Organic And Biological Chemistry
Organic And Biological Chemistry
7th Edition
ISBN: 9781305081079
Author: STOKER, H. Stephen (howard Stephen)
Publisher: Cengage Learning,
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Chapter 5, Problem 5.34EP

(a)

Interpretation Introduction

Interpretation:

IUPAC name for the fumaric acid has to be given.

Concept Introduction:

For naming a carboxylic acid in IUPAC nomenclature, the suffix “-oic” is added to the parent alkane name.

IUPAC rules for naming a carboxylic acid:

  • The longest parent carbon chain is identified that includes the carboxyl group.
  • The parent chain name is changed by replacing the suffix “-e” with “-oic acid”.
  • Numbering is done in a way that the carboxyl group is designated as number 1.  This is not indicated in the part of the name because for aldehyde, the carboxyl carbon is always numbered 1.
  • The identity and location of substituents if any has to be determined and this information has to be added in front of the IUPAC name.
  • If the carboxyl functional group is attached to a ring of carbon atoms, the ring is named and “-carboxylic acid” is added as suffix.
  • If the compound contains two carboxyl groups, then suffix “-dioic acid” is added after the parent alkane name.

(a)

Expert Solution
Check Mark

Answer to Problem 5.34EP

IUPAC name of fumaric acid is trans-butenedioic acid.

Explanation of Solution

Structure of fumaric acid is,

Organic And Biological Chemistry, Chapter 5, Problem 5.34EP , additional homework tip 1

The longest continuous carbon chain has to be found out with the carboxyl group in it.  In this it is a four carbon chain.  The structure contains a double bond in it.  The parent carbon chain is butene.  The given structure contains two carboxyl groups.  The carboxylic acid is named by adding suffix “-dioic acid”.  This gives the name of carboxylic acid as butenedioic acid.

Organic And Biological Chemistry, Chapter 5, Problem 5.34EP , additional homework tip 2

Looking for substituents it is found that there are no substituents present in the carbon chain.  Stereochemistry is possible across the double bond.  As the two hydrogen atoms are on the opposite side of double bond, the configuration at the double bond is “trans”.  This has to be included in the name to get the IUPAC name.  IUPAC name of the fumaric acid is found as trans-butenedioic acid.

Organic And Biological Chemistry, Chapter 5, Problem 5.34EP , additional homework tip 3

Conclusion

IUPAC name of fumaric acid is given.

(a)

Interpretation Introduction

Interpretation:

IUPAC name for the pyruvic acid has to be given.

Concept Introduction:

For naming a carboxylic acid in IUPAC nomenclature, the suffix “-oic” is added to the parent alkane name.

IUPAC rules for naming a carboxylic acid:

  • The longest parent carbon chain is identified that includes the carboxyl group.
  • The parent chain name is changed by replacing the suffix “-e” with “-oic acid”.
  • Numbering is done in a way that the carboxyl group is designated as number 1.  This is not indicated in the part of the name because for aldehyde, the carboxyl carbon is always numbered 1.
  • The identity and location of substituents if any has to be determined and this information has to be added in front of the IUPAC name.
  • If the carboxyl functional group is attached to a ring of carbon atoms, the ring is named and “-carboxylic acid” is added as suffix.
  • If the compound contains two carboxyl groups, then suffix “-dioic acid” is added after the parent alkane name.

(a)

Expert Solution
Check Mark

Answer to Problem 5.34EP

IUPAC name of pyruvic acid is 2-oxopropanoic acid.

Explanation of Solution

Structure of pyruvic acid is,

Organic And Biological Chemistry, Chapter 5, Problem 5.34EP , additional homework tip 4

The longest continuous carbon chain has to be found out with the carboxyl group in it.  In this it is a three carbon chain.  The parent alkane is propane.  The given structure contains a carboxyl group.  The carboxylic acid is named by replacing the suffix “-e” with suffix “-oic acid”.  This gives the name of carboxylic acid as propanoic acid.

Organic And Biological Chemistry, Chapter 5, Problem 5.34EP , additional homework tip 5

Looking for substituents it is found that there is a keto group present on the second carbon atom.  Hence, the IUPAC name of the pyruvic acid is 2-oxopropanoic acid.

Organic And Biological Chemistry, Chapter 5, Problem 5.34EP , additional homework tip 6

Conclusion

IUPAC name of pyruvic acid is given.

(c)

Interpretation Introduction

Interpretation:

IUPAC name for the malic acid has to be given.

Concept Introduction:

For naming a carboxylic acid in IUPAC nomenclature, the suffix “-oic” is added to the parent alkane name.

