Common name for the given ester has to be assigned. Concept Introduction: For naming an ester, it can be structurally viewed in a way that contains an acyl group and an alkyl group. Rules to obtain IUPAC name and common name for an ester: Alkyl part appears first in the IUPAC name and it is followed by the acyl part of ester as a separate word. Name of the alkyl part in the ester is just a name of R group. It can be alkyl, cycloalkyl, or aryl group. Acyl part present in the ester is named by considering the acid name and replacing the suffix “-ic acid” with “-ate”. To obtain the common name the alkyl part name is the same while the acyl part name is derived from the common name of the acid by replacing the suffix “-ic acid” with “-ate”.

Question

For the single step reaction: A + B → 2C + 25 kJ If the activation energy for this reaction is 35.8 kJ, sketch an energy vs. reaction coordinate diagram for this reaction. Be sure to label the following on your diagram: each of the axes, reactant compounds and product compounds, enthalpy of reaction, activation energy of the forward reaction with the correct value, activation energy of the backwards reaction with the correct value and the transition state. In the same sketch you drew, after the addition of a homogeneous catalyst, show how it would change the graph. Label any new line "catalyst" and label any new activation energy.

Answer 1

Question

Chapter 16, Problem 16.91EP

(a)

Interpretation Introduction

Interpretation:

Common name for the given ester has to be assigned.

Concept Introduction:

For naming an ester, it can be structurally viewed in a way that contains an acyl group and an alkyl group.

Rules to obtain IUPAC name and common name for an ester:

Alkyl part appears first in the IUPAC name and it is followed by the acyl part of ester as a separate word.

Name of the alkyl part in the ester is just a name of R group. It can be alkyl, cycloalkyl, or aryl group.

Acyl part present in the ester is named by considering the acid name and replacing the suffix “-ic acid” with “-ate”.

To obtain the common name the alkyl part name is the same while the acyl part name is derived from the common name of the acid by replacing the suffix “-ic acid” with “-ate”.

(b)

Interpretation Introduction

Interpretation:

Common name for the given ester has to be assigned.

Concept Introduction:

For naming an ester, it can be structurally viewed in a way that contains an acyl group and an alkyl group.

Rules to obtain IUPAC name and common name for an ester:

Alkyl part appears first in the IUPAC name and it is followed by the acyl part of ester as a separate word.

Name of the alkyl part in the ester is just a name of R group. It can be alkyl, cycloalkyl, or aryl group.

Acyl part present in the ester is named by considering the acid name and replacing the suffix “-ic acid” with “-ate”.

To obtain the common name the alkyl part name is the same while the acyl part name is derived from the common name of the acid by replacing the suffix “-ic acid” with “-ate”.

(c)

Interpretation Introduction

Interpretation:

Common name for the given ester has to be assigned.

Concept Introduction:

For naming an ester, it can be structurally viewed in a way that contains an acyl group and an alkyl group.

Rules to obtain IUPAC name and common name for an ester:

Alkyl part appears first in the IUPAC name and it is followed by the acyl part of ester as a separate word.

Name of the alkyl part in the ester is just a name of R group. It can be alkyl, cycloalkyl, or aryl group.

Acyl part present in the ester is named by considering the acid name and replacing the suffix “-ic acid” with “-ate”.

To obtain the common name the alkyl part name is the same while the acyl part name is derived from the common name of the acid by replacing the suffix “-ic acid” with “-ate”.

(d)

Interpretation Introduction

Interpretation:

Common name for the given ester has to be assigned.

Concept Introduction:

For naming an ester, it can be structurally viewed in a way that contains an acyl group and an alkyl group.

Rules to obtain IUPAC name and common name for an ester:

Alkyl part appears first in the IUPAC name and it is followed by the acyl part of ester as a separate word.

Name of the alkyl part in the ester is just a name of R group. It can be alkyl, cycloalkyl, or aryl group.

Acyl part present in the ester is named by considering the acid name and replacing the suffix “-ic acid” with “-ate”.

To obtain the common name the alkyl part name is the same while the acyl part name is derived from the common name of the acid by replacing the suffix “-ic acid” with “-ate”.

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Answer 2

Question

Chapter 16, Problem 16.91EP

(a)

Interpretation Introduction

Interpretation:

Common name for the given ester has to be assigned.

Concept Introduction:

For naming an ester, it can be structurally viewed in a way that contains an acyl group and an alkyl group.

Rules to obtain IUPAC name and common name for an ester:

Alkyl part appears first in the IUPAC name and it is followed by the acyl part of ester as a separate word.

