Common name for the given ester has to be assigned. Concept Introduction: For naming an ester, it can be structurally viewed in a way that contains an acyl group and an alkyl group. Rules to obtain IUPAC name and common name for an ester: Alkyl part appears first in the IUPAC name and it is followed by the acyl part of ester as a separate word. Name of the alkyl part in the ester is just a name of R group. It can be alkyl, cycloalkyl, or aryl group. Acyl part present in the ester is named by considering the acid name and replacing the suffix “-ic acid” with “-ate”. To obtain the common name the alkyl part name is the same while the acyl part name is derived from the common name of the acid by replacing the suffix “-ic acid” with “-ate”.

Question

A small artisanal cheesemaker is testing the acidity of their milk before it coagulates. During fermentation, bacteria produce lactic acid (K₁ = 1.4 x 104), a weak acid that helps to curdle the milk and develop flavor. The cheesemaker has measured that the developing mixture contains lactic acid at an initial concentration of 0.025 M. Your task is to calculate the pH of this mixture and determine whether it meets the required acidity for proper cheese development. To achieve the best flavor, texture and reduce/control microbial growth, the pH range needs to be between pH 4.6 and 5.0. Assumptions: Lactic acid is a monoprotic acid H H :0:0: H-C-C H :0: O-H Figure 1: Lewis Structure for Lactic Acid For simplicity, you can use the generic formula HA to represent the acid You can assume lactic acid dissociation is in water as milk is mostly water. Temperature is 25°C 1. Write the K, expression for the dissociation of lactic acid in the space provided. Do not forget to include state symbols.…

Answer 1

Question

Chapter 16, Problem 16.91EP

(a)

Interpretation Introduction

Interpretation:

Common name for the given ester has to be assigned.

Concept Introduction:

For naming an ester, it can be structurally viewed in a way that contains an acyl group and an alkyl group.

Rules to obtain IUPAC name and common name for an ester:

Alkyl part appears first in the IUPAC name and it is followed by the acyl part of ester as a separate word.

Name of the alkyl part in the ester is just a name of R group. It can be alkyl, cycloalkyl, or aryl group.

Acyl part present in the ester is named by considering the acid name and replacing the suffix “-ic acid” with “-ate”.

To obtain the common name the alkyl part name is the same while the acyl part name is derived from the common name of the acid by replacing the suffix “-ic acid” with “-ate”.

(b)

Interpretation Introduction

Interpretation:

Common name for the given ester has to be assigned.

Concept Introduction:

For naming an ester, it can be structurally viewed in a way that contains an acyl group and an alkyl group.

Rules to obtain IUPAC name and common name for an ester:

Alkyl part appears first in the IUPAC name and it is followed by the acyl part of ester as a separate word.

Name of the alkyl part in the ester is just a name of R group. It can be alkyl, cycloalkyl, or aryl group.

Acyl part present in the ester is named by considering the acid name and replacing the suffix “-ic acid” with “-ate”.

To obtain the common name the alkyl part name is the same while the acyl part name is derived from the common name of the acid by replacing the suffix “-ic acid” with “-ate”.

(c)

Interpretation Introduction

Interpretation:

Common name for the given ester has to be assigned.

Concept Introduction:

For naming an ester, it can be structurally viewed in a way that contains an acyl group and an alkyl group.

Rules to obtain IUPAC name and common name for an ester:

Alkyl part appears first in the IUPAC name and it is followed by the acyl part of ester as a separate word.

Name of the alkyl part in the ester is just a name of R group. It can be alkyl, cycloalkyl, or aryl group.

Acyl part present in the ester is named by considering the acid name and replacing the suffix “-ic acid” with “-ate”.

To obtain the common name the alkyl part name is the same while the acyl part name is derived from the common name of the acid by replacing the suffix “-ic acid” with “-ate”.

(d)

Interpretation Introduction

Interpretation:

Common name for the given ester has to be assigned.

Concept Introduction:

For naming an ester, it can be structurally viewed in a way that contains an acyl group and an alkyl group.

Rules to obtain IUPAC name and common name for an ester:

Alkyl part appears first in the IUPAC name and it is followed by the acyl part of ester as a separate word.