IUPAC rules for naming a carboxylic acid:

  • The longest parent carbon chain is identified that includes the carboxyl group.
  • The parent chain name is changed by replacing the suffix “-e” with “-oic acid”.
  • Numbering is done in a way that the carboxyl group is designated as number 1.  This is not indicated in the part of the name because for aldehyde, the carboxyl carbon is always numbered 1.
  • The identity and location of substituents if any has to be determined and this information has to be added in front of the IUPAC name.
  • If the carboxyl functional group is attached to a ring of carbon atoms, the ring is named and “-carboxylic acid” is added as suffix.
  • If the compound contains two carboxyl groups, then suffix “-dioic acid” is added after the parent alkane name.

(c)

Expert Solution
Check Mark

Answer to Problem 5.34EP

IUPAC name of malic acid is 2-hydroxybutanedioic acid.

Explanation of Solution

Structure of malic acid is,

Organic And Biological Chemistry, Chapter 5, Problem 5.34EP , additional homework tip 7

The longest continuous carbon chain has to be found out with the carboxyl group in it.  In this it is a four carbon chain.  The parent alkane is butane.  The given structure contains two carboxyl groups.  The carboxylic acid is named by adding the suffix “-dioic acid”.  This gives the name of carboxylic acid as butanedioic acid.

Organic And Biological Chemistry, Chapter 5, Problem 5.34EP , additional homework tip 8

Looking for substituents it is found that there is a hydroxyl group at the second carbon atom.  Hence, the IUPAC name of the malic acid is 2-hydroxybutanoic acid.

Organic And Biological Chemistry, Chapter 5, Problem 5.34EP , additional homework tip 9

Conclusion

IUPAC name of malic acid is given.

(d)

Interpretation Introduction

Interpretation:

IUPAC name for the tartaric acid has to be given.

Concept Introduction:

For naming a carboxylic acid in IUPAC nomenclature, the suffix “-oic” is added to the parent alkane name.

IUPAC rules for naming a carboxylic acid:

  • The longest parent carbon chain is identified that includes the carboxyl group.
  • The parent chain name is changed by replacing the suffix “-e” with “-oic acid”.
  • Numbering is done in a way that the carboxyl group is designated as number 1.  This is not indicated in the part of the name because for aldehyde, the carboxyl carbon is always numbered 1.
  • The identity and location of substituents if any has to be determined and this information has to be added in front of the IUPAC name.
  • If the carboxyl functional group is attached to a ring of carbon atoms, the ring is named and “-carboxylic acid” is added as suffix.
  • If the compound contains two carboxyl groups, then suffix “-dioic acid” is added after the parent alkane name.

(d)

Expert Solution
Check Mark

Answer to Problem 5.34EP

IUPAC name of tartaric acid is 2,3-dihydroxybutanedioic acid.

Explanation of Solution

Structure of tartaric acid is,

Organic And Biological Chemistry, Chapter 5, Problem 5.34EP , additional homework tip 10

The longest continuous carbon chain has to be found out with the carboxyl group in it.  In this it is a four carbon chain.  The parent alkane is butane.  The given structure contains two carboxyl groups.  The carboxylic acid is named by adding the suffix “-dioic acid”.  This gives the name of carboxylic acid as butanedioic acid.

Organic And Biological Chemistry, Chapter 5, Problem 5.34EP , additional homework tip 11

Looking for substituents it is found that there are two hydroxyl groups present, each at the second carbon atom and third carbon atom.  Hence, the IUPAC name of the tartaric acid is 2,3-dihydroxybutanoic acid.

Organic And Biological Chemistry, Chapter 5, Problem 5.34EP , additional homework tip 12

Conclusion

IUPAC name of tartaric acid is given.

