General Chemistry: Atoms First
2nd Edition
ISBN: 9780321809261
Author: John E. McMurry, Robert C. Fay
Publisher: Prentice Hall
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Textbook Question
Chapter 23, Problem 23.64SP
Draw structures corresponding to the following
- (a) 2,4-Dimethyl-2-pentanol
- (b) 2,2-Dimethylcyclohexanol
- (c) 5,5-Diethyl-1-heptanol
- (d) 3-Ethyl-3-hexanol
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Using the conditions of spontaneity to deduce the signs of AH and AS
Use the observations about each chemical reaction in the table below to decide the sign (positive or negative) of the reaction enthalpy AH and reaction entropy
AS.
Note: if you have not been given enough information to decide a sign, select the "unknown" option.
reaction
observations
conclusions
A
This reaction is always spontaneous, but
proceeds slower at temperatures above
120. °C.
ΔΗ is
(pick one)
AS is
(pick one)
ΔΗ is
(pick one)
B
This reaction is spontaneous except above
117. °C.
AS is
(pick one)
ΔΗ is
(pick one)
This reaction is slower below 20. °C than
C
above.
AS is
|(pick one)
?
18
Ar
1
Calculating the pH at equivalence of a titration
Try Again
Your answer is incorrect.
0/5
a
A chemist titrates 70.0 mL of a 0.7089 M hydrocyanic acid (HCN) solution with 0.4574M KOH solution at 25 °C. Calculate the pH at equivalence. The pK of
hydrocyanic acid is 9.21.
Round your answer to 2 decimal places.
Note for advanced students: you may assume the total volume of the solution equals the initial volume plus the volume of KOH solution added.
pH
=
11.43]
G
00.
18
Ar
B•
Biological Macromolecules
Naming and drawing the products of aldose oxidation and reduction
aw a Fischer projection of the molecule that would produce L-ribonic acid if it were subjected to mildly oxidizing reaction conditions.
Click and drag to start drawing a
structure.
X
AP
‡
1/5
Naor
Explanation
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Chapter 23 Solutions
General Chemistry: Atoms First
Ch. 23.1 - Prob. 23.1PCh. 23.1 - Prob. 23.2PCh. 23.1 - Prob. 23.3PCh. 23.1 - Prob. 23.4CPCh. 23.2 - Prob. 23.5PCh. 23.2 - Prob. 23.6PCh. 23.3 - Prob. 23.7PCh. 23.3 - Prob. 23.8PCh. 23.3 - Prob. 23.9CPCh. 23.4 - Prob. 23.10P
Ch. 23.4 - Prob. 23.11PCh. 23.4 - Prob. 23.12PCh. 23.4 - Prob. 23.13PCh. 23.5 - Prob. 23.14PCh. 23.5 - Draw structures corresponding to the following...Ch. 23.6 - Draw structures corresponding to the following...Ch. 23.6 - Write the products from reaction of the following...Ch. 23.6 - Reaction of Br2/FeBr3 with toluene (methylbenzene)...Ch. 23.7 - Prob. 23.19PCh. 23.8 - Draw structures corresponding to the following...Ch. 23.8 - Prob. 23.21PCh. 23.8 - Prob. 23.22CPCh. 23.10 - Prob. 23.23PCh. 23.10 - Prob. 23.24PCh. 23.10 - Prob. 23.25PCh. 23.11 - Prob. 23.26PCh. 23.12 - Show the structure of glyceryl trioleate, a fat...Ch. 23.13 - Prob. 23.28PCh. 23.13 - Prob. 23.29PCh. 23.13 - Prob. 23.30PCh. 23.13 - Prob. 23.31CPCh. 23.13 - Prob. 23.32PCh. 23 - Prob. 23.33CPCh. 23 - Prob. 23.34CPCh. 23 - Prob. 23.35CPCh. 23 - Prob. 23.36CPCh. 23 - Prob. 23.37CPCh. 23 - Prob. 23.38CPCh. 23 - Prob. 23.39CPCh. 23 - Prob. 23.40SPCh. 23 - Prob. 23.41SPCh. 23 - Prob. 23.42SPCh. 23 - Prob. 23.43SPCh. 23 - Prob. 23.44SPCh. 23 - Prob. 23.45SPCh. 23 - Prob. 23.46SPCh. 23 - Prob. 23.47SPCh. 23 - Prob. 23.48SPCh. 23 - What is wrong with each of the following...Ch. 23 - What are the IUPAC names of the following alkanes?Ch. 23 - Prob. 23.51SPCh. 23 - Prob. 23.52SPCh. 23 - Prob. 23.53SPCh. 23 - Prob. 23.54SPCh. 23 - Prob. 23.55SPCh. 23 - Prob. 23.56SPCh. 23 - Prob. 23.57SPCh. 23 - Prob. 23.58SPCh. 23 - Prob. 23.59SPCh. 23 - Prob. 23.60SPCh. 23 - Prob. 23.61SPCh. 23 - Prob. 23.62SPCh. 23 - Prob. 23.63SPCh. 23 - Draw structures corresponding to the following (a)...Ch. 23 - Prob. 23.65SPCh. 23 - Prob. 23.66SPCh. 23 - Prob. 23.67SPCh. 23 - Prob. 23.68SPCh. 23 - Draw and name compounds that meet the following...Ch. 23 - Prob. 23.70SPCh. 23 - Prob. 23.71SPCh. 23 - Prob. 23.72SPCh. 23 - Prob. 23.73SPCh. 23 - Prob. 23.74SPCh. 23 - Prob. 23.75SPCh. 23 - Prob. 23.76SPCh. 23 - Prob. 23.77SPCh. 23 - Prob. 23.78SPCh. 23 - Prob. 23.79SPCh. 23 - Prob. 23.80SPCh. 23 - Prob. 23.81SPCh. 23 - Prob. 23.82SPCh. 23 - Prob. 23.83SPCh. 23 - Prob. 23.84SPCh. 23 - Prob. 23.85SPCh. 23 - Prob. 23.86SPCh. 23 - Prob. 23.87SPCh. 23 - There are two isomeric fat molecules whose...Ch. 23 - Prob. 23.89SPCh. 23 - What is a nucleotide, and what three kinds of...Ch. 23 - What are the names of the sugars in DNA and RNA,...Ch. 23 - Prob. 23.92SPCh. 23 - Prob. 23.93SPCh. 23 - Prob. 23.94SPCh. 23 - Prob. 23.95SPCh. 23 - Prob. 23.96SPCh. 23 - Prob. 23.97SPCh. 23 - Prob. 23.98CHPCh. 23 - Prob. 23.99CHPCh. 23 - Prob. 23.100CHPCh. 23 - Prob. 23.101CHPCh. 23 - Write full structures for the following peptides,...Ch. 23 - Prob. 23.103CHPCh. 23 - Prob. 23.104CHPCh. 23 - Prob. 23.105CHPCh. 23 - Prob. 23.106CHPCh. 23 - Elaidic acid, a component of so-called trans fats,...Ch. 23 - Fumaric acid is an organic substance widely used...
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