Organic And Biological Chemistry
7th Edition
ISBN: 9781305081079
Author: STOKER, H. Stephen (howard Stephen)
Publisher: Cengage Learning,
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Chapter 2.10, Problem 5QQ
Interpretation Introduction
Interpretation:
The major product that will be formed when propene reacts with hydrogen chloride has to be identified based on Markovnikov’s rule from the given options.
Concept Introduction:
In this reaction no atoms or group of atoms are removed. Instead the unsaturated bond is reduced to saturated bond. A general scheme for addition reaction of
Addition reactions can be classified broadly into two types. They are asymmetrical addition reaction and symmetrical addition reaction.
Symmetrical addition reactions is the one in which the same atom or same group of atoms are added across the carbon‑carbon multiple bonds.
Unsymmetrical addition reactions is the one in which the different atom or different group of atoms are added across the carbon‑carbon multiple bonds.
Markovnikov’s rule:
When an unsymmetrical molecule of formula HQ to an unsymmeterical alkene, the hydrogen atom from HQ gets attached to the unsaturated carbon atom which has the most hydrogen atoms. In other words, it can be said that the hydrogen atom gets attached to the unsaturated carbon atom that is least substituted.
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Predict the major products of this organic reaction:
HBr (1 equiv)
cold
?
Some important notes:
• Draw the major product, or products, of this reaction in the drawing area below.
• You can draw the products in any arrangement you like.
• Pay careful attention to the reaction conditions, and only include the major products.
• Be sure to use wedge and dash bonds when necessary, for example to distinguish between major products that are enantiomers.
• Note that there is only 1 equivalent of HBr reactant, so you need not consider the case of multiple additions.
dm
Re
Explanation
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b) Use curved arrows to show the reaction of the radical with hydrogen bromide.
Br:
Br H
..
Answer Bank
Indicate the reaction products when CH3COCH2COOCH2COOC2H5 (ethyl acetoacetoacetate) reacts with 1º OH-/H2O and 2º H3O+
Chapter 2 Solutions
Organic And Biological Chemistry
Ch. 2.1 - Prob. 1QQCh. 2.1 - Prob. 2QQCh. 2.1 - Prob. 3QQCh. 2.2 - Prob. 1QQCh. 2.2 - Prob. 2QQCh. 2.2 - Prob. 3QQCh. 2.2 - Prob. 4QQCh. 2.3 - Prob. 1QQCh. 2.3 - Prob. 2QQCh. 2.3 - Prob. 3QQ
Ch. 2.3 - Prob. 4QQCh. 2.4 - Prob. 1QQCh. 2.4 - Prob. 2QQCh. 2.5 - Prob. 1QQCh. 2.5 - Prob. 2QQCh. 2.5 - Prob. 3QQCh. 2.6 - Prob. 1QQCh. 2.6 - Prob. 2QQCh. 2.6 - Prob. 3QQCh. 2.7 - Prob. 1QQCh. 2.7 - Prob. 2QQCh. 2.7 - Prob. 3QQCh. 2.8 - Prob. 1QQCh. 2.8 - Prob. 2QQCh. 2.9 - Prob. 1QQCh. 2.9 - Prob. 2QQCh. 2.10 - Prob. 1QQCh. 2.10 - Prob. 2QQCh. 2.10 - Prob. 3QQCh. 2.10 - Prob. 4QQCh. 2.10 - Prob. 5QQCh. 2.11 - Prob. 1QQCh. 2.11 - Prob. 2QQCh. 2.11 - Prob. 3QQCh. 2.11 - Prob. 4QQCh. 2.11 - Prob. 5QQCh. 2.12 - Prob. 1QQCh. 2.12 - Prob. 2QQCh. 2.12 - Prob. 3QQCh. 2.12 - Prob. 4QQCh. 2.12 - Prob. 5QQCh. 2.13 - Prob. 1QQCh. 2.13 - Prob. 2QQCh. 2.13 - Prob. 3QQCh. 2.14 - Prob. 1QQCh. 2.14 - Prob. 2QQCh. 2.14 - Prob. 3QQCh. 2.14 - Prob. 4QQCh. 2.15 - Prob. 1QQCh. 2.15 - Prob. 2QQCh. 2.15 - Prob. 3QQCh. 2.15 - Prob. 4QQCh. 2.16 - Prob. 1QQCh. 2.16 - Prob. 2QQCh. 2 - Classify each of the following hydrocarbons as...Ch. 2 - Prob. 