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Chapter 5 Solutions

Organic And Biological Chemistry

Ch. 5.1 - Prob. 1QQCh. 5.1 - Prob. 2QQCh. 5.1 - Prob. 3QQCh. 5.1 - Prob. 4QQCh. 5.1 - Prob. 5QQCh. 5.2 - Prob. 1QQCh. 5.2 - Prob. 2QQCh. 5.2 - Prob. 3QQCh. 5.2 - Prob. 4QQCh. 5.2 - Prob. 5QQ
Ch. 5.3 - Prob. 1QQCh. 5.3 - Prob. 2QQCh. 5.3 - Prob. 3QQCh. 5.4 - Prob. 1QQCh. 5.4 - Prob. 2QQCh. 5.4 - Prob. 3QQCh. 5.5 - Prob. 1QQCh. 5.5 - Prob. 2QQCh. 5.5 - Prob. 3QQCh. 5.6 - Prob. 1QQCh. 5.6 - Prob. 2QQCh. 5.7 - Which of the following statements about acid...Ch. 5.7 - Prob. 2QQCh. 5.7 - Prob. 3QQCh. 5.8 - Prob. 1QQCh. 5.8 - Prob. 2QQCh. 5.8 - Prob. 3QQCh. 5.8 - Prob. 4QQCh. 5.9 - Prob. 1QQCh. 5.9 - Prob. 2QQCh. 5.10 - Prob. 1QQCh. 5.10 - Prob. 2QQCh. 5.11 - Prob. 1QQCh. 5.11 - Prob. 2QQCh. 5.11 - Prob. 3QQCh. 5.12 - Prob. 1QQCh. 5.12 - Prob. 2QQCh. 5.12 - Prob. 3QQCh. 5.12 - Prob. 4QQCh. 5.13 - Prob. 1QQCh. 5.13 - Prob. 2QQCh. 5.14 - Prob. 1QQCh. 5.14 - Prob. 2QQCh. 5.14 - Prob. 3QQCh. 5.15 - Prob. 1QQCh. 5.15 - Prob. 2QQCh. 5.15 - Prob. 3QQCh. 5.16 - Prob. 1QQCh. 5.16 - Prob. 2QQCh. 5.16 - Prob. 3QQCh. 5.17 - Prob. 1QQCh. 5.17 - Prob. 2QQCh. 5.18 - Prob. 1QQCh. 5.18 - Prob. 2QQCh. 5.18 - Prob. 3QQCh. 5.19 - Prob. 1QQCh. 5.19 - Prob. 2QQCh. 5.19 - Prob. 3QQCh. 5.19 - Prob. 4QQCh. 5.20 - Prob. 1QQCh. 5.20 - Prob. 2QQCh. 5.20 - Prob. 3QQCh. 5.20 - Prob. 4QQCh. 5 - Prob. 5.1EPCh. 5 - Prob. 5.2EPCh. 5 - Prob. 5.3EPCh. 5 - Indicate whether or not each of the compounds in...Ch. 5 - Prob. 5.5EPCh. 5 - Prob. 5.6EPCh. 5 - Prob. 5.7EPCh. 5 - Prob. 5.8EPCh. 5 - Prob. 5.9EPCh. 5 - Prob. 5.10EPCh. 5 - Prob. 5.11EPCh. 5 - Prob. 5.12EPCh. 5 - Prob. 5.13EPCh. 5 - Prob. 5.14EPCh. 5 - Prob. 5.15EPCh. 5 - Assign an IUPAC name to each of the following...Ch. 5 - Prob. 5.17EPCh. 5 - Prob. 5.18EPCh. 5 - Prob. 5.19EPCh. 5 - Prob. 5.20EPCh. 5 - Prob. 5.21EPCh. 5 - Prob. 5.22EPCh. 5 - Prob. 5.23EPCh. 5 - Prob. 5.24EPCh. 5 - Prob. 5.25EPCh. 5 - Prob. 5.26EPCh. 5 - Prob. 5.27EPCh. 5 - Prob. 5.28EPCh. 5 - Prob. 5.29EPCh. 5 - Prob. 5.30EPCh. 5 - Prob. 5.31EPCh. 5 - Prob. 5.32EPCh. 5 - Prob. 5.33EPCh. 5 - Prob. 5.34EPCh. 5 - Prob. 5.35EPCh. 5 - Prob. 5.36EPCh. 5 - Prob. 5.37EPCh. 5 - Prob. 5.38EPCh. 5 - Prob. 5.39EPCh. 5 - Prob. 5.40EPCh. 5 - Determine the maximum number of hydrogen bonds...Ch. 5 - Prob. 5.42EPCh. 5 - Prob. 5.43EPCh. 5 - Prob. 5.44EPCh. 5 - Prob. 5.45EPCh. 5 - Prob. 5.46EPCh. 5 - Prob. 5.47EPCh. 5 - Prob. 5.48EPCh. 5 - Prob. 5.49EPCh. 5 - Prob. 5.50EPCh. 5 - Prob. 5.51EPCh. 5 - Prob. 5.52EPCh. 5 - Prob. 5.53EPCh. 5 - Prob. 5.54EPCh. 5 - Draw structural formulas for the following...Ch. 5 - Prob. 5.56EPCh. 5 - Give the