Organic And Biological Chemistry
Organic And Biological Chemistry
7th Edition
ISBN: 9781305081079
Author: STOKER, H. Stephen (howard Stephen)
Publisher: Cengage Learning,
Question
Book Icon
Chapter 5, Problem 5.63EP

(a)

Interpretation Introduction

Interpretation:

Chemical equation for the conversion of given carboxylic acid salt to its parent carboxylic acid using HCl has to be written.

Concept Introduction:

The name of the carboxylic acid itself implies that it is acidic.  Addition of carboxylic acid to water results in ionization.  Hydrogen ion transfer occurs from carboxylic acid to water and hydronium ion is formed.  Carboxylate ion is also formed due to the loss of hydrogen ion from carboxylic acid.

Carboxylate ion is the negative ion which is formed when one or more acidic protons are lost from carboxylic acid.  Similar to carboxylic acid it reacts with strong base to form carboxylic acid salt and water.

Carboxylic acid salts when treated with a strong acid produces carboxylic acid as the product.

Carboxylic acid forms carboxylic acid salt by reacting with a strong base.  The general reaction scheme for the formation of carboxylic acid salt is given as shown below,

Organic And Biological Chemistry, Chapter 5, Problem 5.63EP , additional homework tip 1

The reverse of the above reaction is conversion of carboxylic acid salt to carboxylic acid.  This is accomplished by using strong acid.  The scheme is shown below,

Organic And Biological Chemistry, Chapter 5, Problem 5.63EP , additional homework tip 2

From the above chemical equation it is found that the carboxylic acid salt reacts with strong acid to form carboxylic acid.

(a)

Expert Solution
Check Mark

Explanation of Solution

Given carboxylic acid salt is sodium butanoate.  The structure of sodium butanoate can be given as shown below,

Organic And Biological Chemistry, Chapter 5, Problem 5.63EP , additional homework tip 3

Carboxylic acid sat is converted to carboxylic acid by reaction with strong acid.  In the problem statement it is given that the strong acid is HCl.  Sodium butanoate on reaction with hydrochloric acid gives butanoic acid as product.  The chemical equation for the reaction can be given as,

Organic And Biological Chemistry, Chapter 5, Problem 5.63EP , additional homework tip 4

Conclusion

Chemical equation for the conversion of given carboxylic acid salt to carboxylic acid using hydrochloric acid is written.

(b)

Interpretation Introduction

Interpretation:

Chemical equation for the conversion of given carboxylic acid salt to its parent carboxylic acid using HCl has to be written.

Concept Introduction:

The name of the carboxylic acid itself implies that it is acidic.  Addition of carboxylic acid to water results in ionization.  Hydrogen ion transfer occurs from carboxylic acid to water and hydronium ion is formed.  Carboxylate ion is also formed due to the loss of hydrogen ion from carboxylic acid.

Carboxylate ion is the negative ion which is formed when one or more acidic protons are lost from carboxylic acid.  Similar to carboxylic acid it reacts with strong base to form carboxylic acid salt and water.

Carboxylic acid salts when treated with a strong acid produces carboxylic acid as the product.

Carboxylic acid forms carboxylic acid salt by reacting with a strong base.  The general reaction scheme for the formation of carboxylic acid salt is given as shown below,

Organic And Biological Chemistry, Chapter 5, Problem 5.63EP , additional homework tip 5

The reverse of the above reaction is conversion of carboxylic acid salt to carboxylic acid.  This is accomplished by using strong acid.  The scheme is shown below,

Organic And Biological Chemistry, Chapter 5, Problem 5.63EP , additional homework tip 6

From the above chemical equation it is found that the carboxylic acid salt reacts with strong acid to form carboxylic acid.

(b)

Expert Solution
Check Mark

Explanation of Solution

Given carboxylic acid salt is potassium oxalate.  The structure of potassium oxalate can be given as shown below,

Organic And Biological Chemistry, Chapter 5, Problem 5.63EP , additional homework tip 7

Carboxylic acid sat is converted to carboxylic acid by reaction with strong acid.  In the problem statement it is given that the strong acid is HCl.  Potassium oxalate on reaction with hydrochloric acid gives oxalic acid as product.  The chemical equation for the reaction can be given as,

Organic And Biological Chemistry, Chapter 5, Problem 5.63EP , additional homework tip 8

Conclusion

Chemical equation for the conversion of given carboxylic acid salt to carboxylic acid using hydrochloric acid is written.

