Structural formula for methyl thiopropanoate has to be drawn. Concept Introduction: General structure of thioester can be represented as shown below, From an IUPAC name, the structure of the thioester can be derived. IUPAC name of thioester consists of two parts. In an IUPAC name of thioester, the first part of the name is the alkyl part and the second part is the acid part. Alkyl group have come from the thiol and acyl part from carboxylic acid . The same rule applies for deriving a structure from common name. The only difference is the acyl part name. The acyl part is named using the common name of thiocarboxylic acid.

Question

What units (if any) does the response factor (K) have? Does the response factor (K) depend upon how the concentration is expressed (e.g. molarity, ppm, ppb, etc.)?

Answer 1

Question

Definition Definition Class of organic compounds that contain a carboxyl group ( - COOH ) and has a general formula R - COOH or R - CO 2 H , where R refers to the alkyl, alkenyl, aryl, or other groups. They can undergo different chemical reactions, such as acid-base reactions, esterification, and oxidation. These are essential components of living organisms, playing important roles in metabolic processes, signaling, and as pharmaceuticals.

Chapter 5, Problem 5.138EP

(a)

Interpretation Introduction

Interpretation:

Structural formula for methyl thiopropanoate has to be drawn.

Concept Introduction:

General structure of thioester can be represented as shown below,

From an IUPAC name, the structure of the thioester can be derived. IUPAC name of thioester consists of two parts. In an IUPAC name of thioester, the first part of the name is the alkyl part and the second part is the acid part. Alkyl group have come from the thiol and acyl part from carboxylic acid.

The same rule applies for deriving a structure from common name. The only difference is the acyl part name. The acyl part is named using the common name of thiocarboxylic acid.

(b)

Interpretation Introduction

Interpretation:

Structural formula for methyl thiopropionate has to be drawn.

Concept Introduction:

General structure of thioester can be represented as shown below,

From an IUPAC name, the structure of the thioester can be derived. IUPAC name of thioester consists of two parts. In an IUPAC name of thioester, the first part of the name is the alkyl part and the second part is the acid part. Alkyl group have come from the thiol and acyl part from carboxylic acid.

The same rule applies for deriving a structure from common name. The only difference is the acyl part name. The acyl part is named using the common name of thiocarboxylic acid.

(c)

Interpretation Introduction

Interpretation:

Structural formula for ethyl thioacetate has to be drawn.

Concept Introduction:

General structure of thioester can be represented as shown below,

From an IUPAC name, the structure of the thioester can be derived. IUPAC name of thioester consists of two parts. In an IUPAC name of thioester, the first part of the name is the alkyl part and the second part is the acid part. Alkyl group have come from the thiol and acyl part from carboxylic acid.

The same rule applies for deriving a structure from common name. The only difference is the acyl part name. The acyl part is named using the common name of thiocarboxylic acid.

(d)

Interpretation Introduction

Interpretation:

Structural formula for ethyl thioethanoate has to be drawn.

Concept Introduction:

General structure of thioester can be represented as shown below,

From an IUPAC name, the structure of the thioester can be derived. IUPAC name of thioester consists of two parts. In an IUPAC name of thioester, the first part of the name is the alkyl part and the second part is the acid part. Alkyl group have come from the thiol and acyl part from carboxylic acid.

The same rule applies for deriving a structure from common name. The only difference is the acyl part name. The acyl part is named using the common name of thiocarboxylic acid.

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Answer 2

Question

Definition Definition Class of organic compounds that contain a carboxyl group ( - COOH ) and has a general formula R - COOH or R - CO 2 H , where R refers to the alkyl, alkenyl, aryl, or other groups. They can undergo different chemical reactions, such as acid-base reactions, esterification, and oxidation. These are essential components of living organisms, playing important roles in metabolic processes, signaling, and as pharmaceuticals.

Chapter 5, Problem 5.138EP

(a)

Interpretation Introduction

Interpretation:

Structural formula for methyl thiopropanoate has to be drawn.

Concept Introduction:

General structure of thioester can be represented as shown below,

From an IUPAC name, the structure of the thioester can be derived. IUPAC name of thioester consists of two parts. In an IUPAC name of thioester, the first part of the name is the alkyl part and the second part is the acid part. Alkyl group have come from the thiol and acyl part from carboxylic acid.

The same rule applies for deriving a structure from common name. The only difference is the acyl part name. The acyl part is named using the common name of thiocarboxylic acid.

(b)

Interpretation Introduction

Interpretation:

Structural formula for methyl thiopropionate has to be drawn.

Concept Introduction:

General structure of thioester can be represented as shown below,

From an IUPAC name, the structure of the thioester can be derived. IUPAC name of thioester consists of two parts. In an IUPAC name of thioester, the first part of the name is the alkyl part and the second part is the acid part. Alkyl group have come from the thiol and acyl part from carboxylic acid.

