In aqueous solution, propanamide exhibit basic behavior or not has to be indicated. Concept Introduction: Amines are a class of organic compounds. They are derivatives of ammonia. Similar to the nitrogen atom in ammonia, the amine nitrogen also has a lone pair of electrons on it. This means that amines can act as proton acceptors. When an amine is added to water a proton is transferred to the nitrogen atom. The resulting solution is a basic solution. This contains ammonium ions and hydroxide ions. Amides have a carbonyl group bonded to the nitrogen atom. The carbonyl carbon atom pulls the lone pair of electrons present on the nitrogen strongly. Hence, the nitrogen atom cannot act as a proton acceptor. Amides are not basic in nature.

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Answer 1

Question

Chapter 6, Problem 6.123EP

(a)

Interpretation Introduction

Interpretation:

In aqueous solution, propanamide exhibit basic behavior or not has to be indicated.

Concept Introduction:

Amines are a class of organic compounds. They are derivatives of ammonia. Similar to the nitrogen atom in ammonia, the amine nitrogen also has a lone pair of electrons on it. This means that amines can act as proton acceptors. When an amine is added to water a proton is transferred to the nitrogen atom. The resulting solution is a basic solution. This contains ammonium ions and hydroxide ions.

Amides have a carbonyl group bonded to the nitrogen atom. The carbonyl carbon atom pulls the lone pair of electrons present on the nitrogen strongly. Hence, the nitrogen atom cannot act as a proton acceptor. Amides are not basic in nature.

(b)

Interpretation Introduction

Interpretation:

In aqueous solution, 1-propanamine exhibit basic behavior or not has to be indicated.

Concept Introduction:

Amines are a class of organic compounds. They are derivatives of ammonia. Similar to the nitrogen atom in ammonia, the amine nitrogen also has a lone pair of electrons on it. This means that amines can act as proton acceptors. When an amine is added to water a proton is transferred to the nitrogen atom. The resulting solution is a basic solution. This contains ammonium ions and hydroxide ions.

Amides have a carbonyl group bonded to the nitrogen atom. The carbonyl carbon atom pulls the lone pair of electrons present on the nitrogen strongly. Hence, the nitrogen atom cannot act as a proton acceptor. Amides are not basic in nature.

(c)

Interpretation Introduction

Interpretation:

In aqueous solution, the given compound exhibit basic behavior or not has to be indicated.

Concept Introduction:

Amines are a class of organic compounds. They are derivatives of ammonia. Similar to the nitrogen atom in ammonia, the amine nitrogen also has a lone pair of electrons on it. This means that amines can act as proton acceptors. When an amine is added to water a proton is transferred to the nitrogen atom. The resulting solution is a basic solution. This contains ammonium ions and hydroxide ions.

Amides have a carbonyl group bonded to the nitrogen atom. The carbonyl carbon atom pulls the lone pair of electrons present on the nitrogen strongly. Hence, the nitrogen atom cannot act as a proton acceptor. Amides are not basic in nature.

(d)

Interpretation Introduction

Interpretation:

In aqueous solution, the given compound exhibit basic behavior or not has to be indicated.

Concept Introduction:

Amines are a class of organic compounds. They are derivatives of ammonia. Similar to the nitrogen atom in ammonia, the amine nitrogen also has a lone pair of electrons on it. This means that amines can act as proton acceptors. When an amine is added to water a proton is transferred to the nitrogen atom. The resulting solution is a basic solution. This contains ammonium ions and hydroxide ions.

Amides have a carbonyl group bonded to the nitrogen atom. The carbonyl carbon atom pulls the lone pair of electrons present on the nitrogen strongly. Hence, the nitrogen atom cannot act as a proton acceptor. Amides are not basic in nature.

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For the following reactions, predict the major product. Show stereochemistry where appro

Answer 2

Question

Chapter 6, Problem 6.123EP

(a)

Interpretation Introduction

Interpretation:

In aqueous solution, propanamide exhibit basic behavior or not has to be indicated.

Concept Introduction:

Amines are a class of organic compounds. They are derivatives of ammonia. Similar to the nitrogen atom in ammonia, the amine nitrogen also has a lone pair of electrons on it. This means that amines can act as proton acceptors. When an amine is added to water a proton is transferred to the nitrogen atom. The resulting solution is a basic solution. This contains ammonium ions and hydroxide ions.

Amides have a carbonyl group bonded to the nitrogen atom. The carbonyl carbon atom pulls the lone pair of electrons present on the nitrogen strongly. Hence, the nitrogen atom cannot act as a proton acceptor. Amides are not basic in nature.