2.2EPCh. 2 - Prob. 2.3EPCh. 2 - Prob. 2.4EPCh. 2 - Prob. 2.5EPCh. 2 - Prob. 2.6EPCh. 2 - Prob. 2.7EPCh. 2 - Characterize the physical properties of saturated...Ch. 2 - Prob. 2.9EPCh. 2 - Prob. 2.10EPCh. 2 - Prob. 2.11EPCh. 2 - Prob. 2.12EPCh. 2 - Prob. 2.13EPCh. 2 - Prob. 2.14EPCh. 2 - What is the name of the spatial arrangement for...Ch. 2 - Prob. 2.16EPCh. 2 - Prob. 2.17EPCh. 2 - Prob. 2.18EPCh. 2 - Draw a condensed structural formula for each of...Ch. 2 - Prob. 2.20EPCh. 2 - The following names are incorrect by IUPAC rules....Ch. 2 - The following names are incorrect by IUPAC rules....Ch. 2 - Prob. 2.23EPCh. 2 - Draw a condensed structural formula for each of...Ch. 2 - Prob. 2.25EPCh. 2 - Classify each of the following compounds as...Ch. 2 - Prob. 2.27EPCh. 2 - How many hydrogen atoms are present in a molecule...Ch. 2 - Draw a line-angle structural formula for each of...Ch. 2 - Draw a line-angle structural formula for each of...Ch. 2 - Prob. 2.31EPCh. 2 - Prob. 2.32EPCh. 2 - Prob. 2.33EPCh. 2 - Prob. 2.34EPCh. 2 - Prob. 2.35EPCh. 2 - Prob. 2.36EPCh. 2 - Prob. 2.37EPCh. 2 - Prob. 2.38EPCh. 2 - For each of the following pairs of alkenes,...Ch. 2 - For each of the following pairs of alkenes,...Ch. 2 - Prob. 2.41EPCh. 2 - Prob. 2.42EPCh. 2 - Prob. 2.43EPCh. 2 - Prob. 2.44EPCh. 2 - Prob. 2.45EPCh. 2 - Prob. 2.46EPCh. 2 - For each molecule, indicate whether cistrans...Ch. 2 - Prob. 2.48EPCh. 2 - Prob. 2.49EPCh. 2 - Prob. 2.50EPCh. 2 - Draw a structural formula for each of the...Ch. 2 - Prob. 2.52EPCh. 2 - Prob. 2.53EPCh. 2 - For each of the following molecules, indicate...Ch. 2 - Prob. 2.55EPCh. 2 - Prob. 2.56EPCh. 2 - Prob. 2.57EPCh. 2 - Prob. 2.58EPCh. 2 - Prob. 2.59EPCh. 2 - How many isoprene units are present in a....Ch. 2 - Prob. 2.61EPCh. 2 - Indicate whether each of the following statements...Ch. 2 - Prob. 2.63EPCh. 2 - Prob. 2.64EPCh. 2 - Prob. 2.65EPCh. 2 - Prob. 2.66EPCh. 2 - Prob. 2.67EPCh. 2 - Prob. 2.68EPCh. 2 - Prob. 2.69EPCh. 2 - Prob. 2.70EPCh. 2 - Prob. 2.71EPCh. 2 - Prob. 2.72EPCh. 2 - Prob. 2.73EPCh. 2 - Prob. 2.74EPCh. 2 - Prob. 2.75EPCh. 2 - Prob. 2.76EPCh. 2 - Supply the structural formula of the product in...Ch. 2 - Prob. 2.78EPCh. 2 - Prob. 2.79EPCh. 2 - What reactant would you use to prepare each of the...Ch. 2 - Prob. 2.81EPCh. 2 - Prob. 2.82EPCh. 2 - Prob. 2.83EPCh. 2 - Prob. 2.84EPCh. 2 - Prob. 2.85EPCh. 2 - Prob. 2.86EPCh. 2 - Prob. 2.87EPCh. 2 - Prob. 2.88EPCh. 2 - Prob. 2.89EPCh. 2 - Prob. 2.90EPCh. 2 - Prob. 2.91EPCh. 2 - Prob. 2.92EPCh. 2 - Prob. 2.93EPCh. 2 - Prob. 2.94EPCh. 2 - Prob. 2.95EPCh. 2 - Prob. 2.96EPCh. 2 - Prob. 2.97EPCh. 2 - Prob. 2.98EPCh. 2 - Prob. 2.99EPCh. 2 - Prob. 2.100EPCh. 2 - Prob. 2.101EPCh. 2 - Prob. 2.102EPCh. 2 - Prob. 2.103EPCh. 2 - Prob. 2.104EPCh. 2 - Prob. 2.105EPCh. 2 - Prob. 2.106EPCh. 2 - Prob. 2.107EPCh. 2 - Prob. 2.108EPCh. 2 - Assign each of the compounds in Problem 13-107 an...Ch. 2 - Assign each of the compounds in Problem 13-108 an...Ch. 2 - Prob. 2.111EPCh. 2 - Prob. 2.112EPCh. 2 - Prob. 2.113EPCh. 2 - Prob. 2.114EPCh. 2 - Prob. 2.115EPCh. 2 - Prob. 2.116EPCh. 2 - Prob. 2.117EPCh. 2 - Prob. 2.118EPCh. 2 - Prob. 2.119EPCh. 2 - Prob. 2.120EPCh. 2 - Prob. 2.121EPCh. 2 - Prob. 2.122EPCh. 2 - Prob. 2.123EPCh. 2 - Prob. 2.124EPCh. 2 - Prob. 2.125EPCh. 2 - Prob. 2.126EPCh. 2 - Prob. 2.127EPCh. 2 - Prob. 2.128EPCh. 2 - Prob. 2.129EPCh. 2 - Prob. 2.130EP
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