Name of the alkyl part in the ester is just a name of R group. It can be alkyl, cycloalkyl, or aryl group.

Acyl part present in the ester is named by considering the acid name and replacing the suffix “-ic acid” with “-ate”.

To obtain the common name the alkyl part name is the same while the acyl part name is derived from the common name of the acid by replacing the suffix “-ic acid” with “-ate”.

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A small artisanal cheesemaker is testing the acidity of their milk before it coagulates. During fermentation, bacteria produce lactic acid (K₁ = 1.4 x 104), a weak acid that helps to curdle the milk and develop flavor. The cheesemaker has measured that the developing mixture contains lactic acid at an initial concentration of 0.025 M. Your task is to calculate the pH of this mixture and determine whether it meets the required acidity for proper cheese development. To achieve the best flavor, texture and reduce/control microbial growth, the pH range needs to be between pH 4.6 and 5.0. Assumptions: Lactic acid is a monoprotic acid H H :0:0: H-C-C H :0: O-H Figure 1: Lewis Structure for Lactic Acid For simplicity, you can use the generic formula HA to represent the acid You can assume lactic acid dissociation is in water as milk is mostly water. Temperature is 25°C 1. Write the K, expression for the dissociation of lactic acid in the space provided. Do not forget to include state symbols.…

Curved arrows are used to illustrate the flow of electrons. Using the provided starting and product structures, draw the curved electron-pushing arrows for the following reaction or mechanistic step(s). Be sure to account for all bond-breaking and bond-making steps. :0: :0 H. 0:0 :0: :6: S: :0: Select to Edit Arrows ::0 Select to Edit Arrows H :0: H :CI: Rotation Select to Edit Arrows H. < :0: :0: :0: S:

3:48 PM Fri Apr 4 K Problem 4 of 10 Submit Curved arrows are used to illustrate the flow of electrons. Using the provided starting and product structures, draw the curved electron-pushing arrows for the following reaction or mechanistic step(s). Be sure to account for all bond-breaking and bond-making steps. Mg. :0: Select to Add Arrows :0: :Br: Mg :0: :0: Select to Add Arrows Mg. Br: :0: 0:0- Br -190 H 0:0 Select to Add Arrows Select to Add Arrows neutralizing workup H CH3

Answer 2

Question

Chapter 16, Problem 16.91EP

(a)

Interpretation Introduction

Interpretation:

Common name for the given ester has to be assigned.

Concept Introduction:

For naming an ester, it can be structurally viewed in a way that contains an acyl group and an alkyl group.

Rules to obtain IUPAC name and common name for an ester:

Alkyl part appears first in the IUPAC name and it is followed by the acyl part of ester as a separate word.

Name of the alkyl part in the ester is just a name of R group. It can be alkyl, cycloalkyl, or aryl group.

Acyl part present in the ester is named by considering the acid name and replacing the suffix “-ic acid” with “-ate”.

To obtain the common name the alkyl part name is the same while the acyl part name is derived from the common name of the acid by replacing the suffix “-ic acid” with “-ate”.

(b)

Interpretation Introduction

Interpretation:

Common name for the given ester has to be assigned.

Concept Introduction:

For naming an ester, it can be structurally viewed in a way that contains an acyl group and an alkyl group.

Rules to obtain IUPAC name and common name for an ester:

Alkyl part appears first in the IUPAC name and it is followed by the acyl part of ester as a separate word.

Name of the alkyl part in the ester is just a name of R group. It can be alkyl, cycloalkyl, or aryl group.

Acyl part present in the ester is named by considering the acid name and replacing the suffix “-ic acid” with “-ate”.

To obtain the common name the alkyl part name is the same while the acyl part name is derived from the common name of the acid by replacing the suffix “-ic acid” with “-ate”.

(c)

Interpretation Introduction

Interpretation:

Common name for the given ester has to be assigned.

Concept Introduction:

For naming an ester, it can be structurally viewed in a way that contains an acyl group and an alkyl group.

Rules to obtain IUPAC name and common name for an ester:

Alkyl part appears first in the IUPAC name and it is followed by the acyl part of ester as a separate word.

