expanded structural formula.

Structural formula in which grouping of atoms are done and in which the central atoms along with the other atoms are connected to them are treated as group is known as Condensed structural formula.

Structural formula that shows the bonding between carbon atoms alone in the molecule ignoring the hydrogen atoms being shown explicitly is known as Skeletal structural formula.

Structural formula where a line represent carbon‑carbon bond and the carbon atom is considered to be present in each point and the end of lines is known as Line-angle structural formula.

(a)

Expert Solution

Answer to Problem 4.25EP

The structural formula for formaldehyde is,

Organic And Biological Chemistry, Chapter 4, Problem 4.25EP , additional homework tip 2

Explanation of Solution

The given name of the compound is formaldehyde. From the name it is understood that the parent carbon chain is methane and it contains only one carbon atom. Two hydrogen atoms are attached to the carbonyl carbon atom. The structure of formaldehyde is given below,

Organic And Biological Chemistry, Chapter 4, Problem 4.25EP , additional homework tip 3

Conclusion

Structural formula for the given aldehyde is drawn.

(b)

Interpretation Introduction

Interpretation:

Structural formula for the given aldehyde has to be drawn.

Concept Introduction:

Structure of the given aldehyde can be drawn from the IUPAC name. In the IUPAC name, the parent chain of carbon atom can be identified and then the substituents present in it can also be identified. With these information, the structure for the given compound can be drawn. In an aldehyde the counting has to be always from the carbonyl carbon that is given the number 1.

The structural representation of organic compound can be done in 2D and 3D. In two-dimensional representation, there are four types of representation in which an organic compound can be drawn. They are,

• Expanded structural formula

• Condensed structural formula

• Skeletal structural formula

• Line-angle structural formula

Structural formula which shows all the atoms in a molecule along with all the bonds that is connecting the atoms present in the molecule is known as Expanded structural formula.

Structural formula in which grouping of atoms are done and in which the central atoms along with the other atoms are connected to them are treated as group is known as Condensed structural formula.

Structural formula that shows the bonding between carbon atoms alone in the molecule ignoring the hydrogen atoms being shown explicitly is known as Skeletal structural formula.

Structural formula where a line represent carbon‑carbon bond and the carbon atom is considered to be present in each point and the end of lines is known as Line-angle structural formula.

(b)

Expert Solution

Answer to Problem 4.25EP

The structural formula for propionaldehyde is,

Organic And Biological Chemistry, Chapter 4, Problem 4.25EP , additional homework tip 5

Explanation of Solution

The given name of the compound is propionaldehyde. From the name it is understood that the parent carbon chain is propane and it contains three carbon atoms. The parent chain can be drawn as shown below,

Organic And Biological Chemistry, Chapter 4, Problem 4.25EP , additional homework tip 6

From the name of the given aldehyde, the substituents that are present can be identified. In this case, there are no substitutents. The first carbon atom has to be the carbonyl carbon atom as the given compound is an aldehyde.

Organic And Biological Chemistry, Chapter 4, Problem 4.25EP , additional homework tip 7

Carbon atom has a valence of four. Hence, carbon atom can form four covalent bonds. The remaining bonds are satisfied by hydrogen atom. The structure is obtained as shown below,

Organic And Biological Chemistry, Chapter 4, Problem 4.25EP , additional homework tip 8

Conclusion

Structural formula for the given aldehyde is drawn.

(c)

Interpretation Introduction

Interpretation:

Structural formula for the given aldehyde has to be drawn.

Concept Introduction:

Structure of the given aldehyde can be drawn from the IUPAC name. In the IUPAC name, the parent chain of carbon atom can be identified and then the substituents present in it can also be identified. With these information, the structure for the given compound can be drawn. In an aldehyde the counting has to be always from the carbonyl carbon that is given the number 1.

The structural representation of organic compound can be done in 2D and 3D. In two-dimensional representation, there are four types of representation in which an organic compound can be drawn. They are,

• Expanded structural formula

• Condensed structural formula

• Skeletal structural formula

• Line-angle structural formula

Structural formula which shows all the atoms in a molecule along with all the bonds that is connecting the atoms present in the molecule is known as Expanded structural formula.

Structural formula in which grouping of atoms are done and in which the central atoms along with the other atoms are connected to them are treated as group is known as Condensed structural formula.

Structural formula that shows the bonding between carbon atoms alone in the molecule ignoring the hydrogen atoms being shown explicitly is known as Skeletal structural formula.

