Concept explainers
Interpretation: Extra stabilization that carbocation experience inside box should be explained.
Concept introduction: Organic compounds are covalent in nature that undergoes a reaction by heterolytic cleavage or homolytic cleavage.
In heterolytic cleavage, shared pair of electrons is taken away by one of the atoms which result in charged species. In homolytic cleavage, shared pair of electrons are equally distributed between two atom that results in free radicals.
Carbocation is a general term employed for a postively charged carbon irrespective of valency of carbon. In carbocation, carbon is bonded to 3 atoms or groups and has only sextet of electrons so it behaves as an electron-deficient species. It is
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Organic Chemistry: A Guided Inquiry
- Are endothermic reactions favorable or unfavorable? ... uphillor downhill?arrow_forwardDraw the major organic product(s) of the following reactions including stereochemistry when it is appropriate. H3C HC-CEC-CH2CH3 H3C H₂O/H2SO4/Hg+2 • Use the wedge/hash bond tools to indicate stereochemistry where it exists. • If no reaction occurs, draw the organic starting material. Separate multiple products using the + sign from the drop-down menu. +arrow_forwardSee image belowarrow_forward
- 4. Show the step-by-step process. Do not use shortcut methods. Make it as detailed as it can be. Encode (not hand-written)!arrow_forwardDraw a resonance structure, complete with all formal charges and lone (unshared) electron pairs, that shows the resonance interaction of the acetoxy with the para position in phenyl acetate. phenyl acetate ● CH3 • You do not have to consider stereochemistry. • Include all valence lone pairs in your answer. In cases where there is more than one answer, just draw one. Sn [F ?arrow_forwardBr SO H Br₂/FeBr3 H₂SO4(SO3) NO₂ II Br NO₂ HNO3 /H₂SO4 III H₂O(xs)/ H* remove any ortho product that forms at this point. Br Heat NO₂ IV Br NO₂ ?arrow_forward
- 2. A benzene ring alters the reactivity of a neighboring group in the so-called "benzylic" position, similarly to how a double bond alters the reactivity of groups in the "allylic" position. R .R allylic position benzylic position Benzylic cations, anions, and radicals are all more stable than simple alkyl intermediates. a) Use resonance structures to show the delocalization of the positive charge, negative charge, and unpaired electron of the benzyl cation, anion, and radical.arrow_forwardbn 6. a.) Classify the following carbocations (1°, 2°, or 3°). b.) Encircle the carbocation/s that can rearrange to a more stable structure. smib-t.-S) CH3 CH3 CH3 CH2 CH2 CHz-C+ CH3arrow_forward15.arrow_forward
- Put them in right categoryarrow_forwardThe following alkyl halide can be prepared by HBr addition to two different alkenes that are constitutional isomers. Draw the structures of both. Br ball & stick v + labels • You do not have to consider stereochemistry. • Draw one structure per sketcher. Add additional sketchers using the drop-down menu in the bottom right corner. • Separate structures with + signs from the drop-down menu.arrow_forwardQUESTION 2 Which of the following is the most effective way to stabilize carbocations? O a. Zaitzev's rule O b. Inductive effect C. Hyperconjugation O d. Resonance/conjugationarrow_forward
- Organic Chemistry: A Guided InquiryChemistryISBN:9780618974122Author:Andrei StraumanisPublisher:Cengage Learning