The structure corresponding to the given IUPAC name 3-Methylpentanamide has to be determined. Concept introduction: In chemistry Structure is the arrangement of chemical bonds between atoms in a molecule. Amide is an organic compound in which a carbonyl group C = O bonded to a nitrogen atom. There are primary, secondary and tertiary amides and this classification is based on the number of carbon atoms bonded to the nitrogen atom. Primary amides can be named in the IUPAC system in several ways, For simple amides the suffix – amide is added to the name of the alkyl substituent. The suffix- amide can be used in place of the final –e in the name of the parent compound. For secondary amides an N prefixes the compound giving the shorter carbon chain and its chain prefix name. For tertiary amides an N, N prefixes the compound giving the two shorter carbon chains and their side chain prefix names.

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Answer 1

Question

Chapter 23, Problem 23.71SP

(a)

Interpretation Introduction

Interpretation: The structure corresponding to the given IUPAC name 3-Methylpentanamide has to be determined.

Concept introduction:

In chemistry Structure is the arrangement of chemical bonds between atoms in a molecule.

Amide is an organic compound in which a carbonyl group C=O bonded to a nitrogen atom.

There are primary, secondary and tertiary amides and this classification is based on the number of carbon atoms bonded to the nitrogen atom.

Primary amides can be named in the IUPAC system in several ways,

For simple amides the suffix – amide is added to the name of the alkyl substituent.

The suffix- amide can be used in place of the final –e in the name of the parent compound.

For secondary amides an N prefixes the compound giving the shorter carbon chain and its chain prefix name.

For tertiary amides an N, N prefixes the compound giving the two shorter carbon chains and their side chain prefix names.

(b)

Interpretation Introduction

Interpretation: The structure corresponding to the given IUPAC name N-Phenylacetamide has to be determined.

Concept introduction:

In chemistry Structure is the arrangement of chemical bonds between atoms in a molecule, specifically which atoms are chemically bonded to what other atoms with what kind of chemical bond.

Amide is an organic compound in which a carbonyl group C=O bonded to a nitrogen atom.

There are primary, secondary and tertiary amides and this classification is based on the number of carbon atoms bonded to the nitrogen atom.

Primary amides can be named in the IUPAC system in several ways,

For simple amides the suffix – amide is added to the name of the alkyl substituent.

The suffix- amide can be used in place of the final –e in the name of the parent compound.

For secondary amides an N prefixes the compound giving the shorter carbon chain and its chain prefix name.

For tertiary amides an N, N prefixes the compound giving the two shorter carbon chains and their side chain prefix names.

(c)

Interpretation Introduction

Interpretation: The structure corresponding to the given IUPAC name N-Ethyl-N-methylbenzamide has to be determined.

Concept introduction:

In chemistry Structure is the arrangement of chemical bonds between atoms in a molecule, specifically which atoms are chemically bonded to what other atoms with what kind of chemical bond.

Amide is an organic compound in which a carbonyl group C=O bonded to a nitrogen atom.

There are primary, secondary and tertiary amides and this classification is based on the number of carbon atoms bonded to the nitrogen atom.

Benzamide is an aromatic amide and its structure is,

Primary amides can be named in the IUPAC system in several ways,

For simple amides the suffix – amide is added to the name of the alkyl substituent.

The suffix- amide can be used in place of the final –e in the name of the parent compound.

For secondary amides an N prefixes the compound giving the shorter carbon chain and its chain prefix name.

For tertiary amides an N, N prefixes the compound giving the two shorter carbon chains and their side chain prefix names.

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How many signals do you expect in the H NMR spectrum for this molecule? Br Br Write the answer below. Also, in each of the drawing areas below is a copy of the molecule, with Hs shown. In each copy, one of the H atoms is colored red. Highlight in red all other H atoms that would contribute to the same signal as the H already highlighted red. Note for advanced students: In this question, any multiplet is counted as one signal. Number of signals in the 'H NMR spectrum. For the molecule in the top drawing area, highlight in red any other H atoms that will contribute to the same signal as the H atom already highlighted red. If no other H atoms will contribute, check the box at right. No additional Hs to color in top molecule For the molecule in the bottom drawing area, highlight in red any other H atoms that will contribute to the same signal as the H atom already highlighted red. If no other H atoms will contribute, check the box at right. No additional Hs to color in bottom molecule

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Answer 2

Question

Chapter 23, Problem 23.71SP

(a)

Interpretation Introduction

Interpretation: The structure corresponding to the given IUPAC name 3-Methylpentanamide has to be determined.