Structural formula where a line represent carbon‑carbon bond and the carbon atom is considered to be present in each point and the end of lines is known as Line-angle structural formula.

(c)

Expert Solution

Answer to Problem 4.25EP

The structural formula for 2-chlorobenzaldehyde is,

Organic And Biological Chemistry, Chapter 4, Problem 4.25EP , additional homework tip 10

Explanation of Solution

The given name of the compound is 2-chlorobenzaldehyde. From the name it is understood that the parent carbon chain is benzene ring. The parent chain can be drawn as shown below,

Organic And Biological Chemistry, Chapter 4, Problem 4.25EP , additional homework tip 11

From the name of the given aldehyde, the substituents that are present can be identified. In this case, the substituent is a chloro group in the second carbon atom. The first carbon atom has to be the carbonyl carbon atom as the given compound is an aldehyde.

Organic And Biological Chemistry, Chapter 4, Problem 4.25EP , additional homework tip 12

Carbon atom has a valence of four. Hence, carbon atom can form four covalent bonds. The remaining bonds are satisfied by hydrogen atom. The structure is obtained as shown below,

Organic And Biological Chemistry, Chapter 4, Problem 4.25EP , additional homework tip 13

Conclusion

Structural formula for the given aldehyde is drawn.

(d)

Interpretation Introduction

Interpretation:

Structural formula for the given aldehyde has to be drawn.

Concept Introduction:

Structure of the given aldehyde can be drawn from the IUPAC name. In the IUPAC name, the parent chain of carbon atom can be identified and then the substituents present in it can also be identified. With these information, the structure for the given compound can be drawn. In an aldehyde the counting has to be always from the carbonyl carbon that is given the number 1.

The structural representation of organic compound can be done in 2D and 3D. In two-dimensional representation, there are four types of representation in which an organic compound can be drawn. They are,

• Expanded structural formula

• Condensed structural formula

• Skeletal structural formula

• Line-angle structural formula

Structural formula which shows all the atoms in a molecule along with all the bonds that is connecting the atoms present in the molecule is known as Expanded structural formula.

Structural formula in which grouping of atoms are done and in which the central atoms along with the other atoms are connected to them are treated as group is known as Condensed structural formula.

Structural formula that shows the bonding between carbon atoms alone in the molecule ignoring the hydrogen atoms being shown explicitly is known as Skeletal structural formula.

Structural formula where a line represent carbon‑carbon bond and the carbon atom is considered to be present in each point and the end of lines is known as Line-angle structural formula.

(d)

Expert Solution

Answer to Problem 4.25EP

The structural formula for 2,4-dimethylbenzaldehyde is,

Organic And Biological Chemistry, Chapter 4, Problem 4.25EP , additional homework tip 15

Explanation of Solution

The given name of the compound is 2,4-dimethylbenzaldehyde. From the name it is understood that the parent carbon chain is benzene ring. The parent chain can be drawn as shown below,

Organic And Biological Chemistry, Chapter 4, Problem 4.25EP , additional homework tip 16

From the name of the given aldehyde, the substituents that are present can be identified. In this case, the substituents are two methyl groups, each on second carbon atom and fourth carbon atom. The first carbon atom has to be the carbonyl carbon atom as the given compound is an aldehyde.

Organic And Biological Chemistry, Chapter 4, Problem 4.25EP , additional homework tip 17

Carbon atom has a valence of four. Hence, carbon atom can form four covalent bonds. The remaining bonds are satisfied by hydrogen atom. The structure is obtained as shown below,

Organic And Biological Chemistry, Chapter 4, Problem 4.25EP , additional homework tip 18

Conclusion

Structural formula for the given aldehyde is drawn.

Answer 6

Chapter 4, Problem 4.25EP

(a)

Interpretation Introduction

Interpretation:

Structural formula for the given aldehyde has to be drawn.

Concept Introduction:

Structure of the given aldehyde can be drawn from the IUPAC name. In the IUPAC name, the parent chain of carbon atom can be identified and then the substituents present in it can also be identified. With these information, the structure for the given compound can be drawn. In an aldehyde the counting has to be always from the carbonyl carbon that is given the number 1.

The structural representation of organic compound can be done in 2D and 3D. In two-dimensional representation, there are four types of representation in which an organic compound can be drawn. They are,

• Expanded structural formula

• Condensed structural formula

• Skeletal structural formula

• Line-angle structural formula

Structural formula which shows all the atoms in a molecule along with all the bonds that is connecting the atoms present in the molecule is known as Expanded structural formula.

