Chemistry: Principles and Practice
3rd Edition
ISBN: 9780534420123
Author: Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer
Publisher: Cengage Learning
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Chapter 9, Problem 9.99QE
The molecule nitrosyl chloride, NOCl, has a skeleton structure of O–N–Cl. Two resonance forms can be written; write them both. Use the formal charge stability rules to predict which form is more stable.
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The carbonate anion, CO32- , is a resonance hybrid. Draw all of the important resonance structures for this molecule. If an atom has a nonzero formal charge, be sure the formal charge is shown clearly in the structure. Use the resonance structures to calculate the average formal charge on each O atom (which are all equivalent in the "true" structure). [Note: all of the important contributing resonance structures have octets around each atom that desires an octet.]
When gaseous sulfur trioxide is dissolved in concentratedsulfuric acid, disulfuric acid forms:SO₃(g)+ H₂SO₄(l) →H₂S₂O₇(l) Use bond energies Table to determine ΔH°ᵣₓₙ. (The S atoms in H₂S₂O₇ are bonded through an O atom. Assume Lewis structures with zero formal charges; BE of SNO is 552 kJ/mol.)
There are several possible Lewis structures for the molecule N2O as shown below.
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For Structure A what are the formal charges on atoms:1 , 2 , and 3 ?For Structure B what are the formal charges on atoms:1 , 2 , and 3 ?For Structure C what are the formal charges on atoms:1 , 2 , and 3 ?Compare the formal charges that you calculated for each structure.What is the letter of the BEST Lewis structure for N2O?
Chapter 9 Solutions
Chemistry: Principles and Practice
Ch. 9 - Prob. 9.1QECh. 9 - Prob. 9.2QECh. 9 - Prob. 9.3QECh. 9 - What main factors control the magnitude of lattice...Ch. 9 - Prob. 9.5QECh. 9 - Prob. 9.6QECh. 9 - Prob. 9.7QECh. 9 - Prob. 9.8QECh. 9 - Prob. 9.9QECh. 9 - Prob. 9.10QE
Ch. 9 - Prob. 9.11QECh. 9 - Prob. 9.12QECh. 9 - Prob. 9.13QECh. 9 - Compare the trends in electronegativity and...Ch. 9 - Prob. 9.15QECh. 9 - Prob. 9.16QECh. 9 - Prob. 9.17QECh. 9 - What elements are most likely to form...Ch. 9 - Prob. 9.19QECh. 9 - Prob. 9.20QECh. 9 - Prob. 9.21QECh. 9 - Prob. 9.22QECh. 9 - Prob. 9.23QECh. 9 - Prob. 9.24QECh. 9 - Prob. 9.25QECh. 9 - Prob. 9.26QECh. 9 - Write the formulas of the ionic compounds that...Ch. 9 - Prob. 9.28QECh. 9 - Prob. 9.29QECh. 9 - Prob. 9.30QECh. 9 - Arrange the following series of compounds in order...Ch. 9 - Prob. 9.32QECh. 9 - Prob. 9.33QECh. 9 - Prob. 9.34QECh. 9 - Prob. 9.35QECh. 9 - Draw Lewis structures for the following species....Ch. 9 - Prob. 9.37QECh. 9 - Prob. 9.38QECh. 9 - Write the Lewis structure for the following...Ch. 9 - Prob. 9.40QECh. 9 - Prob. 9.41QECh. 9 - Draw a Lewis structure for each of the following...Ch. 9 - Write the Lewis structure for each compound, with...Ch. 9 - Prob. 9.44QECh. 9 - Prob. 9.45QECh. 9 - Write the Lewis structure for each species, with...Ch. 9 - Prob. 9.47QECh. 9 - Prob. 9.48QECh. 9 - Prob. 9.49QECh. 9 - Arrange the members of each of the following sets...Ch. 9 - Prob. 9.51QECh. 9 - Prob. 9.52QECh. 9 - Prob. 9.53QECh. 9 - For each pair of bonds, indicate the more polar...Ch. 9 - Which molecule has the most polar bond: N2, BrF,...Ch. 9 - Given the bonds C N, C H, C Br, and S O, (a)...Ch. 9 - Prob. 9.57QECh. 9 - Prob. 9.58QECh. 9 - Write the Lewis structures showing formal charge...Ch. 9 - Write the Lewis structures showing formal charge...Ch. 9 - Prob. 9.61QECh. 9 - The connectivity of HNO could be either HNO or...Ch. 9 - Prob. 9.63QECh. 9 - Prob. 9.64QECh. 9 - Write all possible resonance structures for the...Ch. 9 - Prob. 9.66QECh. 9 - Prob. 9.67QECh. 9 - Prob. 9.68QECh. 9 - Prob. 9.69QECh. 9 - Prob. 9.70QECh. 9 - Write all resonance structures of toluene,...Ch. 9 - Write all resonance structures of chlorobenzene,...Ch. 9 - Draw all resonance structures for...Ch. 9 - Prob. 9.74QECh. 9 - Prob. 9.75QECh. 9 - Prob. 9.76QECh. 9 - Write the Lewis structures for the following...Ch. 9 - Write the Lewis structures for the following...Ch. 9 - Prob. 9.79QECh. 9 - Prob. 9.80QECh. 9 - Prob. 9.81QECh. 9 - Prob. 9.82QECh. 9 - Write the Lewis structures of H2CNH and H3CNH2....Ch. 9 - Write the Lewis structures of HNNH and H2NNH2....Ch. 9 - Prob. 9.85QECh. 9 - Prob. 9.86QECh. 9 - Prob. 9.87QECh. 9 - Prob. 9.88QECh. 9 - Prob. 9.89QECh. 9 - Prob. 9.90QECh. 9 - Prob. 9.91QECh. 9 - Prob. 9.92QECh. 9 - Prob. 9.93QECh. 9 - Prob. 9.94QECh. 9 - Prob. 9.95QECh. 9 - Prob. 9.96QECh. 9 - Prob. 9.97QECh. 9 - Prob. 9.98QECh. 9 - The molecule nitrosyl chloride, NOCl, has a...Ch. 9 - Prob. 9.100QECh. 9 - Draw the Lewis structure of BrNO. Which is the...Ch. 9 - Prob. 9.102QECh. 9 - Calculate an approximate enthalpy change (Table...Ch. 9 - Prob. 9.104QECh. 9 - Prob. 9.105QECh. 9 - Prob. 9.106QECh. 9 - Prob. 9.107QE
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Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Similar questions