Name of the alkyl part in the ester is just a name of R group. It can be alkyl, cycloalkyl, or aryl group.

Acyl part present in the ester is named by considering the acid name and replacing the suffix “-ic acid” with “-ate”.

To obtain the common name the alkyl part name is the same while the acyl part name is derived from the common name of the acid by replacing the suffix “-ic acid” with “-ate”.

(d)

Interpretation Introduction

Interpretation:

Common name for the given ester has to be assigned.

Concept Introduction:

For naming an ester, it can be structurally viewed in a way that contains an acyl group and an alkyl group.

Rules to obtain IUPAC name and common name for an ester:

Alkyl part appears first in the IUPAC name and it is followed by the acyl part of ester as a separate word.

Name of the alkyl part in the ester is just a name of R group. It can be alkyl, cycloalkyl, or aryl group.

Acyl part present in the ester is named by considering the acid name and replacing the suffix “-ic acid” with “-ate”.

To obtain the common name the alkyl part name is the same while the acyl part name is derived from the common name of the acid by replacing the suffix “-ic acid” with “-ate”.

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Answer 3

Question

Chapter 16, Problem 16.91EP

(a)

Interpretation Introduction

Interpretation:

Common name for the given ester has to be assigned.

Concept Introduction:

For naming an ester, it can be structurally viewed in a way that contains an acyl group and an alkyl group.

Rules to obtain IUPAC name and common name for an ester:

Alkyl part appears first in the IUPAC name and it is followed by the acyl part of ester as a separate word.

Name of the alkyl part in the ester is just a name of R group. It can be alkyl, cycloalkyl, or aryl group.

Acyl part present in the ester is named by considering the acid name and replacing the suffix “-ic acid” with “-ate”.

To obtain the common name the alkyl part name is the same while the acyl part name is derived from the common name of the acid by replacing the suffix “-ic acid” with “-ate”.

(b)

Interpretation Introduction

Interpretation:

Common name for the given ester has to be assigned.

Concept Introduction:

For naming an ester, it can be structurally viewed in a way that contains an acyl group and an alkyl group.

Rules to obtain IUPAC name and common name for an ester:

Alkyl part appears first in the IUPAC name and it is followed by the acyl part of ester as a separate word.

Name of the alkyl part in the ester is just a name of R group. It can be alkyl, cycloalkyl, or aryl group.

Acyl part present in the ester is named by considering the acid name and replacing the suffix “-ic acid” with “-ate”.

To obtain the common name the alkyl part name is the same while the acyl part name is derived from the common name of the acid by replacing the suffix “-ic acid” with “-ate”.

(c)

Interpretation Introduction

Interpretation:

Common name for the given ester has to be assigned.

Concept Introduction:

For naming an ester, it can be structurally viewed in a way that contains an acyl group and an alkyl group.

Rules to obtain IUPAC name and common name for an ester:

Alkyl part appears first in the IUPAC name and it is followed by the acyl part of ester as a separate word.

Name of the alkyl part in the ester is just a name of R group. It can be alkyl, cycloalkyl, or aryl group.

Acyl part present in the ester is named by considering the acid name and replacing the suffix “-ic acid” with “-ate”.

To obtain the common name the alkyl part name is the same while the acyl part name is derived from the common name of the acid by replacing the suffix “-ic acid” with “-ate”.

(d)

Interpretation Introduction

Interpretation:

Common name for the given ester has to be assigned.

Concept Introduction:

For naming an ester, it can be structurally viewed in a way that contains an acyl group and an alkyl group.

Rules to obtain IUPAC name and common name for an ester:

Alkyl part appears first in the IUPAC name and it is followed by the acyl part of ester as a separate word.

Name of the alkyl part in the ester is just a name of R group. It can be alkyl, cycloalkyl, or aryl group.

Acyl part present in the ester is named by considering the acid name and replacing the suffix “-ic acid” with “-ate”.

To obtain the common name the alkyl part name is the same while the acyl part name is derived from the common name of the acid by replacing the suffix “-ic acid” with “-ate”.

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Answer 4

Question

Chapter 16, Problem 16.91EP

(a)

Interpretation Introduction

Interpretation:

Common name for the given ester has to be assigned.