Concept introduction:

In chemistry Structure is the arrangement of chemical bonds between atoms in a molecule.

Amide is an organic compound in which a carbonyl group C=O bonded to a nitrogen atom.

There are primary, secondary and tertiary amides and this classification is based on the number of carbon atoms bonded to the nitrogen atom.

Primary amides can be named in the IUPAC system in several ways,

For simple amides the suffix – amide is added to the name of the alkyl substituent.

The suffix- amide can be used in place of the final –e in the name of the parent compound.

For secondary amides an N prefixes the compound giving the shorter carbon chain and its chain prefix name.

For tertiary amides an N, N prefixes the compound giving the two shorter carbon chains and their side chain prefix names.

(b)

Interpretation Introduction

Interpretation: The structure corresponding to the given IUPAC name N-Phenylacetamide has to be determined.

Concept introduction:

In chemistry Structure is the arrangement of chemical bonds between atoms in a molecule, specifically which atoms are chemically bonded to what other atoms with what kind of chemical bond.

Amide is an organic compound in which a carbonyl group C=O bonded to a nitrogen atom.

There are primary, secondary and tertiary amides and this classification is based on the number of carbon atoms bonded to the nitrogen atom.

Primary amides can be named in the IUPAC system in several ways,

For simple amides the suffix – amide is added to the name of the alkyl substituent.

The suffix- amide can be used in place of the final –e in the name of the parent compound.

For secondary amides an N prefixes the compound giving the shorter carbon chain and its chain prefix name.

For tertiary amides an N, N prefixes the compound giving the two shorter carbon chains and their side chain prefix names.

(c)

Interpretation Introduction

Interpretation: The structure corresponding to the given IUPAC name N-Ethyl-N-methylbenzamide has to be determined.

Concept introduction:

In chemistry Structure is the arrangement of chemical bonds between atoms in a molecule, specifically which atoms are chemically bonded to what other atoms with what kind of chemical bond.

Amide is an organic compound in which a carbonyl group C=O bonded to a nitrogen atom.

There are primary, secondary and tertiary amides and this classification is based on the number of carbon atoms bonded to the nitrogen atom.

Benzamide is an aromatic amide and its structure is,

Primary amides can be named in the IUPAC system in several ways,

For simple amides the suffix – amide is added to the name of the alkyl substituent.

The suffix- amide can be used in place of the final –e in the name of the parent compound.

For secondary amides an N prefixes the compound giving the shorter carbon chain and its chain prefix name.

For tertiary amides an N, N prefixes the compound giving the two shorter carbon chains and their side chain prefix names.

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Answer 3

Question

Chapter 23, Problem 23.71SP

(a)

Interpretation Introduction

Interpretation: The structure corresponding to the given IUPAC name 3-Methylpentanamide has to be determined.

Concept introduction:

In chemistry Structure is the arrangement of chemical bonds between atoms in a molecule.

Amide is an organic compound in which a carbonyl group C=O bonded to a nitrogen atom.

There are primary, secondary and tertiary amides and this classification is based on the number of carbon atoms bonded to the nitrogen atom.

Primary amides can be named in the IUPAC system in several ways,

For simple amides the suffix – amide is added to the name of the alkyl substituent.

The suffix- amide can be used in place of the final –e in the name of the parent compound.

For secondary amides an N prefixes the compound giving the shorter carbon chain and its chain prefix name.

For tertiary amides an N, N prefixes the compound giving the two shorter carbon chains and their side chain prefix names.

(b)

Interpretation Introduction

Interpretation: The structure corresponding to the given IUPAC name N-Phenylacetamide has to be determined.

Concept introduction:

In chemistry Structure is the arrangement of chemical bonds between atoms in a molecule, specifically which atoms are chemically bonded to what other atoms with what kind of chemical bond.

Amide is an organic compound in which a carbonyl group C=O bonded to a nitrogen atom.

There are primary, secondary and tertiary amides and this classification is based on the number of carbon atoms bonded to the nitrogen atom.

Primary amides can be named in the IUPAC system in several ways,

For simple amides the suffix – amide is added to the name of the alkyl substituent.

The suffix- amide can be used in place of the final –e in the name of the parent compound.

