The number of R-groups present in primary amide has to be given. Concept Introduction: Organic compounds are the important basis of life. They include gasoline, coal, dyes, and clothing fibers etc. The compounds that are obtained from living organisms are termed as organic compounds and those obtained from the earth are known as inorganic compounds. Organic compounds are found in earth also apart from living organisms. All the organic compounds contain the element carbon. Urea was synthesized in the laboratory which is an organic compound. Organic compounds contain heteroatom also. Some of them are nitrogen, sulfur, oxygen etc. Nitrogen containing organic compounds are of two important types and they are amines , amides. One of the carboxylic acid derivative is amide. In this the carboxyl − OH group is replaced by an amino or a substituted amino group. The functional group of amide can be given as, Amides are also classified as primary, secondary, and tertiary amide. Primary amide is the one that has a nitrogen atom that is bonded to two hydrogen atoms. Primary amides are also known as unsubstituted amides. Secondary amide is the one that has a nitrogen atom that is bonded to one hydrogen atom and one alkyl (or aryl) group. Secondary amides are also known as monosubstituted amides. Tertiary amide is the one that has a nitrogen atom that is bonded to two alkyl (or aryl) groups. Tertiary amides are also known as disubstituted amides.

Question

For the decomposition reaction of N2O5(g): 2 N2O5(g) → 4 NO2(g) + O2(g), the following mechanism has been proposed: N2O5 NO2 + NO3 (K1) | NO2 + NO3 → N2O5 (k-1) | NO2 + NO3 NO2 + O2 + NO (k2) | NO + N2O51 NO2 + NO2 + NO2 (K3) → Give the expression for the acceptable rate. → → (A). d[N205] dt == 2k,k₂[N₂O₂] k₁+k₁₂ (B). d[N2O5] =-k₁[N₂O] + k₁[NO₂] [NO3] - k₂[NO₂]³ dt (C). d[N2O5] =-k₁[N₂O] + k [NO] - k₂[NO] [NO] d[N2O5] (D). = dt = -k₁[N2O5] - k¸[NO][N₂05] dt Do not apply the calculations, based on the approximation of the stationary state, to make them perform correctly. Basta discard the 3 responses that you encounter that are obviously erroneous if you apply the formula to determine the speed of a reaction.

Answer 1

Question

Chapter 6, Problem 6.95EP

(a)

Interpretation Introduction

Interpretation:

The number of R-groups present in primary amide has to be given.

Concept Introduction:

Organic compounds are the important basis of life. They include gasoline, coal, dyes, and clothing fibers etc. The compounds that are obtained from living organisms are termed as organic compounds and those obtained from the earth are known as inorganic compounds. Organic compounds are found in earth also apart from living organisms. All the organic compounds contain the element carbon. Urea was synthesized in the laboratory which is an organic compound.

Organic compounds contain heteroatom also. Some of them are nitrogen, sulfur, oxygen etc. Nitrogen containing organic compounds are of two important types and they are amines, amides.

One of the carboxylic acid derivative is amide. In this the carboxyl −OH group is replaced by an amino or a substituted amino group. The functional group of amide can be given as,

Amides are also classified as primary, secondary, and tertiary amide.

Primary amide is the one that has a nitrogen atom that is bonded to two hydrogen atoms. Primary amides are also known as unsubstituted amides.

Secondary amide is the one that has a nitrogen atom that is bonded to one hydrogen atom and one alkyl (or aryl) group. Secondary amides are also known as monosubstituted amides.

Tertiary amide is the one that has a nitrogen atom that is bonded to two alkyl (or aryl) groups. Tertiary amides are also known as disubstituted amides.

(b)

Interpretation Introduction

Interpretation:

The number of R-groups present in tertiary amide has to be given.

Concept Introduction:

Organic compounds are the important basis of life. They include gasoline, coal, dyes, and clothing fibers etc. The compounds that are obtained from living organisms are termed as organic compounds and those obtained from the earth are known as inorganic compounds. Organic compounds are found in earth also apart from living organisms. All the organic compounds contain the element carbon. Urea was synthesized in the laboratory which is an organic compound.

Organic compounds contain heteroatom also. Some of them are nitrogen, sulfur, oxygen etc. Nitrogen containing organic compounds are of two important types and they are amines, amides.

One of the carboxylic acid derivative is amide. In this the carboxyl −OH group is replaced by an amino or a substituted amino group. The functional group of amide can be given as,

Amides are also classified as primary, secondary, and tertiary amide.

Primary amide is the one that has a nitrogen atom that is bonded to two hydrogen atoms. Primary amides are also known as unsubstituted amides.

Secondary amide is the one that has a nitrogen atom that is bonded to one hydrogen atom and one alkyl (or aryl) group. Secondary amides are also known as monosubstituted amides.

Tertiary amide is the one that has a nitrogen atom that is bonded to two alkyl (or aryl) groups. Tertiary amides are also known as disubstituted amides.

(c)

Interpretation Introduction

Interpretation:

The number of R-groups present in monosubstituted amide has to be given.

Concept Introduction:

Organic compounds are the important basis of life. They include gasoline, coal, dyes, and clothing fibers etc. The compounds that are obtained from living organisms are termed as organic compounds and those obtained from the earth are known as inorganic compounds. Organic compounds are found in earth also apart from living organisms. All the organic compounds contain the element carbon. Urea was synthesized in the laboratory which is an organic compound.

Organic compounds contain heteroatom also. Some of them are nitrogen, sulfur, oxygen etc. Nitrogen containing organic compounds are of two important types and they are amines, amides.

One of the carboxylic acid derivative is amide. In this the carboxyl −OH group is replaced by an amino or a substituted amino group. The functional group of amide can be given as,

Amides are also classified as primary, secondary, and tertiary amide.

Primary amide is the one that has a nitrogen atom that is bonded to two hydrogen atoms. Primary amides are also known as unsubstituted amides.

Secondary amide is the one that has a nitrogen atom that is bonded to one hydrogen atom and one alkyl (or aryl) group. Secondary amides are also known as monosubstituted amides.

Tertiary amide is the one that has a nitrogen atom that is bonded to two alkyl (or aryl) groups. Tertiary amides are also known as disubstituted amides.

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For the decomposition reaction of N2O5(g): 2 N2O5(g) → 4 NO2(g) + O2(g), the following mechanism has been proposed: N2O5 NO2 + NO3 (K1) | NO2 + NO3 → N2O5 (k-1) | NO2 + NO3 NO2 + O2 + NO (k2) | NO + N2O51 NO2 + NO2 + NO2 (K3) → Give the expression for the acceptable rate. → → (A). d[N205] dt == 2k,k₂[N₂O₂] k₁+k₁₂ (B). d[N2O5] =-k₁[N₂O] + k₁[NO₂] [NO3] - k₂[NO₂]³ dt (C). d[N2O5] =-k₁[N₂O] + k [NO] - k₂[NO] [NO] d[N2O5] (D). = dt = -k₁[N2O5] - k¸[NO][N₂05] dt Do not apply the calculations, based on the approximation of the stationary state, to make them perform correctly. Basta discard the 3 responses that you encounter that are obviously erroneous if you apply the formula to determine the speed of a reaction.

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