(b)

Interpretation Introduction

Interpretation:

In aqueous solution, 1-propanamine exhibit basic behavior or not has to be indicated.

Concept Introduction:

Amines are a class of organic compounds. They are derivatives of ammonia. Similar to the nitrogen atom in ammonia, the amine nitrogen also has a lone pair of electrons on it. This means that amines can act as proton acceptors. When an amine is added to water a proton is transferred to the nitrogen atom. The resulting solution is a basic solution. This contains ammonium ions and hydroxide ions.

Amides have a carbonyl group bonded to the nitrogen atom. The carbonyl carbon atom pulls the lone pair of electrons present on the nitrogen strongly. Hence, the nitrogen atom cannot act as a proton acceptor. Amides are not basic in nature.

(c)

Interpretation Introduction

Interpretation:

In aqueous solution, the given compound exhibit basic behavior or not has to be indicated.

Concept Introduction:

Amines are a class of organic compounds. They are derivatives of ammonia. Similar to the nitrogen atom in ammonia, the amine nitrogen also has a lone pair of electrons on it. This means that amines can act as proton acceptors. When an amine is added to water a proton is transferred to the nitrogen atom. The resulting solution is a basic solution. This contains ammonium ions and hydroxide ions.

Amides have a carbonyl group bonded to the nitrogen atom. The carbonyl carbon atom pulls the lone pair of electrons present on the nitrogen strongly. Hence, the nitrogen atom cannot act as a proton acceptor. Amides are not basic in nature.

(d)

Interpretation Introduction

Interpretation:

In aqueous solution, the given compound exhibit basic behavior or not has to be indicated.

Concept Introduction:

Amines are a class of organic compounds. They are derivatives of ammonia. Similar to the nitrogen atom in ammonia, the amine nitrogen also has a lone pair of electrons on it. This means that amines can act as proton acceptors. When an amine is added to water a proton is transferred to the nitrogen atom. The resulting solution is a basic solution. This contains ammonium ions and hydroxide ions.

Amides have a carbonyl group bonded to the nitrogen atom. The carbonyl carbon atom pulls the lone pair of electrons present on the nitrogen strongly. Hence, the nitrogen atom cannot act as a proton acceptor. Amides are not basic in nature.

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Answer 3

Question

Chapter 6, Problem 6.123EP

(a)

Interpretation Introduction

Interpretation:

In aqueous solution, propanamide exhibit basic behavior or not has to be indicated.

Concept Introduction:

Amines are a class of organic compounds. They are derivatives of ammonia. Similar to the nitrogen atom in ammonia, the amine nitrogen also has a lone pair of electrons on it. This means that amines can act as proton acceptors. When an amine is added to water a proton is transferred to the nitrogen atom. The resulting solution is a basic solution. This contains ammonium ions and hydroxide ions.

Amides have a carbonyl group bonded to the nitrogen atom. The carbonyl carbon atom pulls the lone pair of electrons present on the nitrogen strongly. Hence, the nitrogen atom cannot act as a proton acceptor. Amides are not basic in nature.

(b)

Interpretation Introduction

Interpretation:

In aqueous solution, 1-propanamine exhibit basic behavior or not has to be indicated.

Concept Introduction:

Amines are a class of organic compounds. They are derivatives of ammonia. Similar to the nitrogen atom in ammonia, the amine nitrogen also has a lone pair of electrons on it. This means that amines can act as proton acceptors. When an amine is added to water a proton is transferred to the nitrogen atom. The resulting solution is a basic solution. This contains ammonium ions and hydroxide ions.

Amides have a carbonyl group bonded to the nitrogen atom. The carbonyl carbon atom pulls the lone pair of electrons present on the nitrogen strongly. Hence, the nitrogen atom cannot act as a proton acceptor. Amides are not basic in nature.

(c)

Interpretation Introduction

Interpretation:

In aqueous solution, the given compound exhibit basic behavior or not has to be indicated.

Concept Introduction:

Amines are a class of organic compounds. They are derivatives of ammonia. Similar to the nitrogen atom in ammonia, the amine nitrogen also has a lone pair of electrons on it. This means that amines can act as proton acceptors. When an amine is added to water a proton is transferred to the nitrogen atom. The resulting solution is a basic solution. This contains ammonium ions and hydroxide ions.

Amides have a carbonyl group bonded to the nitrogen atom. The carbonyl carbon atom pulls the lone pair of electrons present on the nitrogen strongly. Hence, the nitrogen atom cannot act as a proton acceptor. Amides are not basic in nature.

