Chemistry: Principles and Practice
3rd Edition
ISBN: 9780534420123
Author: Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer
Publisher: Cengage Learning
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Chapter 9, Problem 9.21QE
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Chapter 9 Solutions
Chemistry: Principles and Practice
Ch. 9 - Prob. 9.1QECh. 9 - Prob. 9.2QECh. 9 - Prob. 9.3QECh. 9 - What main factors control the magnitude of lattice...Ch. 9 - Prob. 9.5QECh. 9 - Prob. 9.6QECh. 9 - Prob. 9.7QECh. 9 - Prob. 9.8QECh. 9 - Prob. 9.9QECh. 9 - Prob. 9.10QE
Ch. 9 - Prob. 9.11QECh. 9 - Prob. 9.12QECh. 9 - Prob. 9.13QECh. 9 - Compare the trends in electronegativity and...Ch. 9 - Prob. 9.15QECh. 9 - Prob. 9.16QECh. 9 - Prob. 9.17QECh. 9 - What elements are most likely to form...Ch. 9 - Prob. 9.19QECh. 9 - Prob. 9.20QECh. 9 - Prob. 9.21QECh. 9 - Prob. 9.22QECh. 9 - Prob. 9.23QECh. 9 - Prob. 9.24QECh. 9 - Prob. 9.25QECh. 9 - Prob. 9.26QECh. 9 - Write the formulas of the ionic compounds that...Ch. 9 - Prob. 9.28QECh. 9 - Prob. 9.29QECh. 9 - Prob. 9.30QECh. 9 - Arrange the following series of compounds in order...Ch. 9 - Prob. 9.32QECh. 9 - Prob. 9.33QECh. 9 - Prob. 9.34QECh. 9 - Prob. 9.35QECh. 9 - Draw Lewis structures for the following species....Ch. 9 - Prob. 9.37QECh. 9 - Prob. 9.38QECh. 9 - Write the Lewis structure for the following...Ch. 9 - Prob. 9.40QECh. 9 - Prob. 9.41QECh. 9 - Draw a Lewis structure for each of the following...Ch. 9 - Write the Lewis structure for each compound, with...Ch. 9 - Prob. 9.44QECh. 9 - Prob. 9.45QECh. 9 - Write the Lewis structure for each species, with...Ch. 9 - Prob. 9.47QECh. 9 - Prob. 9.48QECh. 9 - Prob. 9.49QECh. 9 - Arrange the members of each of the following sets...Ch. 9 - Prob. 9.51QECh. 9 - Prob. 9.52QECh. 9 - Prob. 9.53QECh. 9 - For each pair of bonds, indicate the more polar...Ch. 9 - Which molecule has the most polar bond: N2, BrF,...Ch. 9 - Given the bonds C N, C H, C Br, and S O, (a)...Ch. 9 - Prob. 9.57QECh. 9 - Prob. 9.58QECh. 9 - Write the Lewis structures showing formal charge...Ch. 9 - Write the Lewis structures showing formal charge...Ch. 9 - Prob. 9.61QECh. 9 - The connectivity of HNO could be either HNO or...Ch. 9 - Prob. 9.63QECh. 9 - Prob. 9.64QECh. 9 - Write all possible resonance structures for the...Ch. 9 - Prob. 9.66QECh. 9 - Prob. 9.67QECh. 9 - Prob. 9.68QECh. 9 - Prob. 9.69QECh. 9 - Prob. 9.70QECh. 9 - Write all resonance structures of toluene,...Ch. 9 - Write all resonance structures of chlorobenzene,...Ch. 9 - Draw all resonance structures for...Ch. 9 - Prob. 9.74QECh. 9 - Prob. 9.75QECh. 9 - Prob. 9.76QECh. 9 - Write the Lewis structures for the following...Ch. 9 - Write the Lewis structures for the following...Ch. 9 - Prob. 9.79QECh. 9 - Prob. 9.80QECh. 9 - Prob. 9.81QECh. 9 - Prob. 9.82QECh. 9 - Write the Lewis structures of H2CNH and H3CNH2....Ch. 9 - Write the Lewis structures of HNNH and H2NNH2....Ch. 9 - Prob. 9.85QECh. 9 - Prob. 9.86QECh. 9 - Prob. 9.87QECh. 9 - Prob. 9.88QECh. 9 - Prob. 9.89QECh. 9 - Prob. 9.90QECh. 9 - Prob. 9.91QECh. 9 - Prob. 9.92QECh. 9 - Prob. 9.93QECh. 9 - Prob. 9.94QECh. 9 - Prob. 9.95QECh. 9 - Prob. 9.96QECh. 9 - Prob. 9.97QECh. 9 - Prob. 9.98QECh. 9 - The molecule nitrosyl chloride, NOCl, has a...Ch. 9 - Prob. 9.100QECh. 9 - Draw the Lewis structure of BrNO. Which is the...Ch. 9 - Prob. 9.102QECh. 9 - Calculate an approximate enthalpy change (Table...Ch. 9 - Prob. 9.104QECh. 9 - Prob. 9.105QECh. 9 - Prob. 9.106QECh. 9 - Prob. 9.107QE
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- Bond Enthalpy When atoms of the hypothetical element X are placed together, they rapidly undergo reaction to form the X2 molecule: X(g)+X(g)X2(g) a Would you predict that this reaction is exothermic or endothermic? Explain. b Is the bond enthalpy of X2 a positive or a negative quantity? Why? c Suppose H for the reaction is 500 kJ/mol. Estimate the bond enthalpy of the X2 molecule. d Another hypothetical molecular compound, Y2(g), has a bond enthalpy of 750 kJ/mol, and the molecular compound XY(g) has a bond enthalpy of 1500 kJ/mol. Using bond enthalpy information, calculate H for the following reaction. X2(g)+Y2(g)2XY(g) e Given the following information, as well as the information previously presented, predict