Name of the alkyl part in the ester is just a name of R group. It can be alkyl, cycloalkyl, or aryl group.

Acyl part present in the ester is named by considering the acid name and replacing the suffix “-ic acid” with “-ate”.

To obtain the common name the alkyl part name is the same while the acyl part name is derived from the common name of the acid by replacing the suffix “-ic acid” with “-ate”.

(b)

Interpretation Introduction

Interpretation:

Common name for the given ester has to be assigned.

Concept Introduction:

For naming an ester, it can be structurally viewed in a way that contains an acyl group and an alkyl group.

Rules to obtain IUPAC name and common name for an ester:

Alkyl part appears first in the IUPAC name and it is followed by the acyl part of ester as a separate word.

Name of the alkyl part in the ester is just a name of R group. It can be alkyl, cycloalkyl, or aryl group.

Acyl part present in the ester is named by considering the acid name and replacing the suffix “-ic acid” with “-ate”.

To obtain the common name the alkyl part name is the same while the acyl part name is derived from the common name of the acid by replacing the suffix “-ic acid” with “-ate”.

(c)

Interpretation Introduction

Interpretation:

Common name for the given ester has to be assigned.

Concept Introduction:

For naming an ester, it can be structurally viewed in a way that contains an acyl group and an alkyl group.

Rules to obtain IUPAC name and common name for an ester:

Alkyl part appears first in the IUPAC name and it is followed by the acyl part of ester as a separate word.

Name of the alkyl part in the ester is just a name of R group. It can be alkyl, cycloalkyl, or aryl group.

Acyl part present in the ester is named by considering the acid name and replacing the suffix “-ic acid” with “-ate”.

To obtain the common name the alkyl part name is the same while the acyl part name is derived from the common name of the acid by replacing the suffix “-ic acid” with “-ate”.

(d)

Interpretation Introduction

Interpretation:

Common name for the given ester has to be assigned.

Concept Introduction:

For naming an ester, it can be structurally viewed in a way that contains an acyl group and an alkyl group.

Rules to obtain IUPAC name and common name for an ester:

Alkyl part appears first in the IUPAC name and it is followed by the acyl part of ester as a separate word.

Name of the alkyl part in the ester is just a name of R group. It can be alkyl, cycloalkyl, or aryl group.

Acyl part present in the ester is named by considering the acid name and replacing the suffix “-ic acid” with “-ate”.

To obtain the common name the alkyl part name is the same while the acyl part name is derived from the common name of the acid by replacing the suffix “-ic acid” with “-ate”.

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Answer 3

Question

Chapter 16, Problem 16.91EP

(a)

Interpretation Introduction

Interpretation:

Common name for the given ester has to be assigned.

Concept Introduction:

For naming an ester, it can be structurally viewed in a way that contains an acyl group and an alkyl group.

Rules to obtain IUPAC name and common name for an ester:

Alkyl part appears first in the IUPAC name and it is followed by the acyl part of ester as a separate word.

Name of the alkyl part in the ester is just a name of R group. It can be alkyl, cycloalkyl, or aryl group.

Acyl part present in the ester is named by considering the acid name and replacing the suffix “-ic acid” with “-ate”.

To obtain the common name the alkyl part name is the same while the acyl part name is derived from the common name of the acid by replacing the suffix “-ic acid” with “-ate”.

(b)

Interpretation Introduction

Interpretation:

Common name for the given ester has to be assigned.

Concept Introduction:

For naming an ester, it can be structurally viewed in a way that contains an acyl group and an alkyl group.

Rules to obtain IUPAC name and common name for an ester:

Alkyl part appears first in the IUPAC name and it is followed by the acyl part of ester as a separate word.

Name of the alkyl part in the ester is just a name of R group. It can be alkyl, cycloalkyl, or aryl group.

Acyl part present in the ester is named by considering the acid name and replacing the suffix “-ic acid” with “-ate”.

To obtain the common name the alkyl part name is the same while the acyl part name is derived from the common name of the acid by replacing the suffix “-ic acid” with “-ate”.

(c)

Interpretation Introduction

Interpretation:

Common name for the given ester has to be assigned.

Concept Introduction:

For naming an ester, it can be structurally viewed in a way that contains an acyl group and an alkyl group.

Rules to obtain IUPAC name and common name for an ester:

Alkyl part appears first in the IUPAC name and it is followed by the acyl part of ester as a separate word.

Name of the alkyl part in the ester is just a name of R group. It can be alkyl, cycloalkyl, or aryl group.