For secondary amides an N prefixes the compound giving the shorter carbon chain and its chain prefix name.

For tertiary amides an N, N prefixes the compound giving the two shorter carbon chains and their side chain prefix names.

(c)

Interpretation Introduction

Interpretation: The structure corresponding to the given IUPAC name N-Ethyl-N-methylbenzamide has to be determined.

Concept introduction:

In chemistry Structure is the arrangement of chemical bonds between atoms in a molecule, specifically which atoms are chemically bonded to what other atoms with what kind of chemical bond.

Amide is an organic compound in which a carbonyl group C=O bonded to a nitrogen atom.

There are primary, secondary and tertiary amides and this classification is based on the number of carbon atoms bonded to the nitrogen atom.

Benzamide is an aromatic amide and its structure is,

Primary amides can be named in the IUPAC system in several ways,

For simple amides the suffix – amide is added to the name of the alkyl substituent.

The suffix- amide can be used in place of the final –e in the name of the parent compound.

For secondary amides an N prefixes the compound giving the shorter carbon chain and its chain prefix name.

For tertiary amides an N, N prefixes the compound giving the two shorter carbon chains and their side chain prefix names.

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Answer 4

Question

Chapter 23, Problem 23.71SP

(a)

Interpretation Introduction

Interpretation: The structure corresponding to the given IUPAC name 3-Methylpentanamide has to be determined.

Concept introduction:

In chemistry Structure is the arrangement of chemical bonds between atoms in a molecule.

Amide is an organic compound in which a carbonyl group C=O bonded to a nitrogen atom.

There are primary, secondary and tertiary amides and this classification is based on the number of carbon atoms bonded to the nitrogen atom.

Primary amides can be named in the IUPAC system in several ways,

For simple amides the suffix – amide is added to the name of the alkyl substituent.

The suffix- amide can be used in place of the final –e in the name of the parent compound.

For secondary amides an N prefixes the compound giving the shorter carbon chain and its chain prefix name.

For tertiary amides an N, N prefixes the compound giving the two shorter carbon chains and their side chain prefix names.

(b)

Interpretation Introduction

Interpretation: The structure corresponding to the given IUPAC name N-Phenylacetamide has to be determined.

Concept introduction:

In chemistry Structure is the arrangement of chemical bonds between atoms in a molecule, specifically which atoms are chemically bonded to what other atoms with what kind of chemical bond.

Amide is an organic compound in which a carbonyl group C=O bonded to a nitrogen atom.

There are primary, secondary and tertiary amides and this classification is based on the number of carbon atoms bonded to the nitrogen atom.

Primary amides can be named in the IUPAC system in several ways,

For simple amides the suffix – amide is added to the name of the alkyl substituent.

The suffix- amide can be used in place of the final –e in the name of the parent compound.

For secondary amides an N prefixes the compound giving the shorter carbon chain and its chain prefix name.

For tertiary amides an N, N prefixes the compound giving the two shorter carbon chains and their side chain prefix names.

(c)

Interpretation Introduction

Interpretation: The structure corresponding to the given IUPAC name N-Ethyl-N-methylbenzamide has to be determined.

Concept introduction:

In chemistry Structure is the arrangement of chemical bonds between atoms in a molecule, specifically which atoms are chemically bonded to what other atoms with what kind of chemical bond.

Amide is an organic compound in which a carbonyl group C=O bonded to a nitrogen atom.

There are primary, secondary and tertiary amides and this classification is based on the number of carbon atoms bonded to the nitrogen atom.

Benzamide is an aromatic amide and its structure is,

Primary amides can be named in the IUPAC system in several ways,

For simple amides the suffix – amide is added to the name of the alkyl substituent.

The suffix- amide can be used in place of the final –e in the name of the parent compound.

For secondary amides an N prefixes the compound giving the shorter carbon chain and its chain prefix name.

For tertiary amides an N, N prefixes the compound giving the two shorter carbon chains and their side chain prefix names.

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Answer 5

Chapter 23, Problem 23.71SP

(a)

Interpretation Introduction

Interpretation: The structure corresponding to the given IUPAC name 3-Methylpentanamide has to be determined.

Concept introduction:

In chemistry Structure is the arrangement of chemical bonds between atoms in a molecule.

Amide is an organic compound in which a carbonyl group C=O bonded to a nitrogen atom.

