General, Organic, and Biological Chemistry
General, Organic, and Biological Chemistry
7th Edition
ISBN: 9781285853918
Author: H. Stephen Stoker
Publisher: Cengage Learning
Question
Book Icon
Chapter 16, Problem 16.130EP

(a)

Interpretation Introduction

Interpretation:

The IUPAC name of reaction products when ethyl pentanoate undergoes ester hydrolysis under acidic conditions has to be written.

Concept Introduction:

Breaking of the carbon‑oxygen single bond present between the “acid part” and “alcohol part” is one of the important reactions of ester.  This process of breaking the bond between the carbon‑oxygen is known as ester hydrolysis or saponification.  The condition prevails in the reaction determines it as ester hydrolysis of saponification.

Ester hydrolysis takes place in ester when it is treated with strong acid or enzymes as catalyst.  Reverse of esterification reaction is the ester hydrolysis.

Saponification is the reaction that ester undergoes when a strong base is used to give the product as carboxylic acid salt and alcohol.

(a)

Expert Solution
Check Mark

Answer to Problem 16.130EP

The IUPAC names of the products obtained are,

General, Organic, and Biological Chemistry, Chapter 16, Problem 16.130EP , additional homework tip  1

Explanation of Solution

Given name of ester is ethyl pentanoate.  The structure of ethyl pentanoate can be given as,

General, Organic, and Biological Chemistry, Chapter 16, Problem 16.130EP , additional homework tip  2

Under acidic conditions, esters undergo hydrolysis resulting in breakage of the carbon‑oxygen single bond that is present between the “acid part” and “alcohol part”.  The product that is obtained on ester hydrolysis in acidic conditions is carboxylic acid and an alcohol.  The complete reaction and the structure of the product obtained can be written as shown below,

General, Organic, and Biological Chemistry, Chapter 16, Problem 16.130EP , additional homework tip  3

The IUPAC names of the product obtained can be given using IUPAC nomenclature of naming the compounds.  The IUPAC names and the structure of the product obtained are,

General, Organic, and Biological Chemistry, Chapter 16, Problem 16.130EP , additional homework tip  4

Conclusion

IUPAC names of the products obtained when ethyl pentanoate undergoes hydrolysis under acidic condition are written.

(b)

Interpretation Introduction

Interpretation:

The IUPAC name of reaction products when ethyl methanoate undergoes ester hydrolysis under acidic conditions has to be written.

Concept Introduction:

Breaking of the carbon‑oxygen single bond present between the “acid part” and “alcohol part” is one of the important reactions of ester.  This process of breaking the bond between the carbon‑oxygen is known as ester hydrolysis or saponification.  The condition prevails in the reaction determines it as ester hydrolysis of saponification.

Ester hydrolysis takes place in ester when it is treated with strong acid or enzymes as catalyst.  Reverse of esterification reaction is the ester hydrolysis.

Saponification is the reaction that ester undergoes when a strong base is used to give the product as carboxylic acid salt and alcohol.

(b)

Expert Solution
Check Mark

Answer to Problem 16.130EP

The structural formula and IUPAC names of the products obtained are,

General, Organic, and Biological Chemistry, Chapter 16, Problem 16.130EP , additional homework tip  5

Explanation of Solution

Given name of ester is ethyl methanoate.  The structure of ethyl methanoate can be given as,

General, Organic, and Biological Chemistry, Chapter 16, Problem 16.130EP , additional homework tip  6

Under acidic conditions, esters undergo hydrolysis resulting in breakage of the carbon‑oxygen single bond that is present between the “acid part” and “alcohol part”.  The product that is obtained on ester hydrolysis in acidic conditions is carboxylic acid and an alcohol.  The complete reaction and the structure of the product obtained can be written as shown below,

General, Organic, and Biological Chemistry, Chapter 16, Problem 16.130EP , additional homework tip  7

The IUPAC names of the product obtained can be given using IUPAC nomenclature of naming the compounds.  The IUPAC names and the structure of the product obtained are,

General, Organic, and Biological Chemistry, Chapter 16, Problem 16.130EP , additional homework tip  8

Conclusion

IUPAC names of the products obtained when ethyl methanoate undergoes hydrolysis under acidic condition are written.