Acyl part present in the ester is named by considering the acid name and replacing the suffix “-ic acid” with “-ate”.

To obtain the common name the alkyl part name is the same while the acyl part name is derived from the common name of the acid by replacing the suffix “-ic acid” with “-ate”.

(d)

Interpretation Introduction

Interpretation:

Common name for the given ester has to be assigned.

Concept Introduction:

For naming an ester, it can be structurally viewed in a way that contains an acyl group and an alkyl group.

Rules to obtain IUPAC name and common name for an ester:

Alkyl part appears first in the IUPAC name and it is followed by the acyl part of ester as a separate word.

Name of the alkyl part in the ester is just a name of R group. It can be alkyl, cycloalkyl, or aryl group.

Acyl part present in the ester is named by considering the acid name and replacing the suffix “-ic acid” with “-ate”.

To obtain the common name the alkyl part name is the same while the acyl part name is derived from the common name of the acid by replacing the suffix “-ic acid” with “-ate”.

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Answer 4

Question

Chapter 16, Problem 16.91EP

(a)

Interpretation Introduction

Interpretation:

Common name for the given ester has to be assigned.

Concept Introduction:

For naming an ester, it can be structurally viewed in a way that contains an acyl group and an alkyl group.

Rules to obtain IUPAC name and common name for an ester:

Alkyl part appears first in the IUPAC name and it is followed by the acyl part of ester as a separate word.

Name of the alkyl part in the ester is just a name of R group. It can be alkyl, cycloalkyl, or aryl group.

Acyl part present in the ester is named by considering the acid name and replacing the suffix “-ic acid” with “-ate”.

To obtain the common name the alkyl part name is the same while the acyl part name is derived from the common name of the acid by replacing the suffix “-ic acid” with “-ate”.

(b)

Interpretation Introduction

Interpretation:

Common name for the given ester has to be assigned.

Concept Introduction:

For naming an ester, it can be structurally viewed in a way that contains an acyl group and an alkyl group.

Rules to obtain IUPAC name and common name for an ester:

Alkyl part appears first in the IUPAC name and it is followed by the acyl part of ester as a separate word.

Name of the alkyl part in the ester is just a name of R group. It can be alkyl, cycloalkyl, or aryl group.

Acyl part present in the ester is named by considering the acid name and replacing the suffix “-ic acid” with “-ate”.

To obtain the common name the alkyl part name is the same while the acyl part name is derived from the common name of the acid by replacing the suffix “-ic acid” with “-ate”.

(c)

Interpretation Introduction

Interpretation:

Common name for the given ester has to be assigned.

Concept Introduction:

For naming an ester, it can be structurally viewed in a way that contains an acyl group and an alkyl group.

Rules to obtain IUPAC name and common name for an ester:

Alkyl part appears first in the IUPAC name and it is followed by the acyl part of ester as a separate word.

Name of the alkyl part in the ester is just a name of R group. It can be alkyl, cycloalkyl, or aryl group.

Acyl part present in the ester is named by considering the acid name and replacing the suffix “-ic acid” with “-ate”.

To obtain the common name the alkyl part name is the same while the acyl part name is derived from the common name of the acid by replacing the suffix “-ic acid” with “-ate”.

(d)

Interpretation Introduction

Interpretation:

Common name for the given ester has to be assigned.

Concept Introduction:

For naming an ester, it can be structurally viewed in a way that contains an acyl group and an alkyl group.

Rules to obtain IUPAC name and common name for an ester:

Alkyl part appears first in the IUPAC name and it is followed by the acyl part of ester as a separate word.

Name of the alkyl part in the ester is just a name of R group. It can be alkyl, cycloalkyl, or aryl group.

Acyl part present in the ester is named by considering the acid name and replacing the suffix “-ic acid” with “-ate”.

To obtain the common name the alkyl part name is the same while the acyl part name is derived from the common name of the acid by replacing the suffix “-ic acid” with “-ate”.

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Answer 5

Chapter 16, Problem 16.91EP

(a)

Interpretation Introduction

Interpretation:

Common name for the given ester has to be assigned.

Concept Introduction:

For naming an ester, it can be structurally viewed in a way that contains an acyl group and an alkyl group.

Rules to obtain IUPAC name and common name for an ester:

Alkyl part appears first in the IUPAC name and it is followed by the acyl part of ester as a separate word.

Name of the alkyl part in the ester is just a name of R group. It can be alkyl, cycloalkyl, or aryl group.

