The number of nitrogen‑hydrogen bonds present in primary amine has to be given. Concept Introduction: Amine is an organic derivative. If in ammonia one or more alkyl, cycloalkyl, or aryl groups are substituted instead of hydrogen atom then it is known as amine. Depending on the number of substitution the amines are classified as primary, secondary or tertiary amine. Primary amine is the one in which only one hydrogen atom in ammonia is replaced by a hydrocarbon group. Secondary amine is the one in which only two hydrogen atoms in ammonia is replaced by a hydrocarbon group. Tertiary amine is the one in which all three hydrogen atoms in ammonia is replaced by a hydrocarbon group. The generalized structural formula for all the amines is,

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Answer 1

Question

Chapter 6, Problem 6.6EP

(a)

Interpretation Introduction

Interpretation:

The number of nitrogen‑hydrogen bonds present in primary amine has to be given.

Concept Introduction:

Amine is an organic derivative. If in ammonia one or more alkyl, cycloalkyl, or aryl groups are substituted instead of hydrogen atom then it is known as amine. Depending on the number of substitution the amines are classified as primary, secondary or tertiary amine. Primary amine is the one in which only one hydrogen atom in ammonia is replaced by a hydrocarbon group. Secondary amine is the one in which only two hydrogen atoms in ammonia is replaced by a hydrocarbon group. Tertiary amine is the one in which all three hydrogen atoms in ammonia is replaced by a hydrocarbon group. The generalized structural formula for all the amines is,

(b)

Interpretation Introduction

Interpretation:

The number of nitrogen‑hydrogen bonds present in secondary amine has to be given.

Concept Introduction:

Amine is an organic derivative. If in ammonia one or more alkyl, cycloalkyl, or aryl groups are substituted instead of hydrogen atom then it is known as amine. Depending on the number of substitution the amines are classified as primary, secondary or tertiary amine. Primary amine is the one in which only one hydrogen atom in ammonia is replaced by a hydrocarbon group. Secondary amine is the one in which only two hydrogen atoms in ammonia is replaced by a hydrocarbon group. Tertiary amine is the one in which all three hydrogen atoms in ammonia is replaced by a hydrocarbon group. The generalized structural formula for all the amines is,

(c)

Interpretation Introduction

Interpretation:

The number of nitrogen‑hydrogen bonds present in tertiary amine has to be given.

Concept Introduction:

Amine is an organic derivative. If in ammonia one or more alkyl, cycloalkyl, or aryl groups are substituted instead of hydrogen atom then it is known as amine. Depending on the number of substitution the amines are classified as primary, secondary or tertiary amine. Primary amine is the one in which only one hydrogen atom in ammonia is replaced by a hydrocarbon group. Secondary amine is the one in which only two hydrogen atoms in ammonia is replaced by a hydrocarbon group. Tertiary amine is the one in which all three hydrogen atoms in ammonia is replaced by a hydrocarbon group. The generalized structural formula for all the amines is,

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(a 4 shows scanning electron microscope (SEM) images of extruded actions of packing bed for two capillary columns of different diameters, al 750 (bottom image) and b) 30-μm-i.d. Both columns are packed with the same stationary phase, spherical particles with 1-um diameter. A) When the columns were prepared, the figure shows that the column with the larger diameter has more packing irregularities. Explain this observation. B) Predict what affect this should have on band broadening and discuss your prediction using the van Deemter terms. C) Does this figure support your explanations in application question 33? Explain why or why not and make any changes in your answers in light of this figure. Figure 4 SEM images of sections of packed columns for a) 750 and b) 30-um-i.d. capillary columns.³

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34. Figure 3 shows Van Deemter plots for a solute molecule using different column inner diameters (i.d.). A) Predict whether decreasing the column inner diameters increase or decrease bandwidth. B) Predict which van Deemter equation coefficient (A, B, or C) has the greatest effect on increasing or decreasing bandwidth as a function of i.d. and justify your answer. Figure 3 Van Deemter plots for hydroquinone using different column inner diameters (i.d. in μm). The data was obtained from liquid chromatography experiments using fused-silica capillary columns packed with 1.0-μm particles. 35 20 H(um) 큰 20 15 90 0+ 1500 100 75 550 01 02 594 05 μ(cm/sec) 30 15 10

Answer 2

Question

Chapter 6, Problem 6.6EP

(a)

Interpretation Introduction

Interpretation:

The number of nitrogen‑hydrogen bonds present in primary amine has to be given.