Structural formula in which grouping of atoms are done and in which the central atoms along with the other atoms are connected to them are treated as group is known as Condensed structural formula.

Structural formula that shows the bonding between carbon atoms alone in the molecule ignoring the hydrogen atoms being shown explicitly is known as Skeletal structural formula.

Structural formula where a line represent carbon‑carbon bond and the carbon atom is considered to be present in each point and the end of lines is known as Line-angle structural formula.

(a)

Expert Solution

Answer to Problem 4.25EP

The structural formula for formaldehyde is,

Organic And Biological Chemistry, Chapter 4, Problem 4.25EP , additional homework tip 2

Explanation of Solution

The given name of the compound is formaldehyde. From the name it is understood that the parent carbon chain is methane and it contains only one carbon atom. Two hydrogen atoms are attached to the carbonyl carbon atom. The structure of formaldehyde is given below,

Organic And Biological Chemistry, Chapter 4, Problem 4.25EP , additional homework tip 3

Conclusion

Structural formula for the given aldehyde is drawn.

Answer 7

Chapter 4, Problem 4.25EP

(a)

Interpretation Introduction

Interpretation:

Structural formula for the given aldehyde has to be drawn.

Concept Introduction:

Structure of the given aldehyde can be drawn from the IUPAC name. In the IUPAC name, the parent chain of carbon atom can be identified and then the substituents present in it can also be identified. With these information, the structure for the given compound can be drawn. In an aldehyde the counting has to be always from the carbonyl carbon that is given the number 1.

The structural representation of organic compound can be done in 2D and 3D. In two-dimensional representation, there are four types of representation in which an organic compound can be drawn. They are,

• Expanded structural formula

• Condensed structural formula

• Skeletal structural formula

• Line-angle structural formula

Structural formula which shows all the atoms in a molecule along with all the bonds that is connecting the atoms present in the molecule is known as Expanded structural formula.

Structural formula in which grouping of atoms are done and in which the central atoms along with the other atoms are connected to them are treated as group is known as Condensed structural formula.

Structural formula that shows the bonding between carbon atoms alone in the molecule ignoring the hydrogen atoms being shown explicitly is known as Skeletal structural formula.

Structural formula where a line represent carbon‑carbon bond and the carbon atom is considered to be present in each point and the end of lines is known as Line-angle structural formula.

Answer 8

(a)

Expert Solution

Answer to Problem 4.25EP

The structural formula for formaldehyde is,

Organic And Biological Chemistry, Chapter 4, Problem 4.25EP , additional homework tip 2

Answer 9

(a)

Expert Solution

Answer 10

(a)

Expert Solution

Answer 11

Expert Solution

Answer 12

Explanation of Solution

The given name of the compound is formaldehyde. From the name it is understood that the parent carbon chain is methane and it contains only one carbon atom. Two hydrogen atoms are attached to the carbonyl carbon atom. The structure of formaldehyde is given below,

Organic And Biological Chemistry, Chapter 4, Problem 4.25EP , additional homework tip 3

Answer 13

Conclusion

Structural formula for the given aldehyde is drawn.

Answer 14

(b)

Interpretation Introduction

Interpretation:

Structural formula for the given aldehyde has to be drawn.

Concept Introduction:

Structure of the given aldehyde can be drawn from the IUPAC name. In the IUPAC name, the parent chain of carbon atom can be identified and then the substituents present in it can also be identified. With these information, the structure for the given compound can be drawn. In an aldehyde the counting has to be always from the carbonyl carbon that is given the number 1.

The structural representation of organic compound can be done in 2D and 3D. In two-dimensional representation, there are four types of representation in which an organic compound can be drawn. They are,

• Expanded structural formula

• Condensed structural formula

• Skeletal structural formula

• Line-angle structural formula

Structural formula which shows all the atoms in a molecule along with all the bonds that is connecting the atoms present in the molecule is known as Expanded structural formula.

Structural formula in which grouping of atoms are done and in which the central atoms along with the other atoms are connected to them are treated as group is known as Condensed structural formula.

Structural formula that shows the bonding between carbon atoms alone in the molecule ignoring the hydrogen atoms being shown explicitly is known as Skeletal structural formula.

Structural formula where a line represent carbon‑carbon bond and the carbon atom is considered to be present in each point and the end of lines is known as Line-angle structural formula.