(d)

Interpretation Introduction

Interpretation:

In aqueous solution, the given compound exhibit basic behavior or not has to be indicated.

Concept Introduction:

Amines are a class of organic compounds. They are derivatives of ammonia. Similar to the nitrogen atom in ammonia, the amine nitrogen also has a lone pair of electrons on it. This means that amines can act as proton acceptors. When an amine is added to water a proton is transferred to the nitrogen atom. The resulting solution is a basic solution. This contains ammonium ions and hydroxide ions.

Amides have a carbonyl group bonded to the nitrogen atom. The carbonyl carbon atom pulls the lone pair of electrons present on the nitrogen strongly. Hence, the nitrogen atom cannot act as a proton acceptor. Amides are not basic in nature.

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Answer 4

Question

Chapter 6, Problem 6.123EP

(a)

Interpretation Introduction

Interpretation:

In aqueous solution, propanamide exhibit basic behavior or not has to be indicated.

Concept Introduction:

Amines are a class of organic compounds. They are derivatives of ammonia. Similar to the nitrogen atom in ammonia, the amine nitrogen also has a lone pair of electrons on it. This means that amines can act as proton acceptors. When an amine is added to water a proton is transferred to the nitrogen atom. The resulting solution is a basic solution. This contains ammonium ions and hydroxide ions.

Amides have a carbonyl group bonded to the nitrogen atom. The carbonyl carbon atom pulls the lone pair of electrons present on the nitrogen strongly. Hence, the nitrogen atom cannot act as a proton acceptor. Amides are not basic in nature.

(b)

Interpretation Introduction

Interpretation:

In aqueous solution, 1-propanamine exhibit basic behavior or not has to be indicated.

Concept Introduction:

Amines are a class of organic compounds. They are derivatives of ammonia. Similar to the nitrogen atom in ammonia, the amine nitrogen also has a lone pair of electrons on it. This means that amines can act as proton acceptors. When an amine is added to water a proton is transferred to the nitrogen atom. The resulting solution is a basic solution. This contains ammonium ions and hydroxide ions.

Amides have a carbonyl group bonded to the nitrogen atom. The carbonyl carbon atom pulls the lone pair of electrons present on the nitrogen strongly. Hence, the nitrogen atom cannot act as a proton acceptor. Amides are not basic in nature.

(c)

Interpretation Introduction

Interpretation:

In aqueous solution, the given compound exhibit basic behavior or not has to be indicated.

Concept Introduction:

Amines are a class of organic compounds. They are derivatives of ammonia. Similar to the nitrogen atom in ammonia, the amine nitrogen also has a lone pair of electrons on it. This means that amines can act as proton acceptors. When an amine is added to water a proton is transferred to the nitrogen atom. The resulting solution is a basic solution. This contains ammonium ions and hydroxide ions.

Amides have a carbonyl group bonded to the nitrogen atom. The carbonyl carbon atom pulls the lone pair of electrons present on the nitrogen strongly. Hence, the nitrogen atom cannot act as a proton acceptor. Amides are not basic in nature.

(d)

Interpretation Introduction

Interpretation:

In aqueous solution, the given compound exhibit basic behavior or not has to be indicated.

Concept Introduction:

Amines are a class of organic compounds. They are derivatives of ammonia. Similar to the nitrogen atom in ammonia, the amine nitrogen also has a lone pair of electrons on it. This means that amines can act as proton acceptors. When an amine is added to water a proton is transferred to the nitrogen atom. The resulting solution is a basic solution. This contains ammonium ions and hydroxide ions.

Amides have a carbonyl group bonded to the nitrogen atom. The carbonyl carbon atom pulls the lone pair of electrons present on the nitrogen strongly. Hence, the nitrogen atom cannot act as a proton acceptor. Amides are not basic in nature.

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Answer 5

Chapter 6, Problem 6.123EP

(a)

Interpretation Introduction

Interpretation:

In aqueous solution, propanamide exhibit basic behavior or not has to be indicated.

Concept Introduction:

Amines are a class of organic compounds. They are derivatives of ammonia. Similar to the nitrogen atom in ammonia, the amine nitrogen also has a lone pair of electrons on it. This means that amines can act as proton acceptors. When an amine is added to water a proton is transferred to the nitrogen atom. The resulting solution is a basic solution. This contains ammonium ions and hydroxide ions.

Amides have a carbonyl group bonded to the nitrogen atom. The carbonyl carbon atom pulls the lone pair of electrons present on the nitrogen strongly. Hence, the nitrogen atom cannot act as a proton acceptor. Amides are not basic in nature.