Acyl part present in the ester is named by considering the acid name and replacing the suffix “-ic acid” with “-ate”.

To obtain the common name the alkyl part name is the same while the acyl part name is derived from the common name of the acid by replacing the suffix “-ic acid” with “-ate”.

(b)

Interpretation Introduction

Interpretation:

Common name for the given ester has to be assigned.

Concept Introduction:

For naming an ester, it can be structurally viewed in a way that contains an acyl group and an alkyl group.

Rules to obtain IUPAC name and common name for an ester:

Alkyl part appears first in the IUPAC name and it is followed by the acyl part of ester as a separate word.

Name of the alkyl part in the ester is just a name of R group. It can be alkyl, cycloalkyl, or aryl group.

Acyl part present in the ester is named by considering the acid name and replacing the suffix “-ic acid” with “-ate”.

To obtain the common name the alkyl part name is the same while the acyl part name is derived from the common name of the acid by replacing the suffix “-ic acid” with “-ate”.

(c)

Interpretation Introduction

Interpretation:

Common name for the given ester has to be assigned.

Concept Introduction:

For naming an ester, it can be structurally viewed in a way that contains an acyl group and an alkyl group.

Rules to obtain IUPAC name and common name for an ester:

Alkyl part appears first in the IUPAC name and it is followed by the acyl part of ester as a separate word.

Name of the alkyl part in the ester is just a name of R group. It can be alkyl, cycloalkyl, or aryl group.

Acyl part present in the ester is named by considering the acid name and replacing the suffix “-ic acid” with “-ate”.

To obtain the common name the alkyl part name is the same while the acyl part name is derived from the common name of the acid by replacing the suffix “-ic acid” with “-ate”.

(d)

Interpretation Introduction

Interpretation:

Common name for the given ester has to be assigned.

Concept Introduction:

For naming an ester, it can be structurally viewed in a way that contains an acyl group and an alkyl group.

Rules to obtain IUPAC name and common name for an ester:

Alkyl part appears first in the IUPAC name and it is followed by the acyl part of ester as a separate word.

Name of the alkyl part in the ester is just a name of R group. It can be alkyl, cycloalkyl, or aryl group.

Acyl part present in the ester is named by considering the acid name and replacing the suffix “-ic acid” with “-ate”.

To obtain the common name the alkyl part name is the same while the acyl part name is derived from the common name of the acid by replacing the suffix “-ic acid” with “-ate”.

Answer 6

Chapter 16, Problem 16.91EP

(a)

Interpretation Introduction

Interpretation:

Common name for the given ester has to be assigned.

Concept Introduction:

For naming an ester, it can be structurally viewed in a way that contains an acyl group and an alkyl group.

Rules to obtain IUPAC name and common name for an ester:

Alkyl part appears first in the IUPAC name and it is followed by the acyl part of ester as a separate word.

Name of the alkyl part in the ester is just a name of R group. It can be alkyl, cycloalkyl, or aryl group.

Acyl part present in the ester is named by considering the acid name and replacing the suffix “-ic acid” with “-ate”.

To obtain the common name the alkyl part name is the same while the acyl part name is derived from the common name of the acid by replacing the suffix “-ic acid” with “-ate”.

Answer 7

Chapter 16, Problem 16.91EP

(a)

Interpretation Introduction

Interpretation:

Common name for the given ester has to be assigned.

Concept Introduction:

For naming an ester, it can be structurally viewed in a way that contains an acyl group and an alkyl group.

Rules to obtain IUPAC name and common name for an ester:

Alkyl part appears first in the IUPAC name and it is followed by the acyl part of ester as a separate word.

Name of the alkyl part in the ester is just a name of R group. It can be alkyl, cycloalkyl, or aryl group.

Acyl part present in the ester is named by considering the acid name and replacing the suffix “-ic acid” with “-ate”.

To obtain the common name the alkyl part name is the same while the acyl part name is derived from the common name of the acid by replacing the suffix “-ic acid” with “-ate”.

Answer 8

(b)

Interpretation Introduction

Interpretation:

Common name for the given ester has to be assigned.

Concept Introduction:

For naming an ester, it can be structurally viewed in a way that contains an acyl group and an alkyl group.

Rules to obtain IUPAC name and common name for an ester:

Alkyl part appears first in the IUPAC name and it is followed by the acyl part of ester as a separate word.

Name of the alkyl part in the ester is just a name of R group. It can be alkyl, cycloalkyl, or aryl group.

Acyl part present in the ester is named by considering the acid name and replacing the suffix “-ic acid” with “-ate”.