Concept Introduction:

Amine is an organic derivative. If in ammonia one or more alkyl, cycloalkyl, or aryl groups are substituted instead of hydrogen atom then it is known as amine. Depending on the number of substitution the amines are classified as primary, secondary or tertiary amine. Primary amine is the one in which only one hydrogen atom in ammonia is replaced by a hydrocarbon group. Secondary amine is the one in which only two hydrogen atoms in ammonia is replaced by a hydrocarbon group. Tertiary amine is the one in which all three hydrogen atoms in ammonia is replaced by a hydrocarbon group. The generalized structural formula for all the amines is,

(b)

Interpretation Introduction

Interpretation:

The number of nitrogen‑hydrogen bonds present in secondary amine has to be given.

Concept Introduction:

Amine is an organic derivative. If in ammonia one or more alkyl, cycloalkyl, or aryl groups are substituted instead of hydrogen atom then it is known as amine. Depending on the number of substitution the amines are classified as primary, secondary or tertiary amine. Primary amine is the one in which only one hydrogen atom in ammonia is replaced by a hydrocarbon group. Secondary amine is the one in which only two hydrogen atoms in ammonia is replaced by a hydrocarbon group. Tertiary amine is the one in which all three hydrogen atoms in ammonia is replaced by a hydrocarbon group. The generalized structural formula for all the amines is,

(c)

Interpretation Introduction

Interpretation:

The number of nitrogen‑hydrogen bonds present in tertiary amine has to be given.

Concept Introduction:

Amine is an organic derivative. If in ammonia one or more alkyl, cycloalkyl, or aryl groups are substituted instead of hydrogen atom then it is known as amine. Depending on the number of substitution the amines are classified as primary, secondary or tertiary amine. Primary amine is the one in which only one hydrogen atom in ammonia is replaced by a hydrocarbon group. Secondary amine is the one in which only two hydrogen atoms in ammonia is replaced by a hydrocarbon group. Tertiary amine is the one in which all three hydrogen atoms in ammonia is replaced by a hydrocarbon group. The generalized structural formula for all the amines is,

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Answer 3

Question

Chapter 6, Problem 6.6EP

(a)

Interpretation Introduction

Interpretation:

The number of nitrogen‑hydrogen bonds present in primary amine has to be given.

Concept Introduction:

Amine is an organic derivative. If in ammonia one or more alkyl, cycloalkyl, or aryl groups are substituted instead of hydrogen atom then it is known as amine. Depending on the number of substitution the amines are classified as primary, secondary or tertiary amine. Primary amine is the one in which only one hydrogen atom in ammonia is replaced by a hydrocarbon group. Secondary amine is the one in which only two hydrogen atoms in ammonia is replaced by a hydrocarbon group. Tertiary amine is the one in which all three hydrogen atoms in ammonia is replaced by a hydrocarbon group. The generalized structural formula for all the amines is,

(b)

Interpretation Introduction

Interpretation:

The number of nitrogen‑hydrogen bonds present in secondary amine has to be given.

Concept Introduction:

Amine is an organic derivative. If in ammonia one or more alkyl, cycloalkyl, or aryl groups are substituted instead of hydrogen atom then it is known as amine. Depending on the number of substitution the amines are classified as primary, secondary or tertiary amine. Primary amine is the one in which only one hydrogen atom in ammonia is replaced by a hydrocarbon group. Secondary amine is the one in which only two hydrogen atoms in ammonia is replaced by a hydrocarbon group. Tertiary amine is the one in which all three hydrogen atoms in ammonia is replaced by a hydrocarbon group. The generalized structural formula for all the amines is,

(c)

Interpretation Introduction

Interpretation:

The number of nitrogen‑hydrogen bonds present in tertiary amine has to be given.

Concept Introduction:

Amine is an organic derivative. If in ammonia one or more alkyl, cycloalkyl, or aryl groups are substituted instead of hydrogen atom then it is known as amine. Depending on the number of substitution the amines are classified as primary, secondary or tertiary amine. Primary amine is the one in which only one hydrogen atom in ammonia is replaced by a hydrocarbon group. Secondary amine is the one in which only two hydrogen atoms in ammonia is replaced by a hydrocarbon group. Tertiary amine is the one in which all three hydrogen atoms in ammonia is replaced by a hydrocarbon group. The generalized structural formula for all the amines is,

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Answer 4

Question

Chapter 6, Problem 6.6EP

(a)

Interpretation Introduction

Interpretation:

The number of nitrogen‑hydrogen bonds present in primary amine has to be given.