- Write all resonance structures of chlorobenzene, C6H5Cl, a molecule with the same cyclic structure as benzene. In all structures, keep the CCl bond as a single bond. Which resonance structures are the most important?arrow_forwardDraw resonance structures for each of these ions: NSO− and SNO−. (The atoms are bonded in the order given in each case, that is, S is the central atom in NSO−.) Use formal charges to determine which ion is likely to be more stable. Explain why the two ions cannot be considered resonance structures of each other.arrow_forwardConsider the pyrosulfate ion, S2O72-. It has no sulfur–sulfur nor oxygen–oxygen bonds. (a) Write a Lewis structure for the pyrosulfate ion using only single bonds. (b) What is the formal charge on the sulfur atoms for the Lewis structure you drew in part (a)? (c) Write another Lewis structure using six bonds and two O—S bonds. (d) What is the formal charge on each atom for the structure you drew in part (c)?arrow_forward
- Given the bonds C N, C H, C Br, and S O, (a) which atom in each is the more electronegative? (b) which of these bonds is the most polar?arrow_forwardBond Enthalpy When atoms of the hypothetical element X are placed together, they rapidly undergo reaction to form the X2 molecule: X(g)+X(g)X2(g) a Would you predict that this reaction is exothermic or endothermic? Explain. b Is the bond enthalpy of X2 a positive or a negative quantity? Why? c Suppose H for the reaction is 500 kJ/mol. Estimate the bond enthalpy of the X2 molecule. d Another hypothetical molecular compound, Y2(g), has a bond enthalpy of 750 kJ/mol, and the molecular compound XY(g) has a bond enthalpy of 1500 kJ/mol. Using bond enthalpy information, calculate H for the following reaction. X2(g)+Y2(g)2XY(g) e Given the following information, as well as the information previously presented, predict whether or not the hypothetical ionic compound AX is likely to form. In this compound, A forms the A+ cation, and X forms the X anion. Be sure to justify your answer. Reaction: A(g)+12X2(g)AX(s)The first ionization energy of A(g) is 400 kJ/mol. The electron affinity of X(g) is 525 kJ/mol. The lattice energy of AX(s) is 100 kJ/mol. f If you predicted that no ionic compound would form from the reaction in Part e, what minimum amount of AX(s) lattice energy might lead to compound formation?arrow_forwardWrite the Lewis structure for nitrosyl fluoride, FNO. Using only a periodic table, identify (a) which is the longer bond. (b) which is the stronger bond. (c) which is the more polar bond.arrow_forward
- Three known isomers exist of N2CO, with the atoms in these sequences: NOCN; ONNC; and ONCN. Write resonance structures for each isomer and use formal charge to predict which isomer is the most stable.arrow_forwardOxygen gas reacts with sulfur tetrafluoride to slowly form sulfur tetrafluoride monoxide gas. Balance the equation for the formation of sulfur tetrafluoride monoxide. chemical reaction: 0,(g) + SF (g) → OSF,(g) Draw the Lewis structure of OSF, where the formal charge is zero on each atom. The sulfur atom is the central atom in the structure, and it is bonded to the oxygen atom and each of the four fluorine atoms. Select Draw Rings More Erase Use the bond energies in the table to estimate the enthalpy of reaction for the formation of sulfur tetrafluoride monoxide. étv Aaarrow_forwardThe cyanate ion (OCN- ) and the fulminate ion (CNO- ) share the same three atoms but have vastly different properties. The cyanate ion is stable, while the fulminate ion is unstable and forms explosive compounds. The resonance structures of the cyanate ion are explored in Example 9.8. Draw Lewis structures for the fulminate ion—including possible resonance forms— and use formal charge to explain why the fulminate ion is less stable (and therefore more reactive) than the cyanate ion.arrow_forward
- Sulfur tetrafluoride reacts slowly with oxygen gas to form sulfur tetrafluoride monoxide. Write a balanced chemical equation for the reaction. In the sulfur tetrafluoride monoxide molecule the O atom and the four F atoms are bonded to a central S atom. Write a Lewis structure for this molecule in which the formal charges of all atoms is zero. Use bond energies to estimate the enthalpy of the above reaction. (S-F bond energy = 327 kJ/mole). Is it endothermic or exothermic? Determine the electron geometry of the molecule and predict two possible molecular geometries. Which of the two molecular geometries in part d is more likely to be observed? Explain.arrow_forwardWrite all resonance structures for NCO− ion. Use formal charges to predict the most stable one (i.e. the one that has the lowest energy configuration) and the least stable. Briefly explain.arrow_forwardCarbon and sulfur form compounds with each other with the formulas CS2 and C3S2. Draw a Lewis structure for each compound that has a formal charge of zero for all atoms in the structure.arrow_forward
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