To obtain the common name the alkyl part name is the same while the acyl part name is derived from the common name of the acid by replacing the suffix “-ic acid” with “-ate”.

Answer 9

(b)

Interpretation Introduction

Interpretation:

Common name for the given ester has to be assigned.

Concept Introduction:

For naming an ester, it can be structurally viewed in a way that contains an acyl group and an alkyl group.

Rules to obtain IUPAC name and common name for an ester:

Alkyl part appears first in the IUPAC name and it is followed by the acyl part of ester as a separate word.

Name of the alkyl part in the ester is just a name of R group. It can be alkyl, cycloalkyl, or aryl group.

Acyl part present in the ester is named by considering the acid name and replacing the suffix “-ic acid” with “-ate”.

To obtain the common name the alkyl part name is the same while the acyl part name is derived from the common name of the acid by replacing the suffix “-ic acid” with “-ate”.

Answer 10

(c)

Interpretation Introduction

Interpretation:

Common name for the given ester has to be assigned.

Concept Introduction:

For naming an ester, it can be structurally viewed in a way that contains an acyl group and an alkyl group.

Rules to obtain IUPAC name and common name for an ester:

Alkyl part appears first in the IUPAC name and it is followed by the acyl part of ester as a separate word.

Name of the alkyl part in the ester is just a name of R group. It can be alkyl, cycloalkyl, or aryl group.

Acyl part present in the ester is named by considering the acid name and replacing the suffix “-ic acid” with “-ate”.

To obtain the common name the alkyl part name is the same while the acyl part name is derived from the common name of the acid by replacing the suffix “-ic acid” with “-ate”.

Answer 11

(c)

Interpretation Introduction

Interpretation:

Common name for the given ester has to be assigned.

Concept Introduction:

For naming an ester, it can be structurally viewed in a way that contains an acyl group and an alkyl group.

Rules to obtain IUPAC name and common name for an ester:

Alkyl part appears first in the IUPAC name and it is followed by the acyl part of ester as a separate word.

Name of the alkyl part in the ester is just a name of R group. It can be alkyl, cycloalkyl, or aryl group.

Acyl part present in the ester is named by considering the acid name and replacing the suffix “-ic acid” with “-ate”.

To obtain the common name the alkyl part name is the same while the acyl part name is derived from the common name of the acid by replacing the suffix “-ic acid” with “-ate”.

Answer 12

(d)

Interpretation Introduction

Interpretation:

Common name for the given ester has to be assigned.

Concept Introduction:

For naming an ester, it can be structurally viewed in a way that contains an acyl group and an alkyl group.

Rules to obtain IUPAC name and common name for an ester:

Alkyl part appears first in the IUPAC name and it is followed by the acyl part of ester as a separate word.

Name of the alkyl part in the ester is just a name of R group. It can be alkyl, cycloalkyl, or aryl group.

Acyl part present in the ester is named by considering the acid name and replacing the suffix “-ic acid” with “-ate”.

To obtain the common name the alkyl part name is the same while the acyl part name is derived from the common name of the acid by replacing the suffix “-ic acid” with “-ate”.

Answer 13

(d)

Interpretation Introduction

Interpretation:

Common name for the given ester has to be assigned.

Concept Introduction:

For naming an ester, it can be structurally viewed in a way that contains an acyl group and an alkyl group.

Rules to obtain IUPAC name and common name for an ester:

Alkyl part appears first in the IUPAC name and it is followed by the acyl part of ester as a separate word.

Name of the alkyl part in the ester is just a name of R group. It can be alkyl, cycloalkyl, or aryl group.

Acyl part present in the ester is named by considering the acid name and replacing the suffix “-ic acid” with “-ate”.

To obtain the common name the alkyl part name is the same while the acyl part name is derived from the common name of the acid by replacing the suffix “-ic acid” with “-ate”.

Answer 14

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Answer 15

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Answer 20

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Answer 25

Ch. 16.1 - Prob. 1QQ Ch. 16.1 - Prob. 2QQ Ch. 16.1 - Prob. 3QQ Ch. 16.1 - Prob. 4QQ Ch. 16.1 - Prob. 5QQ Ch. 16.2 - Prob. 1QQ Ch. 16.2 - Prob. 2QQ Ch. 16.2 - Prob. 3QQ Ch. 16.2 - Prob. 4QQ Ch. 16.2 - Prob. 5QQ

Solution Summary: The author explains that an ester can be structurally viewed in a way that contains an acyl and an alkyl group.

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