There are primary, secondary and tertiary amides and this classification is based on the number of carbon atoms bonded to the nitrogen atom.

Primary amides can be named in the IUPAC system in several ways,

For simple amides the suffix – amide is added to the name of the alkyl substituent.

The suffix- amide can be used in place of the final –e in the name of the parent compound.

For secondary amides an N prefixes the compound giving the shorter carbon chain and its chain prefix name.

For tertiary amides an N, N prefixes the compound giving the two shorter carbon chains and their side chain prefix names.

(b)

Interpretation Introduction

Interpretation: The structure corresponding to the given IUPAC name N-Phenylacetamide has to be determined.

Concept introduction:

In chemistry Structure is the arrangement of chemical bonds between atoms in a molecule, specifically which atoms are chemically bonded to what other atoms with what kind of chemical bond.

Amide is an organic compound in which a carbonyl group C=O bonded to a nitrogen atom.

There are primary, secondary and tertiary amides and this classification is based on the number of carbon atoms bonded to the nitrogen atom.

Primary amides can be named in the IUPAC system in several ways,

For simple amides the suffix – amide is added to the name of the alkyl substituent.

The suffix- amide can be used in place of the final –e in the name of the parent compound.

For secondary amides an N prefixes the compound giving the shorter carbon chain and its chain prefix name.

For tertiary amides an N, N prefixes the compound giving the two shorter carbon chains and their side chain prefix names.

(c)

Interpretation Introduction

Interpretation: The structure corresponding to the given IUPAC name N-Ethyl-N-methylbenzamide has to be determined.

Concept introduction:

In chemistry Structure is the arrangement of chemical bonds between atoms in a molecule, specifically which atoms are chemically bonded to what other atoms with what kind of chemical bond.

Amide is an organic compound in which a carbonyl group C=O bonded to a nitrogen atom.

There are primary, secondary and tertiary amides and this classification is based on the number of carbon atoms bonded to the nitrogen atom.

Benzamide is an aromatic amide and its structure is,

Primary amides can be named in the IUPAC system in several ways,

For simple amides the suffix – amide is added to the name of the alkyl substituent.

The suffix- amide can be used in place of the final –e in the name of the parent compound.

For secondary amides an N prefixes the compound giving the shorter carbon chain and its chain prefix name.

For tertiary amides an N, N prefixes the compound giving the two shorter carbon chains and their side chain prefix names.

Answer 6

Chapter 23, Problem 23.71SP

(a)

Interpretation Introduction

Interpretation: The structure corresponding to the given IUPAC name 3-Methylpentanamide has to be determined.

Concept introduction:

In chemistry Structure is the arrangement of chemical bonds between atoms in a molecule.

Amide is an organic compound in which a carbonyl group C=O bonded to a nitrogen atom.

There are primary, secondary and tertiary amides and this classification is based on the number of carbon atoms bonded to the nitrogen atom.

Primary amides can be named in the IUPAC system in several ways,

For simple amides the suffix – amide is added to the name of the alkyl substituent.

The suffix- amide can be used in place of the final –e in the name of the parent compound.

For secondary amides an N prefixes the compound giving the shorter carbon chain and its chain prefix name.

For tertiary amides an N, N prefixes the compound giving the two shorter carbon chains and their side chain prefix names.

Answer 7

Chapter 23, Problem 23.71SP

(a)

Interpretation Introduction

Interpretation: The structure corresponding to the given IUPAC name 3-Methylpentanamide has to be determined.

Concept introduction:

In chemistry Structure is the arrangement of chemical bonds between atoms in a molecule.

Amide is an organic compound in which a carbonyl group C=O bonded to a nitrogen atom.

There are primary, secondary and tertiary amides and this classification is based on the number of carbon atoms bonded to the nitrogen atom.

Primary amides can be named in the IUPAC system in several ways,

For simple amides the suffix – amide is added to the name of the alkyl substituent.

The suffix- amide can be used in place of the final –e in the name of the parent compound.

For secondary amides an N prefixes the compound giving the shorter carbon chain and its chain prefix name.

For tertiary amides an N, N prefixes the compound giving the two shorter carbon chains and their side chain prefix names.

Answer 8

(b)

Interpretation Introduction

Interpretation: The structure corresponding to the given IUPAC name N-Phenylacetamide has to be determined.

