Butylamine will be present as liquid or gas at room temperature has to be indicated. Concept Introduction: Amines are compounds that contain nitrogen atom bonded to a hydrocarbon group. Methylamines and ethylamines are gases at room temperature. Apart from these, the other amines have raw fish odor.

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Answer 1

Question

Chapter 6, Problem 6.33EP

(a)

Interpretation Introduction

Interpretation:

Butylamine will be present as liquid or gas at room temperature has to be indicated.

Concept Introduction:

Amines are compounds that contain nitrogen atom bonded to a hydrocarbon group. Methylamines and ethylamines are gases at room temperature. Apart from these, the other amines have raw fish odor.

(b)

Interpretation Introduction

Interpretation:

Dimethylamine will be present as liquid or gas at room temperature has to be indicated.

Concept Introduction:

Amines are compounds that contain nitrogen atom bonded to a hydrocarbon group. Methylamines and ethylamines are gases at room temperature. Apart from these, the other amines have raw fish odor.

(c)

Interpretation Introduction

Interpretation:

Ethylamine will be present as liquid or gas at room temperature has to be indicated.

Concept Introduction:

Amines are compounds that contain nitrogen atom bonded to a hydrocarbon group. Methylamines and ethylamines are gases at room temperature. Apart from these, the other amines have raw fish odor.

(d)

Interpretation Introduction

Interpretation:

Dibutylamine will be present as liquid or gas at room temperature has to be indicated.

Concept Introduction:

Amines are compounds that contain nitrogen atom bonded to a hydrocarbon group. Methylamines and ethylamines are gases at room temperature. Apart from these, the other amines have raw fish odor.

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(a 4 shows scanning electron microscope (SEM) images of extruded actions of packing bed for two capillary columns of different diameters, al 750 (bottom image) and b) 30-μm-i.d. Both columns are packed with the same stationary phase, spherical particles with 1-um diameter. A) When the columns were prepared, the figure shows that the column with the larger diameter has more packing irregularities. Explain this observation. B) Predict what affect this should have on band broadening and discuss your prediction using the van Deemter terms. C) Does this figure support your explanations in application question 33? Explain why or why not and make any changes in your answers in light of this figure. Figure 4 SEM images of sections of packed columns for a) 750 and b) 30-um-i.d. capillary columns.³

fcrip = ↓ bandwidth Il temp 32. What impact (increase, decrease, or no change) does each of the following conditions have on the individual components of the van Deemter equation and consequently, band broadening? Increase temperature Longer column Using a gas mobile phase instead of liquid Smaller particle stationary phase Multiple Paths Diffusion Mass Transfer

34. Figure 3 shows Van Deemter plots for a solute molecule using different column inner diameters (i.d.). A) Predict whether decreasing the column inner diameters increase or decrease bandwidth. B) Predict which van Deemter equation coefficient (A, B, or C) has the greatest effect on increasing or decreasing bandwidth as a function of i.d. and justify your answer. Figure 3 Van Deemter plots for hydroquinone using different column inner diameters (i.d. in μm). The data was obtained from liquid chromatography experiments using fused-silica capillary columns packed with 1.0-μm particles. 35 20 H(um) 큰 20 15 90 0+ 1500 100 75 550 01 02 594 05 μ(cm/sec) 30 15 10

Answer 2

Question

Chapter 6, Problem 6.33EP

(a)

Interpretation Introduction

Interpretation:

Butylamine will be present as liquid or gas at room temperature has to be indicated.

Concept Introduction:

Amines are compounds that contain nitrogen atom bonded to a hydrocarbon group. Methylamines and ethylamines are gases at room temperature. Apart from these, the other amines have raw fish odor.

(b)

Interpretation Introduction

Interpretation:

Dimethylamine will be present as liquid or gas at room temperature has to be indicated.

Concept Introduction:

Amines are compounds that contain nitrogen atom bonded to a hydrocarbon group. Methylamines and ethylamines are gases at room temperature. Apart from these, the other amines have raw fish odor.

(c)

Interpretation Introduction

Interpretation:

Ethylamine will be present as liquid or gas at room temperature has to be indicated.

