Interpretation:
The values of m and n should be calculated for the given rate law expression.
Concept introduction:
Rate Law can be expressed as an integrated rate law and a differential rate law.
Differential Rate Law: This describes the change in the concentrations of reactant as a function of time.
Integrated Rate Law: This describes the initial concentrations and the measured concentration of one or more reactants as a function of time.
The proportionality coefficient which relates the rate of
Answer to Problem 13STP
The values of m and nare 1 and 2.
Rate law for the reaction is:
Explanation of Solution
Given information:
Data is given as:
The general expression of rate law is expressed as:
Where, m and n are the experimentally determined values.
Experiment 1:
Rate law expression is written as:
Experiment 2: Rate law expression is written as:
Experiment 3: Rate law expression is written as:
Now, divide equation (2) by (1):
Now, divide equation (3) by (2):
Thus, rate law expression is written as:
Chapter 21 Solutions
Chemistry: Matter and Change
Additional Science Textbook Solutions
Chemistry: Structure and Properties
Chemistry: A Molecular Approach
Chemistry: A Molecular Approach (4th Edition)
CHEMISTRY-TEXT
Introductory Chemistry (6th Edition)
Organic Chemistry (8th Edition)
- ChemistryChemistryISBN:9781305957404Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCostePublisher:Cengage LearningChemistryChemistryISBN:9781259911156Author:Raymond Chang Dr., Jason Overby ProfessorPublisher:McGraw-Hill EducationPrinciples of Instrumental AnalysisChemistryISBN:9781305577213Author:Douglas A. Skoog, F. James Holler, Stanley R. CrouchPublisher:Cengage Learning
- Organic ChemistryChemistryISBN:9780078021558Author:Janice Gorzynski Smith Dr.Publisher:McGraw-Hill EducationChemistry: Principles and ReactionsChemistryISBN:9781305079373Author:William L. Masterton, Cecile N. HurleyPublisher:Cengage LearningElementary Principles of Chemical Processes, Bind...ChemistryISBN:9781118431221Author:Richard M. Felder, Ronald W. Rousseau, Lisa G. BullardPublisher:WILEY