Concept introduction:

In chemistry Structure is the arrangement of chemical bonds between atoms in a molecule, specifically which atoms are chemically bonded to what other atoms with what kind of chemical bond.

Amide is an organic compound in which a carbonyl group C=O bonded to a nitrogen atom.

There are primary, secondary and tertiary amides and this classification is based on the number of carbon atoms bonded to the nitrogen atom.

Primary amides can be named in the IUPAC system in several ways,

For simple amides the suffix – amide is added to the name of the alkyl substituent.

The suffix- amide can be used in place of the final –e in the name of the parent compound.

For secondary amides an N prefixes the compound giving the shorter carbon chain and its chain prefix name.

For tertiary amides an N, N prefixes the compound giving the two shorter carbon chains and their side chain prefix names.

Answer 9

(b)

Interpretation Introduction

Interpretation: The structure corresponding to the given IUPAC name N-Phenylacetamide has to be determined.

Concept introduction:

In chemistry Structure is the arrangement of chemical bonds between atoms in a molecule, specifically which atoms are chemically bonded to what other atoms with what kind of chemical bond.

Amide is an organic compound in which a carbonyl group C=O bonded to a nitrogen atom.

There are primary, secondary and tertiary amides and this classification is based on the number of carbon atoms bonded to the nitrogen atom.

Primary amides can be named in the IUPAC system in several ways,

For simple amides the suffix – amide is added to the name of the alkyl substituent.

The suffix- amide can be used in place of the final –e in the name of the parent compound.

For secondary amides an N prefixes the compound giving the shorter carbon chain and its chain prefix name.

For tertiary amides an N, N prefixes the compound giving the two shorter carbon chains and their side chain prefix names.

Answer 10

(c)

Interpretation Introduction

Interpretation: The structure corresponding to the given IUPAC name N-Ethyl-N-methylbenzamide has to be determined.

Concept introduction:

In chemistry Structure is the arrangement of chemical bonds between atoms in a molecule, specifically which atoms are chemically bonded to what other atoms with what kind of chemical bond.

Amide is an organic compound in which a carbonyl group C=O bonded to a nitrogen atom.

There are primary, secondary and tertiary amides and this classification is based on the number of carbon atoms bonded to the nitrogen atom.

Benzamide is an aromatic amide and its structure is,

Primary amides can be named in the IUPAC system in several ways,

For simple amides the suffix – amide is added to the name of the alkyl substituent.

The suffix- amide can be used in place of the final –e in the name of the parent compound.

For secondary amides an N prefixes the compound giving the shorter carbon chain and its chain prefix name.

For tertiary amides an N, N prefixes the compound giving the two shorter carbon chains and their side chain prefix names.

Answer 11

(c)

Interpretation Introduction

Interpretation: The structure corresponding to the given IUPAC name N-Ethyl-N-methylbenzamide has to be determined.

Concept introduction:

In chemistry Structure is the arrangement of chemical bonds between atoms in a molecule, specifically which atoms are chemically bonded to what other atoms with what kind of chemical bond.

Amide is an organic compound in which a carbonyl group C=O bonded to a nitrogen atom.

There are primary, secondary and tertiary amides and this classification is based on the number of carbon atoms bonded to the nitrogen atom.

Benzamide is an aromatic amide and its structure is,

Primary amides can be named in the IUPAC system in several ways,

For simple amides the suffix – amide is added to the name of the alkyl substituent.

The suffix- amide can be used in place of the final –e in the name of the parent compound.

For secondary amides an N prefixes the compound giving the shorter carbon chain and its chain prefix name.

For tertiary amides an N, N prefixes the compound giving the two shorter carbon chains and their side chain prefix names.

Answer 12

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Answer 13

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Answer 14

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Answer 15

Ch. 23.1 - Prob. 23.1P Ch. 23.1 - Prob. 23.2P Ch. 23.1 - Prob. 23.3P Ch. 23.1 - Prob. 23.4CP Ch. 23.2 - Prob. 23.5P Ch. 23.2 - Prob. 23.6P Ch. 23.3 - Prob. 23.7P Ch. 23.3 - Prob. 23.8P Ch. 23.3 - Prob. 23.9CP Ch. 23.4 - Prob. 23.10P

Solution Summary: The author explains the structure of the compound with the IUPAC name 3-Methylpentanamide.

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Chapter 23 Solutions