The terms that apply for CH 3 − CH 2 − CH 2 − NH 2 has to be given. Concept Introduction: Free amine is the one that has nitrogen atom bonded to three other atoms and a lone pair of electrons is present on it. Deprotonated base is the one that can accept a hydrogen ion. Due to the lone pair of electrons present on the nitrogen atom in amine, it can also be known as deprotonated base. Free base is the one that has a more electronegative atom which can act as a proton acceptor. Amine has a nitrogen atom which can accept a hydrogen ion. Hence, amine can be a proton acceptor. Protonated base is the one in which the nitrogen atom in the amine has four bonds. The fourth bond formed is a coordinate covalent bond. The formed species has a positive charge on it.

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Answer 1

Question

Chapter 6, Problem 6.60EP

(a)

Interpretation Introduction

Interpretation:

The terms that apply for CH3−CH2−CH2−NH2 has to be given.

Concept Introduction:

Free amine is the one that has nitrogen atom bonded to three other atoms and a lone pair of electrons is present on it. Deprotonated base is the one that can accept a hydrogen ion. Due to the lone pair of electrons present on the nitrogen atom in amine, it can also be known as deprotonated base. Free base is the one that has a more electronegative atom which can act as a proton acceptor. Amine has a nitrogen atom which can accept a hydrogen ion. Hence, amine can be a proton acceptor. Protonated base is the one in which the nitrogen atom in the amine has four bonds. The fourth bond formed is a coordinate covalent bond. The formed species has a positive charge on it.

(b)

Interpretation Introduction

Interpretation:

The terms that apply for CH3−CH2−CH2−N+H2−CH3 has to be given.

Concept Introduction:

Free amine is the one that has nitrogen atom bonded to three other atoms and a lone pair of electrons is present on it. Deprotonated base is the one that can accept a hydrogen ion. Due to the lone pair of electrons present on the nitrogen atom in amine, it can also be known as deprotonated base. Free base is the one that has a more electronegative atom which can act as a proton acceptor. Amine has a nitrogen atom which can accept a hydrogen ion. Hence, amine can be a proton acceptor. Protonated base is the one in which the nitrogen atom in the amine has four bonds. The fourth bond formed is a coordinate covalent bond. The formed species has a positive charge on it.

(c)

Interpretation Introduction

Interpretation:

The terms that apply for CH3−NH−CH2−CH3 has to be given.

Concept Introduction:

Free amine is the one that has nitrogen atom bonded to three other atoms and a lone pair of electrons is present on it. Deprotonated base is the one that can accept a hydrogen ion. Due to the lone pair of electrons present on the nitrogen atom in amine, it can also be known as deprotonated base. Free base is the one that has a more electronegative atom which can act as a proton acceptor. Amine has a nitrogen atom which can accept a hydrogen ion. Hence, amine can be a proton acceptor. Protonated base is the one in which the nitrogen atom in the amine has four bonds. The fourth bond formed is a coordinate covalent bond. The formed species has a positive charge on it.

(d)

Interpretation Introduction

Interpretation:

The terms that apply for CH3−CH2−N+H3 has to be given.

Concept Introduction:

Free amine is the one that has nitrogen atom bonded to three other atoms and a lone pair of electrons is present on it. Deprotonated base is the one that can accept a hydrogen ion. Due to the lone pair of electrons present on the nitrogen atom in amine, it can also be known as deprotonated base. Free base is the one that has a more electronegative atom which can act as a proton acceptor. Amine has a nitrogen atom which can accept a hydrogen ion. Hence, amine can be a proton acceptor. Protonated base is the one in which the nitrogen atom in the amine has four bonds. The fourth bond formed is a coordinate covalent bond. The formed species has a positive charge on it.

