(a)
Interpretation:
Given
Concept Introduction:
- Longest carbon chain has to be identified that is attached to nitrogen atom.
- Suffix “-e” in name of the parent chain
alkane is replaced by “-amine”. - Numbering of the carbon chain is done from the end that is near the nitrogen atom.
- Point of attachment of the nitrogen atom in the carbon chain is indicated by a number before the parent chain name.
- In case if substituents are present, then the identity and location of substituents are appended to the front in the parent chain name.
If the compound contains two amine groups, then the suffix “-e” is replaced by diamine. Tertiary and secondary
Common name for amine is given in a single word. Primary amine is named as alkylamine. Secondary amine is named as alkylalkylamine. Tertiary amine is named as alkylalkylalkylamine.
Simplest aromatic amine is aniline. Amino group attached to a benzene ring is known as aniline.
(b)
Interpretation:
Given aromatic amine has to be named as derivative of aniline.
Concept Introduction:
IUPAC nomenclature for amine: There are about five rules to be followed in giving IUPAC name for an amine.
- Longest carbon chain has to be identified that is attached to nitrogen atom.
- Suffix “-e” in name of the parent chain alkane is replaced by “-amine”.
- Numbering of the carbon chain is done from the end that is near the nitrogen atom.
- Point of attachment of the nitrogen atom in the carbon chain is indicated by a number before the parent chain name.
- In case if substituents are present, then the identity and location of substituents are appended to the front in the parent chain name.
If the compound contains two amine groups, then the suffix “-e” is replaced by diamine. Tertiary and secondary amines are named as N-substituted primary amines.
Common name for amine is given in a single word. Primary amine is named as alkylamine. Secondary amine is named as alkylalkylamine. Tertiary amine is named as alkylalkylalkylamine.
Simplest aromatic amine is aniline. Amino group attached to a benzene ring is known as aniline.
(c)
Interpretation:
Given aromatic amine has to be named as derivative of aniline.
Concept Introduction:
IUPAC nomenclature for amine: There are about five rules to be followed in giving IUPAC name for an amine.
- Longest carbon chain has to be identified that is attached to nitrogen atom.
- Suffix “-e” in name of the parent chain alkane is replaced by “-amine”.
- Numbering of the carbon chain is done from the end that is near the nitrogen atom.
- Point of attachment of the nitrogen atom in the carbon chain is indicated by a number before the parent chain name.
- In case if substituents are present, then the identity and location of substituents are appended to the front in the parent chain name.
If the compound contains two amine groups, then the suffix “-e” is replaced by diamine. Tertiary and secondary amines are named as N-substituted primary amines.
Common name for amine is given in a single word. Primary amine is named as alkylamine. Secondary amine is named as alkylalkylamine. Tertiary amine is named as alkylalkylalkylamine.
Simplest aromatic amine is aniline. Amino group attached to a benzene ring is known as aniline.
(d)
Interpretation:
Given aromatic amine has to be named as derivative of aniline.
Concept Introduction:
IUPAC nomenclature for amine: There are about five rules to be followed in giving IUPAC name for an amine.
- Longest carbon chain has to be identified that is attached to nitrogen atom.
- Suffix “-e” in name of the parent chain alkane is replaced by “-amine”.
- Numbering of the carbon chain is done from the end that is near the nitrogen atom.
- Point of attachment of the nitrogen atom in the carbon chain is indicated by a number before the parent chain name.
- In case if substituents are present, then the identity and location of substituents are appended to the front in the parent chain name.
If the compound contains two amine groups, then the suffix “-e” is replaced by diamine. Tertiary and secondary amines are named as N-substituted primary amines.
Common name for amine is given in a single word. Primary amine is named as alkylamine. Secondary amine is named as alkylalkylamine. Tertiary amine is named as alkylalkylalkylamine.
Simplest aromatic amine is aniline. Amino group attached to a benzene ring is known as aniline.
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Chapter 6 Solutions
EBK ORGANIC AND BIOLOGICAL CHEMISTRY
- Choose the best reagents to complete the following reaction. i H A B 1. CH3CH2Na 2. H3O+ 1. CH3CH2MgBr 2. H3O+ 1. CH3MgBr Q C 2. H3O+ 1. H3O+ D 2. CH3MgBr 00 OH Q E CH³MgBrarrow_forwardThe kinetics of a gas phase reaction of the form A → Products results in a rate constant of 0.00781 M/min. For this reaction, the initial concentration of A is 0.501 M. What is the half-life for this reaction?arrow_forwardChoose the best reagents to complete the following reaction. 1. PhNa A 2. H3O+ 1. PhCH2MgBr B 2. H3O+ хё 1. PhMgBr C 2. H3O+ 00 HO Q E D 1. H3O+ 2. PhMgBr PhMgBrarrow_forward
- Please answer all of the questions and provide detailed explanations and include a drawing to show the different signals on the molecule and include which ones should be highlighted.arrow_forwardDraw the major product of this reaction. Ignore inorganic byproducts. Incorrect, 1 attempt remaining 1. LiAlH4 2. H3O+ Q OH ☑ Select to Drawarrow_forwardHow should I graph my data for the Absorbance of Pb and Fe for each mushroom? I want to compare the results to the known standard curve. Software: Excel Spreadsheets Link: https://mnscu-my.sharepoint.com/:x:/g/personal/vi2163ss_go_minnstate_edu/Eb2PfHdfEtBJiWh0ipHZ_kkBW4idWWwvpLPPtqoq2WkgbQ?rtime=HxrF0_tR3Ugarrow_forward
- Provide the proper IUPAC name only for the following compound. Dashes, commas, and spaces must be used correctly, but do not use italics in Canvas.arrow_forwardThe kinetics of a gas phase reaction of the form A → Products results in a rate constant of 0.00781 M/min. For this reaction, the initial concentration of A is 0.501 M. How many minutes will it take for the concentration of A to reach 0.144 Marrow_forwardWhat is the rate for the second order reaction A → Products when [A] = 0.256 M? (k = 0.761 M⁻¹s⁻¹)arrow_forward
- For reaction N2(g) + O2(g) --> 2NO(g) Write the rate of the reaction in terms of change of NO.arrow_forwardDon't used hand raiting and don't used Ai solutionarrow_forwardThe reaction of 2-oxacyclopentanone with hydrochloric acid in water (i.e., "excess") produces which of the following carboxylic acids?arrow_forward
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