Concept Introduction:

Amines are compounds that contain nitrogen atom bonded to a hydrocarbon group. Methylamines and ethylamines are gases at room temperature. Apart from these, the other amines have raw fish odor.

(d)

Interpretation Introduction

Interpretation:

Dibutylamine will be present as liquid or gas at room temperature has to be indicated.

Concept Introduction:

Amines are compounds that contain nitrogen atom bonded to a hydrocarbon group. Methylamines and ethylamines are gases at room temperature. Apart from these, the other amines have raw fish odor.

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Answer 3

Question

Chapter 6, Problem 6.33EP

(a)

Interpretation Introduction

Interpretation:

Butylamine will be present as liquid or gas at room temperature has to be indicated.

Concept Introduction:

Amines are compounds that contain nitrogen atom bonded to a hydrocarbon group. Methylamines and ethylamines are gases at room temperature. Apart from these, the other amines have raw fish odor.

(b)

Interpretation Introduction

Interpretation:

Dimethylamine will be present as liquid or gas at room temperature has to be indicated.

Concept Introduction:

Amines are compounds that contain nitrogen atom bonded to a hydrocarbon group. Methylamines and ethylamines are gases at room temperature. Apart from these, the other amines have raw fish odor.

(c)

Interpretation Introduction

Interpretation:

Ethylamine will be present as liquid or gas at room temperature has to be indicated.

Concept Introduction:

Amines are compounds that contain nitrogen atom bonded to a hydrocarbon group. Methylamines and ethylamines are gases at room temperature. Apart from these, the other amines have raw fish odor.

(d)

Interpretation Introduction

Interpretation:

Dibutylamine will be present as liquid or gas at room temperature has to be indicated.

Concept Introduction:

Amines are compounds that contain nitrogen atom bonded to a hydrocarbon group. Methylamines and ethylamines are gases at room temperature. Apart from these, the other amines have raw fish odor.

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Answer 4

Question

Chapter 6, Problem 6.33EP

(a)

Interpretation Introduction

Interpretation:

Butylamine will be present as liquid or gas at room temperature has to be indicated.

Concept Introduction:

Amines are compounds that contain nitrogen atom bonded to a hydrocarbon group. Methylamines and ethylamines are gases at room temperature. Apart from these, the other amines have raw fish odor.

(b)

Interpretation Introduction

Interpretation:

Dimethylamine will be present as liquid or gas at room temperature has to be indicated.

Concept Introduction:

Amines are compounds that contain nitrogen atom bonded to a hydrocarbon group. Methylamines and ethylamines are gases at room temperature. Apart from these, the other amines have raw fish odor.

(c)

Interpretation Introduction

Interpretation:

Ethylamine will be present as liquid or gas at room temperature has to be indicated.

Concept Introduction:

Amines are compounds that contain nitrogen atom bonded to a hydrocarbon group. Methylamines and ethylamines are gases at room temperature. Apart from these, the other amines have raw fish odor.

(d)

Interpretation Introduction

Interpretation:

Dibutylamine will be present as liquid or gas at room temperature has to be indicated.

Concept Introduction:

Amines are compounds that contain nitrogen atom bonded to a hydrocarbon group. Methylamines and ethylamines are gases at room temperature. Apart from these, the other amines have raw fish odor.

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Answer 5

Chapter 6, Problem 6.33EP

(a)

Interpretation Introduction

Interpretation:

Butylamine will be present as liquid or gas at room temperature has to be indicated.

Concept Introduction:

Amines are compounds that contain nitrogen atom bonded to a hydrocarbon group. Methylamines and ethylamines are gases at room temperature. Apart from these, the other amines have raw fish odor.

(b)

Interpretation Introduction

Interpretation:

Dimethylamine will be present as liquid or gas at room temperature has to be indicated.

Concept Introduction:

Amines are compounds that contain nitrogen atom bonded to a hydrocarbon group. Methylamines and ethylamines are gases at room temperature. Apart from these, the other amines have raw fish odor.

(c)

Interpretation Introduction

Interpretation:

Ethylamine will be present as liquid or gas at room temperature has to be indicated.