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MISSED THIS? Read Section 19.9 (Pages 878-881); Watch IWE 19.10 Consider the following reaction: CH3OH(g) CO(g) + 2H2(g) (Note that AG,CH3OH(g) = -162.3 kJ/mol and AG,co(g)=-137.2 kJ/mol.) Part A Calculate AG for this reaction at 25 °C under the following conditions: PCH₂OH Pco PH2 0.815 atm = 0.140 atm 0.170 atm Express your answer in kilojoules to three significant figures. Ο ΑΣΦ AG = -150 Submit Previous Answers Request Answer □? kJ × Incorrect; Try Again; 2 attempts remaining Calculate the free energy change under nonstandard conditions (AGrxn) by using the following relationship: AGrxn = AGrxn + RTInQ, AGxn+RTInQ, where AGxn is the standard free energy change, R is the ideal gas constant, T is the temperature in kelvins, a is the reaction quotient. Provide Feedback Next >

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Answer 2

Question

Chapter 6, Problem 6.60EP

(a)

Interpretation Introduction

Interpretation:

The terms that apply for CH3−CH2−CH2−NH2 has to be given.

Concept Introduction:

Free amine is the one that has nitrogen atom bonded to three other atoms and a lone pair of electrons is present on it. Deprotonated base is the one that can accept a hydrogen ion. Due to the lone pair of electrons present on the nitrogen atom in amine, it can also be known as deprotonated base. Free base is the one that has a more electronegative atom which can act as a proton acceptor. Amine has a nitrogen atom which can accept a hydrogen ion. Hence, amine can be a proton acceptor. Protonated base is the one in which the nitrogen atom in the amine has four bonds. The fourth bond formed is a coordinate covalent bond. The formed species has a positive charge on it.

(b)

Interpretation Introduction

Interpretation:

The terms that apply for CH3−CH2−CH2−N+H2−CH3 has to be given.

Concept Introduction:

Free amine is the one that has nitrogen atom bonded to three other atoms and a lone pair of electrons is present on it. Deprotonated base is the one that can accept a hydrogen ion. Due to the lone pair of electrons present on the nitrogen atom in amine, it can also be known as deprotonated base. Free base is the one that has a more electronegative atom which can act as a proton acceptor. Amine has a nitrogen atom which can accept a hydrogen ion. Hence, amine can be a proton acceptor. Protonated base is the one in which the nitrogen atom in the amine has four bonds. The fourth bond formed is a coordinate covalent bond. The formed species has a positive charge on it.

(c)

Interpretation Introduction

Interpretation:

The terms that apply for CH3−NH−CH2−CH3 has to be given.

Concept Introduction:

Free amine is the one that has nitrogen atom bonded to three other atoms and a lone pair of electrons is present on it. Deprotonated base is the one that can accept a hydrogen ion. Due to the lone pair of electrons present on the nitrogen atom in amine, it can also be known as deprotonated base. Free base is the one that has a more electronegative atom which can act as a proton acceptor. Amine has a nitrogen atom which can accept a hydrogen ion. Hence, amine can be a proton acceptor. Protonated base is the one in which the nitrogen atom in the amine has four bonds. The fourth bond formed is a coordinate covalent bond. The formed species has a positive charge on it.

(d)

Interpretation Introduction

Interpretation:

The terms that apply for CH3−CH2−N+H3 has to be given.

Concept Introduction:

Free amine is the one that has nitrogen atom bonded to three other atoms and a lone pair of electrons is present on it. Deprotonated base is the one that can accept a hydrogen ion. Due to the lone pair of electrons present on the nitrogen atom in amine, it can also be known as deprotonated base. Free base is the one that has a more electronegative atom which can act as a proton acceptor. Amine has a nitrogen atom which can accept a hydrogen ion. Hence, amine can be a proton acceptor. Protonated base is the one in which the nitrogen atom in the amine has four bonds. The fourth bond formed is a coordinate covalent bond. The formed species has a positive charge on it.

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Answer 3

Question

Chapter 6, Problem 6.60EP

(a)

Interpretation Introduction

Interpretation:

The terms that apply for CH3−CH2−CH2−NH2 has to be given.

