General Chemistry: Atoms First
2nd Edition
ISBN: 9780321809261
Author: John E. McMurry, Robert C. Fay
Publisher: Prentice Hall
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Chapter 23.4, Problem 23.13P
Interpretation Introduction
Interpretation:
The target molecules should be drawn and identified for the given statements by using its name of the starting molecule and two isomeric structures should be identified.
Concept Introduction:
Addition Reaction: It is defined as
Acid Catalyzed Hydration Reaction: The reaction involves breaking of phi bonds between carbon-carbon multiple bonds and addition of alcohol to more substituted position of carbon in the molecule.
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Review of this week's reaction:
H₂NCN (cyanamide) + CH3NHCH2COOH (sarcosine) + NaCl, NH4OH, H₂O --->
H₂NC(=NH)N(CH3)CH2COOH (creatine)
Q7. Draw by hand the reaction of creatine synthesis listed above using line structures without showing
the Cs and some of the Hs, but include the lone pairs of electrons wherever they apply. (4 pts)
Q8. Considering the Zwitterion form of an amino acid, draw the Zwitterion form of Creatine. (2 pts)
Q9. Explain with drawing why the C-N bond shown in creatine structure below can or cannot rotate. (3
pts)
NH2(C=NH)-N(CH)CH2COOH
This bond
Q10. Draw two tautomers of creatine using line structures. (Note: this question is valid because problem
Q9 is valid). (4 pts)
Q11. Mechanism. After seeing and understanding the mechanism of creatine synthesis, students should
be ready to understand the first half of one of the Grignard reactions presented in a past…
Propose a synthesis pathway for the
following transformations. b) c) d)
The rate coefficient of the gas-phase reaction 2 NO2 + O3 → N2O5 + O2 is 2.0x104 mol–1 dm3 s–1 at 300 K. Indicate whether the order of the reaction is 0, 1, or 2.
Chapter 23 Solutions
General Chemistry: Atoms First
Ch. 23.1 - Prob. 23.1PCh. 23.1 - Prob. 23.2PCh. 23.1 - Prob. 23.3PCh. 23.1 - Prob. 23.4CPCh. 23.2 - Prob. 23.5PCh. 23.2 - Prob. 23.6PCh. 23.3 - Prob. 23.7PCh. 23.3 - Prob. 23.8PCh. 23.3 - Prob. 23.9CPCh. 23.4 - Prob. 23.10P
Ch. 23.4 - Prob. 23.11PCh. 23.4 - Prob. 23.12PCh. 23.4 - Prob. 23.13PCh. 23.5 - Prob. 23.14PCh. 23.5 - Draw structures corresponding to the following...Ch. 23.6 - Draw structures corresponding to the following...Ch. 23.6 - Write the products from reaction of the following...Ch. 23.6 - Reaction of Br2/FeBr3 with toluene (methylbenzene)...Ch. 23.7 - Prob. 23.19PCh. 23.8 - Draw structures corresponding to the following...Ch. 23.8 - Prob. 23.21PCh. 23.8 - Prob. 23.22CPCh. 23.10 - Prob. 23.23PCh. 23.10 - Prob. 23.24PCh. 23.10 - Prob. 23.25PCh. 23.11 - Prob. 23.26PCh. 23.12 - Show the structure of glyceryl trioleate, a fat...Ch. 23.13 - Prob. 23.28PCh. 23.13 - Prob. 23.29PCh. 23.13 - Prob. 23.30PCh. 23.13 - Prob. 23.31CPCh. 23.13 - Prob. 23.32PCh. 23 - Prob. 23.33CPCh. 23 - Prob. 23.34CPCh. 23 - Prob. 23.35CPCh. 23 - Prob. 23.36CPCh. 23 - Prob. 23.37CPCh. 23 - Prob. 23.38CPCh. 23 - Prob. 23.39CPCh. 23 - Prob. 23.40SPCh. 23 - Prob. 23.41SPCh. 23 - Prob. 23.42SPCh. 23 - Prob. 23.43SPCh. 23 - Prob. 23.44SPCh. 23 - Prob. 23.45SPCh. 23 - Prob. 23.46SPCh. 23 - Prob. 23.47SPCh. 23 - Prob. 23.48SPCh. 23 - What is wrong with each of the following...Ch. 23 - What are the IUPAC names of the following alkanes?Ch. 23 - Prob. 23.51SPCh. 23 - Prob. 23.52SPCh. 23 - Prob. 23.53SPCh. 23 - Prob. 23.54SPCh. 23 - Prob. 23.55SPCh. 23 - Prob. 23.56SPCh. 23 - Prob. 23.57SPCh. 23 - Prob. 23.58SPCh. 23 - Prob. 23.59SPCh. 23 - Prob. 23.60SPCh. 23 - Prob. 23.61SPCh. 23 - Prob. 23.62SPCh. 23 - Prob. 23.63SPCh. 23 - Draw structures corresponding to the following (a)...Ch. 23 - Prob. 23.65SPCh. 23 - Prob. 23.66SPCh. 23 - Prob. 23.67SPCh. 23 - Prob. 23.68SPCh. 23 - Draw and name compounds that meet the following...Ch. 23 - Prob. 23.70SPCh. 23 - Prob. 23.71SPCh. 23 - Prob. 23.72SPCh. 23 - Prob. 23.73SPCh. 23 - Prob. 23.74SPCh. 23 - Prob. 23.75SPCh. 23 - Prob. 23.76SPCh. 23 - Prob. 23.77SPCh. 23 - Prob. 23.78SPCh. 23 - Prob. 23.79SPCh. 23 - Prob. 23.80SPCh. 23 - Prob. 23.81SPCh. 23 - Prob. 23.82SPCh. 23 - Prob. 23.83SPCh. 23 - Prob. 23.84SPCh. 23 - Prob. 23.85SPCh. 23 - Prob. 23.86SPCh. 23 - Prob. 23.87SPCh. 23 - There are two isomeric fat molecules whose...Ch. 23 - Prob. 23.89SPCh. 23 - What is a nucleotide, and what three kinds of...Ch. 23 - What are the names of the sugars in DNA and RNA,...Ch. 23 - Prob. 23.92SPCh. 23 - Prob. 23.93SPCh. 23 - Prob. 23.94SPCh. 23 - Prob. 23.95SPCh. 23 - Prob. 23.96SPCh. 23 - Prob. 23.97SPCh. 23 - Prob. 23.98CHPCh. 23 - Prob. 23.99CHPCh. 23 - Prob. 23.100CHPCh. 23 - Prob. 23.101CHPCh. 23 - Write full structures for the following peptides,...Ch. 23 - Prob. 23.103CHPCh. 23 - Prob. 23.104CHPCh. 23 - Prob. 23.105CHPCh. 23 - Prob. 23.106CHPCh. 23 - Elaidic acid, a component of so-called trans fats,...Ch. 23 - Fumaric acid is an organic substance widely used...
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