
Organic And Biological Chemistry
7th Edition
ISBN: 9781305081079
Author: STOKER, H. Stephen (howard Stephen)
Publisher: Cengage Learning,
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Chapter 14.4, Problem 6QQ
Interpretation Introduction
Interpretation:
The number of turns of the
Concept Introduction:
The
Unsaturated fatty acids have one or more double/triple bonds between carbon atoms in the hydrocarbon chain. These acids are common components of dietary triacylglycerols.
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Consider the reaction below to answer the following questions:
847
Acetoacetic ester can be prepared by the Claisen self-condensation reaction of ethyl acetate.
H₁C
0
H
0
IL
유
||
OCH2CH3
1. NaOEt, EtOH C
2. H₂O
H3C
CH₂
Cold not tobizmo. S
OCH2CH3
A. Write the complete stepwise mechanism for this reaction. Show all electron flow with arrows and
draw all intermediate structures.
B. Ethyl acetate can be prepared from ethanol as the only organic starting material. Show all reagents
and structures for all intermediates in this preparation.
C. Give the structures of the ester precursors for the following Claisen condensation product and
formulate the reaction.
ou
OEL
A.
What is the correct structure for a-D-glucopyranose?
CH₂OH
a
HO
HO-
OH
b
HO
HO-
OH
HOH₂C
OH
OH
OH
CH₂OH
HO
C.
HO
HO-
OH
OH
CH₂OH
OH
OH
B. Draw structures for the products you would expect to obtain from reaction of B-D-galactopyranose
with each of the following reagents. Be sure to include all relevant stereochemistry. [FOUR only]
A. CH, Ag₂O
B. warm dilute HNO3
C. (CH3CO)20, pryridine
D. NaBH in H₂O
E. CH₂OH, HCI
F. Br₂, H₂O
HO
CH₂OH
HO-
OH
OH
B-D-galactopyranose
Give the major organic product(s) for each of the following reactions or reaction sequences.
CH₂CN
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سجد سی . بلی
H
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OCH3
2 H₂O*
Chapter 14 Solutions
Organic And Biological Chemistry
Ch. 14.1 - Which of the following statements about digestion...Ch. 14.1 - Prob. 2QQCh. 14.1 - The major function of bile released during...Ch. 14.1 - The two major products of triacylglycerol...Ch. 14.1 - Prob. 5QQCh. 14.2 - Hormone-sensitive lipase needed for...Ch. 14.2 - Prob. 2QQCh. 14.2 - Which of the following is not a product of...Ch. 14.3 - Prob. 1QQCh. 14.3 - What is the intermediate compound in the two-step...
Ch. 14.3 - Prob. 3QQCh. 14.4 - In the oxidation of fatty acids, what two...Ch. 14.4 - Prob. 2QQCh. 14.4 - Prob. 3QQCh. 14.4 - Prob. 4QQCh. 14.4 - Prob. 5QQCh. 14.4 - Prob. 6QQCh. 14.5 - Prob. 1QQCh. 14.5 - Prob. 2QQCh. 14.5 - Prob. 3QQCh. 14.6 - Prob. 1QQCh. 14.6 - Prob. 2QQCh. 14.6 - Prob. 3QQCh. 14.6 - Prob. 4QQCh. 14.6 - Prob. 5QQCh. 14.6 - Prob. 6QQCh. 14.7 - The process of lipogenesis occurs in the a....Ch. 14.7 - Prob. 2QQCh. 14.7 - Prob. 3QQCh. 14.7 - Prob. 4QQCh. 14.7 - The reducing agent needed in the process of...Ch. 14.7 - Prob. 6QQCh. 14.8 - Prob. 1QQCh. 14.8 - Prob. 2QQCh. 14.9 - Prob. 1QQCh. 14.9 - Prob. 2QQCh. 14.9 - Prob. 3QQCh. 14.9 - Prob. 4QQCh. 14.10 - Which of the following substances cannot be...Ch. 14.10 - Prob. 2QQCh. 14.10 - Prob. 3QQCh. 14.11 - Prob. 1QQCh. 14.11 - Which of the