Concept Introduction:

Free amine is the one that has nitrogen atom bonded to three other atoms and a lone pair of electrons is present on it. Deprotonated base is the one that can accept a hydrogen ion. Due to the lone pair of electrons present on the nitrogen atom in amine, it can also be known as deprotonated base. Free base is the one that has a more electronegative atom which can act as a proton acceptor. Amine has a nitrogen atom which can accept a hydrogen ion. Hence, amine can be a proton acceptor. Protonated base is the one in which the nitrogen atom in the amine has four bonds. The fourth bond formed is a coordinate covalent bond. The formed species has a positive charge on it.

(b)

Interpretation Introduction

Interpretation:

The terms that apply for CH3−CH2−CH2−N+H2−CH3 has to be given.

Concept Introduction:

Free amine is the one that has nitrogen atom bonded to three other atoms and a lone pair of electrons is present on it. Deprotonated base is the one that can accept a hydrogen ion. Due to the lone pair of electrons present on the nitrogen atom in amine, it can also be known as deprotonated base. Free base is the one that has a more electronegative atom which can act as a proton acceptor. Amine has a nitrogen atom which can accept a hydrogen ion. Hence, amine can be a proton acceptor. Protonated base is the one in which the nitrogen atom in the amine has four bonds. The fourth bond formed is a coordinate covalent bond. The formed species has a positive charge on it.

(c)

Interpretation Introduction

Interpretation:

The terms that apply for CH3−NH−CH2−CH3 has to be given.

Concept Introduction:

Free amine is the one that has nitrogen atom bonded to three other atoms and a lone pair of electrons is present on it. Deprotonated base is the one that can accept a hydrogen ion. Due to the lone pair of electrons present on the nitrogen atom in amine, it can also be known as deprotonated base. Free base is the one that has a more electronegative atom which can act as a proton acceptor. Amine has a nitrogen atom which can accept a hydrogen ion. Hence, amine can be a proton acceptor. Protonated base is the one in which the nitrogen atom in the amine has four bonds. The fourth bond formed is a coordinate covalent bond. The formed species has a positive charge on it.

(d)

Interpretation Introduction

Interpretation:

The terms that apply for CH3−CH2−N+H3 has to be given.

Concept Introduction:

Free amine is the one that has nitrogen atom bonded to three other atoms and a lone pair of electrons is present on it. Deprotonated base is the one that can accept a hydrogen ion. Due to the lone pair of electrons present on the nitrogen atom in amine, it can also be known as deprotonated base. Free base is the one that has a more electronegative atom which can act as a proton acceptor. Amine has a nitrogen atom which can accept a hydrogen ion. Hence, amine can be a proton acceptor. Protonated base is the one in which the nitrogen atom in the amine has four bonds. The fourth bond formed is a coordinate covalent bond. The formed species has a positive charge on it.

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Answer 4

Question

Chapter 6, Problem 6.60EP

(a)

Interpretation Introduction

Interpretation:

The terms that apply for CH3−CH2−CH2−NH2 has to be given.

Concept Introduction:

Free amine is the one that has nitrogen atom bonded to three other atoms and a lone pair of electrons is present on it. Deprotonated base is the one that can accept a hydrogen ion. Due to the lone pair of electrons present on the nitrogen atom in amine, it can also be known as deprotonated base. Free base is the one that has a more electronegative atom which can act as a proton acceptor. Amine has a nitrogen atom which can accept a hydrogen ion. Hence, amine can be a proton acceptor. Protonated base is the one in which the nitrogen atom in the amine has four bonds. The fourth bond formed is a coordinate covalent bond. The formed species has a positive charge on it.

(b)

Interpretation Introduction

Interpretation:

The terms that apply for CH3−CH2−CH2−N+H2−CH3 has to be given.