Concept Introduction:

Amine is an organic derivative. If in ammonia one or more alkyl, cycloalkyl, or aryl groups are substituted instead of hydrogen atom then it is known as amine. Depending on the number of substitution the amines are classified as primary, secondary or tertiary amine. Primary amine is the one in which only one hydrogen atom in ammonia is replaced by a hydrocarbon group. Secondary amine is the one in which only two hydrogen atoms in ammonia is replaced by a hydrocarbon group. Tertiary amine is the one in which all three hydrogen atoms in ammonia is replaced by a hydrocarbon group. The generalized structural formula for all the amines is,

(b)

Interpretation Introduction

Interpretation:

The number of nitrogen‑hydrogen bonds present in secondary amine has to be given.

Concept Introduction:

Amine is an organic derivative. If in ammonia one or more alkyl, cycloalkyl, or aryl groups are substituted instead of hydrogen atom then it is known as amine. Depending on the number of substitution the amines are classified as primary, secondary or tertiary amine. Primary amine is the one in which only one hydrogen atom in ammonia is replaced by a hydrocarbon group. Secondary amine is the one in which only two hydrogen atoms in ammonia is replaced by a hydrocarbon group. Tertiary amine is the one in which all three hydrogen atoms in ammonia is replaced by a hydrocarbon group. The generalized structural formula for all the amines is,

(c)

Interpretation Introduction

Interpretation:

The number of nitrogen‑hydrogen bonds present in tertiary amine has to be given.

Concept Introduction:

Amine is an organic derivative. If in ammonia one or more alkyl, cycloalkyl, or aryl groups are substituted instead of hydrogen atom then it is known as amine. Depending on the number of substitution the amines are classified as primary, secondary or tertiary amine. Primary amine is the one in which only one hydrogen atom in ammonia is replaced by a hydrocarbon group. Secondary amine is the one in which only two hydrogen atoms in ammonia is replaced by a hydrocarbon group. Tertiary amine is the one in which all three hydrogen atoms in ammonia is replaced by a hydrocarbon group. The generalized structural formula for all the amines is,

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Answer 5

Chapter 6, Problem 6.6EP

(a)

Interpretation Introduction

Interpretation:

The number of nitrogen‑hydrogen bonds present in primary amine has to be given.

Concept Introduction:

Amine is an organic derivative. If in ammonia one or more alkyl, cycloalkyl, or aryl groups are substituted instead of hydrogen atom then it is known as amine. Depending on the number of substitution the amines are classified as primary, secondary or tertiary amine. Primary amine is the one in which only one hydrogen atom in ammonia is replaced by a hydrocarbon group. Secondary amine is the one in which only two hydrogen atoms in ammonia is replaced by a hydrocarbon group. Tertiary amine is the one in which all three hydrogen atoms in ammonia is replaced by a hydrocarbon group. The generalized structural formula for all the amines is,

(b)

Interpretation Introduction

Interpretation:

The number of nitrogen‑hydrogen bonds present in secondary amine has to be given.

Concept Introduction:

Amine is an organic derivative. If in ammonia one or more alkyl, cycloalkyl, or aryl groups are substituted instead of hydrogen atom then it is known as amine. Depending on the number of substitution the amines are classified as primary, secondary or tertiary amine. Primary amine is the one in which only one hydrogen atom in ammonia is replaced by a hydrocarbon group. Secondary amine is the one in which only two hydrogen atoms in ammonia is replaced by a hydrocarbon group. Tertiary amine is the one in which all three hydrogen atoms in ammonia is replaced by a hydrocarbon group. The generalized structural formula for all the amines is,

(c)

Interpretation Introduction

Interpretation:

The number of nitrogen‑hydrogen bonds present in tertiary amine has to be given.

Concept Introduction:

Amine is an organic derivative. If in ammonia one or more alkyl, cycloalkyl, or aryl groups are substituted instead of hydrogen atom then it is known as amine. Depending on the number of substitution the amines are classified as primary, secondary or tertiary amine. Primary amine is the one in which only one hydrogen atom in ammonia is replaced by a hydrocarbon group. Secondary amine is the one in which only two hydrogen atoms in ammonia is replaced by a hydrocarbon group. Tertiary amine is the one in which all three hydrogen atoms in ammonia is replaced by a hydrocarbon group. The generalized structural formula for all the amines is,

Answer 6

Chapter 6, Problem 6.6EP

(a)

Interpretation Introduction

Interpretation:

The number of nitrogen‑hydrogen bonds present in primary amine has to be given.