Concept Introduction:

For naming an ester, it can be structurally viewed in a way that contains an acyl group and an alkyl group.

Rules to obtain IUPAC name and common name for an ester:

Alkyl part appears first in the IUPAC name and it is followed by the acyl part of ester as a separate word.

Name of the alkyl part in the ester is just a name of R group. It can be alkyl, cycloalkyl, or aryl group.

Acyl part present in the ester is named by considering the acid name and replacing the suffix “-ic acid” with “-ate”.

To obtain the common name the alkyl part name is the same while the acyl part name is derived from the common name of the acid by replacing the suffix “-ic acid” with “-ate”.

(b)

Interpretation Introduction

Interpretation:

Common name for the given ester has to be assigned.

Concept Introduction:

For naming an ester, it can be structurally viewed in a way that contains an acyl group and an alkyl group.

Rules to obtain IUPAC name and common name for an ester:

Alkyl part appears first in the IUPAC name and it is followed by the acyl part of ester as a separate word.

Name of the alkyl part in the ester is just a name of R group. It can be alkyl, cycloalkyl, or aryl group.

Acyl part present in the ester is named by considering the acid name and replacing the suffix “-ic acid” with “-ate”.

To obtain the common name the alkyl part name is the same while the acyl part name is derived from the common name of the acid by replacing the suffix “-ic acid” with “-ate”.

(c)

Interpretation Introduction

Interpretation:

Common name for the given ester has to be assigned.

Concept Introduction:

For naming an ester, it can be structurally viewed in a way that contains an acyl group and an alkyl group.

Rules to obtain IUPAC name and common name for an ester:

Alkyl part appears first in the IUPAC name and it is followed by the acyl part of ester as a separate word.

Name of the alkyl part in the ester is just a name of R group. It can be alkyl, cycloalkyl, or aryl group.

Acyl part present in the ester is named by considering the acid name and replacing the suffix “-ic acid” with “-ate”.

To obtain the common name the alkyl part name is the same while the acyl part name is derived from the common name of the acid by replacing the suffix “-ic acid” with “-ate”.

(d)

Interpretation Introduction

Interpretation:

Common name for the given ester has to be assigned.

Concept Introduction:

For naming an ester, it can be structurally viewed in a way that contains an acyl group and an alkyl group.

Rules to obtain IUPAC name and common name for an ester:

Alkyl part appears first in the IUPAC name and it is followed by the acyl part of ester as a separate word.

Name of the alkyl part in the ester is just a name of R group. It can be alkyl, cycloalkyl, or aryl group.

Acyl part present in the ester is named by considering the acid name and replacing the suffix “-ic acid” with “-ate”.

To obtain the common name the alkyl part name is the same while the acyl part name is derived from the common name of the acid by replacing the suffix “-ic acid” with “-ate”.

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Answer 5

Chapter 16, Problem 16.91EP

(a)

Interpretation Introduction

Interpretation:

Common name for the given ester has to be assigned.

Concept Introduction:

For naming an ester, it can be structurally viewed in a way that contains an acyl group and an alkyl group.

Rules to obtain IUPAC name and common name for an ester:

Alkyl part appears first in the IUPAC name and it is followed by the acyl part of ester as a separate word.

Name of the alkyl part in the ester is just a name of R group. It can be alkyl, cycloalkyl, or aryl group.

Acyl part present in the ester is named by considering the acid name and replacing the suffix “-ic acid” with “-ate”.

To obtain the common name the alkyl part name is the same while the acyl part name is derived from the common name of the acid by replacing the suffix “-ic acid” with “-ate”.

(b)

Interpretation Introduction

Interpretation:

Common name for the given ester has to be assigned.

Concept Introduction:

For naming an ester, it can be structurally viewed in a way that contains an acyl group and an alkyl group.

Rules to obtain IUPAC name and common name for an ester:

Alkyl part appears first in the IUPAC name and it is followed by the acyl part of ester as a separate word.

Name of the alkyl part in the ester is just a name of R group. It can be alkyl, cycloalkyl, or aryl group.