(b)

Expert Solution

Answer to Problem 4.25EP

The structural formula for propionaldehyde is,

Organic And Biological Chemistry, Chapter 4, Problem 4.25EP , additional homework tip 5

Explanation of Solution

The given name of the compound is propionaldehyde. From the name it is understood that the parent carbon chain is propane and it contains three carbon atoms. The parent chain can be drawn as shown below,

Organic And Biological Chemistry, Chapter 4, Problem 4.25EP , additional homework tip 6

From the name of the given aldehyde, the substituents that are present can be identified. In this case, there are no substitutents. The first carbon atom has to be the carbonyl carbon atom as the given compound is an aldehyde.

Organic And Biological Chemistry, Chapter 4, Problem 4.25EP , additional homework tip 7

Carbon atom has a valence of four. Hence, carbon atom can form four covalent bonds. The remaining bonds are satisfied by hydrogen atom. The structure is obtained as shown below,

Organic And Biological Chemistry, Chapter 4, Problem 4.25EP , additional homework tip 8

Conclusion

Structural formula for the given aldehyde is drawn.

Answer 15

(b)

Interpretation Introduction

Interpretation:

Structural formula for the given aldehyde has to be drawn.

Concept Introduction:

Structure of the given aldehyde can be drawn from the IUPAC name. In the IUPAC name, the parent chain of carbon atom can be identified and then the substituents present in it can also be identified. With these information, the structure for the given compound can be drawn. In an aldehyde the counting has to be always from the carbonyl carbon that is given the number 1.

The structural representation of organic compound can be done in 2D and 3D. In two-dimensional representation, there are four types of representation in which an organic compound can be drawn. They are,

• Expanded structural formula

• Condensed structural formula

• Skeletal structural formula

• Line-angle structural formula

Structural formula which shows all the atoms in a molecule along with all the bonds that is connecting the atoms present in the molecule is known as Expanded structural formula.

Structural formula in which grouping of atoms are done and in which the central atoms along with the other atoms are connected to them are treated as group is known as Condensed structural formula.

Structural formula that shows the bonding between carbon atoms alone in the molecule ignoring the hydrogen atoms being shown explicitly is known as Skeletal structural formula.

Structural formula where a line represent carbon‑carbon bond and the carbon atom is considered to be present in each point and the end of lines is known as Line-angle structural formula.

Answer 16

(b)

Expert Solution

Answer to Problem 4.25EP

The structural formula for propionaldehyde is,

Organic And Biological Chemistry, Chapter 4, Problem 4.25EP , additional homework tip 5

Answer 17

(b)

Expert Solution

Answer 18

(b)

Expert Solution

Answer 19

Expert Solution

Answer 20

Explanation of Solution

The given name of the compound is propionaldehyde. From the name it is understood that the parent carbon chain is propane and it contains three carbon atoms. The parent chain can be drawn as shown below,

Organic And Biological Chemistry, Chapter 4, Problem 4.25EP , additional homework tip 6

From the name of the given aldehyde, the substituents that are present can be identified. In this case, there are no substitutents. The first carbon atom has to be the carbonyl carbon atom as the given compound is an aldehyde.

Organic And Biological Chemistry, Chapter 4, Problem 4.25EP , additional homework tip 7

Carbon atom has a valence of four. Hence, carbon atom can form four covalent bonds. The remaining bonds are satisfied by hydrogen atom. The structure is obtained as shown below,

Organic And Biological Chemistry, Chapter 4, Problem 4.25EP , additional homework tip 8

Answer 21

Conclusion

Structural formula for the given aldehyde is drawn.

Answer 22

(c)

Interpretation Introduction

Interpretation:

Structural formula for the given aldehyde has to be drawn.

Concept Introduction:

Structure of the given aldehyde can be drawn from the IUPAC name. In the IUPAC name, the parent chain of carbon atom can be identified and then the substituents present in it can also be identified. With these information, the structure for the given compound can be drawn. In an aldehyde the counting has to be always from the carbonyl carbon that is given the number 1.

The structural representation of organic compound can be done in 2D and 3D. In two-dimensional representation, there are four types of representation in which an organic compound can be drawn. They are,

• Expanded structural formula

• Condensed structural formula

• Skeletal structural formula

• Line-angle structural formula

Structural formula which shows all the atoms in a molecule along with all the bonds that is connecting the atoms present in the molecule is known as Expanded structural formula.

Structural formula in which grouping of atoms are done and in which the central atoms along with the other atoms are connected to them are treated as group is known as Condensed structural formula.