IUPAC name for each of the following...Ch. 5 - Give the IUPAC name for each of the following...Ch. 5 - Prob. 5.59EPCh. 5 - Prob. 5.60EPCh. 5 - Prob. 5.61EPCh. 5 - Prob. 5.62EPCh. 5 - Prob. 5.63EPCh. 5 - Prob. 5.64EPCh. 5 - Prob. 5.65EPCh. 5 - Which three carboxylic acids have salts that are...Ch. 5 - Prob. 5.67EPCh. 5 - Which carboxylic acid has salts that are used to...Ch. 5 - Prob. 5.69EPCh. 5 - Prob. 5.70EPCh. 5 - Prob. 5.71EPCh. 5 - Prob. 5.72EPCh. 5 - Prob. 5.73EPCh. 5 - Prob. 5.74EPCh. 5 - Prob. 5.75EPCh. 5 - Prob. 5.76EPCh. 5 - Prob. 5.77EPCh. 5 - Prob. 5.78EPCh. 5 - Prob. 5.79EPCh. 5 - Prob. 5.80EPCh. 5 - Prob. 5.81EPCh. 5 - Prob. 5.82EPCh. 5 - Prob. 5.83EPCh. 5 - Prob. 5.84EPCh. 5 - Prob. 5.85EPCh. 5 - Prob. 5.86EPCh. 5 - Prob. 5.87EPCh. 5 - Prob. 5.88EPCh. 5 - Prob. 5.89EPCh. 5 - Prob. 5.90EPCh. 5 - Assign common names to each of the esters in...Ch. 5 - Prob. 5.92EPCh. 5 - Prob. 5.93EPCh. 5 - Assign an IUPAC name to each of the following...Ch. 5 - Draw a structural formula for each of the...Ch. 5 - Prob. 5.96EPCh. 5 - Prob. 5.97EPCh. 5 - Prob. 5.98EPCh. 5 - Prob. 5.99EPCh. 5 - Prob. 5.100EPCh. 5 - Prob. 5.101EPCh. 5 - How many carbon atoms are present in a molecule of...Ch. 5 - Prob. 5.103EPCh. 5 - Prob. 5.104EPCh. 5 - Prob. 5.105EPCh. 5 - Prob. 5.106EPCh. 5 - Prob. 5.107EPCh. 5 - Prob. 5.108EPCh. 5 - Prob. 5.109EPCh. 5 - Prob. 5.110EPCh. 5 - Prob. 5.111EPCh. 5 - Prob. 5.112EPCh. 5 - Prob. 5.113EPCh. 5 - Prob. 5.114EPCh. 5 - Prob. 5.115EPCh. 5 - Prob. 5.116EPCh. 5 - Prob. 5.117EPCh. 5 - Prob. 5.118EPCh. 5 - Prob. 5.119EPCh. 5 - Prob. 5.120EPCh. 5 - Prob. 5.121EPCh. 5 - Prob. 5.122EPCh. 5 - Prob. 5.123EPCh. 5 - Prob. 5.124EPCh. 5 - Write the structural formulas of the reaction...Ch. 5 - Prob. 5.126EPCh. 5 - Prob. 5.127EPCh. 5 - Prob. 5.128EPCh. 5 - Prob. 5.129EPCh. 5 - Prob. 5.130EPCh. 5 - Prob. 5.131EPCh. 5 - Prob. 5.132EPCh. 5 - Prob. 5.133EPCh. 5 - Prob. 5.134EPCh. 5 - Prob. 5.135EPCh. 5 - Prob. 5.136EPCh. 5 - Prob. 5.137EPCh. 5 - Prob. 5.138EPCh. 5 - Prob. 5.139EPCh. 5 - Prob. 5.140EPCh. 5 - Prob. 5.141EPCh. 5 - Prob. 5.142EPCh. 5 - Prob. 5.143EPCh. 5 - Prob. 5.144EPCh. 5 - Prob. 5.145EPCh. 5 - Prob. 5.146EPCh. 5 - Prob. 5.147EPCh. 5 - Prob. 5.148EPCh. 5 - Draw a condensed structural formula for the...Ch. 5 - Draw a condensed structural formula for the...Ch. 5 - Prob. 5.151EPCh. 5 - Prob. 5.152EPCh. 5 - Prob. 5.153EPCh. 5 - Prob. 5.154EPCh. 5 - Prob. 5.155EPCh. 5 - Prob. 5.156EPCh. 5 - Prob. 5.157EPCh. 5 - Prob. 5.158EPCh. 5 - Prob. 5.159EPCh. 5 - Prob. 5.160EPCh. 5 - Prob. 5.161EPCh. 5 - Prob. 5.162EPCh. 5 - Prob. 5.163EPCh. 5 - Prob. 5.164EP
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