(c)

Interpretation Introduction

Interpretation:

Chemical equation for the conversion of given carboxylic acid salt to its parent carboxylic acid using HCl has to be written.

Concept Introduction:

The name of the carboxylic acid itself implies that it is acidic.  Addition of carboxylic acid to water results in ionization.  Hydrogen ion transfer occurs from carboxylic acid to water and hydronium ion is formed.  Carboxylate ion is also formed due to the loss of hydrogen ion from carboxylic acid.

Carboxylate ion is the negative ion which is formed when one or more acidic protons are lost from carboxylic acid.  Similar to carboxylic acid it reacts with strong base to form carboxylic acid salt and water.

Carboxylic acid salts when treated with a strong acid produces carboxylic acid as the product.

Carboxylic acid forms carboxylic acid salt by reacting with a strong base.  The general reaction scheme for the formation of carboxylic acid salt is given as shown below,

Organic And Biological Chemistry, Chapter 5, Problem 5.63EP , additional homework tip 9

The reverse of the above reaction is conversion of carboxylic acid salt to carboxylic acid.  This is accomplished by using strong acid.  The scheme is shown below,

Organic And Biological Chemistry, Chapter 5, Problem 5.63EP , additional homework tip 10

From the above chemical equation it is found that the carboxylic acid salt reacts with strong acid to form carboxylic acid.

(c)

Expert Solution
Check Mark

Explanation of Solution

Given carboxylic acid salt is calcium malonate.  The structure of calcium malonate can be given as shown below,

Organic And Biological Chemistry, Chapter 5, Problem 5.63EP , additional homework tip 11

Carboxylic acid sat is converted to carboxylic acid by reaction with strong acid.  In the problem statement it is given that the strong acid is HCl.  Calcium malonate on reaction with hydrochloric acid gives malonic acid as product.  The chemical equation for the reaction can be given as,

Organic And Biological Chemistry, Chapter 5, Problem 5.63EP , additional homework tip 12

Conclusion

Chemical equation for the conversion of given carboxylic acid salt to carboxylic acid using hydrochloric acid is written.

(d)

Interpretation Introduction

Interpretation:

Chemical equation for the conversion of given carboxylic acid salt to its parent carboxylic acid using HCl has to be written.

Concept Introduction:

The name of the carboxylic acid itself implies that it is acidic.  Addition of carboxylic acid to water results in ionization.  Hydrogen ion transfer occurs from carboxylic acid to water and hydronium ion is formed.  Carboxylate ion is also formed due to the loss of hydrogen ion from carboxylic acid.

Carboxylate ion is the negative ion which is formed when one or more acidic protons are lost from carboxylic acid.  Similar to carboxylic acid it reacts with strong base to form carboxylic acid salt and water.

Carboxylic acid salts when treated with a strong acid produces carboxylic acid as the product.

Carboxylic acid forms carboxylic acid salt by reacting with a strong base.  The general reaction scheme for the formation of carboxylic acid salt is given as shown below,

Organic And Biological Chemistry, Chapter 5, Problem 5.63EP , additional homework tip 13

The reverse of the above reaction is conversion of carboxylic acid salt to carboxylic acid.  This is accomplished by using strong acid.  The scheme is shown below,

Organic And Biological Chemistry, Chapter 5, Problem 5.63EP , additional homework tip 14

From the above chemical equation it is found that the carboxylic acid salt reacts with strong acid to form carboxylic acid.

(d)

Expert Solution
Check Mark

Explanation of Solution

Given carboxylic acid salt is sodium benzoate.  The structure of sodium benzoate can be given as shown below,

Organic And Biological Chemistry, Chapter 5, Problem 5.63EP , additional homework tip 15

Carboxylic acid sat is converted to carboxylic acid by reaction with strong acid.  In the problem statement it is given that the strong acid is HCl.  Sodium benzoate on reaction with hydrochloric acid gives benzoic acid as product.  The chemical equation for the reaction can be given as,

Organic And Biological Chemistry, Chapter 5, Problem 5.63EP , additional homework tip 16

Conclusion

Chemical equation for the conversion of given carboxylic acid salt to carboxylic acid using hydrochloric acid is written.