Concept Introduction:

Free amine is the one that has nitrogen atom bonded to three other atoms and a lone pair of electrons is present on it. Deprotonated base is the one that can accept a hydrogen ion. Due to the lone pair of electrons present on the nitrogen atom in amine, it can also be known as deprotonated base. Free base is the one that has a more electronegative atom which can act as a proton acceptor. Amine has a nitrogen atom which can accept a hydrogen ion. Hence, amine can be a proton acceptor. Protonated base is the one in which the nitrogen atom in the amine has four bonds. The fourth bond formed is a coordinate covalent bond. The formed species has a positive charge on it.

(c)

Interpretation Introduction

Interpretation:

The terms that apply for CH3−NH−CH2−CH3 has to be given.

Concept Introduction:

Free amine is the one that has nitrogen atom bonded to three other atoms and a lone pair of electrons is present on it. Deprotonated base is the one that can accept a hydrogen ion. Due to the lone pair of electrons present on the nitrogen atom in amine, it can also be known as deprotonated base. Free base is the one that has a more electronegative atom which can act as a proton acceptor. Amine has a nitrogen atom which can accept a hydrogen ion. Hence, amine can be a proton acceptor. Protonated base is the one in which the nitrogen atom in the amine has four bonds. The fourth bond formed is a coordinate covalent bond. The formed species has a positive charge on it.

(d)

Interpretation Introduction

Interpretation:

The terms that apply for CH3−CH2−N+H3 has to be given.

Concept Introduction:

Free amine is the one that has nitrogen atom bonded to three other atoms and a lone pair of electrons is present on it. Deprotonated base is the one that can accept a hydrogen ion. Due to the lone pair of electrons present on the nitrogen atom in amine, it can also be known as deprotonated base. Free base is the one that has a more electronegative atom which can act as a proton acceptor. Amine has a nitrogen atom which can accept a hydrogen ion. Hence, amine can be a proton acceptor. Protonated base is the one in which the nitrogen atom in the amine has four bonds. The fourth bond formed is a coordinate covalent bond. The formed species has a positive charge on it.

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Answer 5

Chapter 6, Problem 6.60EP

(a)

Interpretation Introduction

Interpretation:

The terms that apply for CH3−CH2−CH2−NH2 has to be given.

Concept Introduction:

Free amine is the one that has nitrogen atom bonded to three other atoms and a lone pair of electrons is present on it. Deprotonated base is the one that can accept a hydrogen ion. Due to the lone pair of electrons present on the nitrogen atom in amine, it can also be known as deprotonated base. Free base is the one that has a more electronegative atom which can act as a proton acceptor. Amine has a nitrogen atom which can accept a hydrogen ion. Hence, amine can be a proton acceptor. Protonated base is the one in which the nitrogen atom in the amine has four bonds. The fourth bond formed is a coordinate covalent bond. The formed species has a positive charge on it.

(b)

Interpretation Introduction

Interpretation:

The terms that apply for CH3−CH2−CH2−N+H2−CH3 has to be given.

Concept Introduction:

Free amine is the one that has nitrogen atom bonded to three other atoms and a lone pair of electrons is present on it. Deprotonated base is the one that can accept a hydrogen ion. Due to the lone pair of electrons present on the nitrogen atom in amine, it can also be known as deprotonated base. Free base is the one that has a more electronegative atom which can act as a proton acceptor. Amine has a nitrogen atom which can accept a hydrogen ion. Hence, amine can be a proton acceptor. Protonated base is the one in which the nitrogen atom in the amine has four bonds. The fourth bond formed is a coordinate covalent bond. The formed species has a positive charge on it.

(c)

Interpretation Introduction

Interpretation:

The terms that apply for CH3−NH−CH2−CH3 has to be given.