(b)

Interpretation Introduction

Interpretation:

In aqueous solution, 1-propanamine exhibit basic behavior or not has to be indicated.

Concept Introduction:

Amines are a class of organic compounds. They are derivatives of ammonia. Similar to the nitrogen atom in ammonia, the amine nitrogen also has a lone pair of electrons on it. This means that amines can act as proton acceptors. When an amine is added to water a proton is transferred to the nitrogen atom. The resulting solution is a basic solution. This contains ammonium ions and hydroxide ions.

Amides have a carbonyl group bonded to the nitrogen atom. The carbonyl carbon atom pulls the lone pair of electrons present on the nitrogen strongly. Hence, the nitrogen atom cannot act as a proton acceptor. Amides are not basic in nature.

(c)

Interpretation Introduction

Interpretation:

In aqueous solution, the given compound exhibit basic behavior or not has to be indicated.

Concept Introduction:

Amines are a class of organic compounds. They are derivatives of ammonia. Similar to the nitrogen atom in ammonia, the amine nitrogen also has a lone pair of electrons on it. This means that amines can act as proton acceptors. When an amine is added to water a proton is transferred to the nitrogen atom. The resulting solution is a basic solution. This contains ammonium ions and hydroxide ions.

Amides have a carbonyl group bonded to the nitrogen atom. The carbonyl carbon atom pulls the lone pair of electrons present on the nitrogen strongly. Hence, the nitrogen atom cannot act as a proton acceptor. Amides are not basic in nature.

(d)

Interpretation Introduction

Interpretation:

In aqueous solution, the given compound exhibit basic behavior or not has to be indicated.

Concept Introduction:

Amines are a class of organic compounds. They are derivatives of ammonia. Similar to the nitrogen atom in ammonia, the amine nitrogen also has a lone pair of electrons on it. This means that amines can act as proton acceptors. When an amine is added to water a proton is transferred to the nitrogen atom. The resulting solution is a basic solution. This contains ammonium ions and hydroxide ions.

Amides have a carbonyl group bonded to the nitrogen atom. The carbonyl carbon atom pulls the lone pair of electrons present on the nitrogen strongly. Hence, the nitrogen atom cannot act as a proton acceptor. Amides are not basic in nature.

Answer 6

Chapter 6, Problem 6.123EP

(a)

Interpretation Introduction

Interpretation:

In aqueous solution, propanamide exhibit basic behavior or not has to be indicated.

Concept Introduction:

Amines are a class of organic compounds. They are derivatives of ammonia. Similar to the nitrogen atom in ammonia, the amine nitrogen also has a lone pair of electrons on it. This means that amines can act as proton acceptors. When an amine is added to water a proton is transferred to the nitrogen atom. The resulting solution is a basic solution. This contains ammonium ions and hydroxide ions.

Amides have a carbonyl group bonded to the nitrogen atom. The carbonyl carbon atom pulls the lone pair of electrons present on the nitrogen strongly. Hence, the nitrogen atom cannot act as a proton acceptor. Amides are not basic in nature.

Answer 7

Chapter 6, Problem 6.123EP

(a)

Interpretation Introduction

Interpretation:

In aqueous solution, propanamide exhibit basic behavior or not has to be indicated.

Concept Introduction:

Amines are a class of organic compounds. They are derivatives of ammonia. Similar to the nitrogen atom in ammonia, the amine nitrogen also has a lone pair of electrons on it. This means that amines can act as proton acceptors. When an amine is added to water a proton is transferred to the nitrogen atom. The resulting solution is a basic solution. This contains ammonium ions and hydroxide ions.

Amides have a carbonyl group bonded to the nitrogen atom. The carbonyl carbon atom pulls the lone pair of electrons present on the nitrogen strongly. Hence, the nitrogen atom cannot act as a proton acceptor. Amides are not basic in nature.

Answer 8

(b)

Interpretation Introduction

Interpretation:

In aqueous solution, 1-propanamine exhibit basic behavior or not has to be indicated.

Concept Introduction:

Amines are a class of organic compounds. They are derivatives of ammonia. Similar to the nitrogen atom in ammonia, the amine nitrogen also has a lone pair of electrons on it. This means that amines can act as proton acceptors. When an amine is added to water a proton is transferred to the nitrogen atom. The resulting solution is a basic solution. This contains ammonium ions and hydroxide ions.

Amides have a carbonyl group bonded to the nitrogen atom. The carbonyl carbon atom pulls the lone pair of electrons present on the nitrogen strongly. Hence, the nitrogen atom cannot act as a proton acceptor. Amides are not basic in nature.