(c)

Interpretation Introduction

Interpretation:

The IUPAC name of reaction products when isopropyl pentanoate undergoes ester hydrolysis under acidic conditions has to be written.

Concept Introduction:

Breaking of the carbon‑oxygen single bond present between the “acid part” and “alcohol part” is one of the important reactions of ester.  This process of breaking the bond between the carbon‑oxygen is known as ester hydrolysis or saponification.  The condition prevails in the reaction determines it as ester hydrolysis of saponification.

Ester hydrolysis takes place in ester when it is treated with strong acid or enzymes as catalyst.  Reverse of esterification reaction is the ester hydrolysis.

Saponification is the reaction that ester undergoes when a strong base is used to give the product as carboxylic acid salt and alcohol.

(c)

Expert Solution
Check Mark

Answer to Problem 16.130EP

The structural formula and IUPAC names of the products obtained are,

General, Organic, and Biological Chemistry, Chapter 16, Problem 16.130EP , additional homework tip  9

Explanation of Solution

Given name of ester is isopropyl pentanoate.  The structure of isopropyl pentanoate can be given as,

General, Organic, and Biological Chemistry, Chapter 16, Problem 16.130EP , additional homework tip  10

Under acidic conditions, esters undergo hydrolysis resulting in breakage of the carbon‑oxygen single bond that is present between the “acid part” and “alcohol part”.  The product that is obtained on ester hydrolysis in acidic conditions is carboxylic acid and an alcohol.  The complete reaction and the structure of the product obtained can be written as shown below,

General, Organic, and Biological Chemistry, Chapter 16, Problem 16.130EP , additional homework tip  11

The IUPAC names of the product obtained can be given using IUPAC nomenclature of naming the compounds.  The IUPAC names and the structure of the product obtained are,

General, Organic, and Biological Chemistry, Chapter 16, Problem 16.130EP , additional homework tip  12

Conclusion

IUPAC names of the products obtained when isopropyl pentanoate undergoes hydrolysis under acidic condition are written.

(d)

Interpretation Introduction

Interpretation:

The IUPAC name of reaction products when isopropyl methanoate undergoes ester hydrolysis under acidic conditions has to be written.

Concept Introduction:

Breaking of the carbon‑oxygen single bond present between the “acid part” and “alcohol part” is one of the important reactions of ester.  This process of breaking the bond between the carbon‑oxygen is known as ester hydrolysis or saponification.  The condition prevails in the reaction determines it as ester hydrolysis of saponification.

Ester hydrolysis takes place in ester when it is treated with strong acid or enzymes as catalyst.  Reverse of esterification reaction is the ester hydrolysis.

Saponification is the reaction that ester undergoes when a strong base is used to give the product as carboxylic acid salt and alcohol.

(d)

Expert Solution
Check Mark

Answer to Problem 16.130EP

The structural formula and IUPAC names of the products obtained are,

General, Organic, and Biological Chemistry, Chapter 16, Problem 16.130EP , additional homework tip  13

Explanation of Solution

Given name of ester is isopropyl methanoate.  The structure of isopropyl methanoate can be given as,

General, Organic, and Biological Chemistry, Chapter 16, Problem 16.130EP , additional homework tip  14

Under acidic conditions, esters undergo hydrolysis resulting in breakage of the carbon‑oxygen single bond that is present between the “acid part” and “alcohol part”.  The product that is obtained on ester hydrolysis in acidic conditions is carboxylic acid and an alcohol.  The complete reaction and the structure of the product obtained can be written as shown below,

General, Organic, and Biological Chemistry, Chapter 16, Problem 16.130EP , additional homework tip  15

The IUPAC names of the product obtained can be given using IUPAC nomenclature of naming the compounds.  The IUPAC names and the structure of the product obtained are,

General, Organic, and Biological Chemistry, Chapter 16, Problem 16.130EP , additional homework tip  16

Conclusion

IUPAC names of the products obtained when isopropyl methanoate undergoes hydrolysis under acidic condition are written.

