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Concept explainers
(a)
Interpretation:
The possible resonance structures for nitrate ion
Concept Introduction:
The steps to draw the Lewis structure of the molecule are as follows:
Step 1: Find the central atom and place the other atoms around it. The atom in a compound that has the lowest group number or lowest electronegativity considered as the central atom.
Step 2: Estimate the total number of valence electrons.
Step 3: Connect the other atoms around the central atoms to the central atom with a single bond and lower the value of valence electrons by 2 of every single bond.
Step 4: Allocate the remaining electrons in pairs so that each atom can get 8 electrons.
The formula to calculate formal charge of the atom is as follows:
Some molecules and ions do not have one unique Lewis structure. The Lewis structures that differ only in the placement of multiple bonds are called resonance structures.
Resonance structures are defined as a set of two or more Lewis structures that collectively describe the electronic bonding. The actual bonding is an average of the bonding in the resonance structures. Also, not all resonance structures contribute equally in every case. Resonance structures that have high formal charges or that place charges of the same sign on adjacent atoms do not contribute to the bonding.
(a)
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Answer to Problem 9.66QE
Possible resonance structures are as follows:
Explanation of Solution
The skeleton structure is,
The resonance structures are as follows:
For structure I:
Substitute 5 for valence electrons, 0 for number of lone pairs of electrons and 8 for the number of shared electrons in equation (1) to calculate the formal charge on nitrogen atom.
Substitute 6 for valence electrons, 4 for number of lone pairs of electrons and 4 for the number of shared electrons in equation (1) to calculate the formal charge on first oxygen atom.
Substitute 6 for valence electrons, 6 for number of lone pairs of electrons and 2 for the number of shared electrons in equation (1) to calculate the formal charge on second oxygen atom.
Substitute 6 for valence electrons, 6 for number of lone pairs of electrons and 2 for the number of shared electrons in equation (1) to calculate the formal charge on third oxygen atom.
For structure II:
Substitute 5 for valence electrons, 0 for number of lone pairs of electrons and 8 for the number of shared electrons in equation (1) to calculate the formal charge on nitrogen atom.
Substitute 6 for valence electrons, 6 for number of lone pairs of electrons and 2 for the number of shared electrons in equation (1) to calculate the formal charge on first oxygen atom.
Substitute 6 for valence electrons, 4 for number of lone pairs of electrons and 4 for the number of shared electrons in equation (1) to calculate the formal charge on second oxygen atom.
Substitute 6 for valence electrons, 6 for number of lone pairs of electrons and 2 for the number of shared electrons in equation (1) to calculate the formal charge on third oxygen atom.
For structure III:
Substitute 5 for valence electrons, 0 for number of lone pairs of electrons and 8 for the number of shared electrons in equation (1) to calculate the formal charge on nitrogen atom.
Substitute 6 for valence electrons, 6 for lone pair of electrons and 2 for the number of shared electrons in equation (1) to calculate the formal charge on first oxygen atom.
Substitute 6 for valence electrons, 6 for number of lone pairs of electrons and 2 for the number of shared electrons in equation (1) to calculate the formal charge on second oxygen atom.
Substitute 6 for valence electrons, 4 for number of lone pair of electrons and 4 for the number of shared electrons in equation (1) to calculate the formal charge on third oxygen atom.
The possible resonance structures are as follows:
(b)
Interpretation:
The possible resonance structures for nitrous oxide
Concept Introduction:
Refer to part (a).
(b)
![Check Mark](/static/check-mark.png)
Answer to Problem 9.66QE
The possible resonance structures are,
Explanation of Solution
The given skeleton structure is,
The resonance structures are as follows:
For structure I:
Substitute 5 for valence electrons, 4 for the number of lone pairs of electrons and 4 for the number of shared electrons in equation (1) to calculate the formal charge on first
Substitute 5 for valence electrons, 0 for number of lone pairs of electrons and 8 for the number of shared electrons in equation (1) to calculate the formal charge on second nitrogen atom.
Substitute 6 for valence electrons, 4 for number of lone pairs of electrons and 4 for the number of shared electrons in equation (1) to calculate the formal charge on oxygen atom.
For structure II:
Substitute 5 for valence electrons, 2 for the number of lone pairs of electrons and 6 for the number of shared electrons in equation (1) to calculate the formal charge on first
Substitute 5 for valence electrons, 0 for number of lone pairs of electrons and 8 for the number of shared electrons in equation (1) to calculate the formal charge on second nitrogen atom.
Substitute 6 for valence electrons, 6 for number of lone pairs and 2 for the number of shared electrons in equation (1) to calculate the formal charge on third nitrogen atom.
For structure III:
Substitute 5 for valence electrons, 6 for the number of lone pairs of electrons and 2 for the number of shared electrons in equation (1) to calculate the formal charge on first
Substitute 5 for valence electrons, 0 for number of lone pairs of electrons and 8 for the number of shared electrons in equation (1) to calculate the formal charge on second nitrogen atom.
Substitute 6 for valence electrons, 2 for number of lone pairs of electrons and 6 for the number of shared electrons in equation (1) to calculate the formal charge on oxygen atom.
Possible resonance structures are as follows:
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Chapter 9 Solutions
Chemistry: Principles and Practice
- Redraw the flowchartarrow_forwardredraw the flowchart with boxes and molecules written in themarrow_forwardPart I. a) Elucidate the structure of compound A using the following information. • mass spectrum: m+ = 102, m/2=57 312=29 • IR spectrum: 1002.5 % TRANSMITTANCE Ngg 50 40 30 20 90 80 70 60 MICRONS 5 8 9 10 12 13 14 15 16 19 1740 cm M 10 0 4000 3600 3200 2800 2400 2000 1800 1600 13 • CNMR 'H -NMR Peak 8 ppm (H) Integration multiplicity a 1.5 (3H) triplet b 1.3 1.5 (3H) triplet C 2.3 1 (2H) quartet d 4.1 1 (2H) quartet & ppm (c) 10 15 28 60 177 (C=0) b) Elucidate the structure of compound B using the following information 13C/DEPT NMR 150.9 MHz IIL 1400 WAVENUMBERS (CM-1) DEPT-90 DEPT-135 85 80 75 70 65 60 55 50 45 40 35 30 25 20 ppm 1200 1000 800 600 400arrow_forward
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- Draw the curved-arrow mechanism with the drawings of the molecules, not just abbreviations. -NO₂ Sn, HCl (aq) E D H (CH3CO)₂O -NH2 CH3arrow_forwardWhat is/are the product(s) of the following reaction? Select all that apply. * HI A B C OD OH A B OH D Carrow_forwardIn the image, the light blue sphere represents a mole of hydrogen atoms, the purple or teal spheres represent a mole of a conjugate base. A light blue sphere by itself is H+. Assuming there is 2.00 L of solution, answer the following: The Ka of the left & right solution is? The pH of the left & right solution is? The acid on the left & right is what kind of acid?arrow_forward
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