Concept Introduction:

Amine is an organic derivative. If in ammonia one or more alkyl, cycloalkyl, or aryl groups are substituted instead of hydrogen atom then it is known as amine. Depending on the number of substitution the amines are classified as primary, secondary or tertiary amine. Primary amine is the one in which only one hydrogen atom in ammonia is replaced by a hydrocarbon group. Secondary amine is the one in which only two hydrogen atoms in ammonia is replaced by a hydrocarbon group. Tertiary amine is the one in which all three hydrogen atoms in ammonia is replaced by a hydrocarbon group. The generalized structural formula for all the amines is,

Answer 7

Chapter 6, Problem 6.6EP

(a)

Interpretation Introduction

Interpretation:

The number of nitrogen‑hydrogen bonds present in primary amine has to be given.

Concept Introduction:

Amine is an organic derivative. If in ammonia one or more alkyl, cycloalkyl, or aryl groups are substituted instead of hydrogen atom then it is known as amine. Depending on the number of substitution the amines are classified as primary, secondary or tertiary amine. Primary amine is the one in which only one hydrogen atom in ammonia is replaced by a hydrocarbon group. Secondary amine is the one in which only two hydrogen atoms in ammonia is replaced by a hydrocarbon group. Tertiary amine is the one in which all three hydrogen atoms in ammonia is replaced by a hydrocarbon group. The generalized structural formula for all the amines is,

Answer 8

(b)

Interpretation Introduction

Interpretation:

The number of nitrogen‑hydrogen bonds present in secondary amine has to be given.

Concept Introduction:

Amine is an organic derivative. If in ammonia one or more alkyl, cycloalkyl, or aryl groups are substituted instead of hydrogen atom then it is known as amine. Depending on the number of substitution the amines are classified as primary, secondary or tertiary amine. Primary amine is the one in which only one hydrogen atom in ammonia is replaced by a hydrocarbon group. Secondary amine is the one in which only two hydrogen atoms in ammonia is replaced by a hydrocarbon group. Tertiary amine is the one in which all three hydrogen atoms in ammonia is replaced by a hydrocarbon group. The generalized structural formula for all the amines is,

Answer 9

(b)

Interpretation Introduction

Interpretation:

The number of nitrogen‑hydrogen bonds present in secondary amine has to be given.

Concept Introduction:

Amine is an organic derivative. If in ammonia one or more alkyl, cycloalkyl, or aryl groups are substituted instead of hydrogen atom then it is known as amine. Depending on the number of substitution the amines are classified as primary, secondary or tertiary amine. Primary amine is the one in which only one hydrogen atom in ammonia is replaced by a hydrocarbon group. Secondary amine is the one in which only two hydrogen atoms in ammonia is replaced by a hydrocarbon group. Tertiary amine is the one in which all three hydrogen atoms in ammonia is replaced by a hydrocarbon group. The generalized structural formula for all the amines is,

Answer 10

(c)

Interpretation Introduction

Interpretation:

The number of nitrogen‑hydrogen bonds present in tertiary amine has to be given.

Concept Introduction:

Amine is an organic derivative. If in ammonia one or more alkyl, cycloalkyl, or aryl groups are substituted instead of hydrogen atom then it is known as amine. Depending on the number of substitution the amines are classified as primary, secondary or tertiary amine. Primary amine is the one in which only one hydrogen atom in ammonia is replaced by a hydrocarbon group. Secondary amine is the one in which only two hydrogen atoms in ammonia is replaced by a hydrocarbon group. Tertiary amine is the one in which all three hydrogen atoms in ammonia is replaced by a hydrocarbon group. The generalized structural formula for all the amines is,

Answer 11

(c)

Interpretation Introduction

Interpretation:

The number of nitrogen‑hydrogen bonds present in tertiary amine has to be given.

Concept Introduction:

Amine is an organic derivative. If in ammonia one or more alkyl, cycloalkyl, or aryl groups are substituted instead of hydrogen atom then it is known as amine. Depending on the number of substitution the amines are classified as primary, secondary or tertiary amine. Primary amine is the one in which only one hydrogen atom in ammonia is replaced by a hydrocarbon group. Secondary amine is the one in which only two hydrogen atoms in ammonia is replaced by a hydrocarbon group. Tertiary amine is the one in which all three hydrogen atoms in ammonia is replaced by a hydrocarbon group. The generalized structural formula for all the amines is,

Answer 12

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Answer 13

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Answer 15

Ch. 6.1 - Prob. 1QQ Ch. 6.1 - Prob. 2QQ Ch. 6.2 - Prob. 1QQ Ch. 6.2 - Prob. 2QQ Ch. 6.2 - Prob. 3QQ Ch. 6.2 - Prob. 4QQ Ch. 6.3 - Prob. 1QQ Ch. 6.3 - Prob. 2QQ Ch. 6.3 - Prob. 3QQ Ch. 6.3 - Prob. 4QQ

Solution Summary: The author explains that the number of nitrogenhydrogen bonds present in primary amine is given.

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