Concept Introduction:

Amines are compounds that contain nitrogen atom bonded to a hydrocarbon group. Methylamines and ethylamines are gases at room temperature. Apart from these, the other amines have raw fish odor.

(d)

Interpretation Introduction

Interpretation:

Dibutylamine will be present as liquid or gas at room temperature has to be indicated.

Concept Introduction:

Amines are compounds that contain nitrogen atom bonded to a hydrocarbon group. Methylamines and ethylamines are gases at room temperature. Apart from these, the other amines have raw fish odor.

Answer 6

Chapter 6, Problem 6.33EP

(a)

Interpretation Introduction

Interpretation:

Butylamine will be present as liquid or gas at room temperature has to be indicated.

Concept Introduction:

Amines are compounds that contain nitrogen atom bonded to a hydrocarbon group. Methylamines and ethylamines are gases at room temperature. Apart from these, the other amines have raw fish odor.

Answer 7

Chapter 6, Problem 6.33EP

(a)

Interpretation Introduction

Interpretation:

Butylamine will be present as liquid or gas at room temperature has to be indicated.

Concept Introduction:

Amines are compounds that contain nitrogen atom bonded to a hydrocarbon group. Methylamines and ethylamines are gases at room temperature. Apart from these, the other amines have raw fish odor.

Answer 8

(b)

Interpretation Introduction

Interpretation:

Dimethylamine will be present as liquid or gas at room temperature has to be indicated.

Concept Introduction:

Amines are compounds that contain nitrogen atom bonded to a hydrocarbon group. Methylamines and ethylamines are gases at room temperature. Apart from these, the other amines have raw fish odor.

Answer 9

(b)

Interpretation Introduction

Interpretation:

Dimethylamine will be present as liquid or gas at room temperature has to be indicated.

Concept Introduction:

Amines are compounds that contain nitrogen atom bonded to a hydrocarbon group. Methylamines and ethylamines are gases at room temperature. Apart from these, the other amines have raw fish odor.

Answer 10

(c)

Interpretation Introduction

Interpretation:

Ethylamine will be present as liquid or gas at room temperature has to be indicated.

Concept Introduction:

Amines are compounds that contain nitrogen atom bonded to a hydrocarbon group. Methylamines and ethylamines are gases at room temperature. Apart from these, the other amines have raw fish odor.

Answer 11

(c)

Interpretation Introduction

Interpretation:

Ethylamine will be present as liquid or gas at room temperature has to be indicated.

Concept Introduction:

Amines are compounds that contain nitrogen atom bonded to a hydrocarbon group. Methylamines and ethylamines are gases at room temperature. Apart from these, the other amines have raw fish odor.

Answer 12

(d)

Interpretation Introduction

Interpretation:

Dibutylamine will be present as liquid or gas at room temperature has to be indicated.

Concept Introduction:

Amines are compounds that contain nitrogen atom bonded to a hydrocarbon group. Methylamines and ethylamines are gases at room temperature. Apart from these, the other amines have raw fish odor.

Answer 13

(d)

Interpretation Introduction

Interpretation:

Dibutylamine will be present as liquid or gas at room temperature has to be indicated.

Concept Introduction:

Amines are compounds that contain nitrogen atom bonded to a hydrocarbon group. Methylamines and ethylamines are gases at room temperature. Apart from these, the other amines have raw fish odor.

Answer 14

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Answer 15

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Answer 16

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Answer 17

Ch. 6.1 - Prob. 1QQ Ch. 6.1 - Prob. 2QQ Ch. 6.2 - Prob. 1QQ Ch. 6.2 - Prob. 2QQ Ch. 6.2 - Prob. 3QQ Ch. 6.2 - Prob. 4QQ Ch. 6.3 - Prob. 1QQ Ch. 6.3 - Prob. 2QQ Ch. 6.3 - Prob. 3QQ Ch. 6.3 - Prob. 4QQ

Butylamine will be present as liquid or gas at room temperature has to be indicated. Concept Introduction: Amines are compounds that contain nitrogen atom bonded to a hydrocarbon group. Methylamines and ethylamines are gases at room temperature. Apart from these, the other amines have raw fish odor.

Solution Summary: The author explains that butylamine is a liquid at room temperature and contains four carbon atoms in it.

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