Acyl part present in the ester is named by considering the acid name and replacing the suffix “-ic acid” with “-ate”.

To obtain the common name the alkyl part name is the same while the acyl part name is derived from the common name of the acid by replacing the suffix “-ic acid” with “-ate”.

(c)

Interpretation Introduction

Interpretation:

Common name for the given ester has to be assigned.

Concept Introduction:

For naming an ester, it can be structurally viewed in a way that contains an acyl group and an alkyl group.

Rules to obtain IUPAC name and common name for an ester:

Alkyl part appears first in the IUPAC name and it is followed by the acyl part of ester as a separate word.

Name of the alkyl part in the ester is just a name of R group. It can be alkyl, cycloalkyl, or aryl group.

Acyl part present in the ester is named by considering the acid name and replacing the suffix “-ic acid” with “-ate”.

To obtain the common name the alkyl part name is the same while the acyl part name is derived from the common name of the acid by replacing the suffix “-ic acid” with “-ate”.

(d)

Interpretation Introduction

Interpretation:

Common name for the given ester has to be assigned.

Concept Introduction:

For naming an ester, it can be structurally viewed in a way that contains an acyl group and an alkyl group.

Rules to obtain IUPAC name and common name for an ester:

Alkyl part appears first in the IUPAC name and it is followed by the acyl part of ester as a separate word.

Name of the alkyl part in the ester is just a name of R group. It can be alkyl, cycloalkyl, or aryl group.

Acyl part present in the ester is named by considering the acid name and replacing the suffix “-ic acid” with “-ate”.

To obtain the common name the alkyl part name is the same while the acyl part name is derived from the common name of the acid by replacing the suffix “-ic acid” with “-ate”.

Answer 6

Chapter 16, Problem 16.91EP

(a)

Interpretation Introduction

Interpretation:

Common name for the given ester has to be assigned.

Concept Introduction:

For naming an ester, it can be structurally viewed in a way that contains an acyl group and an alkyl group.

Rules to obtain IUPAC name and common name for an ester:

Alkyl part appears first in the IUPAC name and it is followed by the acyl part of ester as a separate word.

Name of the alkyl part in the ester is just a name of R group. It can be alkyl, cycloalkyl, or aryl group.

Acyl part present in the ester is named by considering the acid name and replacing the suffix “-ic acid” with “-ate”.

To obtain the common name the alkyl part name is the same while the acyl part name is derived from the common name of the acid by replacing the suffix “-ic acid” with “-ate”.

Answer 7

Chapter 16, Problem 16.91EP

(a)

Interpretation Introduction

Interpretation:

Common name for the given ester has to be assigned.

Concept Introduction:

For naming an ester, it can be structurally viewed in a way that contains an acyl group and an alkyl group.

Rules to obtain IUPAC name and common name for an ester:

Alkyl part appears first in the IUPAC name and it is followed by the acyl part of ester as a separate word.

Name of the alkyl part in the ester is just a name of R group. It can be alkyl, cycloalkyl, or aryl group.

Acyl part present in the ester is named by considering the acid name and replacing the suffix “-ic acid” with “-ate”.

To obtain the common name the alkyl part name is the same while the acyl part name is derived from the common name of the acid by replacing the suffix “-ic acid” with “-ate”.

Answer 8

(b)

Interpretation Introduction

Interpretation:

Common name for the given ester has to be assigned.

Concept Introduction:

For naming an ester, it can be structurally viewed in a way that contains an acyl group and an alkyl group.

Rules to obtain IUPAC name and common name for an ester:

Alkyl part appears first in the IUPAC name and it is followed by the acyl part of ester as a separate word.

Name of the alkyl part in the ester is just a name of R group. It can be alkyl, cycloalkyl, or aryl group.

Acyl part present in the ester is named by considering the acid name and replacing the suffix “-ic acid” with “-ate”.

To obtain the common name the alkyl part name is the same while the acyl part name is derived from the common name of the acid by replacing the suffix “-ic acid” with “-ate”.

Answer 9

(b)

Interpretation Introduction

Interpretation:

Common name for the given ester has to be assigned.

Concept Introduction:

For naming an ester, it can be structurally viewed in a way that contains an acyl group and an alkyl group.