Want to see more full solutions like this?

Subscribe now to access step-by-step solutions to millions of textbook problems written by subject matter experts!
Students have asked these similar questions
Explain why heat is needed in the hydrolysis of esters
1. Which of the following structural features is possessed by aldehydes but not ketones? a. At least one hydroxyl group is bonded to the carbonyl carbon atom.  b. At least one hydrogen atom is bonded to the carbonyl carbon atom. c. The carbonyl carbon atom is bonded to two other carbon atoms. d. The carbonyl carbon atom is part of a ring structure.   2. What is the IUPAC name of the following compound in the attached photo? a. 3-chloro-4-nitrobenzoic acid b. 2-chloro-4-carboxynitrobenzene c. 2-nitro-5-carboxychlorobenzene d. 2-chloro-1-nitro-4-benzoic acid   3. Which of the following is the correct bond-line structure for CH3C≡C(CH2)2CH(CH3)2? a. Structure I b. Structure II c. Structure III d. Structure IV
how pentanal can be synthesized from each of the following reactants. provide reactants and reagents a. ester b. alkene c. alkyne

Chapter 16 Solutions

General, Organic, and Biological Chemistry

Ch. 16.3 - Prob. 1QQCh. 16.3 - Prob. 2QQCh. 16.3 - Prob. 3QQCh. 16.4 - Prob. 1QQCh. 16.4 - Prob. 2QQCh. 16.4 - Prob. 3QQCh. 16.5 - Prob. 1QQCh. 16.5 - Prob. 2QQCh. 16.5 - Prob. 3QQCh. 16.6 - Prob. 1QQCh. 16.6 - Prob. 2QQCh. 16.7 - Prob. 1QQCh. 16.7 - Prob. 2QQCh. 16.7 - Prob. 3QQCh. 16.8 - Prob. 1QQCh. 16.8 - Prob. 2QQCh. 16.8 - Prob. 3QQCh. 16.8 - Prob. 4QQCh. 16.9 - Prob. 1QQCh. 16.9 - Prob. 2QQCh. 16.10 - Prob. 1QQCh. 16.10 - Prob. 2QQCh. 16.11 - Prob. 1QQCh. 16.11 - Prob. 2QQCh. 16.11 - Prob. 3QQCh. 16.12 - Prob. 1QQCh. 16.12 - Prob. 2QQCh. 16.12 - Prob. 3QQCh. 16.12 - Prob. 4QQCh. 16.13 - Prob. 1QQCh. 16.13 - Prob. 2QQCh. 16.14 - Prob. 1QQCh. 16.14 - Prob. 2QQCh. 16.14 - Prob. 3QQCh. 16.15 - Prob. 1QQCh. 16.15 - Prob. 2QQCh. 16.15 - Prob. 3QQCh. 16.16 - Prob. 1QQCh. 16.16 - Prob. 2QQCh. 16.16 - Prob. 3QQCh. 16.17 - Prob. 1QQCh. 16.17 - Prob. 2QQCh. 16.18 - Prob. 1QQCh. 16.18 - Prob. 2QQCh. 16.18 - Prob. 3QQCh. 16.19 - Prob. 1QQCh. 16.19 - Prob. 2QQCh. 16.19 - Prob. 3QQCh. 16.19 - Prob. 4QQCh. 16.20 - Prob. 1QQCh. 16.20 - Prob. 2QQCh. 16.20 - Prob. 3QQCh. 16.20 - Prob. 4QQCh. 16 - Prob. 16.1EPCh. 16 - Prob. 16.2EPCh. 16 - Prob. 16.3EPCh. 16 - Prob. 16.4EPCh. 16 - Prob. 16.5EPCh. 16 - Prob. 16.6EPCh. 16 - Prob. 16.7EPCh. 16 - Prob. 16.8EPCh. 16 - Prob. 16.9EPCh. 16 - Prob. 16.10EPCh. 16 - Prob. 16.11EPCh. 16 - Prob. 16.12EPCh. 16 - Prob. 16.13EPCh. 16 - Prob. 16.14EPCh. 16 - Prob. 16.15EPCh. 16 - Prob. 16.16EPCh. 16 - Prob. 16.17EPCh. 16 - Prob. 16.18EPCh. 16 - Prob. 16.19EPCh. 16 - Prob. 16.20EPCh. 16 - Prob. 16.21EPCh. 16 - Prob. 16.22EPCh. 16 - Prob. 16.23EPCh. 16 - Prob. 16.24EPCh. 16 - Prob. 16.25EPCh. 16 - Prob. 16.26EPCh. 16 - Prob. 16.27EPCh. 16 - Prob. 16.28EPCh. 16 - Prob. 16.29EPCh. 16 - Prob. 16.30EPCh. 16 - Prob. 16.31EPCh. 16 - Prob. 16.32EPCh. 16 - Prob. 16.33EPCh. 16 - Prob. 16.34EPCh. 16 - Prob. 16.35EPCh. 16 - Prob. 16.36EPCh. 16 - Prob. 16.37EPCh. 16 - Prob. 16.38EPCh. 16 - Prob. 16.39EPCh. 16 - Prob. 16.40EPCh. 16 - Determine the maximum number of hydrogen bonds...Ch. 16 - Prob. 16.42EPCh. 16 - Prob. 16.43EPCh. 16 - Prob. 16.44EPCh. 16 - Prob. 16.45EPCh. 16 - Prob. 16.46EPCh. 16 - Prob. 16.47EPCh. 16 - Prob. 16.48EPCh. 16 - Prob. 16.49EPCh. 16 - Prob. 16.50EPCh. 16 - Prob. 16.51EPCh. 16 - Prob. 16.52EPCh. 16 - Prob. 16.53EPCh. 16 - Prob. 16.54EPCh. 16 - Prob. 16.55EPCh. 16 - Prob. 16.56EPCh. 16 - Give the IUPAC name for each of the following...Ch. 16 - Give the IUPAC name for each of the following...Ch. 16 - Prob. 16.59EPCh. 16 - Give the common name for each of the carboxylic...Ch. 16 - Prob. 16.61EPCh. 16 - Write a chemical equation for the preparation of...Ch. 16 - Prob. 16.63EPCh. 16 - Prob. 16.64EPCh. 16 - Prob. 16.65EPCh. 16 - Prob. 16.66EPCh. 16 - Prob. 16.67EPCh. 16 - Prob. 16.68EPCh. 16 - Prob. 16.69EPCh. 16 - Prob. 16.70EPCh. 16 - Prob. 16.71EPCh. 16 - Prob. 16.72EPCh. 16 - Prob. 16.73EPCh. 16 - Prob. 16.74EPCh. 16 - Prob. 16.75EPCh. 16 - Prob. 16.76EPCh. 16 - Prob. 16.77EPCh. 16 - Prob. 16.78EPCh. 16 - Prob. 16.79EPCh. 16 - Prob. 16.80EPCh. 16 - Prob. 16.81EPCh. 16 - Prob. 16.82EPCh. 16 - Prob. 16.83EPCh. 16 - Prob. 16.84EPCh. 16 - Prob. 16.85EPCh. 16 - Prob. 16.86EPCh. 16 - Prob. 16.87EPCh. 16 - Prob. 16.88EPCh. 16 - Prob. 16.89EPCh. 16 - Prob. 16.90EPCh. 16 - Prob. 16.91EPCh. 16 - Prob. 16.92EPCh. 16 - Assign an IUPAC name to each of the following...Ch. 16 - Prob. 16.94EPCh. 16 - Prob. 16.95EPCh. 16 - Prob. 16.96EPCh. 16 - Prob. 16.97EPCh. 16 - Prob. 16.98EPCh. 16 - Prob. 16.99EPCh. 16 - Prob. 16.100EPCh. 16 - How many carbon atoms are present in a molecule of...Ch. 16 - Prob. 16.102EPCh. 16 - Prob. 16.103EPCh. 16 - Prob. 16.104EPCh. 16 - Prob. 16.105EPCh. 16 - Prob. 16.106EPCh. 16 - Prob. 16.107EPCh. 16 - Prob. 