Chemistry: Principles and Practice
3rd Edition
ISBN: 9780534420123
Author: Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer
Publisher: Cengage Learning
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Chapter 9, Problem 9.12QE
Interpretation Introduction
Interpretation:
The polar bond has to be described. Also, the circumstances under which the polar bond formed have to be determined.
Concept Introduction:
The
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Are there any alternative methods better than the MOHR titration to quantitatively determine salt in a sample?
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Using reaction free energy to predict equilibrium composition
Consider the following equilibrium:
2NO2 (g) = N2O4(g)
AGº = -5.4 kJ
Now suppose a reaction vessel is filled with 4.53 atm of dinitrogen tetroxide (N2O4) at 279. °C. Answer the following questions about this system:
Under these conditions, will the pressure of N2O4 tend to rise or fall?
Is it possible to reverse this tendency by adding NO2?
In other words, if you said the pressure of N2O4 will tend to rise, can that
be changed to a tendency to fall by adding NO2? Similarly, if you said the
pressure of N2O4 will tend to fall, can that be changed to a tendency to
'2'
rise by adding NO2?
If you said the tendency can be reversed in the second question, calculate
the minimum pressure of NO 2 needed to reverse it.
Round your answer to 2 significant digits.
00
rise
☐ x10
fall
yes
no
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1
Chapter 9 Solutions
Chemistry: Principles and Practice
Ch. 9 - Prob. 9.1QECh. 9 - Prob. 9.2QECh. 9 - Prob. 9.3QECh. 9 - What main factors control the magnitude of lattice...Ch. 9 - Prob. 9.5QECh. 9 - Prob. 9.6QECh. 9 - Prob. 9.7QECh. 9 - Prob. 9.8QECh. 9 - Prob. 9.9QECh. 9 - Prob. 9.10QE
Ch. 9 - Prob. 9.11QECh. 9 - Prob. 9.12QECh. 9 - Prob. 9.13QECh. 9 - Compare the trends in electronegativity and...Ch. 9 - Prob. 9.15QECh. 9 - Prob. 9.16QECh. 9 - Prob. 9.17QECh. 9 - What elements are most likely to form...Ch. 9 - Prob. 9.19QECh. 9 - Prob. 9.20QECh. 9 - Prob. 9.21QECh. 9 - Prob. 9.22QECh. 9 - Prob. 9.23QECh. 9 - Prob. 9.24QECh. 9 - Prob. 9.25QECh. 9 - Prob. 9.26QECh. 9 - Write the formulas of the ionic compounds that...Ch. 9 - Prob. 9.28QECh. 9 - Prob. 9.29QECh. 9 - Prob. 9.30QECh. 9 - Arrange the following series of compounds in order...Ch. 9 - Prob. 9.32QECh. 9 - Prob. 9.33QECh. 9 - Prob. 9.34QECh. 9 - Prob. 9.35QECh. 9 - Draw Lewis structures for the following species....Ch. 9 - Prob. 9.37QECh. 9 - Prob. 9.38QECh. 9 - Write the Lewis structure for the following...Ch. 9 - Prob. 9.40QECh. 9 - Prob. 9.41QECh. 9 - Draw a Lewis structure for each of the following...Ch. 9 - Write the Lewis structure for each compound, with...Ch. 9 - Prob. 9.44QECh. 9 - Prob. 9.45QECh. 9 - Write the Lewis structure for each species, with...Ch. 9 - Prob. 9.47QECh. 9 - Prob. 9.48QECh. 9 - Prob. 9.49QECh. 9 - Arrange the members of each of the following sets...Ch. 9 - Prob. 9.51QECh. 9 - Prob. 9.52QECh. 9 - Prob. 9.53QECh. 9 - For each pair of bonds, indicate the more polar...Ch. 9 - Which molecule has the most polar bond: N2, BrF,...Ch. 9 - Given the bonds C N, C H, C Br, and S O, (a)...Ch. 9 - Prob. 9.57QECh. 9 - Prob. 9.58QECh. 9 - Write the Lewis structures showing formal charge...Ch. 9 - Write the Lewis structures showing formal charge...Ch. 9 - Prob. 9.61QECh. 9 - The connectivity of HNO could be either HNO or...Ch. 9 - Prob. 9.63QECh. 9 - Prob. 9.64QECh. 9 - Write all possible resonance structures for the...Ch. 9 - Prob. 9.66QECh. 9 - Prob. 9.67QECh. 9 - Prob. 9.68QECh. 9 - Prob. 9.69QECh. 9 - Prob. 9.70QECh. 9 - Write all resonance structures of toluene,...Ch. 9 - Write all resonance structures of chlorobenzene,...Ch. 9 - Draw all resonance structures for...Ch. 9 - Prob. 9.74QECh. 9 - Prob. 9.75QECh. 9 - Prob. 9.76QECh. 9 - Write the Lewis structures for the following...Ch. 9 - Write the Lewis structures for the following...Ch. 9 - Prob. 9.79QECh. 9 - Prob. 9.80QECh. 9 - Prob. 9.81QECh. 9 - Prob. 9.82QECh. 9 - Write the Lewis structures of H2CNH and H3CNH2....Ch. 9 - Write the Lewis structures of HNNH and H2NNH2....Ch. 9 - Prob. 9.85QECh. 9 - Prob. 9.86QECh. 9 - Prob. 9.87QECh. 9 - Prob. 9.88QECh. 9 - Prob. 9.89QECh. 9 - Prob. 9.90QECh. 9 - Prob. 9.91QECh. 9 - Prob. 9.92QECh. 9 - Prob. 9.93QECh. 9 - Prob. 9.94QECh. 9 - Prob. 9.95QECh. 9 - Prob. 9.96QECh. 9 - Prob. 9.97QECh. 9 - Prob. 9.98QECh. 9 - The molecule nitrosyl chloride, NOCl, has a...Ch. 9 - Prob. 9.100QECh. 9 - Draw the Lewis structure of BrNO. Which is the...Ch. 9 - Prob. 9.102QECh. 9 - Calculate an approximate enthalpy change (Table...Ch. 9 - Prob. 9.104QECh. 9 - Prob. 9.105QECh. 9 - Prob. 9.106QECh. 9 - Prob. 9.107QE
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