The same rule applies for deriving a structure from common name. The only difference is the acyl part name. The acyl part is named using the common name of thiocarboxylic acid.

(c)

Interpretation Introduction

Interpretation:

Structural formula for ethyl thioacetate has to be drawn.

Concept Introduction:

General structure of thioester can be represented as shown below,

From an IUPAC name, the structure of the thioester can be derived. IUPAC name of thioester consists of two parts. In an IUPAC name of thioester, the first part of the name is the alkyl part and the second part is the acid part. Alkyl group have come from the thiol and acyl part from carboxylic acid.

The same rule applies for deriving a structure from common name. The only difference is the acyl part name. The acyl part is named using the common name of thiocarboxylic acid.

(d)

Interpretation Introduction

Interpretation:

Structural formula for ethyl thioethanoate has to be drawn.

Concept Introduction:

General structure of thioester can be represented as shown below,

From an IUPAC name, the structure of the thioester can be derived. IUPAC name of thioester consists of two parts. In an IUPAC name of thioester, the first part of the name is the alkyl part and the second part is the acid part. Alkyl group have come from the thiol and acyl part from carboxylic acid.

The same rule applies for deriving a structure from common name. The only difference is the acyl part name. The acyl part is named using the common name of thiocarboxylic acid.

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Answer 3

Question

Definition Definition Class of organic compounds that contain a carboxyl group ( - COOH ) and has a general formula R - COOH or R - CO 2 H , where R refers to the alkyl, alkenyl, aryl, or other groups. They can undergo different chemical reactions, such as acid-base reactions, esterification, and oxidation. These are essential components of living organisms, playing important roles in metabolic processes, signaling, and as pharmaceuticals.

Chapter 5, Problem 5.138EP

(a)

Interpretation Introduction

Interpretation:

Structural formula for methyl thiopropanoate has to be drawn.

Concept Introduction:

General structure of thioester can be represented as shown below,

From an IUPAC name, the structure of the thioester can be derived. IUPAC name of thioester consists of two parts. In an IUPAC name of thioester, the first part of the name is the alkyl part and the second part is the acid part. Alkyl group have come from the thiol and acyl part from carboxylic acid.

The same rule applies for deriving a structure from common name. The only difference is the acyl part name. The acyl part is named using the common name of thiocarboxylic acid.

(b)

Interpretation Introduction

Interpretation:

Structural formula for methyl thiopropionate has to be drawn.

Concept Introduction:

General structure of thioester can be represented as shown below,

From an IUPAC name, the structure of the thioester can be derived. IUPAC name of thioester consists of two parts. In an IUPAC name of thioester, the first part of the name is the alkyl part and the second part is the acid part. Alkyl group have come from the thiol and acyl part from carboxylic acid.

The same rule applies for deriving a structure from common name. The only difference is the acyl part name. The acyl part is named using the common name of thiocarboxylic acid.

(c)

Interpretation Introduction

Interpretation:

Structural formula for ethyl thioacetate has to be drawn.

Concept Introduction:

General structure of thioester can be represented as shown below,

From an IUPAC name, the structure of the thioester can be derived. IUPAC name of thioester consists of two parts. In an IUPAC name of thioester, the first part of the name is the alkyl part and the second part is the acid part. Alkyl group have come from the thiol and acyl part from carboxylic acid.

The same rule applies for deriving a structure from common name. The only difference is the acyl part name. The acyl part is named using the common name of thiocarboxylic acid.

(d)

Interpretation Introduction

Interpretation:

Structural formula for ethyl thioethanoate has to be drawn.

Concept Introduction:

General structure of thioester can be represented as shown below,

From an IUPAC name, the structure of the thioester can be derived. IUPAC name of thioester consists of two parts. In an IUPAC name of thioester, the first part of the name is the alkyl part and the second part is the acid part. Alkyl group have come from the thiol and acyl part from carboxylic acid.

The same rule applies for deriving a structure from common name. The only difference is the acyl part name. The acyl part is named using the common name of thiocarboxylic acid.

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Answer 4

Question

Definition Definition Class of organic compounds that contain a carboxyl group ( - COOH ) and has a general formula R - COOH or R - CO 2 H , where R refers to the alkyl, alkenyl, aryl, or other groups. They can undergo different chemical reactions, such as acid-base reactions, esterification, and oxidation. These are essential components of living organisms, playing important roles in metabolic processes, signaling, and as pharmaceuticals.

Chapter 5, Problem 5.138EP

(a)

Interpretation Introduction

Interpretation:

Structural formula for methyl thiopropanoate has to be drawn.

Concept Introduction:

General structure of thioester can be represented as shown below,

From an IUPAC name, the structure of the thioester can be derived. IUPAC name of thioester consists of two parts. In an IUPAC name of thioester, the first part of the name is the alkyl part and the second part is the acid part. Alkyl group have come from the thiol and acyl part from carboxylic acid.