Concept Introduction:

Free amine is the one that has nitrogen atom bonded to three other atoms and a lone pair of electrons is present on it. Deprotonated base is the one that can accept a hydrogen ion. Due to the lone pair of electrons present on the nitrogen atom in amine, it can also be known as deprotonated base. Free base is the one that has a more electronegative atom which can act as a proton acceptor. Amine has a nitrogen atom which can accept a hydrogen ion. Hence, amine can be a proton acceptor. Protonated base is the one in which the nitrogen atom in the amine has four bonds. The fourth bond formed is a coordinate covalent bond. The formed species has a positive charge on it.

(d)

Interpretation Introduction

Interpretation:

The terms that apply for CH3−CH2−N+H3 has to be given.

Concept Introduction:

Free amine is the one that has nitrogen atom bonded to three other atoms and a lone pair of electrons is present on it. Deprotonated base is the one that can accept a hydrogen ion. Due to the lone pair of electrons present on the nitrogen atom in amine, it can also be known as deprotonated base. Free base is the one that has a more electronegative atom which can act as a proton acceptor. Amine has a nitrogen atom which can accept a hydrogen ion. Hence, amine can be a proton acceptor. Protonated base is the one in which the nitrogen atom in the amine has four bonds. The fourth bond formed is a coordinate covalent bond. The formed species has a positive charge on it.

Answer 6

Chapter 6, Problem 6.60EP

(a)

Interpretation Introduction

Interpretation:

The terms that apply for CH3−CH2−CH2−NH2 has to be given.

Concept Introduction:

Free amine is the one that has nitrogen atom bonded to three other atoms and a lone pair of electrons is present on it. Deprotonated base is the one that can accept a hydrogen ion. Due to the lone pair of electrons present on the nitrogen atom in amine, it can also be known as deprotonated base. Free base is the one that has a more electronegative atom which can act as a proton acceptor. Amine has a nitrogen atom which can accept a hydrogen ion. Hence, amine can be a proton acceptor. Protonated base is the one in which the nitrogen atom in the amine has four bonds. The fourth bond formed is a coordinate covalent bond. The formed species has a positive charge on it.

Answer 7

Chapter 6, Problem 6.60EP

(a)

Interpretation Introduction

Interpretation:

The terms that apply for CH3−CH2−CH2−NH2 has to be given.

Concept Introduction:

Free amine is the one that has nitrogen atom bonded to three other atoms and a lone pair of electrons is present on it. Deprotonated base is the one that can accept a hydrogen ion. Due to the lone pair of electrons present on the nitrogen atom in amine, it can also be known as deprotonated base. Free base is the one that has a more electronegative atom which can act as a proton acceptor. Amine has a nitrogen atom which can accept a hydrogen ion. Hence, amine can be a proton acceptor. Protonated base is the one in which the nitrogen atom in the amine has four bonds. The fourth bond formed is a coordinate covalent bond. The formed species has a positive charge on it.

Answer 8

(b)

Interpretation Introduction

Interpretation:

The terms that apply for CH3−CH2−CH2−N+H2−CH3 has to be given.

Concept Introduction:

Free amine is the one that has nitrogen atom bonded to three other atoms and a lone pair of electrons is present on it. Deprotonated base is the one that can accept a hydrogen ion. Due to the lone pair of electrons present on the nitrogen atom in amine, it can also be known as deprotonated base. Free base is the one that has a more electronegative atom which can act as a proton acceptor. Amine has a nitrogen atom which can accept a hydrogen ion. Hence, amine can be a proton acceptor. Protonated base is the one in which the nitrogen atom in the amine has four bonds. The fourth bond formed is a coordinate covalent bond. The formed species has a positive charge on it.

Answer 9

(b)

Interpretation Introduction

Interpretation:

The terms that apply for CH3−CH2−CH2−N+H2−CH3 has to be given.

Concept Introduction:

Free amine is the one that has nitrogen atom bonded to three other atoms and a lone pair of electrons is present on it. Deprotonated base is the one that can accept a hydrogen ion. Due to the lone pair of electrons present on the nitrogen atom in amine, it can also be known as deprotonated base. Free base is the one that has a more electronegative atom which can act as a proton acceptor. Amine has a nitrogen atom which can accept a hydrogen ion. Hence, amine can be a proton acceptor. Protonated base is the one in which the nitrogen atom in the amine has four bonds. The fourth bond formed is a coordinate covalent bond. The formed species has a positive charge on it.