Structural formula that shows the bonding between carbon atoms alone in the molecule ignoring the hydrogen atoms being shown explicitly is known as Skeletal structural formula.

Structural formula where a line represent carbon‑carbon bond and the carbon atom is considered to be present in each point and the end of lines is known as Line-angle structural formula.

(c)

Expert Solution

Answer to Problem 4.25EP

The structural formula for 2-chlorobenzaldehyde is,

Organic And Biological Chemistry, Chapter 4, Problem 4.25EP , additional homework tip 10

Explanation of Solution

The given name of the compound is 2-chlorobenzaldehyde. From the name it is understood that the parent carbon chain is benzene ring. The parent chain can be drawn as shown below,

Organic And Biological Chemistry, Chapter 4, Problem 4.25EP , additional homework tip 11

From the name of the given aldehyde, the substituents that are present can be identified. In this case, the substituent is a chloro group in the second carbon atom. The first carbon atom has to be the carbonyl carbon atom as the given compound is an aldehyde.

Organic And Biological Chemistry, Chapter 4, Problem 4.25EP , additional homework tip 12

Carbon atom has a valence of four. Hence, carbon atom can form four covalent bonds. The remaining bonds are satisfied by hydrogen atom. The structure is obtained as shown below,

Organic And Biological Chemistry, Chapter 4, Problem 4.25EP , additional homework tip 13

Conclusion

Structural formula for the given aldehyde is drawn.

Answer 23

(c)

Interpretation Introduction

Interpretation:

Structural formula for the given aldehyde has to be drawn.

Concept Introduction:

Structure of the given aldehyde can be drawn from the IUPAC name. In the IUPAC name, the parent chain of carbon atom can be identified and then the substituents present in it can also be identified. With these information, the structure for the given compound can be drawn. In an aldehyde the counting has to be always from the carbonyl carbon that is given the number 1.

The structural representation of organic compound can be done in 2D and 3D. In two-dimensional representation, there are four types of representation in which an organic compound can be drawn. They are,

• Expanded structural formula

• Condensed structural formula

• Skeletal structural formula

• Line-angle structural formula

Structural formula which shows all the atoms in a molecule along with all the bonds that is connecting the atoms present in the molecule is known as Expanded structural formula.

Structural formula in which grouping of atoms are done and in which the central atoms along with the other atoms are connected to them are treated as group is known as Condensed structural formula.

Structural formula that shows the bonding between carbon atoms alone in the molecule ignoring the hydrogen atoms being shown explicitly is known as Skeletal structural formula.

Structural formula where a line represent carbon‑carbon bond and the carbon atom is considered to be present in each point and the end of lines is known as Line-angle structural formula.

Answer 24

(c)

Expert Solution

Answer to Problem 4.25EP

The structural formula for 2-chlorobenzaldehyde is,

Organic And Biological Chemistry, Chapter 4, Problem 4.25EP , additional homework tip 10

Answer 25

(c)

Expert Solution

Answer 26

(c)

Expert Solution

Answer 27

Expert Solution

Answer 28

Explanation of Solution

The given name of the compound is 2-chlorobenzaldehyde. From the name it is understood that the parent carbon chain is benzene ring. The parent chain can be drawn as shown below,

Organic And Biological Chemistry, Chapter 4, Problem 4.25EP , additional homework tip 11

From the name of the given aldehyde, the substituents that are present can be identified. In this case, the substituent is a chloro group in the second carbon atom. The first carbon atom has to be the carbonyl carbon atom as the given compound is an aldehyde.

Organic And Biological Chemistry, Chapter 4, Problem 4.25EP , additional homework tip 12

Carbon atom has a valence of four. Hence, carbon atom can form four covalent bonds. The remaining bonds are satisfied by hydrogen atom. The structure is obtained as shown below,

Organic And Biological Chemistry, Chapter 4, Problem 4.25EP , additional homework tip 13

Answer 29

Conclusion

Structural formula for the given aldehyde is drawn.

Answer 30

(d)

Interpretation Introduction

Interpretation:

Structural formula for the given aldehyde has to be drawn.

Concept Introduction:

Structure of the given aldehyde can be drawn from the IUPAC name. In the IUPAC name, the parent chain of carbon atom can be identified and then the substituents present in it can also be identified. With these information, the structure for the given compound can be drawn. In an aldehyde the counting has to be always from the carbonyl carbon that is given the number 1.