whether or not the hypothetical ionic compound AX is likely to form. In this compound, A forms the A+ cation, and X forms the X anion. Be sure to justify your answer. Reaction: A(g)+12X2(g)AX(s)The first ionization energy of A(g) is 400 kJ/mol. The electron affinity of X(g) is 525 kJ/mol. The lattice energy of AX(s) is 100 kJ/mol. f If you predicted that no ionic compound would form from the reaction in Part e, what minimum amount of AX(s) lattice energy might lead to compound formation?arrow_forwardUse average bond enthalpies to calculate the enthalpy change for the following gas-phase reaction. CH3OH(g) + HI(g) --> CH3I(g) + H2O(g) ΔHreaction = ?arrow_forwardExplain the difference between endothermic reactions and exothermic reactions with respect to the bond energies of the bonds broken and formed.arrow_forward
- Define the terms bond enthalpy and mean bond enthalpy.Use examples to illustrate the difference between the two quantities.arrow_forwardUse bond energy values to estimate ΔH for the following reaction in the gas phase. 4 NH3(g) + 3 O2(g) --> 2 N2(g) + 6 H2O(g)arrow_forwardThe bond energy of a C–C single bond averages 347 kJ mol−1; that of a C ≡ C triple bond averages 839 kJ mol−1. Explain why the triple bond is not three times as strong as a single bond.arrow_forward
- General Chemistry 4th Edition McQuarrie Rock • Gallogly University Science Books presented by Macmillan Learning Use the molar bond enthalpy data in the table to estimate Average molar bond enthalpies. (Hpond) the value of AHan for the equation Bond kJ - mol- Bond kJ - mol- NH, (g) + 20,(g) HNO, (g) + H,O(g) О-Н 464 C=N 890 The bonding in the molecules is shown. 0-0 142 N-H 390 C-0 351 N-O 201 O=0 502 N=N 418 C=0 730 N=O 607 C-C 347 F-F 155 C=C 615 Cl-CI 243 C=C 811 Br-Br 192 C-H 414 H-H 435 C-F 439 H-F 565 C-CI 331 H-CI 431 C-Br 276 H-Br 368 C-N 293 H-S 364 C=N 615 S-S 225 AHin = kJ F5 F6 F7 F8 F10 PrtSc F9 F11 F12 & * 6 7 8 9. Y + IIarrow_forwardEthane, a minority component of natural gas, burns to form carbon dioxide and water according to this reaction:2H3C−CH3(g)+7O2(g)→4CO2(g)+6H2O(g)2H3C−CH3(g)+7O2(g)→4CO2(g)+6H2O(g) Note that the average bond energy for the breaking of a bond in CO2CO2 is 799 kJ/molkJ/mol. Use average bond energies to calculate ΔHrxnΔHrxn for this reaction.arrow_forwardThe bond energy of hydrogen, iodine and hydrogen iodide are 218, 107kJ and 299kJ respectively. Estimate the enthalpy of hydrogen iodide formation. Is the reaction endothermic or exothermic? Formation of hydrogen iodide from hydrogen and iodine follows the reaction- H2 (g) + I2 (g) → HI (g)arrow_forward
- In chemical reactions, heat is converted into chemical energy (the potential energy stored in chemical bonds) or vice versa. Bond energy is the energy required to break one mole of the bond in the gas phase. Since it takes energy to break a bond, bond energies are always positive. Conversely, energy is released when bonds are formed. Thus, the enthalpy change for a reaction can be approximated from Part A Calculate the bond energy per mole for breaking all the bonds in methane, CH4. ΔΗ Σ(ΔΗ breaking) + Σ(ΔΗ forming) Express your answer to four significant figures and include the appropriate units. where H represents bond energies for the breaking (positive bond energy) or forming (negative bond energy) of a bond and Hrxn represents the overall enthalpy for the • View Available Hint(s) reaction. Use the table to answer questions about bond energies. HẢ Bond energy Bond (kJ/mol ) Value Units AHCH, = C-C 347 C=C 611 Submit Сн 414 C-O 360 Part B C=OinCO2 799 O-0 142 Calculate the bond…arrow_forwardConsider the fictitious element "X". Based on the following data, what is the X-X bond energy? H2le) + X2{g) → 2HX(g); AH--150 kJ Bond Energy Bond (kJ/mol) H-H 436 H-X 431 Recall that, in general, AH- (sum of bond enthalpies for bonds broken)- (sum of bond enthalpies for bonds formed) O - 276 kl/mol +138 kJ/mol +276 kJ/mol -138 k/mol O +300 kJ/mol Next Previousarrow_forwardA certain element X forms two compounds with hydrogen, XH3 and X2H4 (H2X–XH2). The total bond enthalpies of XH3(g) and X2H4(g) are 846 kJ/mol and 1341 kJ/mol, respectively. What is the average bond enthalpy of the X–X bond?arrow_forward
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