Answer 9

(b)

Interpretation Introduction

Interpretation:

In aqueous solution, 1-propanamine exhibit basic behavior or not has to be indicated.

Concept Introduction:

Amines are a class of organic compounds. They are derivatives of ammonia. Similar to the nitrogen atom in ammonia, the amine nitrogen also has a lone pair of electrons on it. This means that amines can act as proton acceptors. When an amine is added to water a proton is transferred to the nitrogen atom. The resulting solution is a basic solution. This contains ammonium ions and hydroxide ions.

Amides have a carbonyl group bonded to the nitrogen atom. The carbonyl carbon atom pulls the lone pair of electrons present on the nitrogen strongly. Hence, the nitrogen atom cannot act as a proton acceptor. Amides are not basic in nature.

Answer 10

(c)

Interpretation Introduction

Interpretation:

In aqueous solution, the given compound exhibit basic behavior or not has to be indicated.

Concept Introduction:

Amines are a class of organic compounds. They are derivatives of ammonia. Similar to the nitrogen atom in ammonia, the amine nitrogen also has a lone pair of electrons on it. This means that amines can act as proton acceptors. When an amine is added to water a proton is transferred to the nitrogen atom. The resulting solution is a basic solution. This contains ammonium ions and hydroxide ions.

Amides have a carbonyl group bonded to the nitrogen atom. The carbonyl carbon atom pulls the lone pair of electrons present on the nitrogen strongly. Hence, the nitrogen atom cannot act as a proton acceptor. Amides are not basic in nature.

Answer 11

(c)

Interpretation Introduction

Interpretation:

In aqueous solution, the given compound exhibit basic behavior or not has to be indicated.

Concept Introduction:

Amines are a class of organic compounds. They are derivatives of ammonia. Similar to the nitrogen atom in ammonia, the amine nitrogen also has a lone pair of electrons on it. This means that amines can act as proton acceptors. When an amine is added to water a proton is transferred to the nitrogen atom. The resulting solution is a basic solution. This contains ammonium ions and hydroxide ions.

Amides have a carbonyl group bonded to the nitrogen atom. The carbonyl carbon atom pulls the lone pair of electrons present on the nitrogen strongly. Hence, the nitrogen atom cannot act as a proton acceptor. Amides are not basic in nature.

Answer 12

(d)

Interpretation Introduction

Interpretation:

In aqueous solution, the given compound exhibit basic behavior or not has to be indicated.

Concept Introduction:

Amines are a class of organic compounds. They are derivatives of ammonia. Similar to the nitrogen atom in ammonia, the amine nitrogen also has a lone pair of electrons on it. This means that amines can act as proton acceptors. When an amine is added to water a proton is transferred to the nitrogen atom. The resulting solution is a basic solution. This contains ammonium ions and hydroxide ions.

Amides have a carbonyl group bonded to the nitrogen atom. The carbonyl carbon atom pulls the lone pair of electrons present on the nitrogen strongly. Hence, the nitrogen atom cannot act as a proton acceptor. Amides are not basic in nature.

Answer 13

(d)

Interpretation Introduction

Interpretation:

In aqueous solution, the given compound exhibit basic behavior or not has to be indicated.

Concept Introduction:

Amines are a class of organic compounds. They are derivatives of ammonia. Similar to the nitrogen atom in ammonia, the amine nitrogen also has a lone pair of electrons on it. This means that amines can act as proton acceptors. When an amine is added to water a proton is transferred to the nitrogen atom. The resulting solution is a basic solution. This contains ammonium ions and hydroxide ions.

Amides have a carbonyl group bonded to the nitrogen atom. The carbonyl carbon atom pulls the lone pair of electrons present on the nitrogen strongly. Hence, the nitrogen atom cannot act as a proton acceptor. Amides are not basic in nature.

Answer 14

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Answer 15

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Answer 16

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Answer 17

Ch. 6.1 - Prob. 1QQ Ch. 6.1 - Prob. 2QQ Ch. 6.2 - Prob. 1QQ Ch. 6.2 - Prob. 2QQ Ch. 6.2 - Prob. 3QQ Ch. 6.2 - Prob. 4QQ Ch. 6.3 - Prob. 1QQ Ch. 6.3 - Prob. 2QQ Ch. 6.3 - Prob. 3QQ Ch. 6.3 - Prob. 4QQ

Solution Summary: The author explains that amines are a class of organic compounds. They are derivatives of ammonia.

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Chapter 6 Solutions