following B-vitamin-containing...Ch. 14.11 - Prob. 3QQCh. 14 - Indicate whether each of the following aspects of...Ch. 14 - Indicate whether each of the following aspects of...Ch. 14 - Prob. 14.3EPCh. 14 - Prob. 14.4EPCh. 14 - Indicate whether each of the following statements...Ch. 14 - Prob. 14.6EPCh. 14 - Prob. 14.7EPCh. 14 - Prob. 14.8EPCh. 14 - Prob. 14.9EPCh. 14 - Prob. 14.10EPCh. 14 - At what location are free fatty acids and...Ch. 14 - Prob. 14.12EPCh. 14 - Prob. 14.13EPCh. 14 - What is the major metabolic function of adipose...Ch. 14 - What is triacylglycerol mobilization?Ch. 14 - Prob. 14.16EPCh. 14 - Prob. 14.17EPCh. 14 - Triacylglycerols in adipose tissue do not enter...Ch. 14 - In which step of glycerol metabolism does each of...Ch. 14 - Prob. 14.20EPCh. 14 - Prob. 14.21EPCh. 14 - How does the structure of dihydroxyacetone...Ch. 14 - Prob. 14.23EPCh. 14 - Prob. 14.24EPCh. 14 - Prob. 14.25EPCh. 14 - Prob. 14.26EPCh. 14 - Prob. 14.27EPCh. 14 - Identify the oxidizing agent needed in Step 3 of a...Ch. 14 - Prob. 14.29EPCh. 14 - Prob. 14.30EPCh. 14 - Prob. 14.31EPCh. 14 - Prob. 14.32EPCh. 14 - Prob. 14.33EPCh. 14 - Prob. 14.34EPCh. 14 - Prob. 14.35EPCh. 14 - Prob. 14.36EPCh. 14 - Prob. 14.37EPCh. 14 - Prob. 14.38EPCh. 14 - Prob. 14.39EPCh. 14 - Prob. 14.40EPCh. 14 - Prob. 14.41EPCh. 14 - Prob. 14.42EPCh. 14 - How many turns of the -oxidation pathway would be...Ch. 14 - How many turns of the -oxidation pathway would be...Ch. 14 - Prob. 14.45EPCh. 14 - Prob. 14.46EPCh. 14 - Prob. 14.47EPCh. 14 - Prob. 14.48EPCh. 14 - Prob. 14.49EPCh. 14 - Prob. 14.50EPCh. 14 - Prob. 14.51EPCh. 14 - Prob. 14.52EPCh. 14 - Prob. 14.53EPCh. 14 - Prob. 14.54EPCh. 14 - Prob. 14.55EPCh. 14 - Prob. 14.56EPCh. 14 - Prob. 14.57EPCh. 14 - Which yield more NADH, saturated or unsaturated...Ch. 14 - Prob. 14.59EPCh. 14 - Prob. 14.60EPCh. 14 - Prob. 14.61EPCh. 14 - Why does a deficiency of carbohydrates in the diet...Ch. 14 - Prob. 14.63EPCh. 14 - Prob. 14.64EPCh. 14 - Prob. 14.65EPCh. 14 - Prob. 14.66EPCh. 14 - Prob. 14.67EPCh. 14 - Prob. 14.68EPCh. 14 - Prob. 14.69EPCh. 14 - Prob. 14.70EPCh. 14 - Prob. 14.71EPCh. 14 - Prob. 14.72EPCh. 14 - Prob. 14.73EPCh. 14 - Prob. 14.74EPCh. 14 - Prob. 14.75EPCh. 14 - Severe ketosis situations produce acidosis....Ch. 14 - Prob. 14.77EPCh. 14 - Prob. 14.78EPCh. 14 - Prob. 14.79EPCh. 14 - Prob. 14.80EPCh. 14 - Prob. 14.81EPCh. 14 - Prob. 14.82EPCh. 14 - Prob. 14.83EPCh. 14 - Prob. 14.84EPCh. 14 - Prob. 14.85EPCh. 14 - Prob. 14.86EPCh. 14 - Prob. 14.87EPCh. 14 - Prob. 14.88EPCh. 14 - Prob. 14.89EPCh. 14 - Prob. 14.90EPCh. 14 - Prob. 14.91EPCh. 14 - Prob. 14.92EPCh. 14 - Prob. 14.93EPCh. 14 - Prob. 14.94EPCh. 14 - What role does molecular oxygen, O2, play in fatty...Ch. 14 - Prob. 14.96EPCh. 14 - Prob. 14.97EPCh. 14 - Prob. 14.98EPCh. 14 - Prob. 14.99EPCh. 14 - Prob. 14.100EPCh. 14 - Prob. 14.101EPCh. 14 - Prob. 14.102EPCh. 14 - Prob. 14.103EPCh. 14 - Prob. 14.104EPCh. 14 - Prob. 14.105EPCh. 14 - Prob. 14.106EPCh. 14 - Prob. 14.107EPCh. 14 - Prob. 14.108EPCh. 14 - Prob. 14.109EPCh. 14 - Prob. 14.110EPCh. 14 - Prob. 14.111EPCh. 14 - Prob. 14.112EPCh. 14 - Prob. 14.113EPCh. 14 - Prob. 14.114EP
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