The structural representation of organic compound can be done in 2D and 3D. In two-dimensional representation, there are four types of representation in which an organic compound can be drawn. They are,

• Expanded structural formula

• Condensed structural formula

• Skeletal structural formula

• Line-angle structural formula

Structural formula which shows all the atoms in a molecule along with all the bonds that is connecting the atoms present in the molecule is known as Expanded structural formula.

Structural formula in which grouping of atoms are done and in which the central atoms along with the other atoms are connected to them are treated as group is known as Condensed structural formula.

Structural formula that shows the bonding between carbon atoms alone in the molecule ignoring the hydrogen atoms being shown explicitly is known as Skeletal structural formula.

Structural formula where a line represent carbon‑carbon bond and the carbon atom is considered to be present in each point and the end of lines is known as Line-angle structural formula.

(d)

Expert Solution

Answer to Problem 4.25EP

The structural formula for 2,4-dimethylbenzaldehyde is,

Organic And Biological Chemistry, Chapter 4, Problem 4.25EP , additional homework tip 15

Explanation of Solution

The given name of the compound is 2,4-dimethylbenzaldehyde. From the name it is understood that the parent carbon chain is benzene ring. The parent chain can be drawn as shown below,

Organic And Biological Chemistry, Chapter 4, Problem 4.25EP , additional homework tip 16

From the name of the given aldehyde, the substituents that are present can be identified. In this case, the substituents are two methyl groups, each on second carbon atom and fourth carbon atom. The first carbon atom has to be the carbonyl carbon atom as the given compound is an aldehyde.

Organic And Biological Chemistry, Chapter 4, Problem 4.25EP , additional homework tip 17

Carbon atom has a valence of four. Hence, carbon atom can form four covalent bonds. The remaining bonds are satisfied by hydrogen atom. The structure is obtained as shown below,

Organic And Biological Chemistry, Chapter 4, Problem 4.25EP , additional homework tip 18

Conclusion

Structural formula for the given aldehyde is drawn.

Answer 31

(d)

Interpretation Introduction

Interpretation:

Structural formula for the given aldehyde has to be drawn.

Concept Introduction:

Structure of the given aldehyde can be drawn from the IUPAC name. In the IUPAC name, the parent chain of carbon atom can be identified and then the substituents present in it can also be identified. With these information, the structure for the given compound can be drawn. In an aldehyde the counting has to be always from the carbonyl carbon that is given the number 1.

The structural representation of organic compound can be done in 2D and 3D. In two-dimensional representation, there are four types of representation in which an organic compound can be drawn. They are,

• Expanded structural formula

• Condensed structural formula

• Skeletal structural formula

• Line-angle structural formula

Structural formula which shows all the atoms in a molecule along with all the bonds that is connecting the atoms present in the molecule is known as Expanded structural formula.

Structural formula in which grouping of atoms are done and in which the central atoms along with the other atoms are connected to them are treated as group is known as Condensed structural formula.

Structural formula that shows the bonding between carbon atoms alone in the molecule ignoring the hydrogen atoms being shown explicitly is known as Skeletal structural formula.

Structural formula where a line represent carbon‑carbon bond and the carbon atom is considered to be present in each point and the end of lines is known as Line-angle structural formula.

Answer 32

(d)

Expert Solution

Answer to Problem 4.25EP

The structural formula for 2,4-dimethylbenzaldehyde is,

Organic And Biological Chemistry, Chapter 4, Problem 4.25EP , additional homework tip 15

Answer 33

(d)

Expert Solution

Answer 34

(d)

Expert Solution

Answer 35

Expert Solution

Answer 36

Explanation of Solution

The given name of the compound is 2,4-dimethylbenzaldehyde. From the name it is understood that the parent carbon chain is benzene ring. The parent chain can be drawn as shown below,

Organic And Biological Chemistry, Chapter 4, Problem 4.25EP , additional homework tip 16

From the name of the given aldehyde, the substituents that are present can be identified. In this case, the substituents are two methyl groups, each on second carbon atom and fourth carbon atom. The first carbon atom has to be the carbonyl carbon atom as the given compound is an aldehyde.

Organic And Biological Chemistry, Chapter 4, Problem 4.25EP , additional homework tip 17

Carbon atom has a valence of four. Hence, carbon atom can form four covalent bonds. The remaining bonds are satisfied by hydrogen atom. The structure is obtained as shown below,

Organic And Biological Chemistry, Chapter 4, Problem 4.25EP , additional homework tip 18