The same rule applies for deriving a structure from common name. The only difference is the acyl part name. The acyl part is named using the common name of thiocarboxylic acid.

(b)

Interpretation Introduction

Interpretation:

Structural formula for methyl thiopropionate has to be drawn.

Concept Introduction:

General structure of thioester can be represented as shown below,

From an IUPAC name, the structure of the thioester can be derived. IUPAC name of thioester consists of two parts. In an IUPAC name of thioester, the first part of the name is the alkyl part and the second part is the acid part. Alkyl group have come from the thiol and acyl part from carboxylic acid.

The same rule applies for deriving a structure from common name. The only difference is the acyl part name. The acyl part is named using the common name of thiocarboxylic acid.

(c)

Interpretation Introduction

Interpretation:

Structural formula for ethyl thioacetate has to be drawn.

Concept Introduction:

General structure of thioester can be represented as shown below,

From an IUPAC name, the structure of the thioester can be derived. IUPAC name of thioester consists of two parts. In an IUPAC name of thioester, the first part of the name is the alkyl part and the second part is the acid part. Alkyl group have come from the thiol and acyl part from carboxylic acid.

The same rule applies for deriving a structure from common name. The only difference is the acyl part name. The acyl part is named using the common name of thiocarboxylic acid.

(d)

Interpretation Introduction

Interpretation:

Structural formula for ethyl thioethanoate has to be drawn.

Concept Introduction:

General structure of thioester can be represented as shown below,

From an IUPAC name, the structure of the thioester can be derived. IUPAC name of thioester consists of two parts. In an IUPAC name of thioester, the first part of the name is the alkyl part and the second part is the acid part. Alkyl group have come from the thiol and acyl part from carboxylic acid.

The same rule applies for deriving a structure from common name. The only difference is the acyl part name. The acyl part is named using the common name of thiocarboxylic acid.

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Answer 5

Chapter 5, Problem 5.138EP

(a)

Interpretation Introduction

Interpretation:

Structural formula for methyl thiopropanoate has to be drawn.

Concept Introduction:

General structure of thioester can be represented as shown below,

From an IUPAC name, the structure of the thioester can be derived. IUPAC name of thioester consists of two parts. In an IUPAC name of thioester, the first part of the name is the alkyl part and the second part is the acid part. Alkyl group have come from the thiol and acyl part from carboxylic acid.

The same rule applies for deriving a structure from common name. The only difference is the acyl part name. The acyl part is named using the common name of thiocarboxylic acid.

(b)

Interpretation Introduction

Interpretation:

Structural formula for methyl thiopropionate has to be drawn.

Concept Introduction:

General structure of thioester can be represented as shown below,

From an IUPAC name, the structure of the thioester can be derived. IUPAC name of thioester consists of two parts. In an IUPAC name of thioester, the first part of the name is the alkyl part and the second part is the acid part. Alkyl group have come from the thiol and acyl part from carboxylic acid.

The same rule applies for deriving a structure from common name. The only difference is the acyl part name. The acyl part is named using the common name of thiocarboxylic acid.

(c)

Interpretation Introduction

Interpretation:

Structural formula for ethyl thioacetate has to be drawn.

Concept Introduction:

General structure of thioester can be represented as shown below,

From an IUPAC name, the structure of the thioester can be derived. IUPAC name of thioester consists of two parts. In an IUPAC name of thioester, the first part of the name is the alkyl part and the second part is the acid part. Alkyl group have come from the thiol and acyl part from carboxylic acid.

The same rule applies for deriving a structure from common name. The only difference is the acyl part name. The acyl part is named using the common name of thiocarboxylic acid.

(d)

Interpretation Introduction

Interpretation:

Structural formula for ethyl thioethanoate has to be drawn.

Concept Introduction:

General structure of thioester can be represented as shown below,

From an IUPAC name, the structure of the thioester can be derived. IUPAC name of thioester consists of two parts. In an IUPAC name of thioester, the first part of the name is the alkyl part and the second part is the acid part. Alkyl group have come from the thiol and acyl part from carboxylic acid.

The same rule applies for deriving a structure from common name. The only difference is the acyl part name. The acyl part is named using the common name of thiocarboxylic acid.

Answer 6

Chapter 5, Problem 5.138EP

(a)

Interpretation Introduction

Interpretation:

Structural formula for methyl thiopropanoate has to be drawn.

Concept Introduction:

General structure of thioester can be represented as shown below,

From an IUPAC name, the structure of the thioester can be derived. IUPAC name of thioester consists of two parts. In an IUPAC name of thioester, the first part of the name is the alkyl part and the second part is the acid part. Alkyl group have come from the thiol and acyl part from carboxylic acid.