Answer 10

(c)

Interpretation Introduction

Interpretation:

The terms that apply for CH3−NH−CH2−CH3 has to be given.

Concept Introduction:

Free amine is the one that has nitrogen atom bonded to three other atoms and a lone pair of electrons is present on it. Deprotonated base is the one that can accept a hydrogen ion. Due to the lone pair of electrons present on the nitrogen atom in amine, it can also be known as deprotonated base. Free base is the one that has a more electronegative atom which can act as a proton acceptor. Amine has a nitrogen atom which can accept a hydrogen ion. Hence, amine can be a proton acceptor. Protonated base is the one in which the nitrogen atom in the amine has four bonds. The fourth bond formed is a coordinate covalent bond. The formed species has a positive charge on it.

Answer 11

(c)

Interpretation Introduction

Interpretation:

The terms that apply for CH3−NH−CH2−CH3 has to be given.

Concept Introduction:

Free amine is the one that has nitrogen atom bonded to three other atoms and a lone pair of electrons is present on it. Deprotonated base is the one that can accept a hydrogen ion. Due to the lone pair of electrons present on the nitrogen atom in amine, it can also be known as deprotonated base. Free base is the one that has a more electronegative atom which can act as a proton acceptor. Amine has a nitrogen atom which can accept a hydrogen ion. Hence, amine can be a proton acceptor. Protonated base is the one in which the nitrogen atom in the amine has four bonds. The fourth bond formed is a coordinate covalent bond. The formed species has a positive charge on it.

Answer 12

(d)

Interpretation Introduction

Interpretation:

The terms that apply for CH3−CH2−N+H3 has to be given.

Concept Introduction:

Free amine is the one that has nitrogen atom bonded to three other atoms and a lone pair of electrons is present on it. Deprotonated base is the one that can accept a hydrogen ion. Due to the lone pair of electrons present on the nitrogen atom in amine, it can also be known as deprotonated base. Free base is the one that has a more electronegative atom which can act as a proton acceptor. Amine has a nitrogen atom which can accept a hydrogen ion. Hence, amine can be a proton acceptor. Protonated base is the one in which the nitrogen atom in the amine has four bonds. The fourth bond formed is a coordinate covalent bond. The formed species has a positive charge on it.

Answer 13

(d)

Interpretation Introduction

Interpretation:

The terms that apply for CH3−CH2−N+H3 has to be given.

Concept Introduction:

Free amine is the one that has nitrogen atom bonded to three other atoms and a lone pair of electrons is present on it. Deprotonated base is the one that can accept a hydrogen ion. Due to the lone pair of electrons present on the nitrogen atom in amine, it can also be known as deprotonated base. Free base is the one that has a more electronegative atom which can act as a proton acceptor. Amine has a nitrogen atom which can accept a hydrogen ion. Hence, amine can be a proton acceptor. Protonated base is the one in which the nitrogen atom in the amine has four bonds. The fourth bond formed is a coordinate covalent bond. The formed species has a positive charge on it.

Answer 14

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Answer 15

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Answer 16

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Answer 17

Ch. 6.1 - Prob. 1QQ Ch. 6.1 - Prob. 2QQ Ch. 6.2 - Prob. 1QQ Ch. 6.2 - Prob. 2QQ Ch. 6.2 - Prob. 3QQ Ch. 6.2 - Prob. 4QQ Ch. 6.3 - Prob. 1QQ Ch. 6.3 - Prob. 2QQ Ch. 6.3 - Prob. 3QQ Ch. 6.3 - Prob. 4QQ

Solution Summary: The author explains that free amine, free base, and deprotonated bases are given.

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Chapter 6 Solutions