Want to see more full solutions like this?

Subscribe now to access step-by-step solutions to millions of textbook problems written by subject matter experts!
Previous
Chapter 5, Problem 5.62EP
Next
Chapter 5, Problem 5.64EP
Students have asked these similar questions
Some of the theories used to describe interface structure can be distinguished by:1. the measured potential difference.2. the distribution of ions in solution.3. the calculation of charge density.4. the external Helmoltz plane.
When talking about the acidity of carboxylic acids, is it the same thing to say higher or stronger acidity?
Using the following two half-reactions, determine the pH range in which $NO_2^-\ (aq)$ cannot be found as the predominant chemical species in water.* $NO_3^-(aq)+10H^+(aq)+8e^-\rightarrow NH_4^+(aq)+3H_2O(l),\ pE^{\circ}=14.88$* $NO_2^-(aq)+8H^+(aq)+6e^-\rightarrow NH_4^+(aq)+2H_2O(l),\ pE^{\circ}=15.08$

Chapter 5 Solutions

Organic And Biological Chemistry

Ch. 5.1 - Prob. 1QQCh. 5.1 - Prob. 2QQCh. 5.1 - Prob. 3QQCh. 5.1 - Prob. 4QQCh. 5.1 - Prob. 5QQCh. 5.2 - Prob. 1QQCh. 5.2 - Prob. 2QQCh. 5.2 - Prob. 3QQCh. 5.2 - Prob. 4QQCh. 5.2 - Prob. 5QQ
Ch. 5.3 - Prob. 1QQCh. 5.3 - Prob. 2QQCh. 5.3 - Prob. 3QQCh. 5.4 - Prob. 1QQCh. 5.4 - Prob. 2QQCh. 5.4 - Prob. 3QQCh. 5.5 - Prob. 1QQCh. 5.5 - Prob. 2QQCh. 5.5 - Prob. 3QQCh. 5.6 - Prob. 1QQCh. 5.6 - Prob. 2QQCh. 5.7 - Which of the following statements about acid...Ch. 5.7 - Prob. 2QQCh. 5.7 - Prob. 3QQCh. 5.8 - Prob. 1QQCh. 5.8 - Prob. 2QQCh. 5.8 - Prob. 3QQCh. 5.8 - Prob. 4QQCh. 5.9 - Prob. 1QQCh. 5.9 - Prob. 2QQCh. 5.10 - Prob. 1QQCh. 5.10 - Prob. 2QQCh. 5.11 - Prob. 1QQCh. 5.11 - Prob. 2QQCh. 5.11 - Prob. 3QQCh. 5.12 - Prob. 1QQCh. 5.12 - Prob. 2QQCh. 5.12 - Prob. 3QQCh. 5.12 - Prob. 4QQCh. 5.13 - Prob. 1QQCh. 5.13 - Prob. 2QQCh. 5.14 - Prob. 1QQCh. 5.14 - Prob. 2QQCh. 5.14 - Prob. 3QQCh. 5.15 - Prob. 1QQCh. 5.15 - Prob. 2QQCh. 5.15 - Prob. 3QQCh. 5.16 - Prob. 1QQCh. 5.16 - Prob. 2QQCh. 5.16 - Prob. 3QQCh. 5.17 - Prob. 1QQCh. 5.17 - Prob. 2QQCh. 5.18 - Prob. 1QQCh. 5.18 - Prob. 2QQCh. 5.18 - Prob. 3QQCh. 5.19 - Prob. 1QQCh. 5.19 - Prob. 2QQCh. 5.19 - Prob. 3QQCh. 5.19 - Prob. 4QQCh. 5.20 - Prob. 1QQCh. 5.20 - Prob. 2QQCh. 5.20 - Prob. 3QQCh. 5.20 - Prob. 4QQCh. 5 - Prob. 5.1EPCh. 5 - Prob. 5.2EPCh. 5 - Prob. 5.3EPCh. 5 - Indicate whether or not each of the compounds in...Ch. 5 - Prob. 5.5EPCh. 5 - Prob. 5.6EPCh. 