The same rule applies for deriving a structure from common name. The only difference is the acyl part name. The acyl part is named using the common name of thiocarboxylic acid.

Answer 7

Chapter 5, Problem 5.138EP

(a)

Interpretation Introduction

Interpretation:

Structural formula for methyl thiopropanoate has to be drawn.

Concept Introduction:

General structure of thioester can be represented as shown below,

From an IUPAC name, the structure of the thioester can be derived. IUPAC name of thioester consists of two parts. In an IUPAC name of thioester, the first part of the name is the alkyl part and the second part is the acid part. Alkyl group have come from the thiol and acyl part from carboxylic acid.

The same rule applies for deriving a structure from common name. The only difference is the acyl part name. The acyl part is named using the common name of thiocarboxylic acid.

Answer 8

(b)

Interpretation Introduction

Interpretation:

Structural formula for methyl thiopropionate has to be drawn.

Concept Introduction:

General structure of thioester can be represented as shown below,

From an IUPAC name, the structure of the thioester can be derived. IUPAC name of thioester consists of two parts. In an IUPAC name of thioester, the first part of the name is the alkyl part and the second part is the acid part. Alkyl group have come from the thiol and acyl part from carboxylic acid.

The same rule applies for deriving a structure from common name. The only difference is the acyl part name. The acyl part is named using the common name of thiocarboxylic acid.

Answer 9

(b)

Interpretation Introduction

Interpretation:

Structural formula for methyl thiopropionate has to be drawn.

Concept Introduction:

General structure of thioester can be represented as shown below,

From an IUPAC name, the structure of the thioester can be derived. IUPAC name of thioester consists of two parts. In an IUPAC name of thioester, the first part of the name is the alkyl part and the second part is the acid part. Alkyl group have come from the thiol and acyl part from carboxylic acid.

The same rule applies for deriving a structure from common name. The only difference is the acyl part name. The acyl part is named using the common name of thiocarboxylic acid.

Answer 10

(c)

Interpretation Introduction

Interpretation:

Structural formula for ethyl thioacetate has to be drawn.

Concept Introduction:

General structure of thioester can be represented as shown below,

From an IUPAC name, the structure of the thioester can be derived. IUPAC name of thioester consists of two parts. In an IUPAC name of thioester, the first part of the name is the alkyl part and the second part is the acid part. Alkyl group have come from the thiol and acyl part from carboxylic acid.

The same rule applies for deriving a structure from common name. The only difference is the acyl part name. The acyl part is named using the common name of thiocarboxylic acid.

Answer 11

(c)

Interpretation Introduction

Interpretation:

Structural formula for ethyl thioacetate has to be drawn.

Concept Introduction:

General structure of thioester can be represented as shown below,

From an IUPAC name, the structure of the thioester can be derived. IUPAC name of thioester consists of two parts. In an IUPAC name of thioester, the first part of the name is the alkyl part and the second part is the acid part. Alkyl group have come from the thiol and acyl part from carboxylic acid.

The same rule applies for deriving a structure from common name. The only difference is the acyl part name. The acyl part is named using the common name of thiocarboxylic acid.

Answer 12

(d)

Interpretation Introduction

Interpretation:

Structural formula for ethyl thioethanoate has to be drawn.

Concept Introduction:

General structure of thioester can be represented as shown below,

From an IUPAC name, the structure of the thioester can be derived. IUPAC name of thioester consists of two parts. In an IUPAC name of thioester, the first part of the name is the alkyl part and the second part is the acid part. Alkyl group have come from the thiol and acyl part from carboxylic acid.

The same rule applies for deriving a structure from common name. The only difference is the acyl part name. The acyl part is named using the common name of thiocarboxylic acid.

Answer 13

(d)

Interpretation Introduction

Interpretation:

Structural formula for ethyl thioethanoate has to be drawn.

Concept Introduction:

General structure of thioester can be represented as shown below,

From an IUPAC name, the structure of the thioester can be derived. IUPAC name of thioester consists of two parts. In an IUPAC name of thioester, the first part of the name is the alkyl part and the second part is the acid part. Alkyl group have come from the thiol and acyl part from carboxylic acid.

The same rule applies for deriving a structure from common name. The only difference is the acyl part name. The acyl part is named using the common name of thiocarboxylic acid.

Answer 14

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Answer 25

Ch. 5.1 - Prob. 1QQ Ch. 5.1 - Prob. 2QQ Ch. 5.1 - Prob. 3QQ Ch. 5.1 - Prob. 4QQ Ch. 5.1 - Prob. 5QQ Ch. 5.2 - Prob. 1QQ Ch. 5.2 - Prob. 2QQ Ch. 5.2 - Prob. 3QQ Ch. 5.2 - Prob. 4QQ Ch. 5.2 - Prob. 5QQ

Solution Summary: The author explains that the structure of methyl thiopropanoate can be drawn from an IUPAC name.

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