Rules to obtain IUPAC name and common name for an ester:

Alkyl part appears first in the IUPAC name and it is followed by the acyl part of ester as a separate word.

Name of the alkyl part in the ester is just a name of R group. It can be alkyl, cycloalkyl, or aryl group.

Acyl part present in the ester is named by considering the acid name and replacing the suffix “-ic acid” with “-ate”.

To obtain the common name the alkyl part name is the same while the acyl part name is derived from the common name of the acid by replacing the suffix “-ic acid” with “-ate”.

Answer 10

(c)

Interpretation Introduction

Interpretation:

Common name for the given ester has to be assigned.

Concept Introduction:

For naming an ester, it can be structurally viewed in a way that contains an acyl group and an alkyl group.

Rules to obtain IUPAC name and common name for an ester:

Alkyl part appears first in the IUPAC name and it is followed by the acyl part of ester as a separate word.

Name of the alkyl part in the ester is just a name of R group. It can be alkyl, cycloalkyl, or aryl group.

Acyl part present in the ester is named by considering the acid name and replacing the suffix “-ic acid” with “-ate”.

To obtain the common name the alkyl part name is the same while the acyl part name is derived from the common name of the acid by replacing the suffix “-ic acid” with “-ate”.

Answer 11

(c)

Interpretation Introduction

Interpretation:

Common name for the given ester has to be assigned.

Concept Introduction:

For naming an ester, it can be structurally viewed in a way that contains an acyl group and an alkyl group.

Rules to obtain IUPAC name and common name for an ester:

Alkyl part appears first in the IUPAC name and it is followed by the acyl part of ester as a separate word.

Name of the alkyl part in the ester is just a name of R group. It can be alkyl, cycloalkyl, or aryl group.

Acyl part present in the ester is named by considering the acid name and replacing the suffix “-ic acid” with “-ate”.

To obtain the common name the alkyl part name is the same while the acyl part name is derived from the common name of the acid by replacing the suffix “-ic acid” with “-ate”.

Answer 12

(d)

Interpretation Introduction

Interpretation:

Common name for the given ester has to be assigned.

Concept Introduction:

For naming an ester, it can be structurally viewed in a way that contains an acyl group and an alkyl group.

Rules to obtain IUPAC name and common name for an ester:

Alkyl part appears first in the IUPAC name and it is followed by the acyl part of ester as a separate word.

Name of the alkyl part in the ester is just a name of R group. It can be alkyl, cycloalkyl, or aryl group.

Acyl part present in the ester is named by considering the acid name and replacing the suffix “-ic acid” with “-ate”.

To obtain the common name the alkyl part name is the same while the acyl part name is derived from the common name of the acid by replacing the suffix “-ic acid” with “-ate”.

Answer 13

(d)

Interpretation Introduction

Interpretation:

Common name for the given ester has to be assigned.

Concept Introduction:

For naming an ester, it can be structurally viewed in a way that contains an acyl group and an alkyl group.

Rules to obtain IUPAC name and common name for an ester:

Alkyl part appears first in the IUPAC name and it is followed by the acyl part of ester as a separate word.

Name of the alkyl part in the ester is just a name of R group. It can be alkyl, cycloalkyl, or aryl group.

Acyl part present in the ester is named by considering the acid name and replacing the suffix “-ic acid” with “-ate”.

To obtain the common name the alkyl part name is the same while the acyl part name is derived from the common name of the acid by replacing the suffix “-ic acid” with “-ate”.

Answer 14

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Answer 15

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Answer 25

Ch. 16.1 - Prob. 1QQ Ch. 16.1 - Prob. 2QQ Ch. 16.1 - Prob. 3QQ Ch. 16.1 - Prob. 4QQ Ch. 16.1 - Prob. 5QQ Ch. 16.2 - Prob. 1QQ Ch. 16.2 - Prob. 2QQ Ch. 16.2 - Prob. 3QQ Ch. 16.2 - Prob. 4QQ Ch. 16.2 - Prob. 5QQ

Solution Summary: The author explains that an ester can be structurally viewed in a way that contains an acyl and an alkyl group.

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