5 - Prob. 5.7EPCh. 5 - Prob. 5.8EPCh. 5 - Prob. 5.9EPCh. 5 - Prob. 5.10EPCh. 5 - Prob. 5.11EPCh. 5 - Prob. 5.12EPCh. 5 - Prob. 5.13EPCh. 5 - Prob. 5.14EPCh. 5 - Prob. 5.15EPCh. 5 - Assign an IUPAC name to each of the following...Ch. 5 - Prob. 5.17EPCh. 5 - Prob. 5.18EPCh. 5 - Prob. 5.19EPCh. 5 - Prob. 5.20EPCh. 5 - Prob. 5.21EPCh. 5 - Prob. 5.22EPCh. 5 - Prob. 5.23EPCh. 5 - Prob. 5.24EPCh. 5 - Prob. 5.25EPCh. 5 - Prob. 5.26EPCh. 5 - Prob. 5.27EPCh. 5 - Prob. 5.28EPCh. 5 - Prob. 5.29EPCh. 5 - Prob. 5.30EPCh. 5 - Prob. 5.31EPCh. 5 - Prob. 5.32EPCh. 5 - Prob. 5.33EPCh. 5 - Prob. 5.34EPCh. 5 - Prob. 5.35EPCh. 5 - Prob. 5.36EPCh. 5 - Prob. 5.37EPCh. 5 - Prob. 5.38EPCh. 5 - Prob. 5.39EPCh. 5 - Prob. 5.40EPCh. 5 - Determine the maximum number of hydrogen bonds...Ch. 5 - Prob. 5.42EPCh. 5 - Prob. 5.43EPCh. 5 - Prob. 5.44EPCh. 5 - Prob. 5.45EPCh. 5 - Prob. 5.46EPCh. 5 - Prob. 5.47EPCh. 5 - Prob. 5.48EPCh. 5 - Prob. 5.49EPCh. 5 - Prob. 5.50EPCh. 5 - Prob. 5.51EPCh. 5 - Prob. 5.52EPCh. 5 - Prob. 5.53EPCh. 5 - Prob. 5.54EPCh. 5 - Draw structural formulas for the following...Ch. 5 - Prob. 5.56EPCh. 5 - Give the IUPAC name for each of the following...Ch. 5 - Give the IUPAC name for each of the following...Ch. 5 - Prob. 5.59EPCh. 5 - Prob. 5.60EPCh. 5 - Prob. 5.61EPCh. 5 - Prob. 5.62EPCh. 5 - Prob. 5.63EPCh. 5 - Prob. 5.64EPCh. 5 - Prob. 5.65EPCh. 5 - Which three carboxylic acids have salts that are...Ch. 5 - Prob. 5.67EPCh. 5 - Which carboxylic acid has salts that are used to...Ch. 5 - Prob. 5.69EPCh. 5 - Prob. 5.70EPCh. 5 - Prob. 5.71EPCh. 5 - Prob. 5.72EPCh. 5 - Prob. 5.73EPCh. 5 - Prob. 5.74EPCh. 5 - Prob. 5.75EPCh. 5 - Prob. 5.76EPCh. 5 - Prob. 5.77EPCh. 5 - Prob. 5.78EPCh. 5 - Prob. 5.79EPCh. 5 - Prob. 5.80EPCh. 5 - Prob. 5.81EPCh. 5 - Prob. 5.82EPCh. 5 - Prob. 5.83EPCh. 5 - Prob. 5.84EPCh. 5 - Prob. 5.85EPCh. 5 - Prob. 5.86EPCh. 5 - Prob. 5.87EPCh. 5 - Prob. 5.88EPCh. 5 - Prob. 5.89EPCh. 5 - Prob. 5.90EPCh. 5 - Assign common names to each of the esters in...Ch. 5 - Prob. 5.92EPCh. 5 - Prob. 5.93EPCh. 5 - Assign an IUPAC name to each of the following...Ch. 5 - Draw a structural formula for each of the...Ch. 5 - Prob. 5.96EPCh. 5 - Prob. 5.97EPCh. 5 - Prob. 5.98EPCh. 5 - Prob. 5.99EPCh. 5 - Prob. 5.100EPCh. 5 - Prob. 5.101EPCh. 5 - How many carbon atoms are present in a molecule of...Ch. 5 - Prob. 5.103EPCh. 5 - Prob. 5.104EPCh. 5 - Prob. 5.105EPCh. 5 - Prob. 