16.108EPCh. 16 - Prob. 16.109EPCh. 16 - Prob. 16.110EPCh. 16 - Prob. 16.111EPCh. 16 - Prob. 16.112EPCh. 16 - Prob. 16.113EPCh. 16 - Prob. 16.114EPCh. 16 - Prob. 16.115EPCh. 16 - Prob. 16.116EPCh. 16 - Prob. 16.117EPCh. 16 - Prob. 16.118EPCh. 16 - Prob. 16.119EPCh. 16 - Prob. 16.120EPCh. 16 - Prob. 16.121EPCh. 16 - Prob. 16.122EPCh. 16 - Prob. 16.123EPCh. 16 - Prob. 16.124EPCh. 16 - Prob. 16.125EPCh. 16 - Prob. 16.126EPCh. 16 - Prob. 16.127EPCh. 16 - Prob. 16.128EPCh. 16 - Prob. 16.129EPCh. 16 - Prob. 16.130EPCh. 16 - Prob. 16.131EPCh. 16 - Prob. 16.132EPCh. 16 - Prob. 16.133EPCh. 16 - Prob. 16.134EPCh. 16 - Prob. 16.135EPCh. 16 - Prob. 16.136EPCh. 16 - Prob. 16.137EPCh. 16 - Prob. 16.138EPCh. 16 - Prob. 16.139EPCh. 16 - Prob. 16.140EPCh. 16 - Prob. 16.141EPCh. 16 - Prob. 16.142EPCh. 16 - Prob. 16.143EPCh. 16 - Prob. 16.144EPCh. 16 - Prob. 16.145EPCh. 16 - Prob. 16.146EPCh. 16 - Prob. 16.147EPCh. 16 - Prob. 16.148EPCh. 16 - Draw a condensed structural formula for the...Ch. 16 - Prob. 16.150EPCh. 16 - Prob. 16.151EPCh. 16 - Prob. 16.152EPCh. 16 - Prob. 16.153EPCh. 16 - Prob. 16.154EPCh. 16 - Prob. 16.155EPCh. 16 - Prob. 16.156EPCh. 16 - Prob. 16.157EPCh. 16 - Prob. 16.158EPCh. 16 - Prob. 16.159EPCh. 16 - Prob. 16.160EPCh. 16 - Prob. 16.161EPCh. 16 - Prob. 16.162EPCh. 16 - Prob. 16.163EPCh. 16 - Prob. 16.164EP
Knowledge Booster
Background pattern image
Similar questions
SEE MORE QUESTIONS
Recommended textbooks for you
Text book image
Organic And Biological Chemistry
Chemistry
ISBN:9781305081079
Author:STOKER, H. Stephen (howard Stephen)
Publisher:Cengage Learning,
Text book image
General, Organic, and Biological Chemistry
Chemistry
ISBN:9781285853918
Author:H. Stephen Stoker
Publisher:Cengage Learning
Text book image
World of Chemistry, 3rd edition
Chemistry
ISBN:9781133109655
Author:Steven S. Zumdahl, Susan L. Zumdahl, Donald J. DeCoste
Publisher:Brooks / Cole / Cengage Learning
Text book image
Chemistry & Chemical Reactivity
Chemistry
ISBN:9781133949640
Author:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher:Cengage Learning
Text book image
Chemistry for Today: General, Organic, and Bioche...
Chemistry
ISBN:9781305960060
Author:Spencer L. Seager, Michael R. Slabaugh, Maren S. Hansen
Publisher:Cengage Learning
Text book image
Chemistry: Matter and Change
Chemistry
ISBN:9780078746376
Author:Dinah Zike, Laurel Dingrando, Nicholas Hainen, Cheryl Wistrom
Publisher:Glencoe/McGraw-Hill School Pub Co