5.106EPCh. 5 - Prob. 5.107EPCh. 5 - Prob. 5.108EPCh. 5 - Prob. 5.109EPCh. 5 - Prob. 5.110EPCh. 5 - Prob. 5.111EPCh. 5 - Prob. 5.112EPCh. 5 - Prob. 5.113EPCh. 5 - Prob. 5.114EPCh. 5 - Prob. 5.115EPCh. 5 - Prob. 5.116EPCh. 5 - Prob. 5.117EPCh. 5 - Prob. 5.118EPCh. 5 - Prob. 5.119EPCh. 5 - Prob. 5.120EPCh. 5 - Prob. 5.121EPCh. 5 - Prob. 5.122EPCh. 5 - Prob. 5.123EPCh. 5 - Prob. 5.124EPCh. 5 - Write the structural formulas of the reaction...Ch. 5 - Prob. 5.126EPCh. 5 - Prob. 5.127EPCh. 5 - Prob. 5.128EPCh. 5 - Prob. 5.129EPCh. 5 - Prob. 5.130EPCh. 5 - Prob. 5.131EPCh. 5 - Prob. 5.132EPCh. 5 - Prob. 5.133EPCh. 5 - Prob. 5.134EPCh. 5 - Prob. 5.135EPCh. 5 - Prob. 5.136EPCh. 5 - Prob. 5.137EPCh. 5 - Prob. 5.138EPCh. 5 - Prob. 5.139EPCh. 5 - Prob. 5.140EPCh. 5 - Prob. 5.141EPCh. 5 - Prob. 5.142EPCh. 5 - Prob. 5.143EPCh. 5 - Prob. 5.144EPCh. 5 - Prob. 5.145EPCh. 5 - Prob. 5.146EPCh. 5 - Prob. 5.147EPCh. 5 - Prob. 5.148EPCh. 5 - Draw a condensed structural formula for the...Ch. 5 - Draw a condensed structural formula for the...Ch. 5 - Prob. 5.151EPCh. 5 - Prob. 5.152EPCh. 5 - Prob. 5.153EPCh. 5 - Prob. 5.154EPCh. 5 - Prob. 5.155EPCh. 5 - Prob. 5.156EPCh. 5 - Prob. 5.157EPCh. 5 - Prob. 5.158EPCh. 5 - Prob. 5.159EPCh. 5 - Prob. 5.160EPCh. 5 - Prob. 5.161EPCh. 5 - Prob. 5.162EPCh. 5 - Prob. 5.163EPCh. 5 - Prob. 5.164EP
Knowledge Booster
Background pattern image
Similar questions
SEE MORE QUESTIONS
Recommended textbooks for you
Text book image
Organic And Biological Chemistry
Chemistry
ISBN:9781305081079
Author:STOKER, H. Stephen (howard Stephen)
Publisher:Cengage Learning,
Text book image
General, Organic, and Biological Chemistry
Chemistry
ISBN:9781285853918
Author:H. Stephen Stoker
Publisher:Cengage Learning
Text book image
Chemistry for Today: General, Organic, and Bioche...
Chemistry
ISBN:9781305960060
Author:Spencer L. Seager, Michael R. Slabaugh, Maren S. Hansen
Publisher:Cengage Learning
Text book image
Chemistry In Focus
Chemistry
ISBN:9781337399692
Author:Tro, Nivaldo J.
Publisher:Cengage Learning,
Text book image
Chemistry: Matter and Change
Chemistry
ISBN:9780078746376
Author:Dinah Zike, Laurel Dingrando, Nicholas Hainen, Cheryl Wistrom
Publisher:Glencoe/McGraw-Hill School Pub Co
Text book image
Chemistry & Chemical Reactivity
Chemistry
ISBN:9781133949640
Author:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher:Cengage Learning
SEE MORE TEXTBOOKS